• Title/Summary/Keyword: Water leaching

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Leaching of Iron and Aluminum from Red Mud and Preparation of Coagulants (적니로부터 철과 알루미늄의 침출 및 응집제의 제조)

  • Lee, Jae-Rok;Hwang, In-Gook;Bae, Jae-Heum
    • Clean Technology
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    • v.15 no.1
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    • pp.38-41
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    • 2009
  • Red mud is generated as a waste byproduct during the production of aluminum hydroxide/alumina from bauxite ore in the Bayer process. In this study coagulants for wastewater treatment were prepared by leaching iron and aluminum from red mud with hydrochloric acid. The removal efficiency of heavy metal ions by the red mud coagulant increased with increasing the adjusted pH value of the synthetic wastewater. When the red mud coagulant was prepared, the leaching efficiency of Fe decreased with increasing the weight of red mud, while the pH value of the red mud coagulant increased. The solution of the red mud coagulant mixed with water was reacted again with red mud to produce the leached solution, which had higher concentrations of Fe and Al and a higher pH value than the red mud coagulant. Also, its pH value was comparable to that of other coagulants: $FeCl_3$ and $Fe_2(SO_4)_3$.

Guideline for Media-contact Recycling of Steel-Making Slag: Leaching Tests and Comparison of International Recycling Guidelines (제강슬래그의 친환경적 매체접촉형 재활용 방안: 용출시험 및 국내외 재활용 지침 비교)

  • Donghyun Kim;Inseong Hwang;Won Sik Shin
    • Journal of Soil and Groundwater Environment
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    • v.29 no.1
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    • pp.39-50
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    • 2024
  • Slags from steel-making industry have been recycled at a target rate of 95% and most of them are recycled as media-contact type such as fill and cover materials in Korea. However, as they contain free phase CaO during their generation, they may not only expand and collapse upon contact with water, but high pH leachate and heavy metals leaching may occur. In this study, the Korean leaching procedure (KLP) and up-flow percolation test were performed for the samples collected from 17 steel-making production plants in Korea. The waste quality criteria were met in all tests, but pH of the samples was above 10. There are no regulations on the pH of leachate in most of the countries, however, Germany, Italy, and Australia have set a pH range of 10 to 13 for the leachates. Although slag leachate cannot be considered hazardous based only on its high pH, it is necessary to reduce the pH of leachate to minimize the impact on the surrounding environment. Furthermore, conflicting regulations on wastes handling and management in Korea created confusion on the types of wastes subject to recycling. Therefore, an appropriate management plan for steel-making slags needs to be established. To this end, this study attempted to provide a guideline for managing steel-making slag waste by considering international guidelines and current management practices in Korea.

Physico-Chemical Characteristics of Municipal Solid Waste Generated from T City and Leaching Characteristics of the Incineration Ash (T시 생활폐기물의 물리화학적 특성 및 소각재 용출특성)

  • Park, Joon-Seok
    • Journal of the Korea Organic Resources Recycling Association
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    • v.18 no.2
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    • pp.84-92
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    • 2010
  • This research was conducted to investigate physico-chemical characteristics of municipal solid waste (MSW) generated from T City, Gangwon-do and leaching characteristics of the incineration ash. From the results, bulk density of MSW in T city was $231kg/m^3$. Combustible and incombustible components were in 94.0% and 6.0%, respectively. Food waste and papers in combustible component occupied 32.3% and 41.2%. Water, volatile solids, and ash content were 41.3%, 50.5%, and 8.2%. C, H, O, N, S, and Cl showed 51.4%, 6.3%, 26.7%, 1.1%, 0.2%, 0.5%, respectively. Low heating value (2,704 kcal/kg) of T city was similar to 2,764 kcal/kg of Chuncheon and was 1,000 kcal/kg higher than 1,467~1,584 kcal/kg of the past Kuro-gu and Koyang city. The specification of leaching characteristics of the incineration ash were within the Korean regulation standard.

Dimensional Stability of Korean Red Pine Treated with Water Repellents (발수제 처리 소나무재의 치수안정성)

  • Han, Gyu-Seong
    • Journal of the Korea Furniture Society
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    • v.19 no.3
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    • pp.172-179
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    • 2008
  • The objective of this study was to investigate the influence of the water repellents' treatment on the water absorptivity and the dimensional stability of Korean red pine wood(Pinus densiflora). The alkylketene dimer(AKD), fluororesin emulsion(Wood-seal, WS), and paraffin wax emulsions(PW25, PW40, and PW1200) were used as water repellents. PW40 and WS were proved as excellent water repellents for pine wood, because the samples treated with these agents showed high contact angles and large reduction in water absorptivities. Also, the dimensional stability(antiswelling efficiency) of pine wood was considerably improved by water repellents treatments, such as PW40 and WS at the pressure of 2MPa. The water repellent treated woods with WS, PW40, and PW1200 at the pressure of 2MPa were relatively stable to the wet-dry cyclic leaching test.

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The Assessment of Water Quality Contamination Following the Utilization of Coal Ash as Fill Material (성토재로서 석탄회 사용에 따른 수질오염도 평가)

  • 김학삼;조삼덕
    • Geotechnical Engineering
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    • v.11 no.3
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    • pp.5-16
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    • 1995
  • In this paper, two leaching tests(batch test & column test) were carried out to estimate the detrimental effects of coal ash leachates. The variation of constituents and concentration of coal ash leachate with the lapse of leachins time was analysed through the column tests. From the test results, it was found coal tach can be classified as a general waste, and all other items except pH of coal ash leachate are satisfied the concentration requirements for the drinking water. It was also found the concentration of coal ash rapidly decrease with the lapse of the leaching time and become the insignificant value after an elapsed time.

