• Title/Summary/Keyword: Water retention capacity

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A Study on the Elution Mechanism of Ni(II)-Isonitrosoethylacetoacetate Imine Chelates by Reversed Phase High Performance Liquid Chromatography (역상 액체 크로마토그래피에 의한 Ni(II)-Isonitrosoethylacetoacetate Imine 유도체 킬레이트의 용리 메카니즘에 관한 연구)

  • Kim In-Whan;Choi Gang-Yeol;Lee Man-Ho;Kang Chang-Hee;Lee, Won
    • Journal of the Korean Chemical Society
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    • v.36 no.5
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    • pp.697-708
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    • 1992
  • Liquid Chromatographic behavior of Ni(II) in Isonitrosoethylacetoacetate Imine(IEAA-NR), Ni(IEAA-NH)(IEAA-NR)(R = H, CH_3, C-2H_5, n-C_4H_9, C_6H_5-CH_2) chelates were investigated by reversed-phase HPLC on Micropak MCH-5 column using methanol/water as mobile phase. The optimum conditions for the separation of Ni(IEAA-NH)(IEAA-NR) chelates were examined with respect to the effect of the flow rate, sample solvent, mobile phase strength and column temperature. It was fo$und that metal chelates were properly eluted in an acceptable range of capacity factor value(0{\le}logk'{\le}1). The dependence of the logarithm of capacity factor (k') on the volume fraction of water in the binary mobile phase as well as on the liquid-liquid extraction distribution ratio (Dc) in methanol-water/n-alkane extraction system showed the good linearties, and the dependence of the logarithm of capacity factor (k') on the column temperature and on the enthalpy exhibited the good linearties, and the compensation temperature ({\beta}) from the slope was 773.47{\circ}K. It was suggested that the retention of metal chelates was largely affected by the hydrophobic effect.

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Physicochemical Properties and Distribution of Heavy Metals in Stream Sediments of the Daejeon Area (대전지역 주요하천 하상퇴적물의 물리화학적 특성 및 중금속 분포)

  • Jeong, Chan-Ho;Lee, Sang-Gu
    • Journal of the Mineralogical Society of Korea
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    • v.19 no.4 s.50
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    • pp.259-264
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    • 2006
  • This work carried out to analyze the physicochemical properties and investigate the assessment of heavy metal contamination of stream sediments of the Yudeung and the Gab streams in the Daejeon area. The pH of stream sediments of the Yudeung stream shows the range of weak acid and weak alkaline. Most of stream sediments contain about 80% sand grain and have low water and cation retention capacity. Hence the stream sediments are not suitable fur various plans to grow up. The analysis of heavy metals in the stream sediments shows that the concentration of Pb, Cr and Cd increases from upstream to down stream. It is likely that the trend has a relationship with the water. Contamination of stream water. The authors recommend that clay materials be replenished in the stream sediments to increase the self-purification capacity and to make the suitable condition for growing up of various plants, and that water quality of the stream which can Influence into the contamination of stream sediments be monitored.

Integral Antioxidative Capacity of Extracts by Pressurized Organic Solvent from Natural Plants in Jeju (제주 자생식물 고압용매 추출물의 통합적 항산화 능력)

  • Kim, Mi-Bo;Hyun, Sun-Hee;Park, Jae-Sung;Kang, Mi-Ae;Ko, Young-Hwan;Lim, Sang-Bin
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.37 no.11
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    • pp.1491-1496
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    • 2008
  • Twenty natural plants from Jeju were extracted by pressurized organic solvent (100% methanol, $40^{\circ}C$, 13.6 MPa, 10 min). Extraction yield, total phenolic content (TPC) and integral antioxidant capacity were measured, and each component was identified by GC/MS. Extraction yields were high as 21.8%, 21.5, 21.1, 20.7 and 20.1% in Rhus javanica, Euscaphis japonica, Alnus firma, Sapium japonicum and Sorbus alnifolia, respectively. The extracts containing high TPC (mg GAE/g of dry sample) were obtained from Malus sieboldii (68.3), Sapium japonicum (57.6), Pyrrosia lingua (56.6) and Euscaphis japonica (55.1). Integral antioxidant capacities of water-soluble substances were 598, 394, 293 and $270\;{\mu}mol$ ascorbic acid equivalent/g in Geranium thunbergii, Sapium japonicum, Cornus kousa and Rhus javanica, respectively. Integral antioxidant capacities of lipidsoluble substances were 611, 314, 296 and $242\;{\mu}mol$ trolox equivalent/g in Ardisia crenata, Ostrya japonica, Geranium thunbergii and Quercus acuta, respectively. Fifteen major peaks were identified by GC/MS from the extract of pressurized organic solvent from Sapium japonicum. Two polyphenols (gallic acid (retention time (RT) 19.7 min)) and quercetin (33.5 min)), ascorbic acid (RT 35.3 min), and several fatty acids (retention time 18.6, 21.0, 21.8, 21.9 and 23.6 min) were identified, and gallic acid was the major polyphenol component due to high peak area.

