• Title/Summary/Keyword: W-N

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Microstructure and Mechanical Properties of Cr-Mo Steels for Nuclear Industry Applications

  • Kim, Sung-Ho;Ryu, Woo-Seong;Kuk, Il-Hiun
    • Nuclear Engineering and Technology
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    • v.31 no.6
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    • pp.561-571
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    • 1999
  • Microstructure and mechanical properties of five Cr-Mo steels for nuclear industry applications have been investigated. Transmission electron microscopy, energy dispersive spectrometer, differential scanning calorimeter, hardness, tensile, and impact test were used to evaluate the Cr and W effect on the microstructure and mechanical properties. Microstructures of Cr-Mo steels after tempering are classified into three types : bainitic 2.25Cr-lMo steel, martensitic Mod.9Cr-lMo, HT9M, and HT9W steels, and dual phase HT9 steel. The majority of the precipitates were found to be M$_{23}$C$_{6}$ carbides. As minor phases, fine needle-like V(C,N), spherical NbC, fine needle-like Cr-rich Cr$_2$N, and Cr-rich M$_{7}$C$_3$were also found. Addition of 2wt.% W in Cr-Mo steels retarded the formation of subgrain and dissolution of Cr$_2$N precipitates. Hardness and ultimate tensile strength increased with increasing Cr content. Though Cr content of HT9W steel was lower than that of HT9 steel, the hardness of HT9W was higher due to the higher W content. W added HT9W steel had the highest ultimate tensile strength above $600^{\circ}C$. But impact toughness of W added steel (HT9W) and high Cr steel (HT9) was low.w.w.

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The Anodicc PolarizationBehavior of Fe-Cr-Ni-W alloy in 1N HCI Solution (1N 염산 용액에서 Fe-Cr-Ni-W 합금의 양분극 거동에 관한 연구)

  • 윤재돈;강성군
    • Journal of the Korean institute of surface engineering
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    • v.21 no.4
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    • pp.176-182
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    • 1988
  • Effects of Cr, Ni and W on the anodic polarization behavior were investigated for Fe-Cr-Ni-W alloys in deaerated 1N HCI solution. Surface films formed on the polarization were analysed using AES, SEM and EDAX. A higerconcentration of tungten was found in the surface oxide film compared to the matrix. It played an importanet role on incresing the stability of the passive film. The presence of an adequate amount of Cr was essential to increase the pitting resistance of the alloys in acid chloride media. Under 12 wt%cr,alloys containing 6wt%W did not exhidit any passivity at all. The main role of Ni was to control the microstructure rather than to modify the corrosion resistance. In 23 cr-14Ni-^W alloy, the duplex microstructure of ferrite($\delta$-phase) in an austenic matrix was developed. The reson why proferred pitting appeared in austenite and ferrite/austenite interface was that ferrite had more amount of Cr and W than austenite.

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Tunable doping sites and the impacts in photocatalysis of W-N codoped anatase TiO2

  • Choe, Hui-Chae;Sin, Dong-Bin;Yeo, Byeong-Cheol;Song, Tae-Seop;Han, Sang-Su;Park, No-Jeong;Kim, Seung-Cheol
    • Proceedings of the Korean Vacuum Society Conference
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    • 2016.02a
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    • pp.246-246
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    • 2016
  • Tungsten-nitrogen (W-N) co-doping has been known to enhance the photocatalytic activity of anatase titania nanoparticles by utilizing visible light. The doping effects are, however, largely dependent on calcination or annealing conditions, and thus, the massive production of quality-controlled photocatalysts still remains a challenge. Using density functional theory (DFT) thermodynamics and time-dependent DFT (TDDFT) computations, we investigate the atomic structures of N doping and W-N co-doping in anatase titania, as well as the effect of the thermal processing conditions. We find that W and N dopants predominantly constitute two complex structures: an N interstitial site near a Ti vacancy in the triple charge state and the simultaneous substitutions of Ti by W and the nearest O by N. The latter case induces highly localized shallow in-gap levels near the conduction band minimum (CBM) and the valence band maximum (VBM), whereas the defect complex yielded deep levels (1.9 eV above the VBM). Electronic structures suggest that substitutions of Ti by W and the nearest O by N improves the photocatalytic activity of anatase by band gap narrowing, while defective structure degrades the activity by an in-gap state-assisted electron-hole recombination, which explains the experimentally observed deep level-related photon absorption. Through the real-time propagation of TDDFT (rtp-TDDFT), we demonstrate that the presence of defective structure attracts excited electrons from the conduction band to a localized in-gap state within a much shorter time than the flat band lifetime of titania. Based on these results, we suggest that calcination under N-rich and O-poor conditions is desirable to eliminate the deep-level states to improve photocatalysis.

