• Title/Summary/Keyword: Volumetric capacity

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Effect of Biofilter Operation Parameters on Dimethyl Disulfide Removal : Loading, Time, and Concentration

  • Arpacioglu, Bora C.;Kim, Jo-Chun;Allen, Eric R.;Kim, Seoung-Hyun
    • Journal of Environmental Science International
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    • v.11 no.8
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    • pp.783-791
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    • 2002
  • A laboratory-scale dual-column biofilter system was used to study the biofiltration of dimethyl disulfide(DMDS). The biofiltration of DMDS was found to depend on the pollutant loadings rather than the inlet concentrations. It was estimated that the pollutant was only inhibitory to the operation of the biofilters at DMDS concentrations greater than 5500 ppmv A residence time of 30 seconds(120 m$^3$/m$^2$/h volumetric loading) was determined as appropriate for efficient operation(>90%). The maximum elimination capacity for both compost mixtures under the current experimental conditions was found to range from 7.5 to 10 g-DMDS/m$^3$/h. A lower DMDS maximum elimination capacity was exhibited under acidified conditions.

Effect of Mo-doped LiFePO4 Positive Electrode Material for Lithium Batteries

  • Oh, Seung-Min;Sun, Yang-Kook
    • Journal of Electrochemical Science and Technology
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    • v.3 no.4
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    • pp.172-177
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    • 2012
  • Mo-doped $LiFePO_4$ was synthesized via co-precipitation method using sucrose as the carbon source. Structure, surface morphology, and the electrochemical properties of the synthesized olivine compounds were investigated using Rietveld refinement of X-ray diffraction data (XRD), scanning electron microscopy (SEM), and electrochemical charge-ischarge tests. Spherical morphology with the particle size of ${\sim}8{\mu}m$ authenticated the enhanced tap density and volumetric energy density of the synthesized materials. Charge-discharge behavior of $LiFePO_4$ and Mo-doped $LiFePO_4$ cells demonstrated a specific capacity of 130 and 145 mAh $g^{-1}$, respectively. Mo-doped $LiFePO_4$ cells exhibited an excellent discharge capacity at 96 mAh $g^{-1}$ at 7 C-rate.

Low Temperature Adsorption of Hydrogen on Nanoporous Materials

  • Jhung, Sung-Hwa;Yoon, Ji-Woong;Kim, Hye-Kyung;Chang, Jong-San
    • Bulletin of the Korean Chemical Society
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    • v.26 no.7
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    • pp.1075-1078
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    • 2005
  • Hydrogen adsorption on various porous materials have been studied with a volumetric method at low temperature in the pressure of 0-760 torr. Their hydrogen uptakes depend at least partly on microporosity rather than total porosity. However, it is also necessary to consider other parameters such as pore size and pore architecture to explain the adsorption capacity. The heat of adsorption and adsorption-desorption-readsorption experiments show that the hydrogen adsorption over the porous materials are composed of physisorption with negligible contribution of chemisorption. Among the porous materials studied in this work, SAPO-34 has the highest adsorption capacity of 160 mL/g at 77 K and 1 atm probably due to high micropore surface area, micropore volume and narrow pore diameter.

Analysis on Volumetric Efficiency and Torque Characteristics Using Inlet Port Pressure in SI Engines (흡기포트압력을 이용한 SI엔진의 체적효율 및 토크 성능 분석)

  • 이영주;홍성준
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.16 no.7
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    • pp.1408-1418
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    • 1992
  • The valve timing and intake system in SI engine is chosen in order to get the maximum performance at the target rpm. This is a compromise and the performance reduction is expected in a certain rpm range. Therefore, to accomplish the possible engine capacity all over the operation ranges, it is required to investigate the effects of intake system and valve timing on engines more thoroughly. In this paper, it was attempted to examine closely the combined effects on the torque and the volumetric efficiency due to the change of valve timing and intake system dimensions. For this, the inlet port pressure was chosen as a primary parameter to represent engine performance characteristics together with surge tank pressure and induction pressure as secondaries. The inlet port pressure was analyzed in connection with both the secondaries and the performance data. Especially the relation between the inlet port pressure and the torque and volumetric efficiency was investigated on the operating conditions. In this experiment, it was acquired that the performances at specific rpm range could be improved by the combinations of valve timing and intake system. Then it was verified that pressure at a intake system contained useful data for the engine performance. By the analysis of inlet port pressure with the others, it was obtained that the properties of the torque and the volumetric efficiency due to the change of valve timing and intake conditions were able to be defined by the average and the maximum inlet port pressures, the pressure near before the intake valve closing(IVC) point as well as the pressure at IVC point during the intake valve opening duration. These results could be applied to almost all over the experimental conditions.

