• Title/Summary/Keyword: Voc

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Evaluation of sampling and analytical method for emission experiment of pollutants in building materials using small chamber (소형챔버를 이용한 건축자재 오염물질 방출시험방법 평가)

  • Lee, Suk-Jo;Jang, Seong-Ki;Kim, Mi-Hyun;Lee, Hong-Suk;Lim, Jun-Ho;Jang, Mee;Seo, Soo-Yun
    • Analytical Science and Technology
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    • v.18 no.4
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    • pp.344-354
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    • 2005
  • This study was carried out to evaluate the performance of a small chamber sampling and analytical method for the measurement of total volatile organic compounds (TVOC) and formaldehyde (HCHO) emission from building materials. While VOC was determined by the adsorbent tube sampling and sequential thermal desorption coupled with GC/MSD analysis, formaldehyde sampled with DNPH-silica cartridge was analyzed by HPLC. Wide-range performance criteria such as repeatability, desorption efficiency, emission chamber recovery test, duplicate precision, breakthrough volume and method detection limits were investigated for the evaluation of small chamber method. The overall precision of the small chamber sampling and analytical methods was estimated within 20~30% for target compounds. In conclusion, this study demonstrated that the small chamber sampling and analytical method can be reliably applied for the measurement of building materials pollutants.

Mainstream smoke level of harmful substances in korean domestic cigarette brands

  • Choi, Hyun Doc;Song, Seok Ho;Cho, Hoonsik;Kim, Hyung Kyung;Lee, Jin-Hee;Yoon, Soon-Byung;Heo, Seok;Park, Hyoung-Joon
    • Analytical Science and Technology
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    • v.31 no.1
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    • pp.14-22
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    • 2018
  • After signing the WHO FCTC in 2003, South Korea ratified the FCTC in 2005. This study was conducted to provide data on toxic constituents that can be used as useful information for the level of exposure to Korean smokers. Emissions data from five brands of cigarettes were tested under the ISO and "Canadian Intense (HCI)" smoking regimes, respectively. We conducted an analysis of 25 compounds containing nicotine, tar, carbonyls, phenolics, volatile organic compounds (VOCs), and semi-VOC cigarette smoke. Tar and nicotine showed levels of 4.3 to 5.8 mg/cig and 0.4 to 0.5 mg/cig, respectively, which are within the range of tolerance presented in ISO 8243. In the case of carbonyls, formaldehyde was detected within a range of 8.2 to $14.3{\mu}g/cig$, and acetaldehyde was present within a range of 224.7 to $327.2{\mu}g/cig$ under the ISO smoke regime. Crotonaldehyde was not detected under the ISO regime, and all of the carbonyls showed values 2.3 to 4.5 times higher under the HCI regime than those under the ISO regime. Catechol, which showed a level of 47.0 to $80.5{\mu}g/cig$ under the ISO regime and 117.5 to $184.7{\mu}g/cig$ under the HCI regime, was the highest constituent among the phenols. The amount of isoprene was 91.7 to $158.3{\mu}g/cig$ under the ISO regime and 221.0 to 377.0 under the HCI regime. To summarize, most of the constituents showed a tendency to be detected at levels 2 to 4 times higher under the HCI regime than under the ISO regime. Above all, these results represent the first analysis in Korea from an independent institute of tobacco companies under accreditation of ISO 17025.

Comparison of TVOCs emission characterization of paint and putty according to the amendment of test specimen preparation method (시험편 제작방법 변경에 따른 페인트, 퍼티의 TVOCs의 방출 특성 비교)

  • Park, Joon-Man;Yoo, Ji-Ho;Kim, Man-Goo
    • Analytical Science and Technology
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    • v.23 no.2
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    • pp.109-118
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    • 2010
  • Amended at the Law of indoor air quality management open a court according to the test method and excess standard of the fluid building material were changed. It used the paint and the putty in the fluid building material from this research and comparison of amended and original method it led and in about change direction of amended standard with change of the emission rate who is caused by in the amended test method and excess standard it examined. The reduction emission rate about 45% decreases in the change of test period of the paint, there was not an effect of the emission rate whom it follows in change of dry time. Also change of the emission rate whom it follows in change of application quantity the product which above $5\;mg/m^2h$ has the high emission rate the change of the emission rate is big but there was not change of the emission rate from the products of that others. The putty the emission rate about 61% decreases in case in the change of test period, there was not an effect of the emission rate whom it follows at dry time. The emission rate about 164% increased with increase of application quantity. It tried to compare two test methods, it compared in the paint and putty all current test method it was relaxed the possibility of knowing the thing there was a standard.

