• Title/Summary/Keyword: Water Resistivity

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Mechanical Performance Evaluation of Concrete with Recycled Coarse Aggregate Selected by Multi-stage Wind Pressure (다단형 풍압처리에 의해 선별된 순환굵은골재 적용 콘크리트의 역학적 성능 평가)

  • Chu, Young-Kyu;Lee, Seung-Tae;Lee, Se-Hyun
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.10 no.1
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    • pp.1-8
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    • 2022
  • In this study, the mechanical properties of concrete with recycled coarse aggregate (RG) selected by multi-stage wind pressure (MSWP) treatment were evaluated. After evaluating the basic properties of natural and recycled coarse aggregates, the mechanical performance of the recycled coarse aggregates concrete was experimentally investigated. As a result, it was found that the MSWP technique could improve the fundamental properties such as density and water absorption of RG. In addition, the concrete with RG selected by MSWP showed a better mechanical performance, indicating a higher strength values, surface electric resistivity and a lower absorption. Thus, it seems that the MSWP technique can be effective for the production of high-quality RG.

Synthesis and physical properties of Pb10-xCux(PO4)6O: A weak diamagnetic material

  • Yoonseok Han;Taehee Lee;Junwon Rhie;Jaegu Song;Seung-Yeop Paek;Seokmin Choi;Yongmin Kim;Sungmin Park;Hanoh Lee;Tuson Park
    • Progress in Superconductivity and Cryogenics
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    • v.26 no.2
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    • pp.5-8
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    • 2024
  • Recently, Lee et al. claimed that LK-99 isthe first room-temperature superconductor at ambient pressure, which quickly captured the attention of both the scientific community and the general public. We tried to replicate Pb10-xCux(PO4)6O, called as LK-99, and characterized its physical properties by measuring the electrical resistance and Meissner effect. The electrical resistance results for different batches exhibited structural phase transitions at different temperatures, and the magnetic measurements indicated weak diamagnetism at 300 K, which is weaker than that of water. Taken together with the structural analysis, these results suggest that the resistivity transitions are incurred by Cu-S compound generated as a byproduct during the synthesis of LK-99 and LK-99 is not a room-temperature superconductor.

Microstructures and Thermal Properties of Water Quenched Thermoelectric Material in Bi2Te3-PbTe System (급속 응고 된 Bi2Te3-PbTe계 열전소재의 미세구조와 열전 특성)

  • Yim, Ju-Hyuk;Jung, Kyoo-Ho;You, Hyun-Woo;Kim, Kwang-Chon;Kim, Jin-Sang
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.23 no.6
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    • pp.502-507
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    • 2010
  • In order to design nano structured materials with enhanced thermoelectric properties, the alloys in the pseudo-binary $Bi_2Te_3$-PbTe system are investigated for their micro structure properties. For this synthesis, the liquid alloys are cooled by the water quenching method. Micro structure images are obtained by using an electron probe micro analyzer(EPMA). Dendritic and lamellar structures are clearly observed with the variation in the composition ratio between $Bi_2Te_3$ and PbTe. The increase in the $Bi_2Te_3$ composition ratio causes to change of the structure from dendritic to lamellar. The Seebeck coefficient of sample 5, in which the mixture rate of $Bi_2Te_3$ is 83%, is measured as the highest value. In contrast, the others decrease with the increase of the $Bi_2Te_3$ composition ratio. Meanwhile, p-type characteristics are observed in sample 6, at 91%-$Bi_2Te_3$ mixture rate. The power factors of the all samples are calculated with the Seebeck coefficient and resistivity.

Impact of aggressive exposure conditions on sustainable durability, strength development and chloride diffusivity of high performance concrete

