• Proceedings of the IEEK Conference
• /
• 2001.10a
• /
• pp.711-714
• /
• 2001

A new technology to make fluoride gas such as NF$_3$contained in the exhaust gas from semiconductor manufacturing plants convert directly into a harmless substance have been established and new concept on the disposal treatment of global warming gases were presented. Experimental results verify that the chemical reactions can be take place at substantially lower temperature of 80-40$0^{\circ}C$ as compared with the combustion treatment method. Reaction product is mainly metal fluoride which is a harmless and a valuable chemical material as one of new resources. The other favorable characteristics are that the continuous treatment is possible at a low temperature under atmospheric pressure. Furthermore this process is compact, easily controllable and safely operable at low running cost. This paper concerns with a new harmless disposal treatment of toxic global warming gas.

• 한국연소학회:학술대회논문집
• /
• 2000.12a
• /
• pp.132-139
• /
• 2000

Oxygen enriched incineration can increase the incineration capacity for wastes and dramatically reduce air pollutant emissions such as CO and dioxine by the allowing complete combustion of wastes in incinerator. Furthermore, this technology is proven to have many benefits including an energy-saving, cost-effective, and versatile application for diverse wastes compared with the conventional air incineration technology. The reduced pollutant emissions in flue gas and higher incineration efficiency are also available when the oxygen enriched air is used for the high temperature incineration systems. On the basis of the experimental results the oxygen enrichment system is successfully applied to the rotary kiln incinerator for industrial wastes. The oxygen enriched incineration system could be allowed more compact design of incinerator and flue gas treatment system due to both increasing incineration capacity and reducing flue gas volume. Therefore, oxygen enriched incineration technology is becoming highlighted in the waste incinerator which strongly require more stable efficiency and environmentally friendly and safe operationPut Abstract text here.

• 한국생물공학회:학술대회논문집
• /
• 2000.04a
• /
• pp.85-88
• /
• 2000

• Applied Chemistry for Engineering
• /
• v.3 no.2
• /
• pp.201-206
• /
• 1992

Annual amount of plastics waste including rubber and leather waste, generated in 1990 was about 2,600,000 tons. Amount of generation of plastics waste has rapidly increased, but fractions of recycling and incineration have gradually decreased. Recently, two-stage incinerator, consisting of gasifier and gas combustor, draws much attention in Korea. Plastics are gasified in the starved air condition in the gasifier and produced gas is fired in the combustor. Combustion of produced gas is much easier than that of solid plastics, and produces a little pollutants. Standardzation of technology and process automation are still needed, but this incineration technology is in the commercial stage. Next topic concerned with this two-stage incineration will be how to treat complex plastics waste including toxic substances generated from automobiles and household appliances. Pyrolysis, realized by indirect heating in inert atmosphere, can provide high-quality products with minimum emissions. Many plastics are easily decomposed into oil in pyrolysis conditions, which can be utilized as chemical feedstocks, or gasoline or kerosene depending on feed materials and operating conditions. This has been demonstrated in several pilot-scale tests performed in Japan, Germany, etc. Easy removal of HCl from PVC is one of the most decisive merits of pyrolysis process. But in general, further efforts should be made for the process to obtain marketability. The future of pyrolysis process depends on public concern about environmental problems and oil prices.

• Journal of the Korea Academia-Industrial cooperation Society
• /
• v.10 no.12
• /
• pp.3761-3767
• /
• 2009

This study was investigated to determine the combustion characteristics, decomposition efficiency, and the flue gas concentrations after combustion in the high temperature reactor($1,250{\sim}1,400^{\circ}C$, 1 atm) for the liquid wastes(waste oil and waste solvent) generated from the industrial complex. The concentration of nitrogen oxide(NOx) is decreased and the synthetic gas is increased when the mass ratio of $O_2$/waste is about 1.53 because the reaction condition was changed to reduction state. And BTEXs(benzene, toluene, ethylbenzene, xylene) are decomposed more than 99.99%. If the highly concentrated liquid waste (waste oil and waste solvent) is treated under the operating conditions suggested by this study, our treatment method for the liquid waste was found to be proper because of the contaminants emission concentration is very low. In addition, the synthetic gas after combustion can be used as an alternative fuel.