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Determination of Critical Nitrogen Concentration and Dilution Curve for Rice Growth

  • Lee, Byun-Woo;Cui, Ri-Xian;Kim, Min-Ho;Kim, Jun-Hwan;Nam, Hong-Shik
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.47 no.2
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    • pp.127-131
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    • 2002
  • Critical nitrogen concentration (Nc), which is defined as the minimum % N in shoots required to maintain the maximum growth rate of top dry weight (W) at any time, was determined for rice plant. Using two rice varietal groups, japonica varieties and an indica $\times$ japonica "Dasanbyeo", 18 data points fulfilling the statistical criteria for determining Nc were obtained through eight N-fertilization experiments over two years at Suwon (37$^{\circ}$16'N), Korea. Nc dilution curve for each variety was obtained by fitting the Nc-W relationship to power function. However, The critical nitrogen curves for the two variety groups were not different statistically. Thus, a Nc dilution curve was fitted for the Nc data points pooled over the two variety groups and proposed in rice as: Nc=4.08, where W<1.73 t h $a^{-1}$ , Nc=5.197 $W^{0.425}$3/ ($R^2$=0.964), where 1.73 t h $a^{-1}$ <W<12 t h $a^{-l}$. The Nc for W<1.73 t h $a^{-l}$ were estimated as a constant value of 4.08%, the mean value of the maximum N concentration for N-limiting condition and the minimum N concentration for N non-limiting condition. The model for Nc is applicable to diagnosing the nitrogen nutrition status during the rice growth period from emergence to heading stage. The Nc curve well discriminated the 144 data points between the N limiting and the N non-limiting groups regardless of varieties, cultural methods, and years.-limiting groups regardless of varieties, cultural methods, and years.

Implementation of Multilateral Control System for Small UAV Control-Focused on Design (소형 무인기 통제를 위한 다자간 방식 관제시스템 구축방안-설계 중심으로)

  • Choi, Hyun-Taek;Kim, Seok-Kwan;Ryu, Gab-Sang
    • Smart Media Journal
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    • v.6 no.4
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    • pp.65-71
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    • 2017
  • In this paper, we propose a design method for the construction of LTE-based small unmanned aerial vehicle control system to quickly and reliably collect multiple small unmanned aerial vehicle position information simultaneously flying all over the country. In particular, the main requirements are the network (N/W), hardware (H/ W), software(SW), Database(DB), development architecture, and business needs. To satisfy these requirements, N/W, H/W, SW, DB design, and architectural design plan were suggested regarding the design requirements of a small UAV system. To effectively control the small unmanned multi-party system in the system design, the architecture is divided into the front-end service area and the back-end service area according to the function and role of the unit system. In the front-end service area that grasps and controls the position and state of small unmanned aerial vehicles (UAVs), we have studied the design part that can be expanded to N through TCP/IP network by applying Client PC method.

Capacity esitmation of microcell in macro/microcell overlaid W-CDMA WLL system (매크로셀과 마이크로셀이 중첩된 W-CDMA 무선가입자망에서 마이크로셀의 용량 산정)

  • 손성찬;노재성;김수용;조성준
    • The Journal of Korean Institute of Communications and Information Sciences
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    • v.23 no.9A
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    • pp.2153-2164
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    • 1998
  • This paper has presented the parameters for the coexistence between two systems in macro/microcell ovelaid W-CDMA WLL (wideband CDMA wireless local loop) and has calculated the capacity of forward/reverse link in microcell. To produce the capacity for analyzing system interference effects, we have shown tables and graphs with the parameters sucyh as RF channel bandwidth of WLL(W), the transmission rate of service message(R), the required signal power to noise power ratio( $E_{b/}$ $N_{0}$) for achieving accepatable error rate, te user number ( $N_{W1}$, $N_{W2}$) of the neighboring system, the signal power to interference power ratio(.GAMMA.$_{C1B}$, .GAMMA.$_{C2B}$) of the neighboring system, the normalized distance(d) between microcell and macrocell base-station, and microcell to macrocell radius ratio ( $R_{d}$). From the results, we have convinced that the capacity of microcell diminishes as increasing the user number ( $N_{W2}$) in macrocell, increasing the microcell radius, and decreasing the normalized distance(d) between microcell and macrocell base-station. Especially, we have known that when $R_{d}$=0.1, $N_{W2}$ must be below 24 at .GAMMA.$_{C2B}$ = 0 dB and below 8 at .GAMMA.$_{C2B}$ = 4 dB for the acceptable capacity raito to be over 80%. Therfore, this paper is usefult to design microcell W-CDMA WLL for accommodating more user number under the interference effects of macrocell W-CDMA WLL and is expected to be reference in power control if base-station.ation.ion.ation.ation.

