• Title/Summary/Keyword: Waste Glass

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Stabilization/Solidification of Radioactive LiCl-KCl Waste Salt by Using SiO2-Al2O3-P2O5 (SAP) inorganic composite: Part 1. Dechlorination Behavior of LiCl-KCl and Characteristics of Consolidation (SiO2-Al2O3-P2O5 무기복합체를 이용한 LiCl-KCl 방사성 폐기물의 안정화/고형화: Part 1. LiCl-KCl의 탈염화 반응거동 및 고형화특성)

  • Cho, In-Hak;Park, Hwan-Seo;Ahn, Soo-Na;Kim, In-Tae;Cho, Yong-Zun
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.10 no.1
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    • pp.45-53
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    • 2012
  • The metal chloride wastes from a pyrochemical process to recover uranium and transuranic elements has been considered as a problematic waste difficult to apply to a conventional solidification method due to the high volatility and low compatibility with silicate glass. In this study, a dechlorination approach to treat LiCl-KCl waste for final disposal was adapted. In this study, a $SiO_2-Al_2O_3-P_2O_5$ (SAP) inorganic composite as a dechlorination agent was prepared by a conventional sol-gel process. By using a series of SAPs, the dechlorination behavior and consolidation of reaction products were investigated. Different from LiCl waste, the dechlorination reaction occurred mainly at two temperature ranges. The thermogravimetric test indicated that the first reaction range was about $400^{\circ}C$ for LiCl and the second was about $700^{\circ}C$ for KCl. The SAP 1071 (Si/Al/P=1/0.75/1 in molar) was found to be the most favorable SAP as a dechlorination agent under given conditions. The consolidation test revealed that the bulk shape and the densification of consolidated forms depended on the SAP/Salt ratios. The leaching test by PCT-A method was performed to evaluate the durability of consolidated forms. This study provided the basic information on the dechlorination approach. Based on the experimental results, the dechlorination method using a $SiO_2-Al_2O_3-P_2O_5$ (SAP) could be considered as one of alternatives for the immobilization of waste salt.

Strength toss of F-Fiber Obtained from Recycling FRP Ship in a Basic Solution (폐 FRP 선박에서 분리하여 얻은 F섬유의 염기성 용액에서의 강도저하)

  • Lee, Seung-Hee;Kim, Yong-Seop;Yoon, Koo-Young
    • Journal of the Korean Society for Marine Environment & Energy
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    • v.11 no.1
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    • pp.42-45
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    • 2008
  • It has been reported that FRP (fiber reinforced plastic) can be recycled by separating into layers instead of crushing into powder. F-fiber obtained from roving layer separated from FRP, has bigger tensile strength than the bundle of glass fibers of which FRP was made (more than 90%). SEM image of F-fiber shows the presence of some resin. Under the proposition of usage of F-fiber in the concrete material, tensile strength is examined after soaking in a basic solution (NaOH+KOH). The reaction mechanism of strength loss may be considered as an attack of hydroxide ion ($OH^-$) on a chemical bond of Si-O-Si of glass fiber. The simulation graph of the strength loss data implies certain reaction mechanism. While in the early stage kinetically controlled reaction results in a fast drop of tensile strength, after 30 days dispersion rate of hydroxide ion plays a major role in strength loss. This result is similar to the one for the AR glass. An extrapolation of the graph would make an assumption about the lift time of F-fiber possible.

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Strengthening Efficiency for the Various Corner Shapes of RC Member confined with Continuous Fiber Sheets (연속섬유 시트로 보강된 RC 부재의 모서리 형상에 따른 보강 효율에 관한 연구)

  • Ko, Hune-Bum;Lee, Jin-Seop
    • Journal of the Korea Institute of Building Construction
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    • v.8 no.2
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    • pp.113-119
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    • 2008
  • Recently, fiber reinforced polymers(FRP) composite materials are used extensively in the rehabilitation of concrete structural members. A main application is to wrap beams and columns using the continuous fibers sheets to improve their strength and ductility. The corner chamfering affects significantly the performance of the continuous fibers sheets, and could lead to environmental problem with waste and dust. The main purpose of this paper is to verify the effect of corner conditions on the strength of the continuous fiber sheets, and to introduce new attached components which can avoid environmental problem. A total of 15 specimens were tested and carefully checked for three types of continuous fiber sheets(carbon, glass, and aramid) and three types of corner conditions(non-chamfering, chamfering, and device attaching). It is proved that the devices proposed in this research have some capabilities to use for RC member. But additional research will be needed for commercializing.

