• Title/Summary/Keyword: Visible Element

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Photocatalysis of o-, m- and p-Xylene Using Element-Enhanced Visible-Light Driven Titanium Dioxide

  • Kim, Jong-Tae;Kim, Mo-Keun;Jo, Wan-Kuen
    • Journal of Environmental Science International
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    • v.17 no.11
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    • pp.1195-1201
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    • 2008
  • Enhancing with non-metallic elemental nitrogen(N) is one of several methods that have been proposed to modify the electronic properties of bulk titanium dioxide($TiO_2$), in order to make $TiO_2$ effective under visible-light irradiation. Accordingly, current study evaluated the feasibility of applying visible-light-induced $TiO_2$ enhanced with N element to cleanse aromatic compounds, focusing on xylene isomers at indoor air quality(IAQ) levels. The N-enhanced $TiO_2$ was prepared by applying two popular processes, and they were coated by applying two well-known methods. For three o-, m-, and p-xylene, the two coating methods exhibited different photocatalytic oxidation(PCO) efficiencies. Similarly, the two N-doping processes showed different PCO efficiencies. For all three stream flow rates(SFRs), the degradation efficiencies were similar between o-xylene and m,p-xylene. The degradation efficiencies of all target compounds increased as the SFR decreased. The degradation efficiencies determined via a PCO system with N-enhanced visible-light induced $TiO_2$ was somewhat lower than that with ultraviolet(UV)-light induced unmodified $TiO_2$, which was reported by previous studies. Nevertheless, it is noteworthy that PCO efficiencies increased up to 94% for o-xylene and 97% for the m,p-xylene under lower SFR(0.5 L $min^{-1}$). Consequently, it is suggested that with appropriate SFR conditions, the visible-light-assisted photocatalytic systems could also become important tools for improving IAQ.

A Study on Plan Structure Types and Characteristics of Wall Formation in Art Museum Exhibition Spaces

  • Lee, Jong-Sook
    • Architectural research
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    • v.13 no.3
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    • pp.3-10
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    • 2011
  • The Characteristics of space are determined by several factors; however, the element that determines the physical characteristic of floors, walls, and ceiling is the structure. This study constructs a wall to analyze the direct effect that the layout of an exhibition wall has on the element of the wall followed by the structural process and visibility of descriptive analysis and examples of art museums that the shift from a perceptional wall to an experiential wall affected circulation. For elements and formation methods of the wall, first, it is made up of open and closed type exhibition spaces, and it can give abundance in qualitative space rather than a quantitative aspect. Secondly, the directivity of space changes according to the development of the visible axis, thus, directly affects the change in visibility. Thirdly, the difference between spatial structure and visual structure is the difference between the visual axis and spatial structure. The wall formation type followed by the combination method, the simple visible structure, which is the type that possesses the simple combination (Room, Zone, Cluster), repeatedly uses the same size of units of space that is orderly and has few spatial axes and the classification of simple type and simple cluster type, which has few visible axes, also exists. Also, with the complex structure of the maze type it displays the reiterated form of the cluster, which is the space with disorderly combination and has much visible axes and spatial axes. Also, these can be divided into three types: 1) Maze Cluster Type, 2) Cross Road Type, and 3) Open Flexible Type. These wall types lead the various changes in circulation, and even each of the arrangement qualities of the exhibitions should be researched according to its exhibition place type.

A Study on an Experience of Seascape through Korean Popular Songs (대중가요를 통한 바다경관 체험에 관한 연구)

  • 채혜성;권차경;이동화;강영조
    • Journal of the Korean Institute of Landscape Architecture
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    • v.27 no.4
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    • pp.73-79
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    • 1999
  • This study is on the production and the classification of a new appreciation methods of seascape through materials in the words of Korean popular songs. In advance, it is necessary to understand the popular songs as collective representation and the songs are analytic data. In this study, some essential elements of seascape in popular songs are analyzed and classified. They are; 1. visible elements-weather, time, season and object. 2. all senses-vision, audition, olfaction, tactile sense, and spatial sense. 3. the line of vision-static line of vision and dynamic line of vision. In this way data is produced, and then the result of this study makes appreciation methods of seascape developed. In this way, this study results in developed appreciation of seascape. This study on new understanding of appreciation methods of seascape is on the basis of a design method of water-front that is considered a visible scene, not a design of construction elements.

