• Title/Summary/Keyword: WO$_3$

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High-Efficiency Inverted Transparent Blue Organic Light-Emitting Devices

  • Chen, Szu-Yi;Chu, Ta-Ya;Chen, Chao-Jung;Chen, Jenn-Fang;Chen, Chin H.
    • 한국정보디스플레이학회:학술대회논문집
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    • 2006.08a
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    • pp.984-986
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    • 2006
  • We report efficient inverted transparent blue OLEDs (ITOED) with an hole injection layer prepared by co-evaporation of $WO_3$ with NPB, which achieved a total current efficiency of 10.7 cd/A at $20mA/cm^2$ with light emits from both ITO bottom cathode and Au top anode in about 3:1 ratio.

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Characterization of Synthesized WS$_2$ Solid Lubricant (합성 WS$_2$ 고체윤활제의 특성 분석)

  • 신동우;윤대현;최인혁;김인섭
    • Proceedings of the Korean Society of Tribologists and Lubrication Engineers Conference
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    • 1997.10a
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    • pp.211-216
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    • 1997
  • The tungsten disulfide (WS$_2$) solid lubricant was synthesized by two different reaction processes, and the chemical and physical characteristics of synthesized WS$_2$ powder were analyzed in terms of the average particle size, morphology, crystalline phase. The solid WO$_3$ powder with the average size of 0.2 $\mu$m was reacted with CS$_2$ gas flowed with N$_2$ or 96% N$_2$ + 4% H$_2$ forming gas for 36 h and 24 h at 900$\circ$C respectively. In the case of vapour phase transport method, the 3.5 wt% iodine was added as a vapour transport reagent into the composition of tungsten and sulfur powders maintaining a constant molar ratio of W : S = 1 : 2.2. The mixture was then heat treated at 850$\circ$C for 2 weeks in vacuum The reaction product obtained showed the average size of 12 $\mu$m and the hexagonal plate shape of typical solid lubricant with 2H-WS$_2$ crystalline phase.

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Preparation of hybrid organic PEC cell with muti-functional nanomaterial (기능성 나노물질을 포함하는 하이브리드 유기 PEC 셀의 제조)

  • Kim, Min-Gyeong;Jeong, Jae-Hun;Im, Dong-Chan
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2015.11a
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    • pp.266-266
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    • 2015
  • 전 세계적으로 무한한 청정에너지 개발에 대한 연구가 주목받고 있다. 그 중, 수소에너지는 화석연료의 고갈과 환경문제를 동시에 해결할 수 있는 자원이며 수소 생산 방법 중에서도 태양에너지를 이용한 수소 생산 기술은 가장 이상적인 수소 생산 시스템이라 할 수 있다. 대표적인 광전극 소재로는 $WO_3$, ZnO, $Fe_2O_3$, $BiVO_4$ 등과 같은 무기 소재가 주로 사용되고 있으며, 최근에는 Si, CIGS 등과 같은 태양전지와 상기 광전극을 집적하는 탄뎀형 소재/소자가 개발되고 있다. 광전반응이 우수한 전도성 고분자는 광전기화학 전지의 소재로 개발되고 있다. 그러나 유기물의 수중 불안전성 문제 때문에 직접적으로 물에 침전시키는 것이 아니라 외부의 인가 전원용으로 그 사용이 제한적이다. 본 연구에서는 유기계 소재의 direct energy conversion을 위한 효율 및 수중 안정성 향상을 위하여 Ni계 촉매 및 그래핀옥사이드가 융합된 유기기반 광전기화학전지를 개발하였다.

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Explosion-proof LNG/LPG and solvent sensors (방폭형 LNG/LNG 및 솔벤트 센서)

  • Cha, Sung-Ik;Shin, Paik-Kyun;Lee, Boong-Joo;Joo, Sang-Heun;Kim, Jong-Won;Min, Nam-Ki
    • Proceedings of the KIEE Conference
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    • 2003.07c
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    • pp.1475-1477
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    • 2003
  • 본 논문에서는 LNG/LPG 센서와 솔벤트 센서를 국산화한 결과를 보고한다. LNG/LPG 센서는 $SnO_{2-}\;WO_3$ 모물질에 Pd, Pt 촉매를 첨가하여 제작하였다. 센서를 $400^{\circ}C$ 이상에서 동작시키면 CO가 촉매층에서 거의 $CO_2$로 산화되어 감지막의 저항변화에 아무런 기여도 못하기 때문에 팔라듐 촉매 센서부와 백금촉매 센서부의 신호로부터 탄화수소와 CO를 구별할 수 있다. 또한 촉매층 위에 다공성 보호층를 형성하여 촉매층과 감지막을 보호함으로써 장기 안정성이 크게 향상 되었다. 한편, 감지물질로 $BaSnO_3$를 사용해 제작된 솔벤트 센서는 에탄올에 매우 우수한 감도와 선택성을 나타내었다.

