• 제목/요약/키워드: Waste-to-Energy

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A Basic Study on Capture and Solidification of Rare Earth Nuclide (Nd) in LiCl-KCl Eutectic Salt Using an Inorganic Composite With Li2O-Al2O3-SiO2-B2O3 System (Li2O-Al2O3-SiO2-B2O3 구조의 무기합성매질을 이용한 LiCl-KCl 공융염 내 희토류 핵종(Nd)의 분리 및 고화에 관한 기초연구)

  • Kim, Na-Young;Eun, Hee-Chul;Park, Hwan-Seo;Ahn, Do-Hee
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.15 no.1
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    • pp.83-90
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    • 2017
  • The pyroprocessing of spent nuclear fuel generates LiCl-KCl eutectic waste salt containing radioactive rare earth nuclides. It is necessary to develop a simple process for the treatment of LiCl-KCl eutectic waste in a hot-cell facility. In this study, capture and solidification of a rare earth nuclide (Nd) in LiCl-KCl eutectic salt using an inorganic composite with a $Li_2O-Al_2O_3-SiO_2-B_2O_3$ system was conducted to simplify the existing separation and solidification process of rare earth nuclides in LiCl-KCl eutectic waste salt from the pyroprocessing of spent nuclear fuel. More than 98wt% of Nd in LiCl-KCl eutectic salt was captured when the mass ratio of the composite was 0.67 over $NdCl_3$ in the eutectic salt. The content of $Nd_2O_3$ in the Nd captured-composite reached about 50wt%, and this composite was directly fabricated into a homogeneous and chemical resistant glass waste in a monolithic form. These results will be utilized in designing a process to simplify the existing separation and solidification process.

An Energy Self-Sustainable Wireless Sensor System Based on a Microbial Fuel Cell (MFC) and Energy Harvester (EH) (미생물연료전지와 에너지 하베스팅에 기반한 에너지 자립형 무선 센서 시스템)

  • Yeo, Jeongjin;Park, Sojin;Lim, Jonghun;Yang, Yoonseok
    • Journal of Biomedical Engineering Research
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    • v.39 no.5
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    • pp.208-212
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    • 2018
  • Microbial fuel cell (MFC) technology has been attractive since it can not only treat organic waste in an eco-friendly way by digesting it but also generate electricity by the unique metabolic process of microbes. However, it hasn't been employed in practical use until now because it is hard to integrate a small electricity up to an adequate amount of electric power and difficult to keep its bio-electric activity consistent. In this study, we combined an energy harvester with MFC (MFC-EH) to make the power-integration convenient and developed an energy self-sustainable wireless sensor system driven by a stable electric power produced by MFC-EH. Additionally, we build the low power application measuring data to be cast by the web in real-time so that it can be quickly and easily accessed through the internet. The proposed system could contribute to improvement of waste treatment and up-cycling technologies in near future.

RADIATION MONITORING SYSTEM FOR ADVANCED SPENT FUEL CONDITIONING PROCESS FACITLITY

  • Kook Dong-Hak;Choung Won-Myung;Lee Eun-Pyo;You Gil-Sung;Cho Il-Je;Kwon Kie-Chan;Lee Won-Kyoung;Ku Jeoung-Hoe
    • Proceedings of the Korean Radioactive Waste Society Conference
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    • 2005.11b
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    • pp.149-155
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    • 2005
  • The $ACP^1$ is under development for effective management of spent fuel by converting $UO_2$ into U-metal. For demonstration of this process, $\alpha-\gamma$ type new hotcell was built in the $IMEF^2$ basement. To secure against radiation hazard, this facility needs radiation monitoring system which will observe the entire operating area before the hotcell and service area at back of it. This system consists of 7 parts; Area Monitor for $\gamma$-ray, Room Air Monitor for particulate and iodine in both area, Hotcell Monitor for hotcell inside high radiation and rear door interlock, Duct Monitor for particulate of outlet ventilation, Iodine Monitor for iodine of outlet duct, CCTV for watching workers and material movement, Server for management of whole monitoring system. After installation and test of this, radiation monitoring system will be expected to assist the successful ACP demonstration.

