• Fibers and Polymers
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• 제1권1호
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• pp.25-31
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• 2000

Poly(3-hexyl thiophene)(P3HT) and poly(3-dodecyl thiophene)(P3DT) were polymerized by oxidative coupling with ferric chloride. The P3HT light-emitting device emitted red light and it could be observable in the ordinary indoor light. The device had the turn-on electric field of about 3$\times$$10^7$ V/m. The maximum electroluminescene (EL) intensity was obtained when the thickness of polymer layer was about 130 nm in IT0/P3HT/Al device. The maximum external quantum yield was 0.002%. The maximum luminance was 21 cd/$m^2$. The EL intensity decreases with increasing the crystallinity of the polymer layer. By using the oriented poly(3-alkyl thiophene)(PAT) layer as an electroluminescent layer in the ITO/polymer/Al light-emitting devices, the polarized EL light emission was observed. The EL intensity ratio of parallel to perpendicular direction to the stretch direction for P3HT was about 1.40.

• 공업화학
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• 제1권2호
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• pp.154-160
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• 1990

glucose의 농도에 따라 인슐린의 방출을 조절하기 위하여 3급 아민을 함유하는 Hydroxypropyl methacrylate 고분자막을 합성하였다. 이 막의 함수율은 수용액의 pH가 감소함에 따라 증가하였다. 인슐린의 투과도 역시 수용액의 pH가 감소함에 따라 증가하였다. 이 막에 당산화효소를 고정화시킨 acryl amine 막을 부착하여 복합막을 제조하였다. 이 막의 인슐린 투과도는 glucose의 농도가 증가함에 따라 증가하였다.

• 대한의용생체공학회:의공학회지
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• 제10권1호
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• pp.59-66
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• 1989

The Applicability of chitin or chitosan microsphere as means to achieve sustained release of p-aminosalicylic acid(PAS) has been examined. The microsphere of chitin or chitosan containing PAS were prepared by coacervation in acidic aqueous system in range of pH 2.0-4.0. The dissolution test of PAS from polymeric drug system was carried out in vitro test. The dissolution rate of PAS from the microsphere with chitin was significanthly lower than that from the microsphere with chitosan.The dissolution rate of PAS from the microsphere was decreased with increasing of concentration of chitin and chitosan. The sustained release of PAS from the microsphere was more effective at pH 1.2 than pH 6.8.

• 한국환경보건학회지
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• 제33권1호
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• pp.43-48
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• 2007

This study investigated the effects of pH, alkalinity, and chlorine ion which are important water quality impact factors to the corrosion in the simulated distribution system where the copper pipe is affixed. The result shows that pitting index was increased as the alkalinity and chloride ion increase in the distilled water, but there was no relation to pH. Actually the uniform corrosion rate was decreased as the pH increase with the laboratory tap water. In conclusion, it is necessary to control the pH which stands above minimum 7.5 to prevent pitting corrosion in the copper pipe. Consequently, comprehensive research about the effect of lime soda($Ca(OH)_2$) which was used as a coagulation additive in the water treatment plant to pipe corrosion must be accomplished additionally.

• Korean Chemical Engineering Research
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• 제57권1호
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• pp.133-141
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• 2019

침전법으로 환류방법 또는 수열합성법을 이용하여 산 염기점을 갖는 고비표면적 지르코니아를 합성하였다. 제조된 지르코니아는 침전제로 수산화암모늄 수용액을 사용하여 Zr 용액의 pH를 2에서 10 범위 내에서 조절하였으며 질소흡착분석, X-선 회절분석(XRD), 이소프로판올 승온탈착법(IPA-TPD), 주사전자현미경 분석, X-선 광전자분광분석, 산-염기점 분석을 통해 IPA 분해반응의 촉매활성과 연관하여 특성분석을 수행하였다. 환류방법을 사용할 시, tetragonal 상이 높은 지르코니아를 얻기 위해서는 Zr 용액의 pH가 높아야 하며, pH 9 이상에서는 순수한 tetragonal 상의 지르코니아 합성이 가능하였다. 또한, 비표면적이 큰 지르코니아를 얻기 위해서는 높은 pH가 요구되었으며, pH 10에서 합성한 경우에는 $600^{\circ}C$에서 소성 후에도 $260m^2g^{-1}$의 높은 비표면적이 얻어졌다. 하지만 같은 조건 하에서 고압이 수반되는 수열합성에는 $40m^2g^{-1}$ 이하의 매우 낮은 비표면적을 보였으며, monoclinic 상의 지르코니아가 합성되었다. 고 비표면적 tetragonal 상의 지르코니아를 얻기 위해서는 용액의 pH가 가장 큰 영향을 미쳤으며, 용액의 pH와 무관하게 높은 압력이 필요한 수열합성에서는 monoclinic 지르코니아가 생성되었으며 상대적으로 비표면적이 낮게 나타났다. 높은 비표면적과 tetragonal 상을 갖는 지르코니아는 염기점에 비해 산점이 우세하여 IPA 분해반응에서 선택적 탈수반응만 진행되는 프로필렌만 생성되었다.

• 대한전자공학회:학술대회논문집
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• 대한전자공학회 2008년도 하계종합학술대회
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• pp.387-388
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• 2008

In this paper, we have designed and fabricated hyperabrupt varactor diodes. Capacitance variations of hyperabrupt-doped varactor diodes are larger than those of uniform-doped varactor diodes. The measured reverse breakdown voltage of the fabricated varactor diodes was about 20 V. For the anode contact diameter of $50\;{\mu}m$, the maximum capacitance of the fabricated varactor diode was 2.1 pF and the minimum capacitance 0.44 pF. Therefore, the $C_{max}/C_{min}$ ratio was 4.77. Also, for the anode contact diameter of $60\;{\mu}m$, the maximum and minimum capacitances were 2.9 and 0.62 pF, respectively. And, thus, the $C_{max}/C_{min}$ ratio was 4.64.

