• Title/Summary/Keyword: Voc

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Fabrication of Honeycomb Adsorbents by Using the Ceramic Paper and Adsorption Characteristics of VOC (세라믹섬유지를 사용한 허니컴 흡착소자 제조 및 VOC 흡착특성)

  • Yoo, Yoon-Jong;Cho, Churl-Hee;Kim, Hong-Soo;Ahn, Young-Soo;Han, Moon-Hee;Jang, Gun-Eik
    • Journal of the Korean Ceramic Society
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    • v.39 no.11
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    • pp.1035-1041
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    • 2002
  • The adhesion characteristics of adsorbent during impregnation of Y-type and ZSM-5type zeolites into ceramic paper were analyzed, as the amount of silica sol in slurry for impregnation was varied. 31 wt% of zeolite particle, which is useful for VOC adsorption, was evenly dispersed and adhered on ceramic paper and original crystal structure of the zeolite remained unchanged even after binder application and heat treatment. Surface area of the impregnated ceramic paper was decreased compared with that of zeolite powder. And it was found to be attributed to the reduction of volume of mesopore while the volume of micropore under $20{\AA}$ was unchanged. Zeolite-impregnated honeycomb cylinder, whose diameter and length were 10 cm and 40 cm, respectively, was subjected to adsorption/desorption test with respect to toluene, MEK, cyclohexanone. All of the VOC's were removed by adsorption with efficiency higher than 97% and from the static adsorption test, $42 Nm^3/h$ of 300 ppmv-VOC-laden air was calculated be treated continuously, when the honeycomb was used in an adsorptive rotor system.

Development of a Bioscrubber for Treatment of VOC Emissions from Contaminated Soil with Hydrocarbons (유류오염토양으로부터 발생하는 VOC가스처리를 위한 바이오스크러버 개발)

  • 장윤영;황경엽;곽재호;최대기
    • Journal of Korea Soil Environment Society
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    • v.2 no.1
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    • pp.83-90
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    • 1997
  • Aiming at the treatment of large volumes of gas with a low concentration of poorly water soluble VOC(Volatile Organic Compound), a new system is proposed: the combination absorption tower/bioreactor. In the scrubber part of the bioscrubbing system, the contaminating compounds are absorbed in a aqueous phase. The contaminated scrubbing liquid is transported to the bioreactor, where the compounds are biodegraded by aerobic microorganisms (mainly to carbon dioxide, water, and biomass). In this study, separation of a volatile organic compound(VOC) out of a waste gas stream has been carried out using a re-cyclable high boiling point extrant(HBE). The liquid stream containing a high boiling point entrant(HBE) scrubs the gas stream in a direct gas-liquid countercurrent contacting operation in a packed tower for the removal of said component from the gaseous stream. A packed-bed column using Pall Ring was set up in order to simulate practical conditions for the scrubbing tower. The liquid stream transported to the bioreactor is recovered and recycled to the scrubber. The model gas, which contained 400 mg/$\textrm{m}^3$ of toluene, at a rate of 100 L/min, flowed into the packed column where the scrubbing liquid trickled over the packing in countercurrent to the rising gas at 10~15L/min. The bioscrubber designed for large volume air streams containing VOCs showed removal efficiency up to 80% in an optimum operating conditions during the tests fer removing toluene from an air stream by scrubbing the air stream with HBE.

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A preliminary study of sorptive characteristics of aromatic volatile organic compounds (VOC) on clothing materials (방향족 유기화합물의 가스상 시료를 이용한 피복류의 흡착특성 비교에 대한 예비연구)

  • Kim, K.H.;Im, M.S.;Park, S.Y.;Hong, Y.J.;Choi, Y.J.;Lee, Y.S.;Kim, S.D.;Nam, S.H.;Ok, J.S.
    • Analytical Science and Technology
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    • v.19 no.3
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    • pp.255-262
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    • 2006
  • In this study, we attempted to evaluate the sorptive loss of VOC upon their contact with different material surfaces including clothing pieces. For the purpose of this study, we developed a method to evaluate such loss by employing a filter holder pack in the thermal desorption line of the GC/FID system. The calibration curves of different aromatic VOCs including benzene, toluene, and xylene were made by loading them at different quantities through the analytical line. A series of experiments were conducted repetitively to draw calibration data sets for all three materials covering glass fiber, cotton, and nylon. The results were then compared in terms of both material types and of VOC types. The extent of sorptive loss increased in a highly systematic manner across different materials such as glass fiber, cotton, and nylon. The patterns of sorptive loss also increased gradually across VOC type such toward in the direction of increasing molecular weights: benzene, toluene, and xylene. According to this experimental study, it is concluded that sorptive behavior of pollutint compounds like VOC can be controlled by the combined effects of both chemical properties and material characteristics.

