• Journal of the Optical Society of Korea
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• 제14권3호
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• pp.209-214
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• 2010

The Raman shift of water vapor is 3657 $cm^{-1}$, and this Raman signal can be easily separated from other Raman signals or elastic signals. However, it is difficult to make simultaneous Raman measurements on the three phases of water, namely, ice water, liquid water, and water vapor. This is because we must consider the overlap between their Raman spectra. Therefore, very few groups have attempted to make Raman simultaneous measurements even on two elements (water vapor and liquid water, or water vapor and ice water). We have made an effort to find three characteristic Raman wavelengths that correspond to the three phases of water after measuring full Raman spectra of water on particular days that are rainy, snowy or clear. Finally, we have found that the 401-nm, 404-nm, and 408-nm wavelengths are the most characteristic Raman wavelengths that are representative of the water phases when we are using the 355-nm laser wavelength for making measurements.

• 대한기계학회논문집B
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• 제23권5호
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• pp.621-627
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• 1999

This paper presents Raman scattering of liquid water to obtain the characteristics with variation of temperature. Very clear Stokes-Raman signals were observed, which shows H-O vibration stretching and H-O-H vibration bending. The obtained spectrum were processed by FFT filter to extract the noise and base. The spectral shape of the H-O stretching provided a various sensitive signature which allowed temperature to be determined by a curve-fitting technique. Those are Maximum Intensity, Maximum Wave Length, FWHM(Full Width at Half Maximum), PMCR(Polymer Monomer Concentration Ratio) and TSIR(Temperature Sensitive Intensity Ratio). TSIR method shows the highest accuracy of $0.1^{\circ}C$ in mean error and $0.32^{\circ}C$ In maximum error.

• Bulletin of the Korean Chemical Society
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• 제29권6호
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• pp.1247-1249
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• 2008

• 한국광학회지
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• 제6권4호
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• pp.337-344
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• 1995

Q 스위칭 Nd:YAG 레이저 빔을 펌프광으로 하여 $35~62{\mu}m$ 크기의 물방울에서의 공명 유도라만산란 신호를 검출하였다. 신호광은 간격이 일정한 peak들의 형태로 나타났고 방울크기가 커질수록 그 간격이 좁아짐을 관측하였다. 또한 두 물방울을 결합하면서 유도라만산란 신호를 검출한 결과 결합된 물방울이 거의 구의 형태가 될 때 신호광이 공명 특성을 띠게 됨을 확인하였다. 실험으로 측정한 같은 모드순서의 공명모드 사이의 간격오차는 약 5%였다.

• KSBB Journal
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• 제11권5호
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• pp.557-564
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• 1996

Contact lens 재료물질로 사용되어지는 poly(2 h hydroxyethylmethacrylate), poly (HEMA) 는 물을 약 45퍼센트 포함하여 수화젤(hydrogel)을 만들 수 있는 고분자 물질이다. Poly(HEMA)와 단백질의 구성물질인 수용성 아미노산(alanine, argmme, glycine, lysine, methionine, proline, serine)과의 상호작용력과 작용위치에 대한 실험을 FT - IR과 R Raman 분광법을 사용하여 행한 결과 Arg과 Lys 이 가장 크게 작용하였고, 작용크기는 각 pH에 따라 존재하는 이온종과 양에 관계되며, 작용위치는 주로 poly(HEMA) 내에 존재하는 히드록시기에서 일어났다.

• 한국진공학회지
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• 제12권S1호
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• pp.49-51
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• 2003

Amorphous hydrous ruthenium oxide thin films have attracted much interest owing to the possibility of using this material in electrochemical supercapacitors. Recently, it was found that this material is also electrochromic: during the charging/discharging cycle, the optical transmittance of the thin film is modulated. The physical and chemical origin of this phenomenon is not fully understood yet. In this work, we performed in-situ Raman spectroscopy measurements on amorphous hydrous ruthenium oxide thin films during the charging/discharging cycles. Unambiguous changes in the Raman spectrum were observed as protons were injected or extracted from the thin film. When the samples were annealed to reduce the water content, there is a consistent trend in the Raman spectrum. The origins of the Raman features and their relation to the electrochromic and/or supercapacitor characteristics is discussed.

