• Journal of the Korean Ceramic Society
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• v.42 no.11 s.282
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• pp.729-736
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• 2005

HTGR (High Temperature Gas-cooled Reactor) is spotlighted to next generation nuclear power plant for producing the clean hydrogen gas and the electricity. In this study, the spherical $UO_3$ gel particles were prepared by the external gelation process, and the characteristics of these particles were analyzed the particle shape, composition of precipitate, and thermal decomposition characteristics with the Streoscope, FT-IR, and X-ray diffractometer. Raw material of the ADUN (Acid Deficient Uranyl Nitrate) solution, which has [$NO_3$]/[U] mole ratio = 1.75, was obtained from dissolution of the $U_{3}O_{8}$ powder with concentrated $HNO_3$, and its concentration is 3.5 M-U/l. The broth solution is prepared with the ADUN, urea, PVA, and THFA solution. The droplets of the broth solution was made through a nozzle system. From this study, we obtained the following results; 1) an externel chemical gelation process is a suitable method in the spherical $UO_3$ particle production, 2) the particle shape are changed by an urea mixing time, THFA volume, and the viscosity of the broth solution, 3) the amorphous $UO_3$ particles obtained from these experiments was converted to $U_{3}O_{8}$ and then $UO_2$ by heat treatment in hydrogen atmosphere at $600^{\circ}C$.

• 한국전산유체공학회:학술대회논문집
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• 1995.10a
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• pp.76-81
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• 1995

A numerical procedure for the analysis of transient behavior in a monolithic catalytic converter is presented. The thermal behavior of a monolithic catalytic converter is fully coupled with mass transfer and exothermic reaction between exhaust gases and the catalytic converter. In the present study, all these processes are solved simultaneously. The heat transfer process is approximated by combinging one dimensional convection and conduction and the chemical reaction is also simply modelled by using the concepts of reaction rate and reaction heat. All the partial diffenrential equations for the heat transfer, mass transfer and chemical reactions are appximated by using finite volume method. Resulting algebraic equations are solved using the Newton's method. To see the workability of present numerical method, two well known problems, say step increase and step decrease in the gas inlet temperature, have been calculated. Comparion of present solutions with previous solutions shows a good agreement.

• Proceedings of the Korean Society of Propulsion Engineers Conference
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• 2017.05a
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• pp.160-162
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• 2017

When rubber elastomer has contact with fuel, since the component and additive having low molecular weight can flow out, the physical properties of both elastomer and fuel could be hindered. In order to predict the life of the rubber elastomer, this study is to determine the change of weight, thickness, hardness, strain, and compression set as mechanical properties of the sealant rubber O-ring, which was dependent on volume, temperature, and storage time of the contacted fuel. We also determined purity of fuel via GC analysis and measured gross heat of combution. The results could be used as a reference to evaluate the life of the rubber elastomer.

• Journal of ILASS-Korea
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• v.3 no.1
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• pp.19-26
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• 1998

The effect of mixture component makes a nelay time and a long total combustion period $\tau_{p\;max}$. The flame propagation delay $\tau_{df}$ was determined by the record of current ion. The pressure release delay $\tau_{dp}$ and $\tau_{p\;max}$ were determined by the indicated pressure diagram in constant volume of the combustion chamber. The results are as follows: 1) The ignition delay $\tau_t$ time takes the minimum value around $\Phi=1.15$. 2) $\tau_{df}$ and $\tau_t$ time increased according to the increases of the concentrated dilution gases, because the adiabatic flame temperature decreased due to the increases of the heat capacity. But dilution gases have little effect on flame nucleus formation delay 3) The relation between $\tau_t$ time and reciprocal laminar burning velocity is almost linear. 4) The increase of the propagation length is accompanied with increased ratio of the $\tau_{df},\;\tau_{dp},\;\tau_{t},\;\tau_{p\;max}$.

• Proceedings of the Korean Society of Propulsion Engineers Conference
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• 2004.03a
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• pp.499-505
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• 2004

A Propulsion System of the CRW(Canard Rotor Wing) type UAV(Unmanned Aerial Vehicle) was composed of the turbojet engine to generate the propulsive exhaust gas, and the duct system including straight bent ducts, tip-jet nozzles, a master valve and a variable main nozzle for three flight modes such as lift/landing mode, low speed transition flight mode and high speed forward flight mode. In this study, in order to operate safely the propulsion system, the dynamic Performance behavior of the system was modeled and simulated using the SIMULIN $K^{ }$, which is the user-friendly GUI type dynamic analysis tool provided by MATLA $B^{ }$. In the transient performance model, the inter-component volume model was used. The performance analysis using the developed models was performed at various flight condition, valve angle positions and fuel flow schedules, and these results could set the safe flight mode transition region to satisfy the inlet temperature overshoot limitation as well as the compressor surge margin. Performance analysis results using the SIMULIN $K^{ }$ performance program were compared with them using the commercial program GSP.m GSP.