Feasibility Study on Long-Term Continuous Ethanol Production from Cassava Supernatant by Immobilized Yeast Cells in Packed Bed Reactor

  • Liu, Qingguo;Zhao, Nan;Zou, Yanan;Ying, Hanjie;Liu, Dong;Chen, Yong
    • Journal of Microbiology and Biotechnology
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    • v.30 no.8
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    • pp.1227-1234
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    • 2020
  • In this study, yeast cell immobilization was carried out in a packed bed reactor (PBR) to investigate the effects of the volumetric capacity of carriers as well as the different fermentation modes on fuel ethanol production. An optimal volumetric capacity of 10 g/l was found to obtain a high cell concentration. The productivity of immobilized cell fermentation was 16% higher than that of suspended-cell fermentation in batch and it reached a higher value of 4.28 g/l/h in repeated batches. Additionally, using this method, the ethanol yield (95.88%) was found to be higher than that of other tested methods due to low concentrations of residual sugars and free cells. Continuous ethanol production using four bioreactors showed a higher productivity (9.57 g/l/h) and yield (96.96%) with an ethanol concentration of 104.65 g/l obtained from 219.42 g/l of initial total sugar at a dilution rate of 0.092 h-1. Furthermore, we reversed the substrate-feed flow directions in the in-series bioreactors to keep the cells at their highest activity and to extend the length of continuous fermentation. Our study demonstrates an effective method of ethanol production with a new immobilized approach, and that by switching the flow directions, traditional continuous fermentation can be greatly improved, which could have practical and broad implications in industrial applications.

Thermodynamic Properties of R-32(Difluoromethane) and Initial Evaluation of Thermodynamic Perfomance as A R-22 Alternative Refrigerant (대체냉매 R-32(Difluoromethane)의 열역학적 물성과 R-22 대체냉매로서 열역학적 성능의 초기 평가)

  • Park, Y.M.
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.5 no.2
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    • pp.141-155
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    • 1993
  • Thermodynamic properties of R-32 are calculated and its refrigeration performance is evaluated for the purpose the feasibility study of replacing R-22 with R-32. (1) Refrigeration effect of R-32 is superior to that of R-22 because heat of evaporation of R 32 is about 50% higher than that of R-22. However, COP of R-32 system is 10-30% lower than that of R-22 system. It is mainly attributed to the vapor pressore of R-32 being about 62% higher than R-22. (2) Since the pressure ratio and the specific heat ratio of R-32 system is higher than those of R -22, compressor discharging temperature rises as high as to $130-150^{\circ}C$. It may cause mechanical failure of compressor due to the breakdown of lubricant. Compressor should be improved to lower the temperature if R-32 is to replace R-22. (3) Averaged two-phase heat transfer coefficient of R-32 is about 10-20% higher than that of R-22. It may assume better heat exchanger effectiveness but not guarantee the better COP of R-32 system than R-22. (4) The high vapor pressure is the first reason to drop R-32 out of the line of R-22 alternative refrigerant. So, refrigerant mixtures based on R-32 are recommended to adjust the vapor pressure first and keep superior volumetric capacity of R-32.

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Performance Analysis of a $CO_2$ Two-Stage Twin Rotary Compressor ($CO_2$ 2단 트윈 로타리 압축기 성능해석)

  • Kim, Woo-Young;Ahn, Jong-Min;Kim, Hyun-Jin;Cho, Sung-Oug
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.19 no.1
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    • pp.19-27
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    • 2007
  • Analytical investigation on the performance of a two stage twin rotary compressor for $CO_2$ heat pump water heater system has been carried out. A computer simulation program was made based on analytical models for gas compression in control volumes, leakages among neighboring volumes, and dynamics of moving elements of the compressor. Calculated cooling capacity, compressor input, and COP were well compared to those of experiments over the compressor speeds tested. For the operating condition of suction pressure of 3 MPa, and discharge pressure of 9 MPa, and compressor inlet temperature of $35^{\circ}C$, the compressor efficiency was calculated to be 80.2%: volumetric, adiabatic, and mechanical efficiencies were 88.3%, 93.2%, and 92.7%, respectively. For the present compressor model, volumetric and adiabatic efficiencies of the second stage cylinder were lower by about $6{\sim}7%$ than those of the first stage mainly due to the smaller discharge port at the second stage. Parametric study on the discharge port size showed that the compressor performance could be improved by 3.5% just by increasing the discharge port diameter by 20%.

