• Title/Summary/Keyword: Water Purification Material

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Study on the Method of Estimating the Accumulation of Co-60 in Consideration of the Operating History of a NPP (원전 운전환경을 고려한 방사성폐기물 내 Co-60 재고량 평가 방안 연구)

  • Kim Tae-man;Whang Joo-ho
    • Proceedings of the Korean Radioactive Waste Society Conference
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    • 2005.06a
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    • pp.145-150
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    • 2005
  • To dispose of radwaste in a repository, the safety of disposal must be ensured. This study developed a program for estimating radionuclide accumulation of radwaste, based on the material balance method, one of the indirect methods, and performed application evaluation during the 9th preventive maintenance period of Gori Plant 4, one of the commercial power plants in Korea. First of all, to ensure the technique developed in this study is assessed accurately, this study utilized the data regarding the radionuclide removal in the purification system during the shutdown water chemistry control, and a related estimation technique called SCALP. The target nuclide was Co-60, and it turned out that the relative error was less than $1\%$. The estimation result was compared with the result of direct measurement of the radwaste during the corresponding period as presented by commercial power plants. The result showed that the quantity of Co-60 measured by the direct method was about $50\%$ less than that calculated by the technique developed in this study.

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Reduction of perchlorate in aqueous solution using zero valence iron stabilized with alginate bead (알지네이트 비드를 이용하여 안정화한 0가 철의 수용액 상에서의 과염소산 이온의 환원 분해 특성)

  • Joo, Tae-Kyeong;Lee, Jong-Chol;Paeng, Ki-Jung
    • Analytical Science and Technology
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    • v.23 no.6
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    • pp.560-565
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    • 2010
  • Perchlorate ion ($ClO_4^-$) has been widely used as oxidizing agent in military weapon system such as rocket and missile fuel propellant. So it has been challenging to remove the pollutant of perchlorate ion. nanoscale zero valence iron (nZVI) particles are widely employing reduction catalyst for decomposition of perchlorate ion. nZVI particles has increasingly been utilized in groundwater purification and waste water treatment. But it have strong tendency of aggregation, rapid sedimentation and limited mobility. In this study, we focused on reduction of perchlorate ion using nZVI particles immobilized in alginate polymer bead for stabilization. The stabilized nZVI particles displayed much greater surface area, and much faster reaction rates of reduction of perchlorate ion. In this study, an efficient way to immobilize nZVI particles in a support material, alginate bead, was developed by using $Ca^{2+}$ as the cross-linking cations. The efficiency and reusability of the immobilized Fe-alginate beads on the reduction of perchlorate was tested at various temperature conditions.

Study on the narrowed nanopores of anodized aluminum oxide template by thin-film deposition using e-beam evaporation (전자빔 증발법 박막 증착을 이용한 양극 산화 알루미늄 템플릿의 나노 포어 가공 연구)

  • Lee, Seung-Hun;Lee, Minyoung;Kim, Chunjoong;Kim, Kwanoh;Yoon, Jae Sung;Yoo, Yeong-Eun;Kim, Jeong Hwan
    • Journal of Surface Science and Engineering
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    • v.54 no.1
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    • pp.25-29
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    • 2021
  • The fabrication of nanopore membrane by deposition of Al2O3 film using electron-beam evaporation, which is fast, cost-effective, and negligible dependency on substance material, is investigated for potential applications in water purification and sensors. The decreased nanopore diameter owing to increased wall thickness is observed when Al2O3 film is deposited on anodic aluminum oxide membrane at higher deposition rate, although the evaporation process is generally known to induce a directional film deposition leading to the negligible change of pore diameter and wall thickness. This behavior can be attributed to the collision of evaporated Al2O3 particles by the decreased mean free path at higher deposition rate condition, resulting in the accumulation of Al2O3 materials on both the surface and the edge of the wall. The reduction of nanopore diameter by Al2O3 film deposition can be applied to the nanopore membrane fabrication with sub-100 nm pore diameter.

Solid Phase Extraction(SPE) of Curcuminoids from Turmeric by Optimization Analytical Condition (최적 분석조건에 의한 강황으로부터 Curcuminoids의 고체상추출(SPE))

  • Lee, Kwang Jin;Ma, Jin Yeul;Kim, Young Jun;Kim, Young Sik
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.13 no.10
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    • pp.4927-4935
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    • 2012
  • Turmeric is a medicinal herb with various pharmacological activities. Curcumin, demethoxycurcumin(DMC) and bisdemethoxycurcumin(BDMC) were extracted from turmeric by dipping and ultrasonic wave method. And extraction efficiency was identified using solid phase extraction(SPE). The extracted sample were simultaneously separated and analyzed from three kinds of commercial $C_{18}$ reversed-phase high performance liquid chromatography using water and acetonitrile as mobile phase with isocratic elution mode. Flow rate 1.0mL/min, injection volume $10{\mu}L$ and column oven temperature $40^{\circ}C$ at 425nm wavelength has been conducted. From the experimental results, the optimum mobile phase composition of water/acetonitrile 50/50vol% using RS tech column. It is evident that the amount of curcuminoids extracted(extraction time 4h) by 100% MeOH was higher than any aqueous MeOH composition. Finally, in 100% water extraction, the amount(mAU${\times}$mim) of curcuminoids extracted by SPE was 14.3 and 24.5 times respectively higher than ultrasonic wave and dipping method. The shown results can be applied as sources for pharmaceuticals and functional material.