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An Efficient Sulfuric Acid- and Hydrazine-based Process for Recycling Wastewater Generated From U(VI)-Contaminated Soil-Washing

  • Hyun-Kyu Lee;Byung-Moon Jun;Tack-Jin Kim;Sungbin Park;Seonggyu Choi;Jun-Young Jung;Hee-Chul Eun
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.22 no.2
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    • pp.159-171
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    • 2024
  • This study aimed to develop an efficient recycling process for wastewater generated from soil-washing used to remediate uranium (U(VI))-contaminated soil. Under acidic conditions, U(VI) ions leached from the soil were precipitated and separated through neutralization using hydrazine (N2H4). N2H4, employed as a pH adjuster, was decomposed into nitrogen gas (N2), water (H2O), and hydrogen ions (H+) by hydrogen peroxide (H2O2). The residual N2H4 was precipitated when the pH was adjusted using sulfuric acid (H2SO4) to recycle the wastewater in the soil-washing process. This purified wastewater was reused in the soil-washing process for a total of ten cycles. The results confirmed that the soil-washing performance for U(VI)-contaminated soil was maintained when using recycled wastewater. All in all, this study proposes an efficient recycling process for wastewater generated during the remediation of U(VI)-contaminated soil.

Synthesis of Nitrogen-Doped Porous Carbon Fibers Derived from Coffee Waste and Their Electrochemical Application (커피 폐기물 기반의 질소가 포함된 다공성 탄소 섬유의 제조 및 전기화학적 응용)

  • Dong Hyun Kim;Min Sang Kim;Suk Jekal;Jiwon Kim;Ha-Yeong Kim;Yeon-Ryong Chu;Chan-Gyo Kim;Hyung Sub Sim;Chang-Min Yoon
    • Journal of the Korea Organic Resources Recycling Association
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    • v.31 no.1
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    • pp.57-68
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    • 2023
  • In this study, coffee waste was recycled into nitrogen-doped porous carbon fibers as an active material for high-energy EDLC (Electric Double Layer Capacitors). The coffee waste was mixed with polyvinylpyrrolidone and dissolved into dimethylformamide. The mixture was then electrospun to fabricate coffee waste-derived nanofibers (Bare-CWNF), and carbonization process was followed under a nitrogen atmosphere at 900℃. Similar to Bare-CWNF, the as-synthesized carbonized coffee waste-derived nanofibers (Carbonized-CWNF) maintained its fibrous form while preserving the composition of nitrogen. The electrochemical performance was analyzed for carbonized coffee waste (Carbonized-CW)-, carbonized PAN-derived nanofibers (Carbonized-PNF)-, and Carbonized-CWNF-based electrodes in the operating voltage window of -1.0-0.0V, Among the electrodes, Carbonized-CWNF-based electrodes exhibited the highest specific capacitance of 123.8F g-1 at 1A g-1 owing to presence of nitrogen and porous structure. As a result, nitrogen-contained porous carbon fibers synthesized from coffee waste showed excellent electrochemical performance as electrodes for high-energy EDLC. The experimental designed in this study successfully demonstrated the recycling of the coffee waste, one of the plant-based biomass that causes the environmental pollution into high-energy materials, also, attaining the ecofriendliness.

Current Status and Future Prospects of the IAEA Program in the Fields of Nuclear Fuel Cycle and Materials Technologies (핵연료주기 기술개발을 위한 IAEA 프로그램의 추이 분석 및 전망)

  • KIM Kyoung-Pyo;PARK Seong-Won;SEO Chung-Suk;KIM Ho-Dong;SONG Kee-Chan;JEONG Sang-Mun
    • Proceedings of the Korean Radioactive Waste Society Conference
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    • 2005.11a
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    • pp.221-228
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    • 2005
  • The objectives of this paper are to present the general features of the current IAEA programs and their future prospects in the fields of the nuclear fuel cycle and the related materials technologies thus responding to a need to achieve a consolidated understanding of the Agency's programs for an effect ive implementation of the respective national R&D projects in Korea. During the development of the Agency's programs for 2005-2007 in the aforementioned fields. it is foreseen that an considerable attention will be attributed to the concepts, models and opportunities for optimizing the fuel cycle, mining the raw materials, re-using the materials and reducing the waste arisings (e.g. through Partitioning and transmutation), all of which, will Include an enhanced consideration for proliferation and security concerns.

