• Title/Summary/Keyword: WO$_3$

Search Result 728, Processing Time 0.038 seconds

Microwave Dielectric Properties of (Ba1-2xNa2x)(Mg0.5-xZrxW0.5)O3 Ceramics ((Ba1-2xNa2x)(Mg0.5-xZrxW0.5)O3 세라믹스의 마이크로파 유전특성)

  • Yoon, Sang-Ok;Hong, Chang-Bae;Lee, Yun-Joong;Kim, Shin
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
    • /
    • v.30 no.6
    • /
    • pp.356-360
    • /
    • 2017
  • We investigated the phase evolution, microstructure, and microwave dielectric properties of Na- and Zr-doped $Ba(Mg_{0.5}W_{0.5})O_3$ [i.e., ($Ba_{1-2x}Na_{2x})(Mg_{0.5-x}Zr_xW_{0.5})O_3$] ceramics. $BaWO_4$ as a secondary phase was observed in all compositions, and it increased as the dopant concentration increased. All specimens revealed a dense microstructure. For the composition of x=0.01, polyhedral grains were observed. As the dopant concentration increased, the densification and the grain growth were promoted by a liquid phase. The quality factor($Q{\times}f_0$) decreased remarkably, whereas the dielectric constant (${\varepsilon}_r$) tended to decrease as the dopant concentration increased. The dielectric constant, quality factor, and temperature coefficient of the resonant frequency of the composition of x=0.01 sintered at $1,700^{\circ}C$ for 1 h were 18.6, 216,275 GHz, and $-22.0ppm/^{\circ}C$, respectively.

Characteristics of W-Mo Mineralization in Dulaankhaikhan area, Mongolia (몽골 중부 둘란하이한 지역의 W-Mo 부존 특성)

  • Lee, Bum Han;Kim, In Joon;Heo, Chul-Ho
    • Mineral and Industry
    • /
    • v.26
    • /
    • pp.22-31
    • /
    • 2013
  • KIGAM and MRAM (Mineral Resources Authority of Mongolia) performed joint researches on geological survey of Dulaankhaikhan W-Mo occurrences areas in southeastern part of Khangai region. XRD results of tungsten containing quartz vein sample show that tungsten minerals are wolframite, hubnerite and ferberiteore. $WO_3$ grade of samples obtained in Silurian Khotont formation is 0.11-4.43% and that of samples obtained in Permian Delgerkhan complex is 137-3844 ppm. Average total $R_2O_3$ of samples obtained in survey area is 473 ppm which is 2.5 times larger than that of Earth's crust. The highest total $R_2O_3$ is 1326 ppm. Factor analysis results show that two areas of high tungsten contents have similar correlations with tungsten, and therefore we conclude that these two areas have the similar origin of mineralization.

  • PDF

Nonstoichiometry of the Tungsten Oxide (산화 텅스텐의 비화학량론)

  • Ryu, Kwang Hyun;Oh, Eung Ju;Kim, Keu Hong;Yo, Chul Hyun
    • Journal of the Korean Chemical Society
    • /
    • v.39 no.3
    • /
    • pp.157-162
    • /
    • 1995
  • The x values and electrical conductivities of the nonstoichiometric compounds $WO_{3-x}$ have been measured in the temperature range from 350 to 700$^{\circ}C$ under oxygen partial pressure of $2{\times}10_{-1}\;to\;1{\times}10_{-5}$ atm. The enthalpy of the defect formation shows an endothermic process, and the oxygen pressure dependence of the defect formation or 1/n varies from -1/5.2 to -1/5.9. The activation energy and 1/n value for the electrical conductivity are 0.24~0.29 eV and -1/4.3~-1/7.6, respectively. The Tungsten Oxide as a n-type semiconductor has predominently defect model of singly charged oxygen vacancy at low temperature, and of doubly charged oxygen vacancy at high temperature.

  • PDF

Synthesis and Rapid Consolidation of W-1.5 ZrO2 Composite (W-1.5 ZrO2 복합재료 합성과 급속소결)

  • Kim, Seong-Eun;Shon, In-Jin
    • Korean Journal of Materials Research
    • /
    • v.28 no.11
    • /
    • pp.653-658
    • /
    • 2018
  • $ZrO_2$ is a candidate material for hip and knee joint replacements because of its excellent combination of biocompatibility, corrosion resistance and low density. However, the drawback of pure $ZrO_2$ is a low fracture toughness at room temperature. One of the most obvious tactics to cope with this problem is to fabricate a nanostructured composite material. Nanomaterials can be produced with improved mechanical properties(hardness and fracture toughness). The high-frequency induction heated sintering method takes advantage of simultaneously applying induced current and mechanical pressure during sintering. As a result, nanostructured materials can be achieved within very short time. In this study, W and $ZrO_2$ nanopowders are mechanochemically synthesized from $WO_3$ and Zr powders according to the reaction($WO_3+3/2Zr{\rightarrow}W+3/2ZrO_2$). The milled powders are then sintered using high-frequency induction heating within two minutes under the uniaxial pressure of 80MPa. The average fracture toughness and hardness of the nanostructured W-3/2 $ZrO_2$ composite sintered at $1300^{\circ}C$ are $540kg/mm^2$ and $5MPa{\cdot}m^{1/2}$, respectively. The fracture toughness of the composite is higher than that of monolithic $ZrO_2$. The phase and microstructure of the composite is also investigated by XRD and FE-SEM.

