• 제목/요약/키워드: Water mass

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LC-Tandem Mass Spectrometry를 활용한 농업용수 중 Perfluorochemicals 분석시료 전처리법 (Sample Preparation Method for Perfluorochemicals with LC-Tandem Mass Spectrometry in Agricultural Water)

  • 김진효;진초롱;최근형;박병준
    • 농약과학회지
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    • 제19권1호
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    • pp.1-4
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    • 2015
  • 잔류성 유기오염물질인 과불화합물 중 perfluorooctanesufonic acid (PFOS)와 perfluorooctanoic acid (PFOA)의 잔류분석은 환경부 "잔류성 유기오염물질 공정시험기준"에 따라 hydrophilic-lipophilic balance (HLB) solid phase extraction (SPE) 전처리 후 LC-$MS^n$를 이용해 정량 분석하고 있다. 본 연구에서는 환경부 설정 공정시험법에 따라 농업용수 전처리 후, 시험법에서 제거하지 못한 미지의 불순물을 Envi-Carb$^{TM}$을 통해 회수율에 영향을 주지 않고 손쉽게 제거하였다. 또한, 과불화합물 분석에 사용되는 LC-$MS^n$ 중 quadrupole-time-of-flight mass spectrometry (qTOFMS)에서 측정된 PFCs의 정량한계를 평가한 결과, 시험에 사용된 장비간 정량한계 편차가 크게 관찰되었으나, 시험대상 장비 모두 농업용수 중 ng/L 수준으로 잔류하는 과불화합물의 정밀 잔류분석에 사용가능 한 것으로 확인되었다.

Plain water intake of Korean adults according to life style, anthropometric and dietary characteristic: the Korea National Health and Nutrition Examination Surveys 2008-2010

  • Kim, Jihye;Yang, Yoon Jung
    • Nutrition Research and Practice
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    • 제8권5호
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    • pp.580-588
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    • 2014
  • BACKGROUND/OBJECTIVES: The objective of the study was to provide useful insights into plain water intake of Korean adults according to life style, anthropometric, and dietary characteristics. SUBJECTS/METHODS: The data from the 2008-2010 Korea National Health and Nutrition Examination Survey were used. The subjects were 14,428 aged 20-64 years. Water intake was estimated by asking the question "How much water do you usually consume per day?". Dietary intake was estimated by 24-hour dietary recall. A qualitative food frequency questionnaire including 63 food items was also administered. RESULTS: The mean plain water intake for men and women were 6.3 cup/day and 4.6 cup/day, respectively. Plain water intake increased as lean body mass, waist circumference, and body mass index levels increased, except for percentage of body fat. As energy and alcohol intakes increased, plain water intake increased. As total weight of food intake and total volume of food intake increased, plain water intake increased. Plain water intake increased as consumption of vegetables increased. Plain water intake increased as frequencies of green tea, alcoholic drink, and all beverages were increased in men. Plain water intake increased with increased frequencies of green tea, milk, soy milk, and alcoholic drink and decreased frequencies of coffee and soda in women. CONCLUSIONS: Our results suggest that persons who had a higher waist circumference or lean body mass and women with higher BMI consumed more plain water. The persons eating high quality diet, or the persons who had more vegetables, green tea, milk, soy milk, or alcoholic drink consumed more plain water.

남극 브랜스필드 해협에서 입자 플럭스 계절변화 (Seasonal Variations of Particle Fluxes in the Bransfield Strait, Antarctica)

  • 김동선;김동엽;김영준;강영철
    • Ocean and Polar Research
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    • 제24권2호
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    • pp.153-166
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    • 2002
  • Particle fluxes were measured by using time-series sediment traps in the Bransfield Strait from December 27th, 1999 to December 26th, 2000. Total mass fluxes showed distinct seasonal variations with high fluxes in the austral summer and low fluxes in the austral winter at a 678m water depth in the eastern Bransfield Strait, while they were high only in January and fairly low in other months at a 960m water depth in the central Bransfield Strait. The reason that total mass fluxes occurred only in January at a 960m water depth in the central Bransfield Strait seems to be the strong current in the surface waters, which leads to a substantial amount of terrestrial materials and locally produced organic matter being advected away from the mooring site. Total mass fluxes were very high from January to October at a 1678m water depth in the eastern Bransfield Strait, while they were high only in January and February at a 1860m water depth in the central Bransfield Strait. The fact that total mass fluxes were higher at the deep water in the both sites than at the intermediate water depth may reflect that a substantial amount of terrestrial and organic materials are laterally transported by strong tidal current from the shallow environments to the deep basins.

