• Title/Summary/Keyword: Water density

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Environmentally Assisted Cracking of Alloys at Temperatures near and above the Critical Temperature of Water

  • Watanabe, Yutaka
    • Corrosion Science and Technology
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    • v.7 no.4
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    • pp.237-242
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    • 2008
  • Physical properties of water, such as dielectric constant and ionic product, significantly vary with the density of water. In the supercritical conditions, since density of water widely varies with pressure, pressure has a strong influence on physical properties of water. Dielectric constant represents a character of water as a solvent, which determines solubility of an inorganic compound including metal oxides. Dissociation equilibrium of an acid is also strongly dependent on water density. Dissociation constant of acid rises with increased density of water, resulting in drop of pH. Density of water and the density-related physical properties of water, therefore, are the major governing factors of corrosion and environmentally assisted cracking of metals in supercritical aqueous solutions. This paper discusses importance of "physical properties of water" in understanding corrosion and cracking behavior of alloys in supercritical water environments, based on experimental data and estimated solubility of metal oxides. It has been pointed out that the water density can have significant effects on stress corrosion cracking (SCC) susceptibility of metals in supercritical water, when dissolution of metal plays the key role in the cracking phenomena.

Effects of Soil Texture and Bulk Density on the Least-Limiting Water Range (토성(土性)과 용적밀도(容積密度)가 최소생육제한수분범위(最小生育制限水分範圍)에 미치는 영향(影響))

  • Jo, In-Sang;Hyun, Byung-Keun;Cho, Hyun-Jun;Jang, Yong-Seon;Shin, Jae-Sung
    • Korean Journal of Soil Science and Fertilizer
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    • v.30 no.1
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    • pp.51-55
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    • 1997
  • Three soils, sandy loam, loam and silty clay loam, were selected and three inches soil cores with 4 bulk density(BD) levels were made by compressing the soils wetted with 3 levels water. Mechanical and water characteristics were measured and analyzed the mechanical resistance limiting water, available water and least-limiting water range. Mechanical resistance limiting water(MRLW) were appeared at higher bulk density than $1.6Mg/m^3$ in sandy loam, and $1.4Mg/m^3$ in loam and silty clay loam. The least-limiting water ranges were sharply decreased at the bulk density $1.6Mg/m^3$ in sandy loam and loam, $1.4Mg/m^3$ in silty clay loam. There were big deferences between available water contents and least limiting water ranges in finer texture and higher bulk density soils.

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Observation of local water content and current density in the PEMFC system (고분자 전해질 연료전지의 전류밀도와 국소 함수량 관찰)

  • Ko, Dong-Soo;Moon, Cheor-Ron;Choi, Gyung-Min;Kim, Duck-Jool;Jung, Ji-Hwan
    • 한국신재생에너지학회:학술대회논문집
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    • 2008.05a
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    • pp.69-72
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    • 2008
  • The local water contents and water transfer characteristics in the PEMFC system were investigated by numerical simulations and experiments. The performance of a lab-scale PEMFC is measured for fully humidified gases conditions and non-humidified ones. In order to observe the local water contents and water transfer characteristics inside PEMFC, the numerical simulation using CFD module on STAR-CD(es-pemfc) were conducted. The results show that the water content was increased as increasing current density, whereas it was decreased in high current density region. Then there was close correlation between high water content and internal temperature inside of MEA, and high current density was observed when internal temperature was dramatically increased.

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Molecular Dynamics Simulation Study for Hydroxide Ion in Supercritical Water using SPC/E Water Potential

  • Lee, Song Hi
    • Bulletin of the Korean Chemical Society
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    • v.34 no.10
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    • pp.2925-2930
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    • 2013
  • We present results of molecular dynamics simulations for hydroxide ion in supercritical water of densities 0.22, 0.31, 0.40, 0.48, 0.61, and 0.74 g/cc using the SPC/E water potential with Ewald summation. The limiting molar conductance of $OH^-$ ion at 673 K monotonically increases with decreasing water density. It is also found that the hydration number of water molecules in the first hydration shells around the $OH^-$ ion decreases and the potential energy per hydrated water molecule also decreases in the whole water density region with decreasing water density. Unlike the case in our previous works on LiCl, NaCl, NaBr, and CsBr [Lee at al., Chem. Phys. Lett. 1998, 293, 289-294 and J. Chem. Phys. 2000, 112, 864-869], the number of hydrated water molecules around ions and the potential energy per hydrated water molecule give the same effect to cause a monotonically increasing of the diffusion coefficient with decreasing water density in the whole water density region. The decreasing residence times are consistent with the decreasing potential energy per hydrated water molecule.