Member design and strength characteristics of the MMA mortar composites (I) (MMA 모르터 복합체의 강도특성 및 부재설계 (I))

  • Ji, Hyo-Seon;Mamdouh, El-Badry
    • Journal of the Korean Society for Advanced Composite Structures
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    • v.6 no.3
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    • pp.41-49
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    • 2015
  • The repair of manhole raise has been caused much construction times and disruption of traffic flow, serious environmental pollution from crushed construction wastes, and budget waste due to the repeated repair construction works. In order to overcome such problems, we have developed the new manhole repairing composite structures by using a glass fiber-reinforced polymer (GFRP) pipe, which can raise manhole to the regular height of the overlayed road pavement with rapid construction and minimum traffic jams. This environmental-friendly technology is method completed by the methyl methacrylate monomer (MMA) double wide flanged GFRP pipe composite structures in order to raise manhole to the regular height. In this paper, two kinds of the compressive strength tests of MMA mortar composites were conducted and evaluated by a general compressive strength test, and compressive strength test after freezing-thawing resistance test. It was found that this MMA mortar composites will be used for the application of the double wide flanged GFRP pipe composite structures.

Consolidation of Incineration Fly Ash by Solvothermal Reaction

  • Masuda, Kaoru;Endoh, Shigehisa
    • Proceedings of the IEEK Conference
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    • 2001.10a
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    • pp.655-658
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    • 2001
  • The generation of fly ash tends to increase yearly so that this is currently considered a big environmental concern, which requires appropriate treatment approaches. In this research the consolidation of incineration fly ash by the hot-press solvothermal reaction was investigated to provide an alternative process for the treatment and utilization of this waste material. Results showed that at reaction conditions of 52 K treatment, 20 ㎫ pressure and 60 minutes treatment time, the resulting consolidate exhibited a compressive ness strengths of 37-40 ㎫, a tensile strength of 6.5-7.0 ㎫ and a Rockwell hardness of 20-23 RH15W. These properties are comparable to the compressive ness strength of Portland cement which ranges from 30-40 ㎫ as well as with the tensile strengths of mortar, ganite, artificial lightweight aggregate and solidified high connote whose values are 2-2.5 ㎫, 5-9 ㎫, 5-10 ㎫ and 3-5 ㎫ respectively- Furthermore, by mixing fly ash with glass at 50% ratio and then subjecting to similar treatment conditions, a consolidate with even higher tensile strength of 12.5-13.3 ㎫ and hardness of 77-80 RH15W may be achieved.

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On the effect of GFRP fibers on retrofitting steel shear walls with low yield stress

  • Edalati, S.A.;Yadollahi, Y.;Pakar, I.;Bayat, M.
    • Earthquakes and Structures
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    • v.8 no.6
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    • pp.1453-1461
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    • 2015
  • In this article the non-linear behavior of the shear wall with low yield stress retrofitted with Glass Fiber Reinforced Polymer (GFRP) is investigated under pushover loading. The models used in this study are in ${\frac{1}{2}}$ scale of one story frame and simple steel plates with low yield stress filled the frame span. The models used were simulated and analyzed using finite elements method based on experimental data. After verification of the experimental model, various parameters of the model including the number of GFRP layers, fibers positioning in one or two sides of the wall, GFRP angles in respect to the wall and thickness of the steel plate were studied. The results have shown that adding the GFRP layers, the ultimate shear capacity is increased and the amount of energy absorbed is decreased. Besides, the results showed that using these fibers in low-thickness plates is effective and if the positioning angle of the fibers on the wall is diagonal, its behavior will improve.

Improvement of Organics and Nitrogen Removal by HRT and Recycling Rate in Air Lift Reactors (공기부상반응조에서 체류시간과 반송율에 의한 유기물질 및 질소제거 향상에 관한 연구)

  • Kim, Jin-Ki;Yu, Sung-Whan;Lim, Bong-Su
    • Journal of Korean Society on Water Environment
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    • v.22 no.1
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    • pp.45-50
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    • 2006
  • This study was performed to evaluate the air lift reactors (ALR) by variations of HRT and recycling rate. Air lift reactor was composed of bioreactor and clarifier above it. To remove organic matters and nitrogen through the formation of microbic film and filtration, bio-filter reactors were filled with clay, glass, bead, waste plastic, respectively. Influent wastewater was fed to biofilter reactor, and effluent wastewater from bio-filter reactor was injected ALR again, instead of adding external carbon source. Effluent BOD concentration was satisfied with lower than 10 mg/L in recycling rate 100% regardless of the variation of HRT and the kinds of media materials. In HRT 4 hr, recycling rate 100%, BOD removal efficiency rate was from about 85 to 90%, COD removal efficiency rate was higher than 90%. Effluent TN concentration was satisfied with less than 20 mg/L, if HRT was maintained by over than 6 hr regardless of recycling rate and media materials. Over than HRT was 4 hr, microbes concentration in air lift reactor was maintained over than 2,500 mg/L constantly, not sensitive to environmental condition, and organic removal was effective as it was higher.