Experimental study on the condensation of sonic steam in the underwater environment

  • Meng, Zhaoming;Zhang, Wei;Liu, Jiazhi;Yan, Ruihao;Shen, Geyu
    • Nuclear Engineering and Technology
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    • 제51권4호
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    • pp.987-995
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    • 2019
  • Steam jet condensation is of great importance to pressure suppression containment and automatic depressurization system in nuclear power plant. In this paper, the condensation processes of sonic steam jet in a quiescent subcooled pool are recorded and analyzed, more precise understanding are got in direct contact condensation. Experiments are conducted at atmospheric pressure, and the steam is injected into the subcooled water pool through a vertical nozzle with the inner diameter of 10 mm, water temperature in the range of $25-60^{\circ}C$ and mass velocity in the range of $320-1080kg/m^2s$. Richardson number is calculated based on the conservation of momentum for single water jet and its values are in the range of 0.16-2.67. There is no thermal stratification observed in the water pool. Four condensation regimes are observed, including condensation oscillation, contraction, expansion-contraction and double expansion-contraction shapes. A condensation regime map is present based on steam mass velocity and water temperature. The dimensionless steam plume length increase with the increase of steam mass velocity and water temperature, and its values are in the range of 1.4-9.0. Condensation heat transfer coefficient decreases with the increase of steam mass velocity and water temperature, and its values are in the range of $1.44-3.65MW/m^2^{\circ}C$. New more accurate semi-empirical correlations for prediction of the dimensionless steam plume length and condensation heat transfer coefficient are proposed respectively. The discrepancy of predicted plume length is within ${\pm}10%$ for present experimental results and ${\pm}25%$ for previous researchers. The discrepancy of predicted condensation heat transfer coefficient is with ${\pm}12%$.

가막만 빈산소 수괴의 특성 (The Characteristics of Oxygen Deficient Water Mass in Gamak Bay)

  • 김정배;이상용;유준;최양호;정창수;이필용
    • 한국해양환경ㆍ에너지학회지
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    • 제9권4호
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    • pp.216-224
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    • 2006
  • 하계 가막만에서 발생하는 빈산소 수괴의 형성과정과 그 특성을 규명하기 위하여 2005년 6월 17일부터 2005년 9월 12일까지 주 간격으로 조사하였다. 표층 수온은 내만에서 만 입구로 갈수록 낮았으나, 저층 수온은 만 입구와 내만보다 만 중앙에서 높게 나타났다. 수괴의 수직적인 성층은 매우 발달하였으며, 수온약층은 수심 3-5m에서 관측되었다. 저층의 빈산소 수괴는 7월초에 내만 안쪽에서 나타났으며, 8월초에는 만 중앙부까지 확산되었다. 수괴의 평균투명도와 광소멸 계수($K_d$)는 각각 4.0m와 0.47로 나타났다. 저층의 영양염과 클로로필 ${\alpha}$ 농도는 표층보다 유의하게 높았으며, 만 입구보다 내만에서 높게 나타났다. 빈산소 수괴의 저층에서 퇴적물의 산소투과 깊이는 지극히 낮았으며, 산소소모율은 빈산소가 소멸된 수괴에서 보다 낮았다. 빈산소 수괴가 발생하는 기간동안 용존 산소 농도는 저층의 영양염 농도와 유의한 역 상관관계를 보였으나, 표층 영양염 농도와는 유의한 관계를 보이지 않았다. 저층에서 산소 감소의 촉진은 퇴적물에서 산소소모율 증가와 저층 부근에서 미생물에 의한 유기물 분해 때문인 것으로 판단되었다.

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암모니아/물 흡수식 냉동기의 판형 재생기의 수치해석 (Numerical Analysis of a Plate Type Generator for Ammonia/Water Absorption Refrigerators)

  • 지제환;정은수;정시영
    • 대한기계학회:학술대회논문집
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    • 대한기계학회 2001년도 춘계학술대회논문집D
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    • pp.304-310
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    • 2001
  • A numerical model which simulates the heat and mass transfer processes within a counter-current plate type generator for ammonia/water absorption refrigerators was developed. Ammonia/water solution flows downward under gravity and ammonia/water vapor generated by flow boiling flows upward. The flow pattern within the generator was assumed to be a bubbly flow, and the liquid and vapor phase were assumed to be saturated. It was shown that the boiling of ammonia occurred mainly in the upper part of the generator. The effects of the generator length, the wall temperature and the mass flow rate of ammonia/water solution into the generator on the generation of ammonia/water vapor were investigated.

