• Title/Summary/Keyword: Volatile release

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On the use of spectral algorithms for the prediction of short-lived volatile fission product release: Methodology for bounding numerical error

  • Zullo, G.;Pizzocri, D.;Luzzi, L.
    • Nuclear Engineering and Technology
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    • v.54 no.4
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    • pp.1195-1205
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    • 2022
  • Recent developments on spectral diffusion algorithms, i.e., algorithms which exploit the projection of the solution on the eigenfunctions of the Laplacian operator, demonstrated their effective applicability in fast transient conditions. Nevertheless, the numerical error introduced by these algorithms, together with the uncertainties associated with model parameters, may impact the reliability of the predictions on short-lived volatile fission product release from nuclear fuel. In this work, we provide an upper bound on the numerical error introduced by the presented spectral diffusion algorithm, in both constant and time-varying conditions, depending on the number of modes and on the time discretization. The definition of this upper bound allows introducing a methodology to a priori bound the numerical error on short-lived volatile fission product retention.

Core Release Model Evaluation in the ISAAC Code for PHWR

  • Song Yong-Mann;Park Soo-Yong;Kim Dong-Ha;Kim Hee-Dong
    • Nuclear Engineering and Technology
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    • v.36 no.1
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    • pp.36-46
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    • 2004
  • The ISAAC fission product release calculation is based on detailed FPRAT models developed by Jaycor. For volatile fission product release calculations, either the Cubicciotti steam oxidation correlation or the NUREG-0772 correlation is used. In this study, evaluation is carried out for these volatile fission product release models. As a result, in the case of early release, the IDCOR model with an in-vessel Te release option shows the most conservative results and for the late release case, the NUREG-0772 model shows the most conservative results. Considering both early and late release, the IDCOR model with an in-vessel Te bound option is evaluated to show mitigated conservative results. In addition, a sensitivity study on detailed core nodalization is performed. In the study, 380 horizontal fuel channels in the Wolsong plant are nodalized into 12 (6 channels per loop, $3{\times}3$ Core Pass) representative channels and detailed by 16/20/24 channels. For reference accidents, LOAH and large LOCA are selected as representing high and low pressure sequences, respectively. According to the results, the original 12 channel approach with $3{\times}3$ core passes is evaluated to be sufficient as an optimal scheme.

The Effects of Volatile Organic Compounds on Apoptosis of Human Neutrophils and Eosinophils

  • Yang, Eun-Ju;Kim, In-Sik
    • Biomedical Science Letters
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    • v.16 no.2
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    • pp.123-126
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    • 2010
  • Volatile organic compounds are commonly off gassed from various building materials and can induce sick building syndrome. Volatile organic compounds such as formaldehyde, xylene and toluene are known as toxic agents in immune cells. Human leukocytes, particularly, neutrophils and eosinophils play important roles in the regulation of immune responses. In this study, we investigated the toxic effects of formaldehyde, ortho-xylene (o-xylene), para-xylene (p-xylene) and toluene on the apoptosis of neutrophils and eosinophils isolated from the blood of healthy donors. Formaldehyde increased the constitutive apoptosis of neutrophils and eosinophils. o-xylene, p-xylene and toluene increased the spontaneous apoptosis of eosinophils, but not that of neutrophils. Formaldehyde increased the protein level of IL-8 in neutrophils and eosinophils, and suppressed the MCP-1 expression in neutrophils. The release of IL-6 from neutrophils was diminished by volatile organic compounds used in this study. In conclusion, formaldehyde, xylene and toluene elevate the apoptosis of neutrophils and eosinophils, and regulate the release of cytokine and chemokine in neutrophils and eosinophils. These results indicate that formaldehyde, xylene and toluene have a cytotoxicity in human neutrophils and eosinophils and may damage the modulation of immune responses.

Combustion Characteristics of Coal Particle Array (미분탄 입자들의 배열에 따른 연소특성)

  • Cho, Chong-Pyo;Kim, Ho-Young;Chung, Jin-Taek
    • 한국연소학회:학술대회논문집
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    • 2004.11a
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    • pp.117-123
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    • 2004
  • The burning characteristics of interacting coal particles in a convective flow are numerically investigated at various Reynolds numbers. The transient combustion of 2-dimensionally arranged particles, both the fixed particle distances of 5 radii to 20 radii horizontally and 3 radii to 24 radii vertically, is studied. The results obtained from the present numerical analysis reveal that the transient flame configuration and retardation of particle temperature augmentation with the horizontal or vertical particle spacing substantially influence devolatilization process and carbon conversion ratio of interacting particles. Volatile release and carbon conversion ratio of the second particle with decreasing horizontal and vertical particle spacing decrease gradually, whereas those of the first particle with decreasing vertical particle spacing increases due to flow acceleration. When the vertical particle spacing is smaller than $6R_{o}$, volatile release and carbon conversion ratio of the second particle decrease greatly due to reduction of flame penetration depth.