AC impedance study on the interface between organic electrolyte and amorphous $WO_3$ thin film relating to the electrochemical intercalation of lithium (비정질 $WO_3$ 박막과 전해질 계면에서의 리튬 층간 반응의 교류 임피던스 해석)

  • Kim Byoung-Chul;Ju Jeh-Beck;Sohn Tae-Won
    • Journal of the Korean Electrochemical Society
    • /
    • v.1 no.1
    • /
    • pp.33-39
    • /
    • 1998
  • To AC impedance study was performed in this study on the interfacial reaction between organic electrolyte and amorphous tungsten oxides thin film, cathodically coloring oxide, prepared by e-beam evaporation method in the 1 M $LiClO_4/PC$ organic solution. The electrochemical reactions at the interface were analyzed by the transient method and the complex impedance spectroscopy. The impedance spectrums showed that the electro-chemical intercalation of lithium cations was consisted of the following three steps; the first step, the charge transfer reaction of lithium cation at the interface between amorphous tungsten oxides thin film and the organic electrolyte, the second step, the adsorption of lithium atom on the surface of amorphous tungsten oxides thin film, and then the third step, the absorption and the diffusion of lithium atom into amorphous tungsten oxides thin layer. The bleaching and the coloring characteristics of amorphous tungsten oxides thin film were explained in terms of thermodynamic and kinetic variables, the simulated $R_{ct},\;C_{dl},\;D$ and $\sigma_{Li}$ by CNLS fitting method. Especially it was found that the limiting values of electrochromic reaction were the molar ratio of lithium, y=0.167 and the electrode potential, E=2.245 V (vs. Li).

A Textual Research on Hu ShunShen (胡舜申)'s Life and Works (호순신(胡舜申)의 생애와 저술에 관한 연구)

  • Oh, Dong Kee
    • Korean Journal of Heritage: History & Science
    • /
    • v.44 no.3
    • /
    • pp.44-61
    • /
    • 2011
  • This study consider the life and works of Hu ShunShen(胡舜申) who was the author of JiRiSinBub(地理新法) which the representative FengShui book in Choson dynasty. His adult name is RuJia(汝嘉). He was born in on September 6, 1091 at JiXi(績溪) in China as a son of Ho Xian(胡咸). He left his hometown with his family to avoid war and settled down in HuZhou(胡州). He took up an official post with his brother's YinPu(蔭補), and held several provincial official posts. After serving as vice governor(通判) of ShuZhou(舒州), he became supervisor of taoist temple(崇道觀) in TaiZhou(台州) and retired from office. After burying his father, he took an interest in fengShui(風水) and studied for a long time. People say that JiangXiDilixinfa(江西地理新法) is the well-known FengShui book written by him. When he was 74 years old, he suggested opening SheMen(蛇門) gate and XuMen(胥門) gate in SuZhou(蘇州) castle by "WoMenZhongGao(吳門忠告)". But it didn't come ture. He died March 9, 1177 at the age of 87 and was buried in HuZhou(胡州). His elder brother Hu Shunzhi(胡舜陟) and nephew HuZi(胡仔) is well-known. He had a son named Hu wei(胡偉) who served pacification commissioners of JiangXi(江西宣撫使). His Works were YiSiSiZhouLu(乙巳泗州錄), YiYouBiLuanLu(己酉避亂錄) as essay and YinYangBeiYong(陰陽備用), JiRiSinBub(地理新法), "WoMenZhongGao(吳門忠告)" as fengShui text.

Transition Program for Youth With Disabilities: Research Trend Analysis and Systematic Review (장애청소년의 전환프로그램 : 연구 동향 분석과 체계적 고찰)

  • An, Su-bin;Park, Hae Yean
    • Therapeutic Science for Rehabilitation
    • /
    • v.11 no.3
    • /
    • pp.23-36
    • /
    • 2022
  • Objectives : This study aimed to provide basic data on intervention strategies that occupational therapists can access by systematically analyzing the intervention and effectiveness for youth with disabilities. Methods : The RISS, PubMed, and Web of Science databases were used to search for papers published between 2006 and 2021. The keywords were "Disability AND Adolescents OR Young adult AND Transition education OR Transition program". Seven papers were selected for analysis, and the full text was reviewed. The keywords and national relations were analyzed and visualized using the WoS (Web of Science) and VOSviewer programs. Results : The participants were classified into five types (ASD or ADHD, ID, DD, and physical disability). The areas used for the intervention were mixed into three categories: occupation (academic), self-management (time), and interaction (personal relations and communication). Sociality and adaptation, quality of life, and at least one of the three categories of daily life activities showed significant improvement. Conclusions : This study can be used as basic data to expand the area where only OTs can contribute while grasping the research trend of the conversion program and presenting the direction of exchange with various experts by organizing the application and its effects.