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Effect of nano-stabilizer on geotechnical properties of leached gypsiferous soil

  • Bahrami, Reza;Khayat, Navid;Nazarpour, Ahad
    • Geomechanics and Engineering
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    • v.23 no.2
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    • pp.103-113
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    • 2020
  • Gypsiferous soils classified as problematic soils due to the dissolution of gypsum. Presence of gypsum in the soils texture subjected to steady flow can cause serious damages for the buildings, roads and water transmission canals. Therefore, researchers have conducted a series of physical, mechanical and microstructural laboratory tests to study the effect of gypsum leaching on the geotechnical properties of a lean clay containing 0%, 3%, 6%, 9%, 12%, and 15% raw gypsum. In addition, a combination of two nano-chemical stabilizers named Terrasil and Zycobond was used in equal proportions to stabilize the gypsiferous clayey samples. The results indicated that gypsum leaching considerably changed the physical and mechanical properties of gypsiferous soils. Further, adding the combination of Terrasil and Zycobond nano-polymeric stabilizers to the gypsiferous soil led to a remarkable reduction in the settlement drop, compressibility, and electrical conductivity (EC) of the water passing through the specimens, resulting in improving the engineering properties of the soil samples. The X-ray diffraction patterns indicate that stabilization by terrasil and zycobond causes formation of new peaks such as CSH and alteration of pure soil structure by adding raw gypsum. Scanning electron microscope (SEM) images show the denser texture of the soil samples due to chemical stabilization and decrease of Si/Al ratio which indicates by Energy dispersive X-ray (EDS) interpretation, proved the enhance of shear strength in stabilized samples.

An Experimental Study on the Waste Polyethylene Aggregate for Construction Materials (폐비닐 골재의 기본특성에 관한 연구)

  • Kim, Young-Chin
    • Journal of the Korean GEO-environmental Society
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    • v.4 no.4
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    • pp.5-16
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    • 2003
  • The aggregate out of waste polyethylene was made in order to recycle waste polyethylene wasted in the country side. Many physical and mechanical experiments which include leaching test, specific gravity test, compaction test, LA abrasion test, large-scaled shear test, and permeability test were performed for the waste polyethylene aggregate. The thermal conductivity test, unfrozen water content test and frost heave test were also performed. The temperature distribution for both gravels and waste polyethylene aggregate, which were constructed in the frost heave layer in the field, was measured in winter season of continuous 2 years and compared.

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Hydrogen Reduction Behavior of NCM-based Lithium-ion Battery Cathode Materials (NCM계 리튬이온 배터리 양극재의 수소환원 거동)

  • So-Yeong Lee;So-Yeon Lee;Dae-Hyeon Lee;Ho-Sang Sohn
    • Journal of Powder Materials
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    • v.31 no.2
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    • pp.163-168
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    • 2024
  • As the demand for lithium-ion batteries for electric vehicles is increasing, it is important to recover valuable metals from waste lithium-ion batteries. In this study, the effects of gas flow rate and hydrogen partial pressure on hydrogen reduction of NCM-based lithium-ion battery cathode materials were investigated. As the gas flow rate and hydrogen partial pressure increased, the weight loss rate increased significantly from the beginning of the reaction due to the reduction of NiO and CoO by hydrogen. At 700 ℃ and hydrogen partial pressure above 0.5 atm, Ni and Li2O were produced by hydrogen reduction. From the reduction product and Li recovery rate, the hydrogen reduction of NCM-based cathode materials was significantly affected by hydrogen partial pressure. The Li compounds recovered from the solution after water leaching of the reduction products were LiOH, LiOH·H2O, and Li2CO3, with about 0.02 wt% Al as an impurity.

Ion Exchange of Synthetic Na-fluor-tetrasilicic Mica(I) (합성 나타륨형 불소 4 규소운모의 이온교환(I))

  • 송종택
    • Journal of the Korean Ceramic Society
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    • v.21 no.3
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    • pp.217-220
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    • 1984
  • The leaching of Na-fluor-tetrasilicic mica $NaMg_{2.5}(Si_4O_{10})F_2$ (Na-TSM) in the deionized water was investigated by measuring the pH released Na and Mg contents in the suspension. According to the results it was found that $Na^+$ ions of interlayer in the Na-TSM were easily replaced by $H^+$ ions from the deionized water because $Na^+$ ions of I were repidly diffused to form a large hydrated electric double layer in the suspension.

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A Study on the Separation of Membrane and Leaching of Platinum and Ruthenium by Hydrochloric Acid from MEA of Fuel Cell (연료전지용(燃料電池用) 막전극접합체(膜電極接合體)의 막분리(膜分離) 및 염산(鹽酸)에 의한 백금(白金)과 루테늄의 침출(浸出)에 관(關)한 연구(硏究))

  • Lee, Jin-A;Kang, Hong-Yoon;Ryu, Ho-Jin
    • Resources Recycling
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    • v.21 no.3
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    • pp.15-20
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    • 2012
  • In this paper, we carried out separation of membrane and leaching of Pt and Ru using hydrochloric acid from MEA(membrane-electrode assembly) of fuel cell. In this method, these were separated from MEA of fuel cell using the distilled water, 10 vol.% butanol solution and 15 vol.% cationic surfactant(Koremul-LN-7) by dipping method without the dispersion of catalyst particles. And the leaching of Pt and Ru containing in the separated carbon paper catalysts has been studied by hydrochloric acid using $HNO_3$ or $H_2O_2$ as a oxidant. The leaching ratio of Pt and Ru were higher when $H_2O_2$ was used as a oxidant and the optimum conditions were obtained in 8M HCl, the amount of $H_2O_2$ 5M and 6 hours of leaching time at $90^{\circ}C$. In this condition, extraction of Pt and Ru were 98% and 71.5%, respectively.