Preparation of Natural Wall Paint by Using Sericite Clay (견운모를 이용한 벽마감용 천연페인트 제조)

  • Kim, Munui;Lalhmunsiama, Lalhmunsiama;Lee, Seung-Mok;Jin, Kang-Jung
    • Applied Chemistry for Engineering
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    • v.28 no.5
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    • pp.501-505
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    • 2017
  • Due to the rapid urbanization and increased population, there is an increase in airtight nature of buildings which causes serious indoor air pollution. Among several indoor air pollutants, volatile organic compounds (VOCs) emitted from paint are of major concern. Therefore, there is an urge for the development of environmental friendly paint products. In this wok, a natural wall paint (NWP) was prepared by utilizing a natural clay material "sericite" as a main component. A small chamber test was carried out to identify the toxic substances release from NWP and the results were compared with two eco-friendly commercial paints. The total VOCs were detected in trace level inside the test chamber and their concentrations were below the recommended indoor air quality standards. Toluene was not detected for NWP, whereas formaldehyde was observed in trace level. The toxicity index results were compared with two commercial paints and found that NWP exhibited less harmful gas emission. Based on certification rating of building materials, NWP can be classified as the first grade of building materials. Due to the above advantages, the use of sericite as a major component in NWP will be a useful technique to maintain the indoor air quality.

The Design and Implementation of a Real-Time FMD Cattle Burial Sites Monitoring System Based-on Wireless Environmental Sensors (u-EMS : 센서네트워크 기반의 가축매몰지 악취환경정보 실시간 모니터링 시스템 설계 및 구현)

  • Moon, Seung-Jin;Kim, Hong-Gyu;Park, Kyu-Hyun
    • The Journal of Korean Institute of Communications and Information Sciences
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    • v.36 no.12B
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    • pp.1708-1721
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    • 2011
  • Recent outbreak of cattle diseases such as foot-and-mouth disease(FMD) requires constant monitoring of burial sites of mass cull of cattles. However, current monitoring system takes environmental samples from burial sites with period of between one and two weeks, which makes it impossible for non-stop management of hazardous bio-waste. Therefore, in this study, we suggest an improved real-time environmental monitoring system for such bio-hazardous sites based on wireless sensor networks, which makes constant surveillance of the FMD burial sites possible. The system consists mainly several wireless environmental monitoring sensors(i.e dust, Co2, VOC, NH3, H2S, temperature, humidity) nodes and GPS location tracking nodes. Through analysis of the relayed of the environmental monitoring data via gateway, the system makes it possible for constant monitoring and quick response for emergency situation of the burial sites. In order to test the effectiveness of the system, we have installed a set of sensor to gas outlets of the burial sites, then collected and analyzed measured bio-sensing data. We have conducted simulated emergency test runs and was able to detect and monitor the foul smell constantly. With our study, we confirm that the preventive measures and quick response of bio environmental accident are possible with the help of a real-time environmental monitoring system.

Annual Base Performance Evaluation on Cell Temperature and Power Generation of c-Si Transparent Spandrel BIPV Module depending on the Backside Insulation Level (스팬드럴용 투광형 결정계 BIPV창호의 후면단열 조건에 따른 연간 온도 및 발전성능 분석 연구)

  • Yoon, Jong-Ho;Oh, Myung-Hwan;Kang, Gi-Hwan;Lee, Jae-Bum
    • Journal of the Korean Solar Energy Society
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    • v.32 no.4
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    • pp.24-33
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    • 2012
  • Recently, finishing materials at spandrel area, a part of curtain-wall system, are gradually forced to improve thermal insulation performance in order to enhance the building energy efficiency. Also, Building Integrated Photovoltaics(BIPV) systems have been installed in the exterior side of the spandrel area, which is generally composed of windows. Those BIPVs aim to achieve high building energy efficiency and supply the electricity to building. However, if transparent BIPV module is combined with high insulated spandrel, it would reduce the PV efficiency for two major reasons. First, temperature in the air space, located between window layer and finishing layer of the spandrel area, can significantly increase by solar heat gain, because the space has a few air density relative to other spaces in building. Secondly, PV has a characteristics of decreased Voltage(Voc and Vmp) with the increased temperature on the PV cell. For these reasons, this research analyzed a direct interrelation between PV Cell temperature and electricity generation performance under different insulation conditions in the spandrel area. The different insulation conditions under consideration are 1) high insulated spandrel(HIS) 2) low insulated spandrel(LIS) 3) PV stand alone on the ground(SAG). As a result, in case of 1) HIS, PV temperature was increased and thus electricity generation efficiency was decreased more than other cases. To be specific, each cases' maximum temperature indicated that 1) HIS is $83.8^{\circ}C$, 2) LIS is $74.2^{\circ}C$, and 3) SAG is $66.3^{\circ}C$. Also, each cases yield electricity generation like that 1) HIS is 913.3kWh/kWp, 2) LIS is 942.8kWh/kWp, and 3) SAG is 981.3kWh/kWp. These result showed that it is needed for us to seek to the way how the PV Cell temperature would be decreased.