  • Al-Bahar, Suad;Husain, A.
    • Structural Monitoring and Maintenance
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    • v.2 no.1
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    • pp.35-48
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    • 2015
  • The main objective of this study is to evaluate the long-term performance of various concrete composites in natural marine environment prevailing in the Gulf region. Durability assessment studies of such nature are usually carried out under aggressive environments that constitute seawater, chloride and sulfate laden soils and wind, and groundwater conditions. These studies are very vital for sustainable development of marine and off shore reinforced concrete structures of industrial design such as petroleum installations. First round of testing and evaluation, which is presented in this paper, were performed by standard tests under laboratory conditions. Laboratory results presented in this paper will be corroborated with test outcome of ongoing three years field exposure conditions. The field study will include different parameters of investigation for high performance concrete including corrosion inhibitors, type of reinforcement, natural and industrial pozzolanic additives, water to cement ratio, water type, cover thickness, curing conditions, and concrete coatings. Like the laboratory specimens, samples in the field will be monitored for corrosion induced deterioration signs and for any signs of failureover initial period ofthree years. In this paper, laboratory results pertaining to microsilica (SF), ground granulated blast furnace slag (GGBS), epoxy coated rebars and calcium nitrite corrosion inhibitor are very conclusive. Results affirmed that the supplementary cementing materials such as GGBS and SF significantly impacted and enhanced concrete resistivity to chloride ions penetration and hence decrease the corrosion activities on steel bars protected by such concretes. As for epoxy coated rebars applications under high chloride laden conditions, results showed great concern to integrity of the epoxy coating layer on the bar and its stability. On the other hand corrosion inhibiting admixtures such as calcium nitrite proved to be more effective when used in combination with the pozzolanic additives such as GGBS and microsilica.

The Physical Properties Variation of Grout Materials and Improvement of Grouting Effects on Application of High Performance Injection Equipment (고성능 주입장비의 적용에 따른 주입재의 물성변화 및 주입효과 증진에 관한 연구)

  • 천병식;김진춘;김백영
    • Journal of the Korean Geotechnical Society
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    • v.19 no.4
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    • pp.179-190
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    • 2003
  • The grout based on solution type makes it difficult to get the improvement of ground strength and the effefct of water curtain because it has lower strength and durability than suspension type. Nowadays, the technology of particle acceleration, that enhance the material permeability, such as grout based on solution type, and inexpensive grout, is being required. For these reasons, in this study, using wet milling system, we evaluated physical properties of manufactured factors such as water-cement ratio of particles before being milled, optimum milling capacity by controlling milling time and rpm, viscosity of materials, permeation coefficient, and unconfined compressive strength. Also, using micro wet milling apparatus which could manufacture ordinary Portland cement and high speed shear mix which could forcefully separate conglomerate particles in situ, we performed electrical resistivity investigation and falling head permeability tests to analyze differences of grouting effects. From these results, we found that the permeability of the applied equipment was much superior, and in the case of using high speed shear mixer, particles of grout material were well separated.

Regression and ANN models for durability and mechanical characteristics of waste ceramic powder high performance sustainable concrete

  • Behforouz, Babak;Memarzadeh, Parham;Eftekhar, Mohammadreza;Fathi, Farshid
    • Computers and Concrete
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    • v.25 no.2
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    • pp.119-132
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    • 2020
  • There is a growing interest in the use of by-product materials such as ceramics as alternative materials in construction. The aim of this study is to investigate the mechanical properties and durability of sustainable concrete containing waste ceramic powder (WCP), and to predict the results using artificial neural network (ANN). In this order, different water to binder (W/B) ratios of 0.3, 0.4, and 0.5 were considered, and in each W/B ratio, a percentage of cement (between 5-50%) was replaced with WCP. Compressive and tensile strengths, water absorption, electrical resistivity and rapid chloride permeability (RCP) of the concrete specimens having WCP were evaluated by related experimental tests. The results showed that by replacing 20% of the cement by WCP, the concrete achieves compressive and tensile strengths, more than 95% of those of the control concrete, in the long term. This percentage increases with decreasing W/B ratio. In general, by increasing the percentage of WCP replacement, all durability parameters are significantly improved. In order to validate and suggest a suitable tool for predicting the characteristics of the concrete, ANN model along with various multivariate regression methods were applied. The comparison of the proposed ANN with the regression methods indicates good accuracy of the developed ANN in predicting the mechanical properties and durability of this type of concrete. According to the results, the accuracy of ANN model for estimating the durability parameters did not significantly follow the number of hidden nodes.