Optimum Compaction Test of Roller Compacted Concrete Pavement (롤러전압 콘크리트포장의 적정 다짐실험 방안 고찰)

  • Chung, Gun Woo;Lee, Seung Woo
    • International Journal of Highway Engineering
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    • v.17 no.3
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    • pp.27-33
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    • 2015
  • PURPOSES : To ensure appropriate RCC properties with sufficient strength development and workability, it is necessary to secure a proper level of consistency. It is also necessary to secure maximum dry density, which is an important factor for increasing the interaction of aggregate interlocking, leading to an augmentation of RCC strength. On the other hand, the dry density of RCC can be changed owing to the compaction conditions, water content, and particle size distribution. A Proctor test and a modified Proctor test were used for determining the optimum water content needed to achieve maximum dry density with different amounts of compaction energy. A Vebe test, on the other hand, was used for checking the level of consistency, which is important for producing a workable mixture. METHODS : To confirm the degree of compaction at various particle sizes, RCC mixtures with different sand/aggregate ratios were evaluated. The Proctor test and modified Proctor test were applied to these mixtures to check the effect of the aggregate gradation and compaction energy on the maximum dry density and optimum water content. During each test, three specimens were produced for all types of water content under each aggregate gradation. A compaction curve and the optimum water content and maximum dry density for each aggregate gradation were then obtained for both tests. The range of water content for the appropriate consistency of each aggregate gradation was determined through a Vebe test. The optimum water content was then evaluated based on this range. RESULTS : The compaction test results show that the modified Proctor test provides a higher maximum dry density and lower optimum water content compared with the standard Proctor test. For the modified Proctor test, two cases of aggregate gradation (s/a = 30% and 70%) had the optimum water contents outside of the appropriate water content range. For the standard Proctor test, on the other hand, none of aggregate gradations provided the optimum water content within the desired range. CONCLUSIONS : The modified Proctor test should be used for an RCC mixture design because it can provide adequacy between maximum dry density and consistency. Moreover, the compaction roller has become highly developed for higher compaction energy.

A Model for Predicting the Density of Glycerol Water Mixture, and Its Applicability to Other Alcohol Water Mixture

  • Liu, Tianhao;Lee, Seung Hwan;Lim, Jong Kuk
    • Journal of Integrative Natural Science
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    • v.14 no.3
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    • pp.99-106
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    • 2021
  • A mixture of alcohol and water is commonly used as antifreeze, liquor, and the fundamental solvents for the manufacture of cosmetics, pharmaceuticals, and inks in our daily life. Since various properties of alcohol water mixtures such as density, boiling or melting point, viscosity, and dielectric constant are determined by their mixing ratio, it is very important to know the mixing ratio to predict their properties. One of simple method to find the mixing ratio is measuring the density of the mixtures. However, it is not easy to predict the mixing ratio from the density of the mixtures because the relationship between mixing ratio and density has not been established well. The relationship is dependent on the relative sizes of solute and solvent molecules, and their interactions. Recently, an empirical model to predict the density of glycerol water mixture from their mixing ratio has been introduced. The suggested model is simple but quite accurate for glycerol water mixture. In this article, we investigated the applicability of this model to different alcohol water mixtures. Densities for six different alcohol water mixtures containing various alcohols (e.g., ethylene glycol, 1,3-propane diol, propylene glycol, methanol, ethanol, and 1-propanol) were simulated and compared to experimentally measured ones to investigate the applicability of the model proposed for glycerol water mixtures to other alcohol water mixtures. The model predicted the actual density of all alcohol water mixtures tested in this article with high accuracy at various ratios. This model can probably be used to predict the mixing ratio of other alcohol water mixtures from their densities beyond 6 alcohols tested in this article from their densities.

Evaluation of coolant density history effect in RBMK type fuel modelling

  • Tonkunas, Aurimas;Pabarcius, Raimоndas;Slavickas, Andrius
    • Nuclear Engineering and Technology
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    • v.52 no.11
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    • pp.2415-2421
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    • 2020
  • The axial heterogeneous void distribution in a fuel channel is a relevant and important issue during nuclear reactor analysis for LWR, especially for boiling water channel-type reactors. Variation of the coolant density in fuel channel has an effect on the neutron spectrum that will in turn have an impact on the values of absolute reactivity, the void reactivity coefficient, and the fuel isotopic compositions during irradiation. This effect is referring to as the history effect in light water reactor calculations. As the void reactivity effect is positive in RBMK type reactors, the underestimation of water density heterogeneity in 3D reactor core numerical calculations could cause an uncertainty during assessment of safe operation of nuclear reactor. Thus, this issue is analysed with different cross-section libraries which were generated with WIMS8 code at different reference water densities. The libraries were applied in single fuel model of the nodal code of QUABOX-CUBBOX/HYCA. The thermohydraulic part of HYCA allowed to simulate axial water distribution along fuel assembly model and to estimate water density history effect for RBMK type fuel.