Soil Health Assessment of Soil Washing and Landfarming Treated Soils (토양세척 및 토양경작 정화 토양의 건강성 평가)

  • Yong min Yi;Kijune Sung
    • Journal of Environmental Impact Assessment
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    • v.32 no.2
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    • pp.112-122
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    • 2023
  • To restore the ecological function of contaminated soil and maximize the ecological services provided by the soil, besides the toxicity orrisk caused by pollutants, the functional aspects of the soil ecosystem should be considered. In this study, a method for evaluating the health of cleaned soil was presented, and the applicability of the proposed evaluation method was examined by applying it to soil treated with washing and landfarming. Productivity, habitat, water retention capacity, nutrient cycling, carbon retention capacity, and buffering capacity were used as soil health evaluation indicators. The results showed that the soil health was not completely recovered after remediation, and even in the case of the washed soil, the health was lower than before remediation. On the other hand, there was no significant change in soil quality due to oil pollution, but soil health deteriorated. Unlike the slightly improved soil quality after landfarming treatment, soil health was not completely restored. Therefore, the results of this study indicate that it is desirable to consider both soil quality and health when evaluating the remediation effect. The soil health evaluation method proposed in this study can be usefully utilized for the sustainable use of cleaned soil and to promote ecosystem services.

A study on the quick graphical method of flood routing (홍수추적 속산도식해법에 대한 소고)

  • 박정근
    • Magazine of the Korean Society of Agricultural Engineers
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    • v.18 no.1
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    • pp.4079-4086
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    • 1976
  • In many reservoir projects, economic considerations will necessitate a design utilizing surcharge. Determination of the most economical combination of surcharge and spillway capacity for a given spillway crest level will require flood routing studies and economic studies of the dam-reservoir-spillway combinations. Many methods of actual flood routing have been devised, each of them with its advantages and disadvantages. Some of these methods are listed below: (1) Arithmetical trial-and-error method. (2) Modified Puls' method (3) Cheng's graphical method (4) Horton's arithmetical method (5) Ekadahl's arithmetical method (6) Digital computer programming. For the purpose of preliminary design and cost estimating of dams and spillways, it is often required to estimate, for a given design flood and spillway crest level. the approximate values of two among the three characteristics of the spillway spillway length, maximum discharge and surcharge depth at maximum discharge, when one of these quantities is given. As is well known, the outflow hydrograph for an ungated overflow spillway assumes the form of a wave-shaped curve with a minimum point for Q=o At zero time and a maximum point for Q=Qmax at its intersection with the falling leg of the inflow hydrograph (see Fig. 4) The shaded area between the inflow and outflow hydrographs represents at the approximate scale the temporary retention Vt. In line with the remarks, draw by free hand the assumed outflow hydrograph with its maximum point for the given Qmax (see Fig. 4) and by planimetration find Vt. From the reservoir capacity curve (Fig. 3) find Vs for the given spillway crest level and make V=Vs+Vt. From the above curve find surcharge water elevation for V and surcharge depth Hmax over spillway crest. From the discharge formula compute {{{{L= { Q} over { { CH}^{3/2 } } }}}} The methed provides a means for a quick and fairly accurate estimation of spillway capacity.