Effects of Soil Types and Tillage Systems on Soil Water Movement in the Root Zone of Cornfields (옥수수포장의 토양 수분함량에 대한 토성과 경운의 영향)

  • Kim, Won-Il;Jeong, Goo-Bok;Koh, Mun-Hwan;Huck, M.G.;Park, Ro-Dong
    • Korean Journal of Soil Science and Fertilizer
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    • v.35 no.4
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    • pp.197-206
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    • 2002
  • Volumetric soil water contents through a soil profile were monitored to identify the effects of tillage systems and soil physico-chemical characteristic on soil water movement from the soil profile. Water content profiles under no tillage (NT) and conventional tillage (CT) practices were compared at two commercial farms in central Illinois from 1992 through 1994, using neutron-scattering techniques in weekly intervals during each growing season. The volumetric water content of surface soil layers was affected more by tillage systems and rainfall amounts, whereas that of the subsoil layers was more strongly affected by soil types. Soil water percolated faster through Saybrook and Catlin soils than through Drummer, Flanagan, and Ipava soils because Saybrook and Catlin soils have lower clay content and water-retention capacity and higher permeability than Drummer, Flanagan, and Ipava soils. Increased soil organic matter (SOM) in Drummer, Flanagan, and Ipava soils would be attributable to the higher soil water retention than other soil types. Soil water contents in the corn root zone were consistently higher under CT plots than under NT plots.

Bioreactor Cultures of Lithospermum erythrorhizon for Shikonin Production with In Situ Extraction (동시 추출을 겸한 생물반응기에서 Lithospermum erythrorhizon 배양에 의한 shikonin 생산)

  • 김동진;장호남
    • Microbiology and Biotechnology Letters
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    • v.18 no.5
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    • pp.525-529
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    • 1990
  • Plant cell cultures of Lithospermum erythrorhizon were performed in stirred tank and packed-bed reactors with in situ extraction by n-hexadecane. The specific shikonin production and volumetric shikonin productivity of stirred tank reactor reached 1.5 mg shikoninlg cell and 400$\mu g$ shikonin/(L.day), respectively. In packed-bed reactor with calcium alginate-immobilized cells specific shikonin production and volumetric productivity reached 2.0 mg shikoninlg cell and 2857$\mu g$ shikonin/(L.day), which were 1.3 and 7.1 times higher than those of stirred tank reactor, respectively. The higher shikonin production and productivity of packed-bed reactor seemed to be due to high cell loading capacity of calcium alginate immobilized cells in packed-bed reactor and improved cell-cell contact.

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The Synthesis and Electrochemical Performance of Microspherical Porous LiFePO4/C with High Tap Density

  • Cho, Min-Young;Park, Sun-Min;Kim, Kwang-Bum;Lee, Jae-Won;Roh, Kwang Chul
    • Journal of Electrochemical Science and Technology
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    • v.3 no.3
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    • pp.135-142
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    • 2012
  • Over the past few years, $LiFePO_4$ has been actively studied as a cathode material for lithium-ion batteries because of its advantageous properties such as high theoretical capacity, good cycle life, and high thermal stability. However, it does not have a very good power capability owing to the low lithium-ion diffusivity and poor electronic conductivity. Reduction in particle size of $LiFePO_4$ to the scale of nanometers has been found to dramatically enhance the above properties, according to many earlier reports. However, because of the intrinsically low tap density of nanomaterials, it is difficult to commercialize this method. Many studies are being carried out to improve the volumetric energy density of this material and many methods have been reported so far. This paper provides a brief summary of the synthesis methods and electrochemical performances of micro-spherical $LiFePO_4$ having high volumetric energy density.