Engineering Approach to Crop Production in Space (우주에서 작물 생산을 위한 공학적 접근)

  • Kim Yong-Hyeon
    • Journal of Bio-Environment Control
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    • v.14 no.3
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    • pp.218-231
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    • 2005
  • This paper reviews the engineering approach needed to support humans during their long-term missions in space. This approach includes closed plant production systems under microgravity or low pressure, mass recycling, air revitalization, water purification, waste management, elimination of trace contaminants, lighting, and nutrient delivery systems in controlled ecological life support system (CELSS). Requirements of crops f3r space use are high production, edibility, digestibility, many culinary uses, capability of automation, short stems, and high transpiration. Low pressure on Mars is considered to be a major obstacle for the design of greenhouses fer crop production. However interest in Mars inflatable greenhouse applicable to planetary surface has increased. Structure, internal pressure, material, method of lighting, and shielding are principal design parameters for the inflatable greenhouse. The inflatable greenhouse operating at low pressure can reduce the structural mass and atmosphere leakage rate. Plants growing at reduced pressure show an increasing transpiration rates and a high water loss. Vapor pressure increases as moisture is added to the air through transpiration or evaporation from leaks in the hydroponic system. Fluctuations in vapor pressure will significantly influence total pressure in a closed system. Thus hydroponic systems should be as tight as possible to reduce the quantity of water that evaporates from leaks. And the environmental control system to maintain high relative humidity at low pressure should be developed. The essence of technologies associated with CELSS can support human lift even at extremely harsh conditions such as in deserts, polar regions, and under the ocean on Earth as well as in space.

Effective Costal Environmental Management by Conjugation of Modeling of Bio-Purification and Total Allowable Pollutant Loads in Masan Bay (생물정화기작과 총허용오염부하량을 연계한 마산만의 효율적 해양환경 개선방안)

  • Eom, Ki-Hyuk;Kim, Gui-Young;Lee, Won-Chan;Lee, Dae-In
    • Journal of the Korean Society for Marine Environment & Energy
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    • v.15 no.1
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    • pp.38-46
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    • 2012
  • This study carried out current status, characteristics, and problems of coastal environment management on semi-enclosed Masan Bay in Korea and suggests cost-effective and eco-friendly water quality management policy. The pollutants from terrestrial sources into the Bay have apparently environmental pollution problems, such as eutrophication, red tide, and hypoxia. The carrying capacity of the Bay is estimated by hydrodynamic model and ecosystem model, material circulation including bivalve in ecosystem is analyzed by the growth model of bivalve. The resulting reduction in the input load was found to be 50~90%, which is unrealistic. When the efficiency of water quality improvement through bivalve farming was assessed based on the autochthonous COD, 30.7% of the total COD was allochthonous COD and 69.3% was autochthonous COD. The overall autochthonous COD reduction rate by bivalve aquaculture farm was found to be about 6.7%. This study indicate that bivalve farming is about 31% less expensive than advanced treatment facilities that remove both nitrogen and phosphorous.

Phytochemical-based Tannic Acid Derivatives as Draw Solutes for Forward Osmosis Process (정삼투 공정의 유도용질로서의 식물 화학물질 기반의 탄닌산 유도체)

  • Kim, Taehyung;Ju, Changha;Kang, Hyo
    • Membrane Journal
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    • v.28 no.3
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    • pp.157-168
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    • 2018
  • Potassium tannate (TA-K), which is prepared by base treatment of the bio-renewable tannic acid (TA), was evaluated for its potential application as a draw solute for water purification by forward osmosis. The forward osmosis and recovery properties of TA-K were systematically investigated. In the application of forward osmosis through the active layer facing feed solution (AL-FS) method, the water flux of TA-K draw solution was significantly higher than that of the TA draw solution, while that of the latter was not identified. At a low concentration of 100 mM, the osmotic pressure (1,135 mOsmol/kg) of the TA-K draw solution was approximately 6.5 times that (173 mOsmol/kg) of the NaCl draw solution. Furthermore, the water flux and specific salt flux (6.14 LMH, 1.26 g/L) of the TA-K draw solution at 100 mM were approximately 2.5 and 0.5 times those of the NaCl draw solution (2.46 LMH, 2.63 g/L) at the same concentration, respectively. For reuse, TA-K was precipitated by using a metal ion and recovered through membrane filtration. This study demonstrates the applicability of a phytochemical material as a draw solute for forward osmosis.