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Effect of TiC Content on Oxidation Behavior of Sintered WC-TiC-TaC Alloys

  • Tanaka, Hiroki;Mouri, Shigeki;Nakahara, Kenji;Sano, Hideaki;Zheng, Guo Bin;Uchiyama, Yasuo
    • Proceedings of the Korean Powder Metallurgy Institute Conference
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    • 2006.09a
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    • pp.352-353
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    • 2006
  • The effect of TiC content on oxidation behavior of the sintered WC-TiC-TaC alloys with 2 mass% TaC and different TiC amounts of 3-45 mass% was investigated through oxidation tests in air at 973K. As a result of the tests, it was revealed that with increasing TiC content in the alloys, mass changes caused by oxidation and thickness of the scale decreased. Thus, it is considered that the main component of the scales changed gradually from $WO_3$ to $TiO_2$ with increasing TiC content in the alloys, and oxygen diffusion through the scale to the alloys was inhibited gradually.

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Fabrication of Nano-sized WC/Co Composite Powder by Direct Reduction and Carburization with Carbon

  • Lee, Dong-Ryoul;Lee, Wan-Jae
    • Proceedings of the Korean Powder Metallurgy Institute Conference
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    • 2006.09a
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    • pp.642-643
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    • 2006
  • Direct reduction and carburization process was thought one of the best methods to make nano-sized WC powder. The oxide powders were mixed with graphite powder by ball milling in the compositions of WC-5,-10wt%Co. The mixture was heated at the temperatures of $600{\sim}800^{\circ}C$ for 5 hours in Ar. The reaction time of the reduction and carburization was decreased as heating temperatures and cobalt content increased. The mean size of WC/Co composite powders was about 260 nm after the reactions. And the mean size of WC grains in WC/Co composite powders was about 38 nm after the reaction at $800^{\circ}C$ for 5 hours.

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Research Trends on Literature Reviews in Scopus Journals by Authors from Indonesia, Japan, South Korea, Vietnam, Singapore, and Malaysia: A Bibliometric Analysis from 2003 to 2022

  • Prakoso Bhairawa Putera;Amelya Gustina
    • Asian Journal of Innovation and Policy
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    • v.12 no.3
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    • pp.304-322
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    • 2023
  • Text data mining ('big data methods') is one of the most widely used approaches during the COVID-19 pandemic. In particular, text data mining on Scopus databases or Web of Science (WoS). Text data mining is widely used to collect literature for later bibliometric analysis, and in the end, it becomes a literature review article. Therefore, in this article, we reveal the trend of publication of literature reviews in Scopus journals from Indonesia, Japan, South Korea, Vietnam, Singapore, and Malaysia. This article describes two essential parts, namely 1) a comparison of international publication trends and subject area of literature review publications, and 2) a comparison of Top 5 for Authors, Affiliation, Source Title, and Collaboration Country.

On the Genesis of Okbang Tungsten Deposits (옥방(玉房) 중석광상(重石鑛床)의 성인(成因)에 관(關)한 연구(硏究) -특(特)히 남부광체(南部鑛體)에 대(對)하여-)

  • Youn, Jeung Su
    • Economic and Environmental Geology
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    • v.12 no.4
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    • pp.181-195
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    • 1979
  • The Nambu orebodies of the Okbang tungsten mine are hosted in the Precambrian amphibolite and Weonnam formation. These orebodies can be classified into two types; The scheelite-bearing ore vein occurring in the amphibolite (the Nambu 1, 2 adits) and tungsten-bearing quartz vein along the contact between the amphibolite and the Weonnam formation (the Young-ho, -1, -2, -3 levels). The scheelite-bearing ore vein in the amphilbolite is discontinuous, narrow, and highly irregular in geometry, occurring only within the amphibolite with which of the vein is graduational. Based on these feature of the mode of occurrence, the origin of this ore type might be attributed to a potential segregation of tungsten ore fluid in situ from hornblenditic basic magma of the host rock. Tungsten-bearing quartz vein, however, is considered to have deposited along the N30-60E trending fractures as a later hypothermal vein after the hornblendite was emplaced. The principal ore mineral is scheelite with minor amount of wolframite, and the gangue minerals are quartz, and small amounts of fluorite, pyrrhotite, chalcopyrite and calcite. Fluid inclusion study of minerals from the Nambu orebody reveals that the fluids in fluorite of the scheelite-bearning ore vein attained a temperature range of $208{\sim}256^{\circ}C$ and those in quartz from the tungsten-bearing quartz vein a temperature range of $220{\sim}357^{\circ}C$. The real formation temperatures can be somewhat higher than filling temperatures, if pressure correction is made. Chemical analysis of 8 amphibolitc samples on major and some trace elements indicate that the amphibolite is igneous origin. On a Niggli diagram (al-alk)versus c, the analytical values are plotted on an igneous field, and on a Niggli diagram mg versus c they follow a karroo igneous trend line. According to the Ba, Cr, and Ni versus Niggli mg plots suggested by Leake (1964), Okbang amphibolite fall outside a pelitic field and compare favorably with his plots form ortho-amphibolites. Analitical values of $MoO_3$ of 8 samples of scheelite minerals from the Nambu orebody indicate that the tungsten-bearing quartz vein (type n) of Nambu orebody shows a range from 1. 69% to 4.38% which is higher than 0.94%~3.25% $MoO_3$ for the scheelite-bearing ore vein (type I). This fact indicates that the type II was deposited in a lower $fO_2/higher$ $fO_2$ environment and under lower temperature than the type I. Analysis of major components $WO_3$, MnO, and FeO of 6 samples of wolframite from the type II veins revealed that they contain 73.35~76.2% $WO_3$, 7.94~11.63% MnO, and 10.53~14.82% FeO. MnO/FeO ratios of wolframite shows the range of 0.85~1.17 which suggests a slightly higher temperature type of deposits than other major tungsten deposits in the country.

