• Title/Summary/Keyword: Waste iron oxide

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Adsorption Characteristics of Hydrogen Sulfide on Iron Hydroxide-based Adsorbent (수산화철계 흡착제의 황화수소 흡착 특성)

  • Ryu, Seung Hyeong;Seo, Youngjoo;Park, Joonwoo;Kim, Shin Dong;Park, Seong Soon
    • Journal of Korea Society of Waste Management
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    • v.34 no.5
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    • pp.468-473
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    • 2017
  • This study was carried out to examine the characteristics of hydrogen sulfide adsorption using an iron hydroxide-based adsorbent. The prepared adsorbent was discussed with regard to its adsorption capacity and analyzed via surface analysis methods to illustrate the physical characteristics of hydrogen sulfide adsorption. As the drying temperature increased, the adsorption capacity of the adsorbent decreased from 29.15wt% to 22.73wt%. The adsorption capacity was decreased as the space velocity increased and showed an adsorption capacity of about 3.65 at $3,157.6h^{-1}$. The effect of sulfur dioxide was to decrease the adsorption capacity from 29.15wt% to 27.94wt%. The adsorbent exhibited the amorphous type in its physical appearance based on XRD and EDS analysis.

Comparison of Anodic Community in Microbial Fuel Cells with Iron Oxide-Reducing Community

  • Yokoyama, Hiroshi;Ishida, Mitsuyoshi;Yamashita, Takahiro
    • Journal of Microbiology and Biotechnology
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    • v.26 no.4
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    • pp.757-762
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    • 2016
  • The group of Fe(III) oxide-reducing bacteria includes exoelectrogenic bacteria, and they possess similar properties of transferring electrons to extracellular insoluble-electron acceptors. The exoelectrogenic bacteria can use the anode in microbial fuel cells (MFCs) as the terminal electron acceptor in anaerobic acetate oxidation. In the present study, the anodic community was compared with the community using Fe(III) oxide (ferrihydrite) as the electron acceptor coupled with acetate oxidation. To precisely analyze the structures, the community was established by enrichment cultures using the same inoculum used for the MFCs. High-throughput sequencing of the 16S rRNA gene revealed considerable differences between the structure of the anodic communities and that of the Fe(III) oxide-reducing community. Geobacter species were predominantly detected (>46%) in the anodic communities. In contrast, Pseudomonas (70%) and Desulfosporosinus (16%) were predominant in the Fe(III) oxide-reducing community. These results demonstrated that Geobacter species are the most specialized among Fe(III)-reducing bacteria for electron transfer to the anode in MFCs. In addition, the present study indicates the presence of a novel lineage of bacteria in the genus Pseudomonas that highly prefers ferrihydrite as the terminal electron acceptor in acetate oxidation.

Study on Tar Reforming by Using the Catalyst Derived from Wastes (폐기물유래 촉매를 이용한 타르 개질에 관한 연구)

  • Sung, Hojin;Nam, Sungbang;Pakr, Yeongsu;Gu, Jaehoi
    • 한국연소학회:학술대회논문집
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    • 2014.11a
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    • pp.267-270
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    • 2014
  • Since contaminants of syngas obtained from the biomass gasification are removed, the syngas is clean fuel. In this study a high-efficiency energy production system is developed. The system produces electricity using a waste pressure and feeds a low-pressure steam to Dyeing industrial complex. Also, iron oxide derived from dyeing sludge is utilized as a self-catalyst to reform a tar and reduce a tar emission from gasifier. This system increases the amount of syngas and finally achieves a highly efficient gasification.

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An Experimental Study on Development of Eco-Friendly Color Concrete Using Industrial Waste Red Mud (산업폐기물 레드머드를 사용한 친환경 칼라 콘크리트 개발에 관한 실험적 연구)

  • Jeong, Dong-Young;Choi, Kyoung-Rag;Kim, Moon-Hoon;Hong, Chong-Hyun
    • Journal of Environmental Science International
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    • v.16 no.8
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    • pp.929-939
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    • 2007
  • Red mud is a waste generated by the aluminium industry, and its disposal is a major problem for this industry. Red mud has a reddish-brown color and superfine particle characteristics. So, it can be a promising pigment admixture for concrete industry. An experimental study was conducted to investigate the potential use of red mud in color concrete. The micro structures of red mud and iron oxide pigment such as porosity, pore size distribution, diameter of particle were analyzed with the aid of SEM, X-ray diffraction(XRD), and the infrared absorbance. Tests on physical properties of color concrete, such as strength, slump, early shrinkage crack patterns, and color characteristics were carried out and the results were reported in this paper.

Single-Particle Characterization of Municipal Solid Waste (MSW) Ash Particles Using Low- Z Particle Electron Probe X-ray Microanalysis (단일입자분석(Low-Z Particle Electron Probe X-ray Microanalysis)을 이용한 도시 소각재 입자의 특성분석)

  • Hwang Hee Jin;Kim Hye Kyeong;Ro Chul-Un
    • Journal of Korean Society for Atmospheric Environment
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    • v.21 no.3
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    • pp.367-375
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    • 2005
  • Low-Z particle Electron Probe X-ray Microanalysis was applied to characterize MSW fly- and bottom -ash particle samples originated from two municipal incinerators (denoted as A and B) in Korea. According to their chemical composition, many distinctive particle types were identified. In A fly ash, the major chemical species are carbon-rich, aluminosilicates and many particles are composed of as a mixture of $ CaCO_3$ and other chemical species such as $CaSO_4$ or $CaCl_2$. For B fly ash, Fe, iron oxide, NaCl and NaCl-containing particles are the most abundant. In bottom ash, A and B were composed of similar chemical species such as carbon-rich, Fe, iron oxide, $CaCO_3$, and aluminosilicates. It was demonstrated that the single-particle characterization using this low-Z particle EPMA technique provided detailed information on various types of chemical species in the MSW ash samples. In addition, the technique has advantage over conventional analytical techniques in the point that both crystalline and glass-like ash particles can be analyzed at the same time.

