• Title/Summary/Keyword: Water residence time

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Control of Dimethyl Sulfide Emissions Using Biofiltration

  • Kong, Sei-Hun;Kim, Jo-Chun;Allen, Eric R.;Park, Jong-Kil
    • Journal of Environmental Science International
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    • v.11 no.8
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    • pp.819-827
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    • 2002
  • Laboratory scale experiments were conducted to evaluate the performance of a biofilter for eliminating dimethyl sulfide(DMS). A commercial compost/pine bark nugget mixture served as the biofilter material for the experiments. The gas flow rate and DMS concentration entering the filter were varied to study their effect on the biofilter efficiency. The operating parameters, such as the residence time, inlet concentration, pH, water content, and temperature, were all monitored throughout the filter operation. The kinetic dependence of the DMS removal along the column length was also studied to obtain a quantitative description of the DMS elimination. High DMS removal efficiencies(>95%) were obtained using the compost filter material seeded with activated sludge. DMS pollutant loading rates of up to 5.2 and 5.5 g-DMS/m$^3$/hr were effectively handled by the upflow and downflow biofilter columns, respectively. The macrokinetics of the DMS removal were found to be fractional-order diffusion-limited over the 9 to 25 ppm range of inlet concentrations tested. The upflow column had an average macrokinetic coefficient(K$\_$f/) of 0.0789 $\pm$ 0.0178 ppm$\^$$\sfrac{1}{2}$//sec, while the downflow column had an average coefficient of 0.0935 $\pm$ 0.0200 ppm$\^$$\sfrac{1}{2}$//sec. Shorter residence times resulted in a lower mass transfer of the pollutant from the gas phase to the aqueous liquid phase, thereby decreasing the efficiency.

Seasonal characteristics of thermal and chemical stratification in Lake Paldang (팔당호의 계절별 열적 및 화학적 층화 특성)

  • Son, Ju Yeon;Park, Jin Rak;Noh, Hye Ran;Yu, Soon Ju;Im, Jong Kwon
    • Journal of Korean Society on Water Environment
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    • v.36 no.1
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    • pp.1-13
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    • 2020
  • The purpose of this study was to investigate the thermal and chemical stratification in Lake Paldang 2013-2018 weekly using Schmidt's stability index (SSI) and the index of chemical stratification (IC-i). The annual average for SSI was 19.1 g cm/㎠ with the maximum value of 45.3 g cm/㎠ in the summer and the minimum value of 4.8 g cm/㎠ in fall-winter showing seasonal differences as well as increased vertical mixing in the summer. The lake stability increased higher in 2016 as compared with the other period. The most influential factors of thermal stratification were temperature and heavy rainfall. Especially, high water temperature and a prolonged residence duration caused by reduced rainfall and inflows could result in an increase of the stratification period. While decreasing inflow and outflow at the end of the rainfall, the thermal stratification was restrengthened within 7-14 days, and then stabilized rapidly before the rainfall. IC-DO increased with high air temperature in the spring and fall-winter. However increasing sunshine duration and residence time and decreasing rate of outflow caused an increase of IC-DO in the summer. Rainfall (less than 800 mm/year) and discharge (less than 200 CMS) significantly declined in 2015 resulting in IC-DO (0.77) increased more than three times over the other years and bottom water hypoxia occurred. The SSI and IC-i used in this study could be applied to other lakes to understand changes in stratification and mixing dynamics.

Establishing the Models for Optimized Design of Water Injection in Boilers with Waste-heat-recovery System (가습연소 폐열회수 보일러의 물분사 설계모델 구축에 관한 연구)

  • Shin, Jaehun;Moon, Seoksu
    • Journal of ILASS-Korea
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    • v.26 no.2
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    • pp.96-103
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    • 2021
  • In order to improve the overall efficiency and meet the emission regulations of boiler systems, the heat exchanging methods between inlet air and exhaust gas have been used in boiler systems, named as the waste-heat-recovery condensing boiler. Recently, to further improve the overall efficiency and to reduce the NOx emission simultaneously, the concept of the water injection into the inlet air is introduced. This study suggests the models for the optimized design parameters of water injection for waste-heat-recovery condensing boilers and performs the analysis regarding the water injection amount and droplet sizes for the optimized water injection. At first, the required amount of the water injection was estimated based on the 1st law of thermodynamics under the assumption of complete evaporation of the injected water. The result showed that the higher the inlet air and exhaust gas temperature into the heat exchanger, the larger the amount of injected water is needed. Then two droplet evaporation models were proposed to analyze the required droplet size of water injection for full evaporation of injected water: one is the evaporation model of droplet in the inlet air and the other is that on the wall of heat exchanger. Based on the results of two models, the maximum allowable droplet sizes of water injection were estimated in various boiler operating conditions with respect to the residence time of the inlet air in the heat exchanger.