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Estimation of the Residence Time for Renewal of the East Sea Intermediate Water using MICOM

  • Seung, Young-Ho;Kim, Kuk-Jin
    • Journal of the korean society of oceanography
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    • 제32권1호
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    • pp.17-27
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    • 1997
  • Miami Isopycnic Coordinate Ocean Model is applied to the East Sea to estimate the renewal time of the upper Intermediate Water The model gives about 10 years of renewal time. Extrapolating this result to the whole water mass below, including the upper Intermediate Water, leads to about 81.4 years of renewal time, which is quite comparable to that obtained by Kim and Kim (1997) based on the recent observations. Deep winter mixing occurs in the north of the basin. The areas of the largest water mass conversion, from the upper mixed to the intermediate below, are along the periphery of the deep mixing zone. Large portion of the renewed Intermediate Water then advects along the Korean and Japanese coasts. It is concluded that the high-oxygen content Intermediate Water found off the Korean coast (Kim and Chung, 1984) is in part locally formed but mostly advected from the deep mixing zone.

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다관형 잠열축열장치의 축열특성연구 -물을 매체로 한 축열 및 방열과정 분석- (Study on the Thermal Storage Characteristics of a Multi-capsule type LTES System -Analysis for Heat Charging and Discharging Process for Water Flow-)

  • 김영복
    • Journal of Biosystems Engineering
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    • 제19권1호
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    • pp.62-69
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    • 1994
  • This study was designed to seek information on the heat charging and discharging characteristics of a multi-capsule type LTES(Latent Heat of Fusion Thermal Energy Storage) system, and especially prediction equation of outlet water temperature from the system. During heat charging process, the water temperature in the LTES tank increased very slowly in comparison with a predicted one and was kept near the melting point of the PCM for about 25 minutes. During heat discharging process, the latent heat discharging period of the outlet water temperature became longer as the inlet water temperature became higher and/or mass flow rate became lower. The dimensionless temperature of the outlet water was predicted by linking three equations of ${\theta}=1.1Exp(-{\tau}/0.82)$, ${\theta}=-0.06{\tau}+0.3$, ${\theta}=0.8Exp(-{\tau}/1.4)$ ($r^2{\leq}0.88$) depending on discharging period regardless of mass flow rates on the case of the inlet water temperature at $21.5^{\circ}C$.

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New 3D failure analysis of water-filled karst cave beneath deep tunnel

  • Zhang, R.;Yang, X.L.
    • Geomechanics and Engineering
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    • 제18권1호
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    • pp.1-9
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    • 2019
  • In this study, both 2D and 3D failure shapes of rock mass above the water-filled cavity are put forward when the surrounding rock mass cannot bear the pressure caused by the water-filled cavity. Based on the analytical expressions derived by kinematic approach, the profiles of active and passive failure patterns are plotted. The sensitivity analysis is conducted to explore the influences of different rock parameters on the failure profiles. During the excavation of the deep tunnels above the karst cavity, the water table always changes because of progressive failure of cavity roof. Therefore, it is meaningful to discuss the effects of varying water level on the failure patterns of horizontal rock layers. The changing laws of the scope of the failure pattern obtained in this work show good consistency with the fact, which could be used to provide a guide in engineering.

Non-absorbable Gas Effects on Heat and Mass Transfer in Falling Film Absorption

  • Kim, Byongjoo;Lee, Chunkyu
    • Journal of Mechanical Science and Technology
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    • 제17권4호
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    • pp.581-589
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    • 2003
  • Film absorption involves simultaneous heat and mass transfer in the gas-liquid system. While the non-absorbable gas does not participate directly In the absorption process. its pretence does affect the overall heat and mass transfer. An experimental study was performed to investigate the heat and mass transfer characteristics of LiBr-H$_2$O solution flow ing over 6-row horizontal tubes with the water vapor absorption in the pretence of non-absorbable gases. The volumetric concentration of non-absorbable gas, air, was varied from 0.17 to 10.0%. The combined effects of the solution flow rate and its concentration on the heat and mass transfer coefficients were also examined. The presence of 2% volumetric concentration of air resulted in a 25% reduction in the Nusselt number and 41% reduction in the Sherwood number Optimum film Reynolds number was found to exist at which the heat and mass transfer reach their maximum value independent of air contents. Reduced Nusselt and Sherwood numbers. defined as the ratio of Nusselt and Sherwood numbers at given non-absorbable gas content to that with pure water vapor, were correlated to account for the reduction in the heat and mass transfer due to non-absorbable gases in a falling film absorption process.