• Title/Summary/Keyword: Water Splitting

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Physical and Mechanical Properties of Permeable Polymer Concrete

  • Sung, Chan-Yong
    • Magazine of the Korean Society of Agricultural Engineers
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    • v.39 no.2
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    • pp.44-50
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    • 1997
  • Permeable polymer concrete can be applied to roads, sidewalks, river embankment, drain pipes, conduits, retaining walls, yards, parking lots, plazas, interlocking blocks, etc.. This study was to explore a possibility of using stone dust and heavy calcium carbonate as fillers for the permeable polymer concrete. Different mixing pro-portions were tried to find an optimum mixing proportion of the permeable polymer concrete. The tests were carried out at 20 f 1 t and 60 ${\pm}$ 2% relative humidity. At 7 days of curing, compressive, flexural and splitting tensile strengths and water permeability ranged between 209~246kgf/cm$^2$, 101 ~ l2lkgf/cm$^2$, 36~52kgf/cm$^2$ and 3.076 ~ 4.390L/cm$^3\;^2$/hr, respectively. It was concluded that the stone dust and heavy calcium carbonate could be used in the permeable polymer concrete.

Strength Characteristics of No-Fine Concrete Containing Recycled Aggregates (재생골재를 함유한 무잔골재 콘크리트의 강도특성)

  • 김태근;이광명;김낙경;고용일
    • Proceedings of the Korea Concrete Institute Conference
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    • 1998.10c
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    • pp.1-6
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    • 1998
  • Recently, as to destruction and renovation of aged building, waste concretes have been reclaimed near foreshore and filled up underground. Recycling demolished concrete as aggregate helps to settle economic and environmental problems of obtaining superior aggregates from natural sources and to dispose waste concretes. An experimental study was carried out to investigate the strength characteristics of no-fine concrete containing recycled aggregates. The cement-aggregate weight ratios of 1: 5, 1: 6, 1: 7 and water-cement ratios of 30, 35, 40, 45% were chosen for the mix design of no-fine concretes. The compressive and splitting tensile strength at 7 and 28 days were measured for 12 different mixes. On the basis of test results, the optimum mix proportion of no-fine concrete containing recycled aggregates was determined and applied to the production of retaining wall block.

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Fracture Behavior of Concrete Beam Subjected to Dynamic Loading (동적하중을 받는 콘크리트보의 파괴거동)

  • Kang, Sung-Hoo;Kim, Woo;Park, Sun-Joon
    • Proceedings of the Korea Concrete Institute Conference
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    • 1995.04a
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    • pp.257-262
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    • 1995
  • In this study, after concrete cylinders were made on the condition of varying water-to -cement ratio, and cured 80 days compressive strength and splitting tensile strength were performed and moduls of elasticy is obtained. The fracture energy was obtained by acting three point bending on the 80cm in length. This test involved static loading test and dynamic loading test. In this work, the new interrelation of the material constants was obtained clearly and the property of the mixture was inspected, including the relation between the fracture energy and all kind of the material constants.

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Effect of Metakaolin Content on the Properties of High Strength Concrete

  • Dinakar, P.;Sahoo, Pradosh K.;Sriram, G.
    • International Journal of Concrete Structures and Materials
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    • v.7 no.3
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    • pp.215-223
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    • 2013
  • This study presents the effect of incorporating metakaolin (MK) on the mechanical and durability properties of high strength concrete for a constant water/binder ratio of 0.3.MK mixtures with cement replacement of 5, 10 and 15 % were designed for target strength and slump of 90 MPa and $100{\pm}25mm$. From the results, it was observed that 10 % replacement level was the optimum level in terms of compressive strength. Beyond 10 %replacement levels, the strength was decreased but remained higher than the control mixture. Compressive strength of 106 MPa was achieved at 10 % replacement. Splitting tensile strength and elastic modulus values have also followed the same trend. In durability tests MK concretes have exhibited high resistance compared to control and the resistance increases as the MK percentage increases. This investigation has shown that the local MK has the potential to produce high strength and high performance concretes.

Design of Heat Exchanger for Section 3 of SI Hydrogen Production Process (SI 수소생산 공정 Section 3 열교환기 설계)

  • Kim, Ki-Sub;Park, Byung Heung
    • Journal of Institute of Convergence Technology
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    • v.7 no.1
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    • pp.19-22
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    • 2017
  • SI process is one of the most advanced thermochemical water splitting cycles enabling mass production of hydrogen without emitting carbon dioxide when coupled to nuclear heat energy. The highest temperature (close to $1000^{\circ}C$) required in SI process is well matched with the outlet temperature of a coolant circulating a high-temperature gas-cooled reactor at around $950^{\circ}C$. In Section 3, some heat exchangers are included to recover heats from process flows at high temperature. In this work, we designed a heat exchanger based on the $1Nm^3/hr$ $H_2$ production capacity using commercial tools for chemical process design.