• 한국정보통신학회:학술대회논문집
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• 한국정보통신학회 2012년도 춘계학술대회
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• pp.158-161
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• 2012

대기 중 에어로졸과 수증기 농도를 측정하기 위한 라만방식 레이저 레이다 시스템을 개발하였다. 송신시스템은 Nd:YAG laser 3rd harmonic Generator 및 빔 확대기로 구성되며, 대기 중에 송신되는 파장은 355 nm 이다. 수신시스템은 500 mm 망원경과 3채널 분광기, 광전자증배관 검출기 및 신호처리모듈로 구성되며 최종적으로 처리되는 신호의 파장은 355 nm. 387 nm, 그리고 408 nm 이다. 본 시스템은 대기권의 수증기의 수직 농도분포를 약 100~200 m 의 분해능과 3~4 km의 가 측정거리를 가지고 측정할 수 있다.

• 센서학회지
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• 제31권4호
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• pp.266-270
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• 2022

Owing to the rising volume of seaborne trade, oil spills damage the marine environment for over 250 yearly. Thus, various analysis methods such as the Fourier-transform infrared (FTIR), Raman spectroscope, and gas chromatography are used to monitor oil spills at sea, but these methods are expensive. Recently, to reduce operational costs, an underwater fluorometer was adopted. However, this approach is not ideal for the remote sensing of oil spills because the device gets submerged in the sea. In this study, we have designed and developed a monitoring system that uses ultraviolet fluorescence to detect spilled oil or water from a distance, as well as proposed an analyzing method defining based on water Raman signal and QF535. Each fluorescence spectrum of water, oil (crude oil), and Bunker A was obtained using the system, and was calculated and analyzed from the spectrum individually. Based on the results of the analysis, we could successfully identity water and oil at a long distance.

• Current Optics and Photonics
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• 제2권1호
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• pp.15-22
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• 2018

To measure atmospheric temperature, water vapor, and aerosol simultaneously, an efficient multi-function Raman lidar using an ultraviolet-wavelength laser has been developed. A high-performance spectroscopic box that utilizes multicavity interference filters, mounted sequentially at small angles of incidence, is used to separate the lidar return signals at different wavelengths, and to extract the signals with high efficiency. The external experiments are carried out for simultaneous detection of atmospheric temperature, water vapor, and aerosol extinction coefficient in Beijing, under clear and hazy weather conditions. The vertical profiles of temperature, water vapor, and aerosol extinction coefficient are analyzed. The results show that for an integration time of 5 min and laser energy of 200 mJ, the mean deviation between measurements obtained by lidar and radiosonde is small, and the overall trend is similar. The statistical temperature error for nighttime is below 1 K up to a height of 6.2 km under clear weather conditions, and up to a height of 2.5 km under slightly hazy weather conditions, with 5 min of observation time. An effective range for simultaneous detection of temperature and water vapor of up to 10 km is achieved. The temperature-inversion layer is found in the low troposphere. Continuous observations verify the reliability of Raman lidar to achieve real-time measurement of atmospheric parameters in the troposphere.

• 한국광학회지
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• 제22권6호
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• pp.283-290
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• 2011

수증기의 혼합비를 측정하기 위하여 라만 라이다 시스템을 설계 제작하였다. 시스템을 검증하기 위하여 가강수량과 분포에 대하여 상용 마이크로파 라이오메터(MWR)와 GPS 신호를 이용하는 방법과 비교 연구를 수행하였다. GNSS 방법으로 측정한 총가강수량과 본 라이다 방법에서는 작은 차이를 보였는데, 이는 라이다 방법으로 얻을 수 있는 수증기의 측정고도가 제한적이기 때문이다. 반면에 MWR 방법과 라이다 방법으로 얻은 고도에 따른 수증기량은 수증기량이 급격하게 변하는 구름 경계나 경계고도 근처에서 심한 차이를 보이고 있었다. MWR은 그 밀도가 급격하게 변하는 곳에서 취약한 점을 보였으나 개발된 라만 라이다의 경우는 그 밀도가 급격히 변하는 곳에서도 측정이 원활하게 이루어지고 있음을 알 수 있었다.