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Influence of the Starting Materials and Sintering Conditions on Composition of a Macroporous Adsorbent as Permeable Reactive Barrier (초기 소재와 소성조건이 투수반응벽체인 대공극흡착제 조상에 미치는 영향)

  • Chung, Doug-Young;Lee, Bong-Han;Jung, Jae-H.
    • Korean Journal of Soil Science and Fertilizer
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    • v.42 no.4
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    • pp.239-248
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    • 2009
  • In this investigation, we observed surface morphology and porosity of a macroporous adsorbent made of Na-bentonite and Ca-bentonite as structure formation materials and grounded waste paper as macropore forming material for the development of a permeable reactive barrier to remove heavy metals in groundwater. Therefore, we selected minerals having higher cation exchange capacity among 2:1 clay minerals and other industrial minerals because sintering can significantly influence cation exchange capacity, resulting in drastic decrease in removal of heavy metals. The results showed that the increasing sintering temperature drastically decreased CEC by less than 10 % of the indigenous CEC carried by the selected minerals. One axial compressibility test results showed that the highest value was obtained from 5% newspaper waste pulp for both structure formation materials of Na-bentonite and Ca-bentonite although there were not much difference in bulk density among treatments. The pore formation influenced by sintering temperature and period contributes removal of heavy metals passing through the sintered macroporous media having different water retention capacity.

Characteristics of Soil Conditioner Pellets Fabricated by Self-propagating Combustion Methods Using Coal Refuse (석탄폐석의 자열소성을 이용한 토양개량용 펠릿의 제조와 특성)

  • Kim, Byoung-Gon;Lee, Gye-Seung;Nam, Chul-Woo;Park, Chong-Lyuck
    • Korean Journal of Soil Science and Fertilizer
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    • v.41 no.6
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    • pp.379-386
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    • 2008
  • Calcined clay granules (pellet) have been used as a soil conditioner. The space among the pellets can secure drainage of water in soil and, simultaneously, can keep water for plants in the inner pore of that. However, the usage of the pellet has been restrained because fabrication of that requires a high energy and cost for heating over the temperate of $1000^{\circ}C$. Recently, SCS(Self-propagating Combustion and Sintering) method was developed and this method use the combustion energy of the preliminary mixed combustible. The SCS method is suitable to fabrication of small porous aggregate and requires a very low cost. This research applied the SCS method to coal refuses for fabrication of soil conditioner pellets. The coal refuses were pulverized under the size of $100{\mu}m$ and the pulverized powders were pelletized to the size of 4~6mm. The pellets were heated at the temperature of $1200^{\circ}C$ in the SCS furnace that was specially prepared for this research. Characteristics of the pellets were investigated and were compared with that of ordinary calcined clay pellet of kaolin; porosity, pore size distribution, bulk density, pH and etc.. Characteristics of the moisture retention in the pellets were measured by the centrifugal method: ASTM D425-88. The pellets of the coal refuses showed the higher values of the field capacity and the plant-available water than that of kaolin pellet. These results suggest the very low cost process that can utilize the coal refuses and can fabricate the lightweight porous soil conditioner of the very high plant-available water.

The Comparative Effect of Carrot and Lemon Fiber as a Fat Replacer on Physico-chemical, Textural, and Organoleptic Quality of Low-fat Beef Hamburger

  • Soncu, Eda Demirok;Kolsarici, Nuray;Cicek, Neslihan;Ozturk, Gorsen Salman;Akoglu, Ilker T.;Arici, Yeliz kasko
    • Food Science of Animal Resources
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    • v.35 no.3
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    • pp.370-381
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    • 2015
  • This study was designed to determine the usability of lemon fiber (LF-2%, 4%, 6%) and carrot fiber (CF-2%, 4%, 6%) to produce lowfat beef hamburgers. To that end, a certain amount of fat was replaced with each fiber. The proximate composition, pH value, cholesterol content, cooking characteristics, color, texture profile, and sensory properties of low-fat beef hamburgers were investigated. LF increased moisture content and cooking yield due to its better water binding properties, while CF caused higher fat and cholesterol contents owing to its higher fat absorption capacity (p<0.05). LF resulted in a lighter, redder, and more yellow color (p<0.05). Hardness, gumminess, springiness, and chewiness parameters decreased when the usage level of both fibers increased (p<0.05). However, more tender, gummy, springy, and smoother hamburgers were produced by the addition of CF in comparison with LF (p<0.05). Moreover, hamburgers including CF were rated with higher sensory scores (p<0.05). In conclusion, LF demonstrated better technological results in terms of cooking yield, shrinkage, moisture retention, and fat retention. However it is suggested that CF produces better low-fat hamburgers since up to 2% CF presented sensory and textural properties similar to those of regular hamburgers.