• Journal of the Korean Institute of Gas
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• v.5 no.1
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• pp.29-36
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• 2001

The permeation properties of $O_2\;and\;N_2$ were measured for bromobisphenol A polysulfone(BPSf), bisphenol A trimethylsilylated polysulfone(TMSPSf) and their blend membrane to investigate the structure-properties relationships. BPSf shows relatively high permselectivity. It can be explained that the strong polarity of bromine in BPSf increases chain packing ability. In this case the distance of polymer chains is reduced by increasing of interchain interaction by induced dipole. TMSPSf shows relatively high permeability. The higher value of permeability coefficients for TMSPSf is due to the substitution of very bulky trimethylsilyl groups. The replacement of phenyl hydrogens of bisphenol A polysulfone(PSf) with trimethylsilyl groups results in higher fractional free volume(FFV). In this work, taking into account the complimentary features of BPSf and TMSPSf, BPSf/TMSPSf blend was prepared and the compatibility in mixing are examined. The BPSf/TMSPSf blend shows higher permeability than commercial PSf, with minimum loss of selectivity. The miscibility of the BPSf/TMSPSf blend is confirmed by the single glass transition temperature.

• Journal of Hydrogen and New Energy
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• v.34 no.6
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• pp.767-772
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• 2023

In this study, combustion experiments were conducted at various engine speeds under full-load conditions using a single-cylinder diesel engine by blending butanol, pentanol, and octanol with diesel at a volume ratio of 10%. Experimental results revealed that higher alcohol-diesel blends resulted in lower brake torque and brake power than pure diesel due to the lower calorific value and the cooling effect during evaporation. An evident improvement in the brake thermal efficiency of the blended fuels was observed at engine speeds below 2,000 rpm, with the butanol blend exhibiting the highest thermal efficiency overall. Furthermore, the brake-specific fuel consumption of the higher alcohol-diesel blends was lower than that of pure diesel at speeds below 2,200 rpm. When using blended fuels, the exhaust gas temperature decreased under lean mixture conditions due to heat loss to the air and the cooling effect from fuel evaporation.

• Proceedings of the Korea Institute of Fire Science and Engineering Conference
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• 1997.11a
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• pp.289-296
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• 1997

This paper discribes an experimental explosion risk assessment study on refrigerators containing flammable hydrocarbon refrigerant. A refrigerator used in this study is a larder fridge type, 215 liter in volume. The hydrocarbon refrigerant used in the refrigerator is iso-butane(C$_4$H$_{10}$). For the explosion safety assessment of the refrigerator, temperature of compressor, cooling air circulation fan motor, defrost heater and inner lamp were measured during the operation. And to confirm the ignitablity of flammable gas by the electric spark of the switches of the refrigerator, ON-OFF test of all switches were conducted with compulsorily near the stoichiometric concentration atmosphere of iso-butane-air mixture. As the result of experiment above mentioned and another experiment for the explosion safety assessment, we can conclude that explosion hazard in connection with the use of hydrocarbon refrigerant was few.w.

• Economic and Environmental Geology
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• v.53 no.6
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• pp.793-807
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• 2020

The policy for Green New Deal will promote the shift of the application to coal as feedstock from coal as fuel. Coal can be used as fuel for production of hydrogen and as feedstock materials such as synthetic graphite or activated carbon. Hydrogen is obtained from syngas produced through Steam carbon(SC), Water-Gas Shift(WGS), and Carbonation reactions, and these processes should be used in conjunction with CO2 sequestration technology. Anthracite has a potential in terms of cost advantage as a feedstock compared to a petroleum pitch, because Synthetic graphite is prepared by heat treating an anthracite with high rank to a graphitization temperature which is in the range of 2400~2800℃, in the presence of inorganic catalyst such as silicon or iron. From several studies, it has been confirmed that coal-based activated carbon(AC) is manufactured with quality similar to the large specific surface area and much micropore volume of lignin-based AC, can be prepared. Therefore it is expected that lignin-based AC is replaced to coal-based AC.

• Journal of Sensor Science and Technology
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• v.23 no.6
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• pp.383-387
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• 2014

Electrically conductive polypyrrole-polyvinylpyrrolidone (PPy-PVP) nanofiber mats with a core-shell structure have been successfully fabricated by a two-step process: the formation of FeCl3-containing PVP nanofiber mat by electrospinning, and the vapor-phase polymerization (VPP) of pyrrole monomer on the mat in a sealed chamber at room temperature. Surface morphology and chemical composition of the PPy-PVP mat were characterized by SEM, EDX and FTIR analyses. The as-prepared nonwoven mat was composed of PPy-PVP nanofibers with an average diameter of 300 nm. The sheet conductivity of the nanofiber mat was measured to be approximately 0.01 S/cm by a four-point probe. We have also investigated gas-sensing properties of PPy-PVP nanofiber mat upon exposure to methanol vapor. The PPy-PVP nanofiber sensors were observed to have excellent methanol-sensing performance. The nanofiber-based core-shell nanostructure could give an opportunity to fabricate a highly sensitive and fast response sensor due to its high surfaceto-volume ratio.