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Hybrid infrared-visible multiview correlation to study damage in a woven composite complex-shaped specimen

  • Andrija Zaplatic;Zvonimir Tomicevic;Xuyang Chang;Ivica Skozrit;Stephane Roux;Francois Hild
    • Coupled systems mechanics
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    • v.12 no.5
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    • pp.445-459
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    • 2023
  • In this study, a cyclic tensile test on a notched butterfly specimen made of woven glass fiber composite was performed on a modified Arcan fixture. During the mechanical test, the sample was monitored with a hybrid stereoscopic system comprised of two visible lights and one infrared camera. The visible light cameras were employed for kinematic measurements using a finite-element-based multiview correlation technique. A semi-hybrid correlation approach was followed, providing Lagrangian temperature fields of the Region of Interest. Due to the complex composite architecture and specimen shape, localized shearing was observed during the tensile loading. Furthermore, asymmetrical damage developed around the notches as revealed by localized strains and thermal hot spots.

Preparation of WO3-TiO2 Photocatalyst and Evaluation of Its Photo-activity in the Visible Light Range (가시광 활성 WO3-TiO2 복합체 광촉매의 제조 및 이의 특성 평가)

  • Yeo, In-Chul;Kang, In-Cheol
    • Journal of Powder Materials
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    • v.20 no.6
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    • pp.474-478
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    • 2013
  • The most general photocatalyst, $TiO_2$ and $WO_3$, are acknowledged to be ineffective in range of visible light. Therefore, many efforts have been directed at improving their activity such as: band-gap narrowing with non-metal element doping and making composites with high specific surface area to effectively separate electrons and holes. In this paper, the method was introduced to prepare a photo-active catalyst to visible irradiation by making a mixture with $TiO_2$ and $WO_3$. In the $TiO_2-WO_3$ composite, $WO_3$ absorbs visible light creating excited electrons and holes while some of the excited electrons move to $TiO_2$ and the holes remain in $WO_3$. This charge separation reduces electron-hole recombination resulting in an enhancement of photocatalytic activity. Added Ag plays the role of electron acceptor, retarding the recombination rate of excited electrons and holes. In making a mixture of $TiO_2-WO_3$ composite, the mixing route affects the photocatalytic activity. The planetary ball-mill method is more effective than magnetic stirring route, owing to a more effective dispersion of aggregated powders. The volume ratio of $TiO_2(4)$ and $WO_3(6)$ shows the most effective photocatalytic activity in the range of visible light in the view point of effective separation of electrons and holes.

Design and Manufacture of an Off-axis Aluminum Mirror for Visible-light Imaging

  • Zhang, Jizhen;Zhang, Xin;Tan, Shuanglong;Xie, Xiaolin
    • Current Optics and Photonics
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    • v.1 no.4
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    • pp.364-371
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    • 2017
  • Compared to one made of glass, an aluminum mirror features light weight, compact design, low cost, and quick manufacturing. Reflective mirrors and supporting structures can be made from the same material, to improve the athermal performance of the system. With the rapid development of ultraprecise machining technologies, the field of applications for aluminum mirrors has been developed rapidly. However, most of them are rotationally symmetric in shape, and are used for infrared applications. In this paper, the design and manufacture of an off-axis aluminum mirror used for a three-mirror-anastigmat (TMA) optical system at visible wavelengths is presented. An optimized, lightweight design provides a weight reduction of more than 40%, while the surface deformation caused by earth's gravity can meet the required tolerance. The two pieces of an off-axis mirror can be diamond-turned simultaneously in one setup. The centrifugal deformation of the off-axis mirror during single-point diamond turning (SPDT) is simulated through the finite-element method (FEM). The techniques used to overcome centrifugal deformation are thoroughly described in this paper, and the surface error is reduced to about 1% of the original value. After post-polishing, the form error is $1/30{\lambda}$ RMS and the surface roughness is better than 5 nm Ra, which can meet the requirements for visible-light imaging.

Design of Vehicle Safety Protocol on Visible Light Communication using LED (LED 가시광 통신을 이용한 자동차 안전 프로토콜 설계)

  • Kim, Ho-Jin;Kong, In-Yeup
    • Proceedings of the Korean Institute of Information and Commucation Sciences Conference
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    • 2010.05a
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    • pp.563-565
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    • 2010
  • LED is low power and pro-environment semiconductor element. That can be used not only as the lighting function but also for Visible Light Communication(VLC). The VLC is the communication technology that can send data by blinking a fluorescent or LED using visible spectrum. That velocity of blinking can not be usually recognized by eyesight. Visible Light Communication using LED can be used in many fields. In the field of ITS(Intelligent Transportation System), Under construction on the road, Emitting traffic signs can be applied to transfer the vehicle information. In this paper, Emitting traffic signs in addition to the VLC give information about road condition, safety distance and the lane change. We design Communication protocol to provide safety service and verify protocol by experiment.