Physicochemical Properties and Antioxidant Activity of Ground Pork with Noni (Morinda citrifolia) Powder (노니(Morinda citrifolia)분말을 첨가한 분쇄돈육의 이화학적 특성 및 항산화 활성)

  • Lee, Si-Hyung;Choi, Young-Joon;Choi, Gang-Won;Lee, Kyung-Soo;Jung, In-Chul
    • The Korean Journal of Food And Nutrition
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    • v.33 no.3
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    • pp.331-338
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    • 2020
  • The purpose of this study was to examine the effect of noni (Morinda citrifolia) powder on the physicochemical properties and antioxidant activities of ground pork meat. Four samples of ground pork meat were prepared as follow: CON without noni powder, NP0.5 with 0.5% noni powder, NP1.0 with 1.0% noni powder, and NP1.5 with 1.5% noni powder. The moisture content of CON was the highest (p<0.05). The ash, fiber, fat retention, hardness, cohesiveness, gumminess, chewiness, lightness, and yellowness increased with the addition of the noni powder (p<0.05). The protein, fat, water holding capacity, cooking yield, moisture retention, springiness,and redness of the cooked meat were not significantly different among the samples. The pH of CON was the highest among the samples (p<0.05). The TBARS of CON, NP0.5, NP1.0, and NP1.5 were 0.48, 0.41, 0.36 and 0.34 mg/kg, respectively, and the NP1.5 was the lowest (p<0.05). The DPPH radical scavenging activity of CON, NP0.5, NP1.0, and NP1.5 were 10.4%, 20.8%, 34.6% and 45.3%, respectively, and the NP1.5 was the highest (p<0.05). Consequently, these results support the possible use of noni powder for meat product industry, as addition of noni powder enhances the antioxidant activities of ground pork meat.

Quercetin extracted from Sophora japonica flower improves growth performance, nutrient digestibility, cecal microbiota, organ indexes, and breast quality in broiler chicks

  • Dang, De Xin;Cho, Sungbo;Wang, Huan;Seok, Woo Jeong;Ha, Jung Heun;Kim, In Ho
    • Animal Bioscience
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    • v.35 no.4
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    • pp.577-586
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    • 2022
  • Objective: The objective of this study was to evaluate the effects of supplementing quercetin extracted from Sophora japonica flower (QS) to the diet of broiler chicks on their growth performance, apparent nutrient digestibility, cecal microbiota, serum lipid profiles, relative organ weight, and breast muscle quality. Methods: A total of 1,088 1-day-old broiler chicks (mixed sex) were randomly assigned to four groups based on the initial body weight (43.00±0.29 g). The experimental period was 35 days (starter, days 0 to 7; grower, days 7 to 21; finisher, days 21 to 35). There were 17 replicate cages per treatment and 16 birds per cage. Dietary treatments consisted of birds receiving basal diet without quercetin as the control group and treatment groups consisted of birds fed basal diet supplemented with 0.2, 0.4, or 0.6 g/kg QS. Results: With the increase of the QS dosage, body weight gain during days 0 to 7 (p = 0.021), 7 to 21 (p = 0.010), and 1 to 35 (p = 0.045), feed intake during days 0 to 7 (p = 0.037) and 1 to 35 (p = 0.025), apparent dry matter digestibility (p = 0.008), apparent energy retention (p = 0.004), cecal lactic acid bacteria counts (p = 0.023), the relative weight of breast muscle (p = 0.014), pH value from breast muscle (p<0.001), and the water holding capacity of breast muscle (p = 0.012) increased linearly, whereas the drip loss from breast muscle (p = 0.001) decreased linearly. Conclusion: The addition of QS in the diet of broiler chicks had positive effects on the breast muscle yield and breast muscle quality, and improved the dry matter digestibility and energy retention by increasing cecal beneficial bacteria counts, thus improving growth performance.