Synthesis of O/W Emulsion of Alkyd Resin for Reducing of VOC (VOC 절감을 위한 알키드 수지의 O/W 에멀젼 제조)

  • Lee, Young Sang;Lee, Euy Soo;Ha, Jin Kuk
    • Journal of Adhesion and Interface
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    • v.11 no.1
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    • pp.9-14
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    • 2010
  • O/W emulsions were prepared with the phase inversion emulsification methods. The emulsifiers were used the UNIQ-1 (isopropylamine alkyl aryl sulphonate) and UNIQ-2 (alkoxylated glycol ether). Investigated effect that HLB value, agitator velocity and manufacture temperature get in mean particle size of emulsions. Mean particle size receives much effect of HLB value. Also, estimated stability about storage temperature and light. Emulsion's mean particle size was 193 nm lastly, reduced VOC amount used 90% than existing alkyd resin.

A Numerical Analysis of the Abatement of VOC with Different Photocatalytic Honeycomb Filters (광촉매 필터형상에 따른 휘발성 유기화합물의 제거에 관한 수치해석적 연구)

  • 류무성;김창녕
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.16 no.1
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    • pp.1-7
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    • 2004
  • This study has been numerically conducted to investigate the removal efficiency of Volatile Organic Compound (VOC) for different photocatalytic honeycomb filters. Recently, the photocatalysis is being applied to air-cleaner, air-conditioner and vacuum-cleaner with the capability of air-purification, sterilization and antibiosis. However, photocatalysis is less efficient than other methods for removing VOC except in the case of low concentration. So far most of studies have focused on an improvement of the photocatalytic materials, but this study have placed emphasis on the improvements of shape of photocatalytic honeycomb filter. UV irradiation, concentration profile and pressure drop have been investigated for different cross sections of filters and for different filter lengths. Light intensity is dropped sharply with increasing distance from the UV-lamp, and becomes very low in the middle of the filters. Since photocatalytic reaction rate is a function of light intensity, VOC concentration gradient might be small in the middle of long filters. Thus, most of reaction have risen within only three times of dimensionless axial distance. These results can be used effectively for the design of advanced photocatalytic honeycomb filters.

Evaluating Vehicle Emission Reduction (CO, VOC and NOx) Using Real-time Traffic Information (실시간교통정보 이용에 따른 차량의 CO, VOC, NOx 저감효과 평가)

  • Kim, Jun-Hyung;Um, Jung-Sup
    • Journal of Environmental Impact Assessment
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    • v.20 no.2
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    • pp.217-226
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    • 2011
  • This paper was inspired by the fact that Real-time Traffic Information Service could play a key role in reducing incomplete combustion time remarkably since it can provide traffic jam information in real-time basis. Emission characteristics of experimental engines were studied with variable travel distances and speed of car in terms of traffic information provided. 12 Km distance road of Susung district in Daegu is taken as an experimental area to examine this new approach. The emission was tested while the driving was done at 8 AM, 3 PM, 6 PM which represents various traffic conditions. The reduced emission has been measured for a travel distance running at different loads (conventional shortest route and Real-time Traffic Information) and various loads (CO, VOC and NOx) are all inventoried and calculated in terms of existing emission factors. The emission has been shown to reduce linearly with travel distance : carbon monoxide (20.56%), VOC (29.21%), NOx(8.86%).