Application of Thermodynamic Models for Analysis on SI Thermochemical Hydrogen Production Process (SI 열화학 수소 생산 공정의 분석을 위한 열역학 모델의 적용)

  • Lee, Jun Kyu;Kim, Ki-Sub;Park, Byung Heung
    • Journal of Institute of Convergence Technology
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    • v.2 no.2
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    • pp.30-34
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    • 2012
  • The SI thermochemical cycle process accomplishes water splitting through distinctive three chemical reactions. We focused on thermodynamic models applicable to the process. Recently, remarkable models based on the assumed ionic species have been developed to describe highly nonideal behavior on the liquid phase reactions. ElecNRTL models with ionic reactions were proposed in order to provide reliable process simulation results for phase equilibrium calculations in Section II and III. In this study, the current thermodynamic models of SI thermochemical cycle process were briefly described and the calculation results of the applied ElecNRTL models for phase equilibrium calculations were illustrated for binary systems.

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전기투석과 확산투석을 이용한 공정개발

  • 문승현
    • Proceedings of the Membrane Society of Korea Conference
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    • 1996.10a
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    • pp.8-11
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    • 1996
  • 전기투석은 역삼투압, 한외여과와 함께 가장 많이 이용되고 막공정 중의 하나이다. 전기투석은 다른 막공정과 같이 막의 선택성에 의한 분리조작이며 병렬식 배열에 의한 막의 이용이 가능하고 막오염 현상이 있으며 따라서 막-유체간의 접촉에 대한 제어가 필요하다. 전기투석은 운전목적에 따라 desalting electrodialysis(ED)와 water-splitting electrodiaiysis(WSED)로 구분할 수 있다. Desalting electrodialysis는 고전적 의미의 탈염을 위한 전기투석공정이며 WSED는 bipolar membrane을 이용하여 염을 산과 염기로 분리시키는 기능을 갖는 전기투석 공정을 말한다. WSED는 전기적으로 물을 분리한다는 의미로서 Electrohydrolysis로 불리기도 한다. WSED의 기본원리는 bipolar membrane의 양쪽면에서 수소이옹과 수산이온을 발생시켜 산 또는 염기용액으로 전달하고 bipolar membrane에 접하고 있는 양이온 또는 음이온 교환막에서는 각 용액의 전기적 중성을 유지하기 위해 대응하는 이온을 투과시키는 것이다. WSED는 염으로부터 산 염기제조 뿐만아니라 염의 형태로 생성되는 유기산, 아미노산 등 발효생성물의 회수 또는 acidification에 이용되고 있다.

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Mechanical and Durability Performance of Roller-Compacted Concrete with Fly Ash for Dam Applications

  • Park, Chan-Gi;Yoon, Jong-Whan;Kim, Wan-Young;Won, Jong-Pil
    • International Journal of Concrete Structures and Materials
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    • v.1 no.1
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    • pp.57-61
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    • 2007
  • This study investigated the mechanical and durability performance of roller-compacted concrete (RCC) with fly ash for dam applications. A test program studied the effects on the properties of fresh and hardened RCC with fly ash replacement ratio, as well as the long-term durability of the resulting mixture. Fly ash replaced 20, 30, 40, and 50% by mass of the cement. Laboratory tests of the compressive strength, splitting tensile strength, shear strength, chloride ion permeability, abrasion, and drying shrinkage were conducted. The test results demonstrated that 30% fly ash replacement is an optimum level, and that this mixture has excellent mechanical and durability properties.

Fabrication of Metal-Semiconductor Interface in Porous Silicon and Its Photoelectrochemical Hydrogen Production

  • Oh, Il-Whan;Kye, Joo-Hong;Hwang, Seong-Pil
    • Bulletin of the Korean Chemical Society
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    • v.32 no.12
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    • pp.4392-4396
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    • 2011
  • Porous silicon with a complex network of nanopores is utilized for photoelectrochemical energy conversion. A novel electroless Pt deposition onto porous silicon is investigated in the context of photoelectrochemical hydrogen generation. The electroless Pt deposition is shown to improve the characteristics of the PS photoelectrode toward photoelectrochemical $H^+$ reduction, though excessive Pt deposition leads to decrease of photocurrent. Furthermore, it is found that a thin layer (< 10 ${\mu}m$) of porous silicon can serve as anti-reflection layer for the underlying Si substrate, improving photocurrent by reducing photon reflection at the Si/liquid interface. However, as the thickness of the porous silicon increases, the surface recombination on the dramatically increased interface area of the porous silicon begins to dominate, diminishing the photocurrent.

Single Nanoparticle Photoluminescence Studies of Visible Light-Sensitive TiO2 and ZnO Nanostructures

  • Yoon, Minjoong
    • Rapid Communication in Photoscience
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    • v.2 no.1
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    • pp.9-17
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    • 2013
  • Visible light-sensitive $TiO_2$ and ZnO nanostructure materials have attracted great attention as the promising material for solar energy conversion systems such as photocatalysts for water splitting and environmental purification as well as nano-biosensors. Success of their applications relies on how to control their surface state behaviors related to the exciton dynamics and optoelectronic properties. In this paper, we briefly review some recent works on single nanoparticle photoluminescence (PL) technique and its application to observation of their surface state behaviors which are raveled by the conventional ensemble-averaged spectroscopic techniques. This review provides an opportunity to understand the temporal and spatial heterogeneities within an individual nanostructure, allowing for the potential use of single-nanoparticle approaches in studies of their photoenergy conversion and nano-scale optical biosensing.