Performance of High-Flowable Retaining Wall Material Using Ground Granulated Blast-Furnace Slag and Steel Fiber (고로슬래그미분말 및 강섬유를 적용한 고유동 흙막이 벽체 재료의 성능 평가)

  • Kim, Donggyou;Yu, Kangmin;Lee, Seungtae
    • Journal of the Korean GEO-environmental Society
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    • v.23 no.11
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    • pp.5-11
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    • 2022
  • The objective of this study is to evaluate the mechanical properties of high-flowable retaining wall material (RWM) incorporated with ground granulated blast-furnace slag (SG) and steel fiber (SF) based on a comparison with those of ordinary portland cement (OPC). To produce the specimens of RWM, some chemical agents such as superplasticizer (SP), air-entrained agent (AEA) and viscosity modifying agent (VMA) are added in the fresh RWM. The compressive, split tensile and flexural strength measurements were performed on the hardened RWM specimens. Additionally, surface electric resistivity and absorption tests according to ASTM standards were carried out at predetermined periods after water curing. It was found that the mechanical properties of slag cement concrete (SGC) RWM mix are better than those ordinary portland cement concrete (OPC) RWM mix. The effect of SF is remarkable to improve the mechanical properties of RWM mixes. It is noted that the usage of SG shows a beneficial effect to resist water penetration as well as long-term strength development of RWM mixes.

New Approaches for Overcoming Current Issues of Plasma Sputtering Process During Organic-electronics Device Fabrication: Plasma Damage Free and Room Temperature Process for High Quality Metal Oxide Thin Film

  • Hong, Mun-Pyo
    • Proceedings of the Korean Vacuum Society Conference
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    • 2012.02a
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    • pp.100-101
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    • 2012
  • The plasma damage free and room temperature processedthin film deposition technology is essential for realization of various next generation organic microelectronic devices such as flexible AMOLED display, flexible OLED lighting, and organic photovoltaic cells because characteristics of fragile organic materials in the plasma process and low glass transition temperatures (Tg) of polymer substrate. In case of directly deposition of metal oxide thin films (including transparent conductive oxide (TCO) and amorphous oxide semiconductor (AOS)) on the organic layers, plasma damages against to the organic materials is fatal. This damage is believed to be originated mainly from high energy energetic particles during the sputtering process such as negative oxygen ions, reflected neutrals by reflection of plasma background gas at the target surface, sputtered atoms, bulk plasma ions, and secondary electrons. To solve this problem, we developed the NBAS (Neutral Beam Assisted Sputtering) process as a plasma damage free and room temperature processed sputtering technology. As a result, electro-optical properties of NBAS processed ITO thin film showed resistivity of $4.0{\times}10^{-4}{\Omega}{\cdot}m$ and high transmittance (>90% at 550 nm) with nano- crystalline structure at room temperature process. Furthermore, in the experiment result of directly deposition of TCO top anode on the inverted structure OLED cell, it is verified that NBAS TCO deposition process does not damages to the underlying organic layers. In case of deposition of transparent conductive oxide (TCO) thin film on the plastic polymer substrate, the room temperature processed sputtering coating of high quality TCO thin film is required. During the sputtering process with higher density plasma, the energetic particles contribute self supplying of activation & crystallization energy without any additional heating and post-annealing and forminga high quality TCO thin film. However, negative oxygen ions which generated from sputteringtarget surface by electron attachment are accelerated to high energy by induced cathode self-bias. Thus the high energy negative oxygen ions can lead to critical physical bombardment damages to forming oxide thin film and this effect does not recover in room temperature process without post thermal annealing. To salve the inherent limitation of plasma sputtering, we have been developed the Magnetic Field Shielded Sputtering (MFSS) process as the high quality oxide thin film deposition process at room temperature. The MFSS process is effectively eliminate or suppress the negative oxygen ions bombardment damage by the plasma limiter which composed permanent magnet array. As a result, electro-optical properties of MFSS processed ITO thin film (resistivity $3.9{\times}10^{-4}{\Omega}{\cdot}cm$, transmittance 95% at 550 nm) have approachedthose of a high temperature DC magnetron sputtering (DMS) ITO thin film were. Also, AOS (a-IGZO) TFTs fabricated by MFSS process without higher temperature post annealing showed very comparable electrical performance with those by DMS process with $400^{\circ}C$ post annealing. They are important to note that the bombardment of a negative oxygen ion which is accelerated by dc self-bias during rf sputtering could degrade the electrical performance of ITO electrodes and a-IGZO TFTs. Finally, we found that reduction of damage from the high energy negative oxygen ions bombardment drives improvement of crystalline structure in the ITO thin film and suppression of the sub-gab states in a-IGZO semiconductor thin film. For realization of organic flexible electronic devices based on plastic substrates, gas barrier coatings are required to prevent the permeation of water and oxygen because organic materials are highly susceptible to water and oxygen. In particular, high efficiency flexible AMOLEDs needs an extremely low water vapor transition rate (WVTR) of $1{\times}10^{-6}gm^{-2}day^{-1}$. The key factor in high quality inorganic gas barrier formation for achieving the very low WVTR required (under ${\sim}10^{-6}gm^{-2}day^{-1}$) is the suppression of nano-sized defect sites and gas diffusion pathways among the grain boundaries. For formation of high quality single inorganic gas barrier layer, we developed high density nano-structured Al2O3 single gas barrier layer usinga NBAS process. The NBAS process can continuously change crystalline structures from an amorphous phase to a nano- crystalline phase with various grain sizes in a single inorganic thin film. As a result, the water vapor transmission rates (WVTR) of the NBAS processed $Al_2O_3$ gas barrier film have improved order of magnitude compared with that of conventional $Al_2O_3$ layers made by the RF magnetron sputteringprocess under the same sputtering conditions; the WVTR of the NBAS processed $Al_2O_3$ gas barrier film was about $5{\times}10^{-6}g/m^2/day$ by just single layer.