On-line GC Analysis of Odorous VOC and S Gas Pollutant Levels in Ambient Air of a Residential Area at Ansan City, Korea (안산시 주거지역을 중심으로 한 환경대기 중 휘발성 유기화합물과 황계열 성분의 온라인 연속측정 연구)

  • Kim K.-H;Ju DW;Choi YJ;Hong YJ;Sa JH;Park JH;Jeon EC;Choi CR;Koo YS
    • Journal of Korean Society for Atmospheric Environment
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    • v.21 no.1
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    • pp.107-118
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    • 2005
  • In this study, the concentrations of major odorous compounds including reduced sulfur compounds (OMS, CS$_2$, and DMDS) and aromatic VOC (benzene, toluene, xylene, etc.) were measured continuously using an on-line GC analytical system. Our measurements were made from a residential area of Ansan sity during about two week period of October, 2004. The highest mean concentrations of Sand VOC were found as 56.9 pbb of DMS and 21.7 ppb of toluene, respectively. The results of this study generally show that the pollution levels for both types of chemicals are significant relative to previous measurement results reported from comparable sites, if the results are compared simply in terms of the magnitude of the measured concentration data. Moreover, when the relative importance of different compounds is compared in terms of the odor strength, it indicated that the contribution of reduced S compounds may be much more important than that of VOC in the study area.

The Comparison of VOC Characteristics Emitted from Wood-based Panels Using GC/FID and GC/MS (GC/FID와 GC/MS 분석법에 의한 목질제품에서의 VOC 방출특성 비교)

  • Hwang, Yoon-Seo;Park, Hyun-Ju;Son, Youn-Suk;Kim, Jo-Chun
    • Journal of Korean Society for Atmospheric Environment
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    • v.27 no.4
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    • pp.436-442
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    • 2011
  • In this study, the Total Volatile Organic Compounds (TVOC) emitted from wood-based panels were compared by two analytical methods using the GC/FID and the GC/MS. Japanese Larch, Yellow Poplar, Particle Board (PB) and Medium Density Fiberboard (MDF) were selected as target materials. Major compounds emitted from the panels were Toluene, ${\alpha}$-pinene, ${\beta}$-pinene and limonene. In case of TVOC using GC/FID method, MDF E2 (1,497 ${\mu}g/m^3$) revealed the highest concentration among all wood-based panels, while Japanese Larch (1,772 ${\mu}g/m^3$) showed the highest value with respect to GC/MS method. Furthermore, it was found that the amount of VOC emitted from panels was different depending upon analytical methods. This significant difference was attributed to analytical sensitivities of GC/FID and GC/MS for various VOC. Besides, it was found that the composition ratios of main VOC compounds were not significantly different.

Consideration of the analytical bias involved in the detection of total volatile organic compounds (TVOC) (총휘발성유기화합물 (TVOC) 검량의 오차인자에 대한 연구)

  • Kim, K.H.
    • Analytical Science and Technology
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    • v.17 no.6
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    • pp.489-495
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    • 2004
  • In this article, various aspects of errors involved in the measurement of TVOC were examined as part of study to develop the indoor pollution indices. For this purpose, TVOC term was computed by two different calibration approaches, i.e., by assuming all VOC are detected in the same manner as toluene and by summing up as many individual VOC as possible. The results of our study indicate that the common, toluene-based method suffers from errors inherent in the development of such theory. Consequently, it is concluded that more research efforts have to be directed to the improvement of such concept as TVOC.

A Numerical Analysis of VOC Removal in Honeycomb Photocatalytic Reactor (벌집형 광촉매 반응기의 VOC 제거에 관한 수치해석적 연구)

  • 류무성;김창녕
    • Proceedings of the Korea Air Pollution Research Association Conference
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    • 2003.05b
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    • pp.385-386
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    • 2003
  • 건축자재의 제작 및 도장공정, 합성수지 제조공정 등에서 많이 배출되는 휘발성 유기화합물(Volitile Organic Compounds, 이하 VOCs)은 이동성이 강하고 악취를 유발할 뿐만 아니라 마취성이 강하여 잠재적인 독성 및 발암성을 가진다. 이러한 VOCs의 제거방법 중 광촉매 제거법은 380 nm 이하의 자외선을 흡수하여 표면에서 생긴 전자와 정공으로 대부분의 유해물질을 제거하는 비교적 최근에 개발된 방법이다. 광촉매는 한번의 설치로 반영구적으로 사용할 수 있고 인체에 무해하며 유지비용이 적게 든다는 장점으로 인해 크게 부각되고 있다. (중략)

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