Development of Simple Density Measurement System for Watermelons (수박 밀도의 간편 계측시스템 개발)

  • 최규홍;이강진;최동수;김기영;손재룡
    • Journal of Biosystems Engineering
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    • v.29 no.2
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    • pp.167-174
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    • 2004
  • Density is a physical property which contains information relating to the internal quality of fruits and vegetables, and can be used as an index for nondestructive quality evaluation. Density sorting has been employed by farmers for some agricultural products since ancient times. In this study, an automatic density measuring system based on the platform scale or water displacement method was developed for density sorting of watermelon. It consisted of water tan, load cell, net tray, electric motor, limit switch, control system and its program. The resolution of density was 0.001 g/㎤. In order to calibrate and evaluate the accuracy, the density was measured using a balloon kept in cold water. It showed 1.002 g/㎤ which almost correspond to real density of water. Test results with 6 watermelons and 3 replications showed that the standard deviations of the dens were 0.001∼0.004 g/㎤. The relationship between density and internal quality of watermelon was investigated using the system. The densities of hollow watermelons were less than 0.950 g/㎤, it was apparent that the density of the watermelon was related to the degree of hollowness. But the soluble solid contents and internal defects could not be estimated from the density.

A Study on Survival and Growth of whiteleg shrimp(Litopenaeus vannamei) according to Water Temperature and Rearing Density in Low Salinity Conditions (저염분 조건에서 수온 및 사육밀도에 따른 흰다리새우(Litopenaeus vannamei) 생존 및 성장에 관한 연구)

  • Chul Won, Kim;Han Seung, Kang
    • Journal of Marine Life Science
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    • v.7 no.2
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    • pp.213-220
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    • 2022
  • This study was conducted to investigate the effect of environmental factors such as water temperature and rearing density on the survival and growth of Litopenaeus vannamei under low salinity conditions. Overall, in the higher water temperature, the higher survival rate comes out and in the lower rearing density, the higher the survival rate does. In a study on feed efficiency, weight gain (WG) increased significantly as water temperature increased, and weight gain according to rearing density significantly decreased as rearing density increased. The growth rate of L. vannamei was faster when the water temperature was higher (water temperature 31℃) under low salinity conditions. In addition, in the evaluation of the growth rate according to the rearing density, it was confirmed that the growth rate was accelerated at a low rearinging density. It is believed that the results of this study will be usefully applied to the determination of the optimal rearinging density and breeding water temperature of L. vannamei in low salinity condition.

Water Temperature, Rearing Density and Feeding Rate on Growth and Survival Rate of Red Marbled Rockfish, Sebastiscus tertius Larvae (수온, 자어밀도 및 먹이공급량에 따른 붉은쏨뱅이, Sebastiscus tertius 자어의 성장과 생존율)

  • 허성범;임상구;김철원;김광수
    • Journal of Aquaculture
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    • v.12 no.3
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    • pp.213-220
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    • 1999
  • This study was performed to investigate the effects of water temperature and stocking density and rotifer density on the mass production of larval red marbled rockfish, Sebastiscus tertius. Total length of the marbled rockfish larva grown in $23^{\circ}C$ of water temperature were 10.80mm, which was the best, while those grown in $29^{\circ}C$ of water temperature were 6.28mm, which was the lowest. The survival rates of red marbled rockfish larvae grown in $20^{\circ}C$ and $23^{\circ}C$ were 24.0% and 18.5%, respectively. However, the survival rate of red marbled rockfish larvae grown in $26^{\circ}C$ was $7^{\circ}C$ and no larvae survived in $29^{\circ}C$. The total length of red marvled rockfish larva stocked at the density of 5 and 10 larvaper liter of water were high, which were 11.52 mm and 11.22 mm, respectively, but those stocked at the density of 30 larva per liter of water were 7.55mm, which was the lowest. The survival rate of red marbled rockfish larva stocked at the density of 2.5 larva per liter of water was 52.0%, which was the best, but the lowest, 18.0% for the red marbled rockfish larva stocked at the density of 30 larva per liter. There was a trend toward decrease in survival rate of red marbled rockfish larva as their stocking density increased. The survival rates of red marbled rockfish larva fed rotifers at the density of 10 and 5 individuals per ml were high, 48.5% and 48.0%, and their total lengths were 11.92 and 11.89mm, respectively, which grew relatively fast. The survival rate and the total length of red marbled rockfish larva fed rotifers at the density of 30 individuals per ml were the lowest, which were 8.40mm and 21.5%, respectively. Also, red marbled rockfish larva fed rotifers at the density of more than 20 individuals per ml achieved poor survival and growth. These results indicated that the proper conditions for the mass production of larval red marbled rockfish were $23^{\circ}C$ of water temperature, fish larva stocking density of 5 to 10 larva per liter of water and rotifers density of 5 to 10 individuals per ml as live feed.

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