• Journal of Soil and Groundwater Environment
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• v.29 no.2
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• pp.1-10
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• 2024

With industrial development, the inevitable increase in both organic and inorganic waste necessitates the exploration of waste treatment and utilization methods. This study focuses on co-pyrolyzing lignin and red mud to generate metalbiochar, aiming to demonstrate their potential as effective adsorbents for water pollutant removal. Thermogravimetric analysis revealed mass loss of lignin below 660℃, with additional mass loss occurring (>660℃) due to the phase change of metals (i.e., Fe) in red mud. Characterization of the metal-biochar indicated porous structure embedded with zero-valent iron/magnetite and specific functional groups. The adsorption experiments with 2,4-dichlorophenol and Cd(II) revealed the removal efficiency of the two pollutants reached its maximum at the initial pH of 2.8. These findings suggest that copyrolysis of lignin and red mud can transform waste into valuable materials, serving as effective adsorbents for diverse water pollutants.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.15 no.9
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• pp.5425-5433
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• 2014

This study examined the effects of the key parameters on the power efficiency of the waste heat power plant using the EES program to obtain data for the design of the 20kW Kalina power plant. The parameters include the ammonia mass fraction, vapor pressure, heat source temperature, and the cooling water temperature. According to the analyses, a lower ammonia mass fraction and a higher vapor pressure increase the efficiency, in general. On the other hand, this study shows that there is a specific region with a very low ammonia mass fraction, where the efficiency decreases with ammonia mass fraction. Regarding the vapor pressure at the turbine inlet, the power efficiency increases with increasing vapor pressure. In addition, it was found that the influence of the vapor pressure on the efficiency increases with increasing ammonia mass fraction. Finally, the optimal condition for the maximum power efficiency is defined in this study, i.e., the maximum efficiency was 15% with a 25bar vapor pressure, $160^{\circ}C$ heat source temperature, $10^{\circ}C$ cooling water temperature, and 0.4 ammonia mass fraction.

• Journal of Korean Society on Water Environment
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• v.36 no.4
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• pp.284-299
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• 2020

Dam reservoirs play a particularly crucial role in processing the allochthonous and the autochthonous dissolved (DOC) and the particulate (POC) organic carbon and in the budget of global carbon cycle. However, the complex physical and biogeochemical processes make it difficult to capture the temporal and spatial dynamics of the DOC and the POC in reservoirs. The purpose of this study was to simulate the dynamics of the DOC and the POC in Daecheong Reservoir using the 3-D hydrodynamics and water quality model (AEM3D), and to quantify the mass balance through the source and sink fluxes analysis. The AEM3D model was calibrated using field data collected in 2017 and showed reasonable performance in the water temperature and the water quality simulations. The results showed that the allochthonous and autochthonous proportions of the annual total organic carbon (TOC) loads in the reservoir were 55.5% and 44.5%, respectively. In season, the allochthonous loading was the highest (72.7%) in summer, while in autumn, the autochthonous loading was the majority (77.1%) because of the basal metabolism of the phytoplankton. The amount of the DOC discharged to downstream of the dam was similar to the allochthonous load into the reservoir. However, the POC was removed by approximately 96.6% in the reservoir mainly by the sedimentation. The POC sedimentation flux was 36.21 g-C/㎡/yr. In terms of space, the contribution rate of the autochthonous organic carbon loading was high in order of the riverine zone, the transitional zone, and the lacustrine zone. The results of the study provide important information on the TOC management in the watersheds with extensive stagnant water, such as dam reservoirs and weir pools.

• Tunnel and Underground Space
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• v.7 no.1
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• pp.13-19
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• 1997

It is necessary to study on thermo-hydro-mechanical effect at rock mass performing project such as radiowaste disposal in deep rock mass. In this study, thermo-hydro-mechanical coupling analysis which is considered interaction and the variation of rock properties induced by temperature increase was performed for the circular shaft when appling temperature of 20$0^{\circ}C$ at the shaft wall. The shaft is diameter of 2 m and under hydrostatic stress of 5 MPa. In the cases, thermal expansion by temperature increase progress from the wall to outward and thermal expansion could induce tensile stress over the tensile strength of rock mass at the wall. When rock properties were given as a function of temperature, thermal expansion increased, tensile stress zone expanded. Lately, water flow is activated by increase of permeability and decrease of viscosity.