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ON w-COPURE FLAT MODULES AND DIMENSION

  • Bouba, El Mehdi;Kim, Hwankoo;Tamekkante, Mohammed
    • Bulletin of the Korean Mathematical Society
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    • v.57 no.3
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    • pp.763-780
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    • 2020
  • Let R be a commutative ring. An R-module M is said to be w-flat if Tor R1 (M, N) is GV -torsion for any R-module N. It is known that every flat module is w-flat, but the converse is not true in general. The w-flat dimension of a module is defined in terms of w-flat resolutions. In this paper, we study the w-flat dimension of an injective w-module. To do so, we introduce and study the so-called w-copure (resp., strongly w-copure) flat modules and the w-copure flat dimensions for modules and rings. The relations between the introduced dimensions and other (classical) homological dimensions are discussed. We also study change of rings theorems for the w-copure flat dimension in various contexts. Finally some illustrative examples regarding the introduced concepts are given.

Electrical and Structural Properties of $V_{2-n}W_nO_5$ Thin Films as a function of Tungsten Contents (텅스텐 첨가에 따른 $V_{2-n}W_nO_5$ 박막의 구조적, 전기적 특성)

  • Nam, Sung-Pill;Lee, Sung-Gap;Lee, Seon-Gi;Lee, Young-Hie
    • Proceedings of the KIEE Conference
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    • 2008.10a
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    • pp.117-118
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    • 2008
  • The $V_{1.85}W_{0.15}O_5$ thin films deposited on Pt/Ti/$SiO_2$/Si substrates by RF sputtering method exhibited fairly good TCR and dielectric properties. It was found that film crystallinity, dielectric properties, and TCR properties were strongly dependent upon the annealing temperature. The dielectric constants of the $V_{1.85}W_{0.15}O_5$ thin films annealed at $400^{\circ}C$ were 38.11, with a dielectric loss of 1%, respectively. Also, the TCR values of the $V_{1.85}W_{0.15}O_5$ thin films annealed at $400^{\circ}C$ were about -3.45%/K.

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$SiH_4$ Soak Effects for Optimization of Tungsten Plug Deposition on TiN Barrier Metal

  • Kim, Sang-Yang;Seo, Yong-Jin;Lee, Woo-Sun;Chung, Hun-Sang;Kim, Chang-Il;Chang, Eui-Goo;Chung, Yong-Ho
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.05b
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    • pp.54-56
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    • 2001
  • The $SiH_4$ soak step is widely used during the CVD Tungsten(W) plug deposition process on the Ti/TiN barrier metal to prevent the $WF_6$ attack to the underlayer metal. We tried to reduce or skip the time of $SiH_4$ soak process to optimize W-plug deposition process on Via. The electrical characteristics including Via resistance and the structure of W film are affected according to $SiH_4$ soak time. The elimination possibility of $SiH_4$ soak process was confirmed in the case of that the CVD W film grows on the stable Ti/TiN underlayer.

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ON THE COMPUTATION OF THE NON-PERIODIC AUTOCORRELATION FUNCTION OF TWO TERNARY SEQUENCES AND ITS RELATED COMPLEXITY ANALYSIS

  • Koukouvinos, Christos;Simos, Dimitris E.
    • Journal of applied mathematics & informatics
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    • v.29 no.3_4
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    • pp.547-562
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    • 2011
  • We establish a new formalism of the non-periodic autocorrelation function (NPAF) of two sequences, which is suitable for the computation of the NPAF of any two sequences. It is shown, that this encoding of NPAF is efficient for sequences of small weight. In particular, the check for two sequences of length n having weight w to have zero NPAF can be decided in $O(n+w^2{\log}w)$. For n > w^2{\log}w$, the complexity is O(n) thus we cannot expect asymptotically faster algorithms.