A Study on the Research Trends on Literacy in Library and Information Science (문헌정보학 분야의 리터러시 연구 동향 분석)

  • Jang, Su Hyun;Nam, Young Joon
    • Journal of the Korean Society for information Management
    • /
    • v.39 no.3
    • /
    • pp.263-292
    • /
    • 2022
  • The purpose of this study is to identify the topics of research related to the concepts of literacy in the field of Library and Information Science which is related to user education in libraries. Data were collected from the WoS and KCI databases, and complementary keyword analysis and topic modeling analysis techniques were used to identify topics of literature-related research articles in the field of Library and Information Science. Findings presented that there was a difference in keywords and topics between the two databases. Literacy-related topics identified from the KCI database were classified into three groups through topic modeling. Also, it was analyzed that there is a difference between the overall literacy-related research trend, the timing of the surge in research volume, and key frequent keywords in the Library and Information Science field confirmed in the study. In particular, in the study of literacy in all fields, a number of words such as 'literacy', 'education', 'media', and 'digital' were derived. However, in literature research in the field of Library and Information Science, keywords such as 'information utilization ability' and 'school library' appeared. Based on this, it was concluded that research on the ability to develop an evaluative eye for information is needed in line with today's information environment, where information is rapidly increasing in Korea in the future.

Physicochemical Characterization of Powder Byproducts Generated from a Metallization Process and Its 1st Scrubber in the Semiconductor Industry (반도체 메탈공정 및 1차 스크러버에서 생성되는 파우더 부산물의 물리화학적 특성분석)

  • Choi, Kwang-Min;Jung, Myung-Koo;An, Hee-Chul
    • Journal of Korean Society of Occupational and Environmental Hygiene
    • /
    • v.25 no.3
    • /
    • pp.294-300
    • /
    • 2015
  • Objectives: The aim of this study is to identify physicochemical properties such as chemical composition, size, shape and crystal structure of powder byproducts generated from a metallization process and its 1st scrubber in the semiconductor industry. Methods: Powder samples were collected from inner chambers during maintenance of the W-plug process equipment (using tungsten hexafluoride as a precursor material) and its 1st scrubber. The chemical composition, size and shape of the powder particles were determined by field emission scanning electron microscopy (SEM) and transmission electron microscopy (TEM) equipped with an energy dispersive spectroscope (EDS). The crystal structure of the powders was analyzed by X-ray diffraction (XRD). Results: From the SEM-EDS and TEM-EDS analyses, O and W were mainly detected, which indicates the powder byproducts are tungsten trioxide ($WO_3$), whereas Al, F and Ti were detected as low peaks. The powder particles were spherical and nearly spherical, and the particle size collected from the process equipment and its 1st scrubber showed 10-20 nm (agglomerates: 55-90 nm) and 16-20 nm (agglomerates: 80-120 nm) as primary particles, respectively. The XRD patterns of the yellow powder byproducts exhibit five peaks at $23.8^{\circ}$ $33.9^{\circ}$ $41.74^{\circ}$ $48.86^{\circ}$ and $54.78^{\circ}$ which correspond to the (200), (220), (222), (400), and (420) planes of cubic $WO_3$. Conclusions: We elucidated the physicochemical characteristics of the powder byproducts collected from W-plug process equipment and its 1st scrubber. This study should provide useful information for the development of alternative strategies to improve the working environment and workers' health.

Chemiresistive Sensor Array Based on Semiconducting Metal Oxides for Environmental Monitoring

  • Moon, Hi Gyu;Han, Soo Deok;Kang, Min-Gyu;Jung, Woo-Suk;Jang, Ho Won;Yoo, Kwang Soo;Park, Hyung-Ho;Kang, Chong Yun
    • Journal of Sensor Science and Technology
    • /
    • v.23 no.1
    • /
    • pp.15-18
    • /
    • 2014
  • We present gas sensing performance based on $2{\times}2$ sensor array with four different elements ($TiO_2$, $SnO_2$, $WO_3$ and $In_2O_3$ thin films) fabricated by rf sputter. Each thin film was deposited onto the selected $SiO_2$/Si substrate with Pt interdigitated electrodes (IDEs) of $5{\mu}m$ spacing which were fabricated on a $SiO_2$/Si substrate using photolithography and dry etching. For 5 ppm $NO_2$ and 50 ppm CO, each thin film sensor has a different response to offers the distinguishable response pattern for different gas molecules. Compared with the conventional micro-fabrication technology, $2{\times}2$ sensor array with such remarkable response pattern will be open a new foundation for monolithic integration of high-performance chemoresistive sensors with simplicity in fabrication, low cost, high reliablity, and multifunctional smart sensors for environmental monitoring.