Study on the Relationship between Aggregation Structure and Flow Rate Depending on Extrusion Temperature at Complex Mold of (Activated Carbon/Polymer Binder) ((활성탄/고분자바인더)복합성형체의 압출온도에 따르는 응집구조 및 유량 상관성에 관한 연구)

  • Lim, Yong Gyun;Kim, Young Jun;Park, Sang Jin;Hong, Sung-Kyu
    • Korean Chemical Engineering Research
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    • v.52 no.2
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    • pp.261-265
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    • 2014
  • As the need for miniaturization in water purification filter increases, the development of filter media for single filtration with multiple function was strongly required. In this study, the molded activated carbon composed of single unit was manufactured by extrusion-sintering process, and then the flow rate, density and porosity were investigated using the molded activated carbon manufactured at various extrusion temperature. We confirmed that it was possible to manufacture the single unit-molded activated carbon when the extrusion temperature was $140{\sim}230^{\circ}C$ more than $133^{\circ}C$ being of polymer binder melting point, and the optimal extrusion temperature for the molded activated carbon with maximum flow rate was $170^{\circ}C$ since the molded activated carbon had low density and high through porosity. Also we confirmed that the flow rate through the molded activated carbon was strongly dependent upon through pore porosity compared to total porosity for the molded activated carbon.

Verification of Antibacterial Activities of Oriental Herbal Medicine Extracts (한약재 추출물의 항균활성 검증)

  • Lee, Chang-Eun;Jo, Jung-Kwon;Kim, Jae-Deok;Lee, Dong-Geun;Kim, Won-Seok;Lee, Sang-Hyeon
    • Journal of Life Science
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    • v.27 no.6
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    • pp.611-616
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    • 2017
  • The antibacterial activities of nine oriental herbal medicine extracts were measured against seven kinds of bacteria known to cause food poisoning and disease. The extracts were prepared with distilled water using an autoclave ($121^{\circ}C$ for 30 min). The extraction yields of nine oriental herbal medicines were in the rage of 0.5%-33.4%. The antibacterial activities were evaluated using the paper-disc method. Extracts of Hwangryeon, Jiyu, and Ohbaeja showed antibacterial activities while the others did not. Extracts of Coptis japonica, Hwangryeon, and Sanguisorba officinalis, Jiyu showed antibacterial activities only against Clostridium perfringens and Listeria monocytogenes. Extracts of Rhus javanica, Ohbaeja showed the strongest antibacterial activities against all the bacteria tested. The minimum inhibitory concentration (MIC) and minimum bactericidal concentration (MBC) of R. javanica extracts were in the range of 2.4~20 mg/ml for the bacteria tested. In conclusion, the extract of R. javanica showed superior antibacterial activities against the seven bacterial strains tested. The MIC and MBC values for each bacterium were represented as strain names (MIC, MBC), which were Bacillus cereus (11.2, 20), Clostridium perfringens (2.4, 4.7), Escherichia coli (9.1, 9.1), Listeria monocytogenes (11.1, 20), Salmonella typhi (4.7, 9.1), Staphylococcus aureus (2.4, 4.7), and Vibrio parahaemolyticus (2.4, 5.3). Further purification and study of this antibacterial material would be helpful for developing antibiotics or promoting synergistic effects with known antibiotics, producing antibacterial material for lengthening the shelf-life of food, and so on.

Biogeochemical Organic Carbon Cycles in the Intertidal Sandy Sediment of Nakdong Estuary (낙동강 하구 갯벌 사질 퇴적물에서 생지화학적 유기탄소순환)

  • Lee, Jae-Seong;Park, Mi-Ok;An, Soon-Mo;Kim, Seong-Gil;Kim, Seong-Soo;Jung, Rae-Hong;Park, Jong-Soo;Jin, Hyun-Gook
    • The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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    • v.12 no.4
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    • pp.349-358
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    • 2007
  • In order to understand biogeochemical cycles of organic carbon in the permeable intertidal sandy sediments of the Nakdong estuary, we estimated the organic carbon production and consumption rates both in situ and in the laboratory. The Chl-a content of the sediment and the nutrient concentrations in below surface pore water in the sandy sediment were lower than in the muddy sediment. The sediment oxygen consumption rates were relatively high, especially when compared with rates reported from other coastal muddy sediments with higher organic carbon contents. This implied that both the organic carbon degradation and material transport in the sandy sediment were enhanced by advection-related process. The simple mass balance estimation of organic carbon fluxes showed that the major sources of carbon in the sediment would originate from benthic microalgae and detrital organic carbon derived from salt marsh. The daily natural biocatalzed filtration, extrapolated from filtration rates and the total area of the Nakdong estuary, was one order higher than the maximum capability of sewage plants in Busan metropolitan city. This implies that the sandy sediment contributes greatly to biogeochemical purification in the area, and is important for the re-distribution of materials in the coastal environment.