Current Status of Ilmenite Beneficiation Technology for Production of TiO2 (TiO2 제조를 위한 일메나이트 처리기술 현황)

  • Sohn, Ho-Sang;Jung, Jae-Young
    • Resources Recycling
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    • v.25 no.5
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    • pp.64-74
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    • 2016
  • Titanium and iron are closely related in nature, although titanium is the ninth most abundant element in the Earth's crust. Iron in titanium ores must be removed for use as feedstocks in the manufacture of titanium dioxide pigments and pure $TiCl_4$ for metal titanium. In this study, various beneficiation processes of ilmenite for production of $TiO_2$ have been reviewed and compared. Most of these processes involve a combination of pyrometallurgy and hydrometallurgy. These beneficiation processes of ilmenite generate considerable quantities of wastes primarily in the form of iron salt, iron oxide and acidic effluents. Therefore, it is important that recovery of acid value from waste and conversion of iron bearing waste to useful materials for development of new beneficiation processes of ilmenite.

Effect of magnetic separation in removal of Cr and Ni from municipal solid waste incineration (MSWI) bottom ash (생활폐기물(生活廢棄物) 소각(燒却) 바닥재의 자력선별(磁力選別)에 따른 크롬과 니켈의 거동(擧動))

  • Ahn, Ji-Whan;Um, Nam-Il;Cho, Kye-Hong;Oh, Myung-Hwan;You, Kwang-Suk;Han, Gi-Chun;Cho, Hee-Chan;Han, Choon;Kim, Byong-Gon
    • Resources Recycling
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    • v.16 no.6
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    • pp.3-9
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    • 2007
  • Although the ferrous material was separated by the magnetic separation before the incineration process, the municipal solid waste incineration bottom ash generated during incinerator in metropolitan area consists of many iron products which account for about $3{\sim}11%$ as well as ceramics and glasses. The formation of $NiFe_2O_4$ and $FeCr_2O_4$ with a $Fe_3O_4-Fe_2O_3$ (similar to pure Fe) on the surface of iron product was found during air-annealing in the incinerator at $1000^{\circ}C$, because Ni and Cr has a chemical attraction about iron is using to coat with Ni and Cr metals for poish or to prevent corrosion. Therefore, Fe-Ni Cr oxide can be formed on durface of the iron product and it can be separated from bottom ash through the magnetic separation. So, in this study, the separation ratio of heavy metals as magnetic separation and mineralogical formation of Fe-ion(heavy metal) in ferrous metals corroded were investigated. As the result, the separation ratio of Ni and Cr based on particle sizes accounted for about $45{\sim}50%$, and Cu and Pb accounted for below 20%. Also, the leaching concentration of Ni and Cr in bottom ash separated by magnetic separation was lower than that in fresh bottom ash.

Study on the Recovery of Tin Oxide and Metallurgical Tin from the Waste Steel Ball for Barrel Plating (바렐도금용 폐Steel Ball로부터 산화주석 및 금속주석 회수에 관한 연구)

  • Kim, Dae Weon;Jang, Seong Tae
    • Journal of the Korean Ceramic Society
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    • v.49 no.6
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    • pp.505-510
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    • 2012
  • A study of the recovery of tin and nickel from steel ball scraps for barrel plating was carried out through a physical treatment, a leaching treatment, hydrogen reduction and an electrolysis experiment. The recovery of the iron component was over 95% by the physical treatment. We obtained tin oxide in the form of metastannic acid ($SnO_2{\cdot}xH_2O$) with impurities of less than 5% from the leaching treatment. We also recovered the high-purity metallurgical tin at a rate that exceeded 99.9% by the electrolysis of crude tin obtained from the hydrogen reduction of metastannic acid.

Study on magnetic separation of waste water using superconducting magnet (초전도 전자석을 이용한 제철소 폐수처리용 자기분리 연구)

  • Ha, Dong-Woo;Kim, Tae-Hyung;Oh, Sang-Soo;Ha, Hong-Soo;Park, Sung-Kook;Lee, Sang-Gil;Roh, Yu-Mi
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2006.06a
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    • pp.87-88
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    • 2006
  • It is needed several large reservoirs and long time in order to remove suspended solid like steel fines and iron oxide at steel making factory. If removing rate of suspended solid in rolling coolant is improved, the productivity of working process can be increased and the area of reservoir can be reduced. Pre-treatment to add extra magnetization of suspended solid was studied Iron hydroxide and electrolytic dissociation were used for pretreatment. High gradient magnetic separation (HGMS) system was used for removing of magnetized suspended solid. Removing ratio showed over than 99% in the coolant containing magnetic fines. Magnetic properties of suspended solid were investigated after mixed with Al2(SO2)3 and organic flocculant by using electrochemical treatment.

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