• Title/Summary/Keyword: Water soluble ion

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Soluble Single-Molecule Magnet: Mn12-stearate.

  • Park, Chi Dong;Jeong, Duk Yeong
    • Bulletin of the Korean Chemical Society
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    • v.22 no.6
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    • pp.611-615
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    • 2001
  • A new polynuclear complex of manganese stearate has been prepared by substitution of acetate with stearic acid. The stearate ion with long alkyl chain was used to isolate molecular $Mn_{12}$ cluster from each other. The $Mn_{12}$-stearate compound prepared is soluble in most organic solvents and resistant against water catalyzed reduction. The $Mn_{12}$-stearate compound shows similar electrochemical, magnetic properties to the pristine $Mn_{12}$-acetate.

A Study on Examination of Application in Waste Filled Land and Performance Evaluation as Waterproofing Material by the Spray Water-Soluble Rubber Asphalt (뿜칠형 수용성 고무화 아스팔트 차수재의 성능평가 및 폐기물 매립지 적용성 검토에 관한 연구)

  • 이성일;정문정;김형무;오상근
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2001.11a
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    • pp.163-168
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    • 2001
  • This study examinated the application in construction field and the development of waterproofing material system by the spray water-soluble rubber asphalt to solve the problems of synthetic polymer sheet and gio membrane(A mat sheet of Bentonite) that had been used domestic waterproofing material in advance. As the result of study, characters of study water-souble rubber asphalt are the follows; 1) The amount of water absorption was '0.06'g and the seepage quantity was '0'g in result. 2) The tensile strength was about 30.7kgf/$cm^2$ and the elongation was about 72.4% in result. 3) After reliance of temperature test had been ended, the tensile strength was about 72.4kg/$cm^2$ in low temperature and about 30.7kgf/$cm^2$ in normal temperature. 4) After acid and alkaline treatment had been ended, the tensile strength was about 19.7kgf/$cm^2$ and about 21.9kgf/$cm^2$ in result. 5) After chlorine ion treatment had been ended, the tensile strength was 28.5kgf/$cm^2$ and the elongation was 250% in result. So, this study can propose the spray water-soluble rubber asphalt to satisfy the security and durability of waste filled land.

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A Study on Examination of Application in Waste Filled Land and Performance Evaluation as Waterproofing Material by the Spray Water-Soluble Rubber Asphalt (뿜칠형 수용성 고무화 아스팔트 차수재의 성능평가 및 폐기물 매립지 적용성 검토에 관한 연구)

  • 오상근;김형무;정문정;최은수
    • Journal of the Korea Institute of Building Construction
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    • v.1 no.2
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    • pp.165-173
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    • 2001
  • This study examinated the application in construction field and the development of waterproofing material system by the spray water-soluble rubber asphalt to solve the problems of synthetic polymer sheet and gio membrane(A mat sheet of Bentonite) that had been used domestic waterproofing material in advance. As the result of study, characters of study water-soluble rudder asphalt are the follows: 1) The amount of water absorption was '0.06'g and the seepage quality was '0'g in result. 2) The tensile strength was about 30.7kgf/$\textrm{cm}^2 and the elongation was about 72.4% in result. 3) After reliance of temperature test had been ended, the tensile strength was about 72.4kgf/$\textrm{cm}^2 in low temperature and about 30.7kgf/$\textrm{cm}^2 in normal temperature. 4) After acid and alkaline treatment had been ended, the tensile strength was about 19.7kgf/$\textrm{cm}^2$ and about 21.9kgf/$\textrm{cm}^2 in result. 5) After chlorine ion treatment had been ended, the tensile strength was 28.5kgf/$\textrm{cm}^2$ and the elongation was 250% in result. 6) The impact performance was subsided at 1.5m height. 7) After promotion weathering had been ended, the tensile and elongation was about 26.0kgf/$\textrm{cm}^2, 214% in result. So, this study can propose the spray water-soluble rubber asphalt to satisfy the and durability of waste filled land.

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A Study on the Assessment of Pollution Level of Precipitation at Kangwha, 1992 (江華地域 降水의 汚染度 評價에 關한 硏究)