Water Quality Modeling of the Ara Canal, Using EFDC-WASP Model in Series (3차원 EFDC-WASP 연계모델을 이용한 경인아라뱃길 수질 예측)

  • Yin, Zhenhao;Seo, Dongil
    • Journal of Korean Society of Environmental Engineers
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    • v.35 no.2
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    • pp.101-108
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    • 2013
  • Ara Canal is the first artificial canal in Korea that connects the Han River and the Yellow Sea. Due to mixture of waters with different salinity and water quality, complicated hydrodynamic and water quality distributions are expected to occur inside the canal. An integrated hydrodynamic and water quality modeling system was developed using the 3 dimensional hydrodynamic model, EFDC (Environmental Fluid Dynamics Code) and the water quality model WASP (Water Quality Analysis and Simulation Program). According to the modeling results, BOD, TN, TP and Chl-a concentrations inside the canal were lower at the West Gate side than the Han River side since influent concentrations of the West Gate side are significantly lower. Chemical stratification due to salinity difference were more evident at the West Gate side as vertical salinity difference were more pronounced in this area. On the other hand, Chl-a concentrations showed more pronounced vertical distribution at the Han River side as Chl-a concentrations were higher in this area. It was notable that Dissolved Oxygen concentrations can be lower than 2 mg/L occasionally in the middle part of the canal. While major factor affecting DO concentrations in the canal are inflows via both gates, the other important factor was found to be BOD decay in the canal due to extended hydraulic residence time. This study can be used to predict hydrodynamic conditions and water quality in the canal during the year and thus can be helpful in the development of gate operation method of the canal.

An Experimental Study on the Application of Electrolysis to Nightsoil Treatment Plant Effluent, as a Means of Advanced Treatment Techonology (전해처리법(電解處理法)에 의한 분뇨(糞尿) 2차 처리수(處理水)의 고도처리(高度處理)에 관한 연구(硏究))

  • Chung, Kyeong Jin;Kim, Dong Min;Lee, Dong Houn
    • Journal of Korean Society of Water and Wastewater
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    • v.9 no.2
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    • pp.77-83
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    • 1995
  • The effluent from conventional nightsoil treatment plants contains nutrients, color and chlorides, in addition to residual organics and suspended solids, and thereby causes substantial pollution problems in receving water resources. In order to verify the usefullness of electrolysis in removing those residual pollutants from such conventional nightsoil treatment plant effluent, a bench scale experiment was conducted using sufficiently dilluted human nightsoil as experiment feeds. The result showed mean removals of 45% of total phosphorus and 85% of color, in addition 87% of residual BOD, 47% of residual COD and 85% of residual SS. The optimum electric current was found to be 15 ampere and the optimum hydraulic residence time 21/2 hour.

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Determination of Ammonia-N in Environmental Water by Air-segmented FIA

  • Feng, Yong-Lai;Tian, Li-Ching;Wang, Wei;Wu, Qiao-Znen
    • Analytical Science and Technology
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    • v.8 no.4
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    • pp.787-792
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    • 1995
  • A method for determination of ammonia-N in environmental water by air-segmented flow injection analysis using the colour reaction of phenol and sodium hypochlorite with ammonia was described in this paper. When the reaction temperature is $70^{\circ}C$ and the reaction residence time is 5 minutes, a sample frequency of $60-90h^{-1}$ can be achieved. The detection limit and relative deviation are $0.05mg.ml^{-1}$ and 4%, respectively. The recovery of this method is 96 - 110%, and the determination results of the method are greatly agreement with standard colorimetric method.