• Journal of Microbiology and Biotechnology
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• 제4권3호
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• pp.165-170
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• 1994

An efficient and convenient method of introducing transposable elements into acetic acid bacteria was developed by the method of conjugal transfer. The ampicillin-resistant strain, Acetobacter sp. HA, was selected to be conjugated with two E. coli strains, WA803 containing pGS9 and AC8001 harboring pJB4JI. The Tn5 containing suicide vector pGS9 or pJB4JI, was transferred from E. coli to Acetobacter sp. HA and kanamycin-ampicillin-resistant transconjugants obtained at high frequencies. The conjugal frequencies of pGS9 and pJB4JI were 6.20$\times$$l0^{-1} and 2.79$\times$l0{-1}$ per recipient, respectively. The transfer method was applied on four different strains of Acetobacter. The conjugal transfer frequencies ranged from 2.00$\times$$l0^{-2} to 4.45$\times$l0^{-8}$ per recipient in the three strains. Some transconjugants tested were found to contain Tn5 DNA in their genomes and this was confirmed by Southem blot analysis. This is the first study which shows that Tn5 mutagenesis can be applied to successfully isolate mutants of Acetobacter genus.

• Composites Research
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• 제30권2호
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• pp.138-144
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• 2017

탄소나노튜브(CNT)를 이용하여 신율이 뛰어난 p-DCPD를 지로 사용하여 손상감지용 고분자 필름 센서를 연구하였다. CNT를 수지에 혼합시킬 경우 중합을 방해하여 1차 개환만 진행되었다. CNT 농도에 따른 정적접 촉각을 측정하여 계면의 젖음성을 측정하였다. 높은 신율을 가지는 p-DCPD에 CNT를 혼합시킴으로써 전도성을 확보하였고, CNT 농도에 따른 인장강도 및 전기저항 분산도 평가를 실시하였을 경우 0.5 wt% CNT/p-DCPD 조건이 최적의 조건임을 확인하였다. CNT/p-DCPD 센서의 내구성을 평가하기 위해 동적 피로 실험을 실시하여 인장응력에 따른 전기저항 변화를 평가하였다. 초기 3회 사이클 동안은 전기저항 변화도와 응력간의 결과가 유사한 경향을 나타내었다. CNT/p-DCPD 센서의 활용을 위해 에폭시 기지 표면에 센서를 붙이고 기지 재료의 파괴거동을 확인하였다. 기지 파괴가 발생되기 전에 CNT/p-DCPD 센서의 전기저항 점핑 신호를 관찰할 수 있었다. 이는 기지재료에 발생된 균열에 의해 CNT/p-DCPD 센서와 기지간의 접착 파괴로 발생된 신호이며, 이러한 신호를 이용하여 기지재료의 균열 및 파괴를 예측해 볼 수 있었다.

• Korean Membrane Journal
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• 제4권1호
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• pp.25-35
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• 2002

The gas permeation properties have been studied on carbon molecular sieve (CMS) membranes prepared by pyrolysis of P84 polyimide under various conditions. P84 polyimide shows high permselectivities (O$_2$/N$_2$= 9.17 and CO$_2$/N$_2$= 35) for various gas pairs and has a good processibility because it is easily soluble in high polar solvents such as N-methylpyrrolidinone (NMP), dimethylformamide (DMF), and N,N-dimethylacetamide (DMAc). After pyrolysis under Ar flow, the change in the heating rate was found to affect the gas permeation properties to some extent. The permeabilities of the selected gases were shown to be in the order He ＞ CO$_2$＞ O$_2$＞ N$_2$for all the CMS membranes, whose order was in accordance with the order of kinetic gas diameters. It also revealed that the pyrolysis temperature considerably influenced the gas permeation properties of the CMS membranes derived from P84 polyimide. The CMS membranes pyrolized at 700$\^{C}$ temperature exhibited the highest permeability with relatively targe loss in permselectivity. This means that the pyrolysis temperature should be varied in accordance with target gases to be separated.

• 한국환경농학회지
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• 제30권3호
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• pp.229-233
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• 2011

BACKGROUND: Soil acidification, which is known to be one of the reasons of forest decline, is associated with decreases in exchangeable Ca and increases in Al concentration, leading to low Ca/Al ratio in soil solution. As tree rings are datable archives of environmental changes, Ca/Al ratios of annual growth ring may show decreasing pattern in accordance with the progress of soil acidification. This study was conducted to investigate Ca/Al pattern of Pinus densiflora tree ring in an attempt to test its usefulness as an indicator of historical soil acidification. METHODS AND RESULTS: Three P. densiflora tree disks were collected from P. densiflora forests in Jeonnam province, and soil samples (0-10, 10-20, and 20-30 cm in depth) were also collected from the tree locations. Soils were analyzed for pH and exchangeable Ca and Al concentrations, and Ca/Al was calculated. Annual growth rings formed between 1969 and 2007 were separated and analyzed for Ca/Al. Soil Ca/Al was positively (P<0.01) correlated with soil pH, suggesting that soil acidification decreased Ca while increasing Al availability, lowering Ca/Al in soil solution. The Ca/Al of tree rings also showed a decreasing pattern from 18.2 to 5.5 during the period, and this seemed to reflect historical acidification of the soils. CONCLUSION(s): The relationship between soil pH and Ca/Al and the decreasing pattern of Ca/Al of tree ring suggest that Ca/Al of tree ring needs to be considered as a proxy of the progress of soil acidification in P. densiflora forest in southern Korea.