• Journal of environmental and Sanitary engineering
• /
• v.20 no.1 s.55
• /
• pp.64-75
• /
• 2005

The total production of food waste was about 11,398ton/day('03) in Korea. Also, food waste was treated by landfill, incineration, reuse and anaerobic digestion. The method of food waste treatment depended primarily on landfill. However, the method of landfill causing social problems was prevented to treat food waste in the first of January 2005.12) Thus, anaerobic digestion is an important method to treat food waste because of possibility of energy recovery as methane gas. In this study, the possibility of food waste treatment containing high organic material and low pH in the one stage anaerobic reactor to save cost and time and energy recovery using $CH_{4}$ gas by the hybrid anaerobic reactor (HAR) was measured. The HAR was designed by combing the merits of the anaerobic filter (AF) to minimize the microorganism shock when food waste of very low pH was injected and up-flow anaerobic sludge blanket (UASB) to prevent from plugging and channeling phenomena by large suspended solids when semi solids were injected. Granule was packed in the section of HAR. The purpose of the BMP experiment was to measure the amount of methane generated when organic material was resolved under anaerobic conditions, to grasp bio resolution of organic material. Total accumulated methane production per VS amount was $0.471(m^{3}/\cal{kg}\;VS)$. So, the value was about $81.2\%$ of theoretical methane production which was $0.58(m^{3}/\cal{kg}\;VS)$ by elementary analysis and organic matter removal velocity (K) was $0.18(d^{-1})$. From these results, food waste was treated by anaerobic treatment. From this study, $CH_{4}$ generation from food waste (11,398 ton/day) could be estimated. By using an energy conversion factor of Braun's study, $5.97KWh/m^{3}\;CH4,\;60\%\;of\;CH_{4}$ gas generation, the amount of total energy producing food waste is to 6,727MWh/day. It could be confirmed that energy recovery using $CH_{4}$ gas was possible. Above these results, food waste containing organic matters of high concentration could be treated in HRT 30 days under an anaerobic condition, using the hybrid anaerobic reactor and reuse of $CH_{4}$ gas was possible.

• Journal of Korean Society of Water and Wastewater
• /
• v.26 no.5
• /
• pp.629-636
• /
• 2012

This study focuses on the feasibility of bio-gas production using anaerobic digestion by measuring methane generation and biodegradability through the BMP test of industrial organic wastes. Organic wastes consist of entrails of pigs and organic residues of rumen generated from slaughter houses, wastewater sludge from slaughter waste water, fish offal and residues of vegetables from public wholesale markets, and wastewater sludge from the process of wastewater treatment in paper mill. The cumulative methane production by BMP test ranges from 149.3 ml/g-VS to 406.6 ml/g-VS and this is similar to methane generation of the normal wastewater sludge and food waste. As a result of measurement of biodegradability, wastewater sludge (S1 ~ S4) is low, ranging from 27.1% to 58.9 % and organic residues of rumen (G1) is low at 49.6 %. In conclusion, it turned out that raising the hydrolysis by various pre-treatments is necessary in order to produce bio-gas by using industrial organic wastes.

• Journal of Korea Foundry Society
• /
• v.15 no.5
• /
• pp.477-482
• /
• 1995

A computer simulation model of various smelting process for melting waste sand was developed by using energy and material balance concept. This model can predict the coal, flux and oxygen consumption and the volume and temperature of off-gas. The major critical variables for smelting process can be explained by using the analysis of energy and material balance. The major conclusions were as follows; 1. The most important variables for smelting process were high post-combustion ratio, high heat transfer efficiency and refractory protection technology. 2. For saving energy in this smelting process, selection of raw materials i.e coal, flux are very important, espacially using of low volatile coal is very profitable. 3. The treatment cost of waste sand is high and environmental restriction is severe, in this reason we must be concerned in the treatment of waste sand by smelting process.

• Journal of the Korean institute of surface engineering
• /
• v.36 no.2
• /
• pp.184-193
• /
• 2003

Cyclic sweep voltametry was performed to investigate the electrochemical behavior of heavy metal ions and the organic additives in surface finishing process. And electrolysis using parallel plate electrode electrolyzer was carried out to simulate the treatment of real waste water. Results showed that more than 99 percent of Cu was recovered and selective recovery of Cu in mixed waste water was possible, but the possibility of economical recovery of Ni and Cr were very low due to the evolution of hydrogen gas. Electrochemical oxidation of cyanide and organic additives on anode showed very excellent removal rate. The complete removal of several hundred ppm of cynide was possible within several tens minutes and organics within 2 or 3 hours. Even in case of concentrate waste water, the complete removal of COD by using NaCl and air stirring seemed to be possible.

• Clean Technology
• /
• v.9 no.1
• /
• pp.23-28
• /
• 2003

The generation of food waste in Korea amounts to 4.10 million per year, which corresponds to 820,000 dry ton of organic waste. This has been used traditionally as animal feed or soil conditioner, but its efficacy has remained doubtful in recent years. In this study as an alternative we considered methane production by anaerobic treatment, which has an advantage of 200 million US dollars over aerobic methods. The production of methane amounts to $4.40{\times}10^8m^3$, 3.43% of $1.28{\times}10^8m^3$, total natural gas used in Korea. Furthermore the methane from household kitchen food waste amounts to 28.9% of the total gas used in the kitchen.