  • 강공언;강병욱;김희강
    • Journal of Korean Society for Atmospheric Environment
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    • v.11 no.1
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    • pp.57-68
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    • 1995
  • Precipitation samples were collected by a wet-only automatic acid precipitation sampler at Kangwha island on the western coast in Korea, through January until December 1992. pH, electric conductivity and the concentrations of major water-soluble ion components such as N $H_{4}$$^{+}$, $Ca^{2+}$, $K^{+}$, $Mg^{2+}$, N $a^{+}$, N $O_{3}$$^{[-10]}$ , S $O_{4}$$^{2-}$ and C $l^{[-10]}$ were measured. From the result of checking the validity for assesment of pollution level of precipitation samples by pH using correlation analysis between pH and major components, and t-test of chemical composition between acid rain and non-acid rain, pH proved to be not satisfactory for its pillution level. A more comprehensive method is therefore required. In order to estimate the monthly analytical result of chemical composition of precipitation samples comprehensively, a cluster analysis was used among the various multivariate statistical analysis. As a result of making a cluster analysis for separating the monthly precipitation samples into homogeneous patterns by setting the concentrations of nine major water-soluble ion components as a variable, three homogeneous patterns were obtained. The first pattern was a group of months having average ion concentrations, the second a guoup of months having low ion concentration, and the third a group of months having high ion concentrations. Thus, it was indicated that the pollution level of precipitation was higher on February and lower on May, June, August and September than the other months. As a result, this analysis method could be estimated the chemical coposition of precipitation regionally as well as monthly.monthly.

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Purification and Characterization of the Regulatory Substance of Furfural Biodegradation in Pseudomonas fluorescens (Pseudomonas fluorescens에 의한 Furfural의 분해대사 조절물질에 관하여)

  • 이병웅;유병설;이계준;하영칠
    • Korean Journal of Microbiology
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    • v.23 no.4
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    • pp.241-247
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    • 1985
  • The objectives of this study were to isolate and identify ninhydrin positive substande(s) produced in the culture broth of Pseudomonas fluorescens. It was found that the NPS could stimulate bioconversion of furfural into furoic acid. In order to isolate the NPS from the culture broth, cell free filtrate was subjected to ion-exchange chromatography, gel-permeation and finally to cellulose column chromatography. The purified NPS was white amorphous power and very soluble in water, slightly soluble in methanol and very insoluble in organic solvents. UV, and IR absorption spectra. $^H$ and $^{13}C-NMR$ were measured in order to identify the chemical structure of the NPS.

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Characteristics of Water-soluble Polysaccharide, Showing Inhibiting Activity on ${\alpha}-Glucosidase$, in Cordyceps militaris

  • Chung, Ha-Yull;Yoo, Mi-Kyong;Kawagishi, Hirokazu
    • Food Science and Biotechnology
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    • v.18 no.3
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    • pp.667-671
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    • 2009
  • Extract of water-soluble polysaccharide (CFWx), showing inhibiting activity on ${\alpha}-glucosidase$, was prepared from the fruiting bodies of Cordyceps militaris by hot-water extraction, and ethanol precipitation. Chemical characteristics of CFWx were as follows: carbohydrate content 30% including 16% of uronic acid; 51% protein content; monosaccharide composition, Man:Glu:Gal (30:43:27); molecular weight $3-5{\times}10^4$. CFWx was further purified by ion-exchange, gel-permeation, and affinity chromatography and $CFWx-AH-{\alpha}$ fraction was isolated. Fundamental structure of $CFWx-AH-{\alpha}$ was deduced as ${\alpha}-(1{\to}4$)-D-glucan with ${\alpha}-(1{\to}3$)- and/or ${\alpha}-(1{\to}6$)-D-glycosidic side chains based on methylation analysis.

Development of Chloride-ion Penetration Device for Concrete Considering Pressure Condition (압력조건을 고려한 콘크리트의 염화물이온 침투 장치 개발)

  • Kim, Gyeong-Tae;Kim, Gyu-Yong;Lee, Sang-Kyu;Hwang, Eui-Chul;Son, Min Jae;Nam, Jeong-Soo
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2018.05a
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    • pp.25-26
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    • 2018
  • In this study, the device was developed for evaluating the effect of pressure on chloride ion penetration of concrete. And chloride-ion penetration depth and water soluble chloride contents was evaluated concrete using ordinary portland cement and blast-furnace slag cement using developed device. As a result, chloride ion penetration of concrete was promoted according to the action of pressure and the exposure period. and the incorporation of blast-furnace slag was effective for chloride attack resistibility under pressure.