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The comparative study of pure and pulsed DC plasma sputtering for synthesis of nanocrystalline Carbon thin films

  • Piao, Jin Xiang;Kumar, Manish;Javid, Amjed;Wen, Long;Jin, Su Bong;Han, Jeon Geon
    • Proceedings of the Korean Vacuum Society Conference
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    • 2016.02a
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    • pp.320-320
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    • 2016
  • Nanocrystalline Carbon thin films have numerous applications in different areas such as mechanical, biotechnology and optoelectronic devices due to attractive properties like high excellent hardness, low friction coefficient, good chemical inertness, low surface roughness, non-toxic and biocompatibility. In this work, we studied the comparison of pure DC power and pulsed DC power in plasma sputtering process of carbon thin films synthesis. Using a close field unbalanced magnetron sputtering system, films were deposited on glass and Si wafer substrates by varying the power density and pulsed DC frequency variations. The plasma characteristics has been studied using the I-V discharge characteristics and optical emission spectroscopy. The films properties were studied using Raman spectroscopy, Hall effect measurement, contact angle measurement. Through the Raman results, ID/IG ratio was found to be increased by increasing either of DC power density and pulsed DC frequency. Film deposition rate, measured by Alpha step measurement, increased with increasing DC power density and decreased with pulsed DC frequency. The electrical resistivity results show that the resistivity increased with increasing DC power density and pulsed DC frequency. The film surface energy was estimated using the calculated values of contact angle of DI water and di-iodo-methane. Our results exhibit a tailoring of surface energies from 52.69 to $55.42mJ/m^2$ by controlling the plasma parameters.

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Delineation of the Slip Weak Zone of Land Creeping with Integrated Geophysical Methods and Slope Stability Analysis (복합 지구물리탐사와 사면 안정해석 자료를 이용한 땅밀림 지역의 활동연약대 파악)

  • Lee, Sun-Joong;Kim, Ji-Soo;Kim, Kwan-Soo;Kwon, Il-Ryong
    • The Journal of Engineering Geology
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    • v.30 no.3
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    • pp.289-302
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    • 2020
  • To determine the shallow subsurface structure and sliding surface of land creeping in 2016 at Hadong-gun, Gyeongsangnam-do, geophysical surveys (electric resistivity, and refraction seismic methods, borehole televiewer) and slope stability analysis were conducted. The subsurface structure delineated with borehole lithologies and seismic velocity structures provided the information that the sediment layer on the top of the slope was rather as thick as 20 m and the underlying weathered rock (anorthosite) was thinner than 1 m. Based on the tension cracks observed during the geological mapping, televiewer scanning was performed at the borehole BH-2 and detected the intensive fracture zones at the ground-water level, associated with the slip weak zones mapped in dipole-dipole electrical resistivity section. Downslope sliding and slightly upward pushing at the apex of high resistive bedrock explains the curved slip plane of the land creeping. Such a convex structure might play a role of natural toe abutment for preventing the downward development of slip weak zones. In slope stability analysis, the safety factors of the slip weak zone are calculated with varying the groundwater levels for dry and rainy seasons and the downslope is founded to be unstable with safety factor of 0.89 due to fully saturated material in rainy season.