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Application of SNCR/SCR Combined process for effective operation of SCR Process

  • 최성우;최상기
    • Journal of Environmental Science International
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    • v.12 no.1
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    • pp.47-54
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    • 2003
  • This paper have examined the optimum combination of SNCR and SCR by varying SNCR injection temperature and NSR ratio along with SCR space velocity. NOx reduction experiments using a SNCR/SCR combined process have been conducted in simple NO/NH$_3$/O$_2$ gas mixtures. Total gas flow rate was kept constant 4 liter/min throughout the SNCR and SCR reactors, where initial NOx concentration was 500 ppm in the presence of 5% O$_2$. Commercial catalyst, sulfated V$_2$O$\_$5/-WO$_3$/TiO$_2$, was used for SCR NOx reduction. The residence time and space velocity were around 1.67 sec, 2,400 h$\^$-1/ and 6,000 h$\^$-1/ in the SNCR and SCR reactors, respectively. SNCR NOx reduction effectively occurred in a temperature window of 900-950$^{\circ}C$. About 88% NOx reduction was achieved with an optimum temperature of 950$^{\circ}C$ and NSR=1.5. SCR NOx reduction using commercial V$_2$O$\_$5/-WO$_3$-SO$_4$/TiO$_2$ catalyst occurred in a temperature window of 200-450$^{\circ}C$ 80-98% NOxreduction was possible with SV=2400 h$\^$-1/ and a molar ratio of 1.0-2.0. A SNCR/SCR(SV=6000 h$\^$-1/) combined process has shown same NOx reduction compared with a stand-alone SCR(SV=2400 h$\^$-1/) unit process of 98% NOx reduction. The NH$_3$-based chemical could routinely achieve SNCR/SCR combined process total NOx reductions of 98% with less than 5 ppm NH$_3$ slip at NSR ranging from about 1.5 to 2.0, SNCR temperature of 900$^{\circ}C$-950$^{\circ}C$, and SCR space velocity of 6000 h$\^$-1/. Particularly, more than 98% NOx reduction was possible using the combined process under the conditions of T$\_$SNCR/=950$^{\circ}C$, T$\_$SCR/=350$^{\circ}C$, 5% O$_2$, SV=6000 h$\^$-1/ and NH$_3$/NOx=1.5. A catalyst volume was about three times reduced by SNCR/SCR combined process compared with SCR process under the same controlled conditions.

Luminescence of $Eu^{3+}$ and $Sm^{3+}$ Doped Potassium Tungstate Phosphor

  • Lee, Gwan-Hyoung;Kim, Tae-Hyung;Kang, Shin-Hoo
    • Journal of Information Display
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    • v.6 no.2
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    • pp.25-29
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    • 2005
  • The luminescent properties of $Eu^{3+}$ and $Sm^{3+}$ doped potassium tungstate phosphor are investigated. The $K_{4-3x}(WO_4)_2:Eu^{3+}\;_x,Sm^{3+}\;_y$ phosphor is produced by firing the mixed precursors, followed by re-firing with a flux. The re-firing process results in the defect-free surface and uniform growth of the particles. The strong absorption in the region of ultra violet light is observed due to the 4f-4f electron transitions of the $Eu^{3+}$ and $Sm^{3+}$ ions. The doping concentration of europium into potassium tungstate is relatively high, compared to other host materials. It is revealed that the crystal structure is a monoclinic with space group, C2/c. This crystal structure facilitated the $Eu^{3+}$ ions to be located with the Eu-Eu distance larger than 5 ${\AA}$ so that concentration quenching does not occur even at high doping concentration. The excitation spectrum could be adjusted by the introduction of the samarium. A small amount of the $Sm^{3+}$ ions that acts as a sensitizer increases the energy absorption peak around 405 nm.