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Petroleum Refinery Effluents Treatment by Advanced Oxidation Process with Methanol

  • Shoucheng, Wen
    • Journal of the Korean Chemical Society
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    • v.58 no.1
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    • pp.76-79
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    • 2014
  • Petroleum refinery effluents are waste originating from industries primarily engaged in refining crude oil. It is a very complex compound of various oily wastes, water, heavy metals and so on. Conventional processes are unable to effectively remove the chemical oxygen demand (COD) of petroleum refinery effluents. Supercritical water oxidation (SCWO) was proposed to treat petroleum refinery effluents. In this paper, methanol was used to investigate co-oxidative effect of methanol on petroleum refinery effluents treatment. The results indicated that supercritical water oxidation is an effective process for petroleum refinery effluents treatment. Adding methanol caused an increase in COD removal. When reaction temperature is $440^{\circ}C$, residence time is 20 min, OE is 0.5 and initial COD is 40000 mg/L, and COD removal increases 8.5%.

Optimization of Kiln Process Parameters of Low-Temperature Sintering Lightweight Aggregate by Response Surface Analysis (반응표면분석법에 따른 저온소성 경량골재의 킬른공정변수 최적화)

  • Lee, Han-Baek;Seo, Chee-Ho
    • Journal of the Korean Ceramic Society
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    • v.47 no.5
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    • pp.365-372
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    • 2010
  • This paper was to evaluate the influence of kiln process parameter(kiln angle, kiln rotating speed) of lightweight aggregate using waste glass and bottom ash with industrial by-products on thermal conductivity, density, water absorption, fracture load and porosity by response surface analysis. In the results of surface plot and contour plot, it has verified that kiln residence time of lightweight aggregate increase as kiln angle and rotating speed decreases. For this reason, pore size and quantity tend to increase by active reaction of forming agent. It seems to be that increase in pore size and quantity have caused decreasing density, fracture load and thermal conductivity, and increasing water absorption. In conclusion, optimization of kiln process parameter on thermal conductivity, density, water absorption, fracture load and porosity by response surface analysis are kiln angle 2.4646%, kiln rotating speed 40.7089 rpm.

Hydro-Biogeochemical Approaches to Understanding of Water and Carbon Cycling in the Gwangneung Forest Catchment (수문생지화학적 접근을 통한 광릉 산림 유역의 물과 탄소 순환 이해)

  • Kim, Su-Jin;Lee, Dong-Ho;Kim, Joon;Kim, Sung
    • Korean Journal of Agricultural and Forest Meteorology
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    • v.9 no.2
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    • pp.109-120
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    • 2007
  • The information on flowpath, storage, residence time, and interactions of water and carbon transport in a catchment is the prerequisite to the understanding and predicting of water and carbon cycling in the mountainous landscapes of Korea. In this paper, along with some up-to-date results, we present the principal methods that are currently used in HydroKorea and CarboKorea research to obtain such information. Various catchment hydrological processes have been examined on the basis of the water table fluctuations, the end-member mixing model, the cross correlation analysis, and cosmogenic radioactive isotope activity. In the Gwangneung catchment, the contribution of surface discharge was relatively large, and the changes in the amount, intensity and patterns of precipitation affected both the flowpath and the mean residence time of water. Particularly during the summer monsoon, changes in precipitation patterns and hydrological processes in the catchment influenced the carbon cycle such that the persistent precipitation increased the discharge of dissolved organic carbon (DOC) concentrated in the surface soil layer. The improved understanding of the hydrological processes presented in this report will enable a more realistic assessment of the effects of climate changes on the water resource management and on the carbon cycling in forest catchments.

Study on the Design of Attached Revolution Body Horizontal Rotary Kiln Dryer and the Optimum Operational Conditions (회전체를 부착한 수평형 로타리킬른 건조로의 설계 및 최적 운전조건 연구)

  • Jung, Dong Hyun;Chun, Young Nam
    • Applied Chemistry for Engineering
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    • v.18 no.6
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    • pp.575-579
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    • 2007
  • Sludge disposal technology has been studied with many researchers since disposal of sewage sludge has been a social problem. The current technologies include incineration, carbonization, pyrolysis, landfilling and fertilization. However, all of these processes require a dry process, because sewage sludge with more than 80% high water content is difficult to be used as a raw material. This study has the purpose to establish the optimal operation conditions and the technology as changing the variables: kiln residence time, sludge load, dryer temperature, by using the previous study that is rotary kiln type dryer designed as a numerical simulation study. As the results, optimum conditions are determined as follows: kiln residence time, sludge load, dryer temperature are $62.5kg/m^3{\cdot}hr$, 26.2 min, $330^{\circ}C$, respectively. Content of water, drying efficiency, weight loss, volume loss show that the results are $10{\pm}2$, 88, 80, 60%, and the dried sludge is released by a dryer below 10 mm.