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Seasonal Size Distribution of Atmospheric Particles in Iksan, Korea

  • Kang, Gong-Unn;Kim, Nam-Song;Rhim, Kook-Hwan
    • Journal of Environmental Health Sciences
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    • v.32 no.6
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    • pp.543-555
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    • 2006
  • During a twenty-day period in 2005, a nine-stage Andersen cascade impactor was used to determine the seasonal size distribution of atmospheric particles and its inorganic ion species sampled for 24hr in Iksan city, located southwest of the Korean peninsula. Samples were analyzed for major water-soluble ion species using Dionex-100 ion chromatograph. Average fine and coarse mass concentrations of atmospheric particles were, respectively, 31.4 and $82.6{\mu}g\;m^{-3}$ in spring and 35.8 and $73.4{\mu}g\;m^{-3}$ in fall-winter during the sampling period of 2005, while measurements of 69.8 and 9.9 were obtained in the sampling period of summer, The size distribution of particulate mass concentration during the non-Asian dust period was generally bimodal, whereas the size distribution of particulate mass concentration during the Asian dust period was unimodal due to the significant increase of coarse particles, which originated from long-range transport of soil dust particles from loess regions of the Asian continent. Among ionic species, $SO{_4}^{2-},\;NH{_4}^+,\;K^+$ were mainly distributed in fine particles due to their characteristics of emission sources and gas-to-particle conversion, while $Na^+,\;Mg^{2+}\;and\;Ca^{2+}$ were dominantly in coarse particles. However, $NO_3{^-}\;and\;Cl^-$ were distributed in both coarse particles and fine particles. Although $SO{_4}^{2-}$ was mainly distributed in fine particles, the size distributions of $SO{_4}^{2-}$ in coarse mode were significantly increased during the Asian dust events compared to those during the non-Asian dust period. $Ca^{2+}$ showed the most abundant species in the atmospheric particles during the Asian dust period. $NH{_4}^+$ was found to mainly exist as $(NH_4)_2SO_4$ in fine particles.

Effect of Stem Bark Extract from Cudrania tricuspidata on the Concentrations of Lipid and Lipid Peroxidation in Rats Fed a Cholesterol Diet. (꾸지뽕나무 수피 추출물의 콜레스테롤 급여 흰쥐의 지질 농도 및 과산화지질 농도에 미치는 영향)

  • 차재영;김대진;조영수
    • Journal of Life Science
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    • v.11 no.4
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    • pp.328-334
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    • 2001
  • Male Sprageu-Dawely rats fed a cholesterol diet (Control group) or cholesterol diet supplemented with the water-soluble extract of stem bark from Cudrania tricuspidata(CTSB group) at the level of 0.5% for 2 weeks. Concentration of triglyceride in serum of CTSB group was significantly lower than that of control group. However, the other lipids concentrations of liver and serum, body weight gain, and food intake did not show significant difference between CTSB group and control group. Antioxidative activities of water-soluble extract from stem bark of Cudrania tricuspidata on the lipid peroxidation in rat were also studied in vivo by measuring the formation of thiobarbituric acid reactive substance(TBARS). Concentration of TBATS in the liver homogenates of CTSB group was significantly higher than that in control group. Nonheme iron concentration was significantly increased in the liver of CTSB group compared to control group. suggested that enhanced nonheme irom was associated with enhanced peroxidation of liver in CTSB group. These results suggested that water soluble extract from stem bark of Cudrania tricuspidata exert the hypotriglycerolemic effect and might amplify the lipid peroxidation of tissues in cholesterol fed rats.

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The Relationship between the Estimated Water Content and Water Soluble Organic Carbon in PM10 at Seoul, Korea (서울시 PM10 내의 수용성 유기탄소와 수분함량과의 상관성 분석)

  • Lee, Seung Ha;Kim, Yong Pyo;Lee, Ji Yi;Lee, Seung Muk
    • Journal of Korean Society for Atmospheric Environment
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    • v.33 no.1
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    • pp.64-74
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    • 2017
  • In this study, we have analyzed relationship between the measured Water Soluble Organic Carbon (WSOC) concentrations and the estimated aerosol water content of $PM_{10}$ (particulate matter with an aerodynamic diameter of less than or equal to $10{\mu}m$) for the period between September 2006 and August 2007 at Seoul, Korea. Water content of $PM_{10}$ was estimated by using a gas/particle equilibrium model, Simulating composition of Atmospheric Particles at Equilibrium 2 (SCAPE2). The WSOC concentrations showed low correlation with Elemental Carbon (EC), but Water Insoluble Organic Carbon (WISOC) were highly correlated with EC. It seemed that hydrophilic groups were produced by secondary formation rather than primary formation. As with the previous studies, WSOC showed good correlation with secondary ions ($NO_3{^-}$, $SO_4{^{2-}}$, $NH_4{^+}$), especially WSOC was highly correlated with $NO_3{^-}$ that is a secondary ion formed by photochemical oxidation from more local sources than $SO_4{^{2-}}$. No apparent correlation between the measured WSOC and estimated water content was observed. However, WSOC showed good correlation with estimated water content when it was assumed that relative humidity was higher than the deliquescence relative humidity of the system. In conclusion, WSOC is correlated with water content by hygroscopic ions and it is expected that nitrate play an important role among the water content and WSOC.