• Journal of the Korean Society of Safety
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• v.6 no.3
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• pp.40-49
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• 1991

To better understand the phenomena inside an absorber, where heat and mass transfer coexist, this study selected the most baslc absorption model from in whifh water vapor is absorbed on the surface of a stationary lithium bromide absurbent solution. The purpose of this study is to obtain basic knowledge of heat and mass transfer processes as affected by Marangoni convection induced by addition of surfactant. We apply a non-flowing bulk absorption model and assume that dropwise surfactant is fixed on the absorbent surface. Four governing equation-continuity, laminar monentum, energy and diffusion are solved numerically to obtain temperature and concentraion distributions during steam absorption with Marangonl convection.. In conclusion, Sh and Nu genrally increase at the initial absorption stage.

• Nuclear Engineering and Technology
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• v.33 no.6
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• pp.585-595
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• 2001

A series of experiments have been carried out to investigate the effects of non-condensable gas on the direct contact film condensation of vapor mixture under an adiabatic wall condition. The average heat transfer coefficient of the direct contact condensation was obtained at the atmospheric pressure with four main parameters ; air-mass fraction, mixture velocity, film Reynolds number, and the degree of water film subcooling having an influence on the condensation heat transfer coefficient. With the analysis of 88 experiments, a correlation of the average Nusselt number for direct contact film condensation of steam/air mixture at an adiabatic vertical wall was proposed as functions of film Reynolds number, mixture Reynolds number, air mass fraction, and Jacob number. The average heat transfer coefficient for steam/air mixture condensation decreased significantly while air mass fraction increased. The average heat transfer coefficients also decreased as the Jacob number increased, and were scarcely affected by the film Reynolds number below a mixture Reynolds number of about 245,000.

• Journal of Mechanical Science and Technology
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• v.19 no.12
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• pp.2289-2295
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• 2005

Two-Phase flow pattern and pressure drop data were obtained for pure refrigerants R134a and R123 and their mixtures as test fluids in a horizontal tube. The flow pattern is observed through tubular sight glasses located at inlet and outlet of the test section. The flow map of Baker developed for air-water two-phase flow at atmospheric pressure failed to predict the observed flow patterns at the higher value of the mass velocity used in the present study. The map of Kattan et al. predicted the data well over the entire region of mass velocity selected in the present study. The measured pressure drop increased with an increase in vapor quality and mass velocity. A new two-phase multiplier was developed from a dimensional analysis of the frictional pressure drop data measured in the present experiment. This new multiplier was found successfully to correlate the frictional pressure drop.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.26 no.8
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• pp.366-374
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• 2014

Experimental mass transfer data, which were obtained for the $CO_2$-water slug flows in vertical tubes with 2, 5, and 8mm diameters, were analyzed in comparison with the penetration theory. It was found that a penetration model with molecular diffusion coefficient cannot predict the experimental data accurately. An effective diffusion coefficient, which considers enhancement effect of interfacial waves, was suggested to improve prediction. Another empirical factor was also suggested to consider the effect of non-uniform interface velocity. A modified penetration model was found to be capable of predicting the experimental data reasonably well.

• Journal of the Korean Solar Energy Society
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• v.27 no.3
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• pp.87-94
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• 2007

In this paper, with water-LiCl-$CaCl_2-Zn(NO_3)_2$ mixture which utilizes solar energy at the evaporator heat source, a thermodynamic analysis was performed to provide design data for a double-effect absorption heating system. A comparative study of the water-LiCl-$CaCl_2-Zn(NO_3)_2$ mixture against the water-LiBr pair was conducted by a computer simulation. The computer simulation is based on mass, material and heat balance equations for each part of the system. Coefficients of performance and flow ratios for effects of different operating temperatures are investigated. It is found that the heating COP is higher for the water-LiCl-$CaCl_2-Zn(NO_3)_2$ mixture than for the water-LiBr pair, and FR is lower for the former.

• Journal of the Korean Solar Energy Society
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• v.26 no.4
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• pp.73-81
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• 2006

In this paper, with water-LiBr-LiSCN mixture which utilizes solar energy as mid temperature range evaporator heat source, a thermodynamic analysis was performed to provide design data for a double-effect absorption heating system. A comparative study of the water-LiBr-LiSCN mixture against the water-LiBr pair was conducted by a computer simulation. The computer simulation is based on mass, material and heat balance equations for each part of the system. Coefficients of performance and flow ratios for effects of different operating temperatures are investigated. It is found that the heating COP is higher for the water-LiBr-LiSCN mixture than for the water-LiBr pair, and FR is lower for the former.