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The Effect of Coal Particle Arrangement and Size Difference on Combustion Characteristics (미분탄 입자의 크기 차이와 배열이 연소특성에 미치는 영향)

  • Kim, Ki-Duck;Kim, Ho-Young;Cho, Chong-Pyo;Yoon, Suk-Goo
    • 한국연소학회:학술대회논문집
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    • 2007.05a
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    • pp.47-53
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    • 2007
  • The laminar combustion characteristics of interacting coal particles in a convective flow are numerically investigated at particle arrangement and size difference. The numerical simulations, which use the two-step global reaction model to account for the surrounding gas effect, show the detailed interaction among the inter-space particles, undergoing devolatilization and subsequent char burning. Several parametric studies, which include the effect of the gas temperature (1700 K), high pressure(10 atm) and variation in geometrical arrangement of the particle diameter on the volatile release rate and the char combustion rate, have been carried out. The comparison indicates that the shift to the multiple particle arrangement resulted in the substantial change of the combustion characteristics and that the volatile release rate of the interacting coal particles exhibits a strong dependency on the particle spacing and size difference.

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Numerical Study on the Devolatilization models of Pulverized Coal in DTF (DTF 내 미분탄 휘발화 모델에 관한 수치적 연구)

  • Kim, Jin-Nam;Kim, Ho-Young
    • 한국연소학회:학술대회논문집
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    • 2002.11a
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    • pp.173-184
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    • 2002
  • In order to evaluate the devolatilization models of pulverized coal, various devolatilization models are examined for the numerical analysis of Drop Tube Furnace.The results of analysis are compared with the experimental results. A numerical study was conducted to explore the sensitivities of the predictions to variation of the model parameters. It helps to elucidate the source of the discrepancies. Three different wall temperature conditions of the DTF, 1100, 1300 and $1500^{\circ}C$ were considered in this analysis. Two fuels are U.S.A. Alaska coal and Australia Drayton coal. The results of analysis with constant rate model, single kinetic rate model and two competing rate modes well presented fast volatile matter release in the early devolatilization. However, in the latter devolatilization they did not coincide with experimental results which presented tardy volatile matter release on account of pyrolysis of high molecular substance. On the other hand, the results of analysis with DAEM(Distribute Activation Energy Model) coincided with experiment al results in overall devolatilization.

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Prepyrolysis Structural Relaxation of Coal Studied by Differential Scanning Calorimetry and Solvent Swelling

  • Yun, Yongseung;Suuberg, E.M.
    • Proceedings of the Korea Society for Energy Engineering kosee Conference
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    • 1993.05a
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    • pp.126-131
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    • 1993
  • Differential Scanning Calorimetry (DSC) and solvent swelling technique have been applied for identifying physical transition temperatures in the macromolecular structure of coals. The transition processes seem to be associated with physical relaxation of the coal structure and are irreversible processes. In Pittsburgh No. 8 high volatile bituminous (hvb) coat one physical transition was noted at 250-30$0^{\circ}C$ (at 8$^{\circ}C$/min) without any significant accompanying weight loss. Coals of higher rank than high volatile bituminous, i.e., Upper Freeport medium volatile bituminous (mvb) and Pocahontas No.3 low volatile bituminous (lvb) coals, exhibit structural relaxation just before the major thermal decomposition process and a sharp increase in solvent swellability accompanies this relaxation. In the case of both the Pittsburgh No.8 and the Upper Freeport coat structural relaxations at around 36$0^{\circ}C$ seem to coincide with release of "guest molecules".les".uot;.

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FISSION PRODUCT AND ACTINIDE RELEASE FROM THE DEBRIS BED TEST PHEBUS FPT4: SYNTHESIS OF THE POST TEST ANALYSES AND OF THE REVAPORISATION TESTING OF THE PLENUM SAMPLES

  • Bottomley P.D.W.;Gregoire A.C.;Carbol P.;Glatz J.P.;Knoche D.;Papaioannou D.;Solatie D.;Van Winckel S.;Gregoire G.;Jacquemain D.
    • Nuclear Engineering and Technology
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    • v.38 no.2
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    • pp.163-174
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    • 2006
  • The $Ph{\acute{e}}bus$ FP project is an international reactor safety project. Its main objective is to study the release, transport and retention of fission products in a severe accident of a light water reactor (LWR). The FPT4 test was performed with a fuel debris bed geometry, to look at late phase core degradation and the releases of low volatile fission products and actinides. Post Test Analyses results indicate that releases of noble gases (Xe, Kr) and high-volatile fission products (Cs, I) were nearly complete and comparable to those obtained during $Ph{\acute{e}}bus$ tests performed with a fuel bundle geometry (FPT1, FPT2). Volatile fission products such as Mo, Te, Rb, Sb were released significantly as in previous tests. Ba integral release was greater than that observed during FPT1. Release of Ru was comparable to that observed during FPT1 and FPT2. As in other $Ph{\acute{e}}bus$ tests, the Ru distribution suggests Ru volatilization followed by fast redeposition in the fuelled section. The similar release fraction for all lanthanides and fuel elements suggests the released fuel particles deposited onto the plenum surfaces. A blockage by molten material induced a steam by-pass which may explain some of the low releases. The revaporisation testing under different atmospheres (pure steam, $H_2/N_2$ and steam /$H_2$) and up to $1000^{\circ}C$ was performed on samples from the first upper plenum. These showed high releases of Cs for all the atmospheres tested. However, different kinetics of revaporisation were observed depending on the gas composition and temperature. Besides Cs, significant revaporisations of other elements were observed: e.g. Ag under reducing conditions, Cd and Sn in steam-containing atmospheres. Revaporisation of small amounts of fuel was also observed in pure steam atmosphere.