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Development of Safeguards System for Advanced Spent Fuel Conditioning Process

  • Lee Tae-Hoon;Song Dae-Yong;Ko Won-Il;Kim Ho-Dong;Jeong Ki-Jeong;Park Seong-Won
    • Proceedings of the Korean Radioactive Waste Society Conference
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    • 2005.06a
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    • pp.426-427
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    • 2005
  • Advanced Spent Fuel Conditioning Process (ACP) is a pyrochemical process in which the spent fuel of PWR is transformed into the uranic metal ingot. Through this process, which has been developed in KAERI since 1998, the radioactivity, the radiotoxicity, the heat and the volume of the PWR spent fuel are reduced by a quarter of the original. To demonstrate a lab-scale process and extract the data for the later pilot-scale process, a demonstration facility of ACP (ACPF) is under construction and the lab-scale demonstration is slated for 2006. To establish the safeguardability of ACPF, a safeguards system including a neutron counter based on non-destructive assay, which is named as ACP Safeguards Neutron Counter (ASNC), the ACP Safeguards Surveillance System (ASSS) which consists of two neutron monitors and five IAEA cameras, and Laser Induced Breakdown System (LIBS) have been developed and are ready to be installed at ACPF. The target materials of ACP to assay with ASNC are categorized into three types among which the first is the uranic metal ingot, the second is the salt waste and the last is $UO_2$ and $U_{3}O_8$ powders, rod cuts and hulls. The Pu content of process nuclear materials can be accounted with ASNC. The ASSS is integrated in the ACP Intelligent Surveillance Software (AISS) in which the IAEA camera images and background signals at the rear doors of ACPF are displayed. The composition of special nuclear materials of ACP can be measured with LIBS which can be a supporting measurement tool for ASNC. The conceptual picture of safeguards system of ACPF is shown in Fig. 1.

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Physicochemical Characteristics of Waste Catalyst and Their In-Process Products from Recycling (폐촉매 및 재활용 중간생성물의 물리화학적 특성 평가)

  • Park, Joon-Seok;Jeun, Byung-Do;Kim, Joung-Dae
    • Journal of Environmental Health Sciences
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    • v.37 no.2
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    • pp.150-158
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    • 2011
  • This research was conducted to estimate the physicochemical characteristics of waste catalyst and its in-process product from recycling and to suggest fundamental data for religious systems such as quality standards. Mo and V contents were increased from the waste catalyst to calcinated material and oxidized material. In the results of a heavy metals leaching test, Pb was not detected in any catalyst, calcinated and oxidized materials. Cu was not detected in the catalyst. However, it was detected in ${\leq}$1.16 mg/l for calcinated material and in 1.34~13.73 mg/l for $MoO_3$ oxidezed material. Concentrations in recycling in-process products (calcinated and oxidized materials) were higher than those of waste catalyst. Oil content of catalyst waste ranged from 0.01-14.03 wt%. Oil contents of calcinated and oxidized materials were greatly decreased compared to the catalyst waste. Carbon and sulfur contents as chemical poisoning material of catalyst waste ranged from 0.33-76.08 wt% and 5.00-22.00 wt%, respectively. The carbon contents of calcinated and oxidized materials showed below 20 wt%. The sulfur content showed below 8wt% for calcinated material and below 0.22 wt% for oxidized material.

Seasonal characterization and present status of municipal solid waste (MSW) management in Varanasi, India

  • Dasgupta, Betty;Yadav, Vijay Laxmi;Mondal, Monoj Kumar
    • Advances in environmental research
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    • v.2 no.1
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    • pp.51-60
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    • 2013
  • The paper aims to characterise the waste generated in municipality of Varanasi, the most populated city in the state of Uttar Pradesh, India. MSW is a heterogeneous waste and composition of the waste varied from season to season. The generation, collection and management of waste have become a major environmental problem in most of the developing cities. MSW was collected from open dumping grounds for 2 consecutive years. Each year was classified into 3 seasons of 4 months. On analysis it was found that the biodegradable fraction is always more than other fractions with a minimum of 48.25% in rainy season. With such a high fraction of biodegradable wastes, options such as composting and biomethanation could be tried to convert waste into energy. The average weight of waste generation at present is 0.460 kg per capita per day. The study showed that waste generation and collection were increasing every year, which may be attributed to increase in population.

An Experimental Study on LTD Stirling Engine (MM-7) for the Development of TM Electric Conversion System (TM발전변환기 개발을 위한 저온도차 스털링엔진(MM-7)의 성능실측 연구)

  • Kim, Yeongmin;Chen, Kuan;Chun, Wongee
    • Journal of Energy Engineering
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    • v.25 no.1
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    • pp.9-14
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    • 2016
  • This study has been carried out to develop TM (Thermal to Mechanical) conversion systems for electric power generation using one of the Low Temperature Differential (LTD) Stirling engines called MM-7 capable of harnessing low temperature waste heat whose temperature is only $20{\sim}30^{\circ}C$ above the ambient. Measurements were made on the torque and rpm for a number of temperature differentials between the engine hot and cold ends, which could be effectively applied in developing the most suitable configuration for the high performance TM (Thermal to Mechanical) conversion system.