Formation of electric circuit for printed circuit board using metal nano particles (금속 나노 입자를 이용한 인쇄 회로 기판의 회로 형성)

  • Joung, Jae-Woo
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2007.06a
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    • pp.545-545
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    • 2007
  • Recently, innovative process has been investigated in order to replace the conventional high-cost micro patterning processes on the electronic products. To produce desirable profit margins from this low cost products, printed circuit board(PCB), will require dramatic changes in the current manufacturing philosophies and processes. Innovative process using metal nano particles replaces the current industry standard of subtractive etched of copper as a highly efficient way to produce robust circuitry on low cost substrates. An advantage of using metal nano particles process in patterned conductive line manufacturing is that the process is additive. Material is only deposited in desired locations, thereby reducing the amount of chemical and material waste. Simply, it just draws on the substrate as glass epoxy or polyimide with metal nano particles. Particles, when their size becomes nano-meter scale, show some specific characteristics such as enhanced reactivity of surface atoms, decrease in melting point, high electric conductivity compared with the bulk. Melting temperature of metal gets low, the metal nano particles could be formated onto polymer substrates and sintered under $300^{\circ}C$, which would be applied in PCB. It can be getting the metal line of excellent electric conductivity.

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A Study on Field-to-lab Test Method for the Safe Transport and Optimum Packaging Design of the Parcel Delivery in Korea (국내 택배화물의 안전운송 및 적정포장을 위한 Field-to-Lab 시험방법 연구)

  • Oh, Jae Young;Suh, Sang Uk;Lim, Mijin
    • KOREAN JOURNAL OF PACKAGING SCIENCE & TECHNOLOGY
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    • v.28 no.2
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    • pp.127-132
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    • 2022
  • The growth of e-commerce market requires more delivery packagings, which protect goods from the damage factors on the delivery. In this study, we have analyzed the distribution environment data (vibration and impact) measured in previous study and compared with global standards (ISTA, ASTM), so that we developed the testing method for Field-to-Lab simulation suitable to the domestic delivery. In order to verify the efficacy of this method, we took the Field-to-Lab tests for 3 packaged products (detergents set, glass tableware set, small furniture), which has been frequent breakages or damages on the actual delivery by e-commerce order, so that we could find out the test results were similar to those of the actual delivery occasions. In addition, we could perform redesign and improvement of the parcel delivery packagings for safe transportation by taking this Field-to-Lab test repeatedly. This test methods was finally proposed to be Korean industrial standard (KS), and is expected to be useful as a designing tool for the packaging optimization between protecting goods and reducing packaging waste.

Performance Evaluation of Artificial Lightweight Aggregate Mortar Manufactured with Waste Glass (폐유리로 제조된 인공경량골재를 이용한 모르타르의 물리적 성능에 대한 평가)

  • Kim, Seong-Soo;Lee, Jeong-Bae;Nam, Ba-Reum;Park, Kwang-Pil
    • Journal of the Korea Concrete Institute
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    • v.21 no.2
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    • pp.147-152
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    • 2009
  • The compressive strength test, bulk density and mortar absorption ratio were carried out to utilize the data as the basic sources for the lightweight mortar and the lightweight concrete, through the study on the physical characteristics of the artificial lightweight aggregate (ALA) made of waste glasses, which was developed for the first time in the country. On the basis of these experiments, the density and the unit volume weight of the ALA showed the value less than 50% of the common aggregate due to the independent pore structure, and the mortar that contains ALA had no big difference from the Control mortar in the test of the absorption ratio. It is judged that this happens based on the internal independent pore structure of the ALA. In case of the mortar containing ALA, there was a tendency of declination in the compressive strength and the bending strength as the mixing rate is increasing, but all mortar showed more than 70% of the Control mortar compressive strength except for the La50 mortar. Hereafter, it is judged that according to the control of the mixing ratio of mineral admixing agent, water and cement, it will realize the equal strength to the control mortar, and the long term edurance is needed to be considered together.