Standardization of Trail Difficulty based on Energy Consumption (에너지 소모량에 기초한 탐방로 난이도 표준화 연구)

  • Hong, Suk-Hwan;Kwon, Tae-Ho;Choi, Song-Hyun;Kim, Kyung-Tae;Kim, Dong-Pil
    • Korean Journal of Environment and Ecology
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    • v.29 no.4
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    • pp.626-635
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    • 2015
  • Recently, the number of trail users in Korea has risen tremendously. Consequently, the cost of safety measures related to hiking is sharply increasing. Despite the safety cost input, the number of heart-related adverse events has been not decreasing. Therefore, this research aims to suggest the use of objective and quantitative trail use information in terms of course difficulty. The study site is Jirisan Dullegil (Jirisan Forest Trail). The currently available trail difficulty information either provides the difficulty rating in terms of 3 to 5 levels according to several empirical difficulty factors reported by staff who maintain the forest or simply states the distance of each trail. Thus, many trail visitors feel a great gap between the given information and actual difficulties they experience. In this study, we tried to assess the degree of difficulty by actual energy consumption. Calculating the volumetric oxygen consumption (VOC) by the distance and gradient not only makes possible an absolute rating but a comparison among the trails as well. Also, it is highly effective to simply describe the exercise intensity of a certain trail. Further, it is easy to check the VOCs' changes by switching the start-end points of the same trail. Providing the trail information of VOCs by sections and directions, we expect to prevent heart-related accidents.

A Study on the Seasonal Survey of the Indoor Air Quality in New Apartment Houses (신축 공동주택의 계절별 실내공기질 실측조사에 관한 연구)

  • Chun, Chu-Young;Kim, Gil-Tae;Hwang, Gi-Huen
    • Land and Housing Review
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    • v.4 no.4
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    • pp.417-424
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    • 2013
  • The purpose of this study was to investigate the characteristics of the indoor air quality by season. The surveyed houses were 48 new apartment complex in 2012 across the country. The houses were carried out the bakeout before the test. The measuring method was "Indoor air quality testing standards process" and the measured items were formaldehyde, benzene, toluene, ethylbenzene, xylene, styrene average emissions. All the items were more emitting during the summer. From June to September the average concentration of formaldehyde emission was higher than other seasons. The average emissions of benzene concentrations in all seasons were released in small quantities. Average emissions of toluene and ethylbenzene concentration from April to August showed slightly higher emissions. Xylene and styrene concentration showed the highest emissions at April, but without large deviations throughout the year.

Condensable Gas Separation using Phenol! Alumina Composite Activated Carbon Hollow Fiber Membranes (페놀수지/알루미나 복합 활성탄소중공사막을 이용한 응축성 기체 분리)

  • Shin, Kyung-Yong;Park, You-In;Kim, Beom-Sik;Koo, Kee-Kahb
    • Membrane Journal
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    • v.20 no.4
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    • pp.312-319
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    • 2010
  • Carbon membrane materials have received considerable attention for the gas separation including hydrocarbon mixture of ingredients of the volatile organic compounds(VOCs) because they possess their higher selectivity, permeability, and thermal stability than the polymeric membranes. The use of activated carbon membranes makes it possible to separate continuously the VOCs mixture by the selective adsorption-diffusion mechanism which the condensable components are preferentially adsorbed in to the micropores of the membrane. The activated carbon hollow fiber membranes with uniform adsorptive micropores on the wall of open pores and the surface of the membranes have been fabricated by the carbonization of a thin film of phenolic resin deposited on porous alumina hollow fiber membrane. Oxidation, carbonization, and activation processing variables were controlled under different conditions in order to improve the separation characteristics of the activated carbon membrane. Properties of activated carbon hollow fiber membranes and the characterization of a gas permeation by pyrolysis conditions were studied. As the result, the activated carbon hollow fiber membranes with good separation capabilities by the molecular size mechanism as well as selective adsorption on the pores surface followed by surface diffusion effective in the recovery hydrocarbons have been obtained. Therefore, these activated carbon membranes prepared in this study are shown as promising candidate membrane for separation of VOCs.

Design of Environmentally Sound Manufacturing Process of Fork Lift using LCA and DfE Methodology (LCA와 DfE기법을 이용한 친환경적인 지게차 제조공정의 설계)

  • Park, Kwang-Ho;Hwang, Yong-Woo;Park, Il-Do
    • Journal of Korean Society of Environmental Engineers
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    • v.27 no.7
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    • pp.677-685
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    • 2005
  • Life Cycle Assessment(LCA) and Design for Environment(DfE) method were applied to design the environmentally sound manufacturing process of f31k lift in this study. Not only external movement of LCA and DfE method in the legal and systemic phase, but also active researches of those in the development phase of case study and application to the industrial field, have been going on. In concretely, the manufacturing processes of the folk lift generating the most environmental impact were examined by applying LCA method, and the environmentally sound manufacturing process was designed by applying, DfE method to the processes. As the results of LCA, environmental impacts for the eco-toxicity and human toxicity of seven major environmental categories were in high value, and so be in the cutting & welding process and painting process among the manufacturing processes. High solid paints, increasing the solid content of the existing solvent paints used in painting process, were developed to reduce the environmental impacts generated in the painting process. By utilizing the high solid paints, about 20% of environmental impacts (as environmental index of LCA) could be reduced.