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Photocatalysis of Sub-ppm-level Isopropyl Alcohol by Plug-flow Reactor Coated with Nonmetal Elements Irradiated with Visible Light

  • Jo, Wan-Kuen
    • Clean Technology
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    • v.18 no.4
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    • pp.419-425
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    • 2012
  • This work explored the characteristics and the photocatalytic activities of S element-doped $TiO_2$ (S-$TiO_2$) and N element-doped $TiO_2$ (N-$TiO_2$) for the decomposition of gas-phase isopropyl alcohol (IPA) at sub-ppm concentrations, using a plug-flow reactor irradiated by 8-W daylight lamp or visible light-emitting-diodes (LEDs). In addition, the generation yield of acetone during photocatalytic processes for IPA at sub-ppm levels was examined. The surface characteristics of prepared S- and N-$TiO_2$ photocatalysts were analyzed to indicate that they could be effectively activated by visible-light irradiation. Regarding both types of photocatalysts, the cleaning efficiency of IPA increased as the air flow rate (AFR) was decreased. The average cleaning efficiency determined via the S-$TiO_2$ system for the AFR of 2.0 L $min^{-1}$ was 39%, whereas it was close to 100% for the AFR of 0.1 L $min^{-1}$. Regarding the N-$TiO_2$ system, the average cleaning efficiency for the AFR of 2.0 L $min^{-1}$ was above 90%, whereas it was still close to 100% for the AFR of 0.1 L $min^{-1}$. In contrast to the cleaning efficiencies of IPA, both types of photocatalysts revealed a decreasing trend in the generation yields of acetone with decreasing the AFR. Consequently, the N-$TiO_2$ system was preferred for cleaning of sub-ppm IPA to S-$TiO_2$ system and should be operated under low AFR conditions to minimize the acetone generation. In addition, 8-W daylight lamp exhibited higher cleaning efficiency of IPA than for visible LEDs.

Synthesis and characterization of noble metal coupled N-TiO2 nanoparticles

  • Lee, Kyusang;Moon, Jiyeon;Kim, Seonmin
    • Proceedings of the Korean Vacuum Society Conference
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    • 2016.02a
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    • pp.374.2-374.2
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    • 2016
  • Volatile organic compounds (VOCs) in the atmosphere are harmful materials which influence indoor air environment and human health. Titanium dioxide ($TiO_2$) is photocatalyst extensively used in degradation of organic compound. To improve the photocatalytic activity in the visible light region, doping with non-metals element or loading noble metals on the surface of $TiO_2$ is generally proposed. In this study, N- doped $TiO_2$ having photocatalytic activity in visible light region was attached noble metal such as Pt, Ag, Pd, Au by coupling method. Catalytic activities of Noble metal coupled $N-TiO_2$ powders were evaluated by the improvement of their photocatalytic activities and the degradation of VOC gas. A UV-Vis spectrophotometer was used to measure the diffuse reflectance spectra of coupled $N-TiO_2$ sample. The photocatlytic activities of as prepared samples were characterized by the decoloration of aqueous MB solution under Xenon light source (UV and visible light). To measure of decomposition VOCs, ethylbenzene was selected for target VOC material and the concentration was monitored under UVLED irradiation in a closed chamber system. Adjusting the initial concentration of 10~12 ppm, to evaluate the removal characteristics by using the coupled $N-TiO_2$.

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Preparation and Characterization and Visible Light Photocatalytic Activity of Fe-Treated AC/TiO2 Composites for Methylene Blue

  • Meng, Za-Da;Zhang, Kan;Oh, Won-Chun
    • Journal of the Korean Ceramic Society
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    • v.46 no.6
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    • pp.621-626
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    • 2009
  • Fe-AC/Ti$O_2$ photocatalysts were prepared by a sol-gel method. The photocatalytic properties of Fe-AC/Ti$O_2$ photocatalysts for the purification of water have been investigated. The samples were characterized by scanning electron microscopy (SEM), specific surface area (BET), X-ray diffraction analysis (XRD), and energy dispersive X-ray spectroscopy (EDX). The photocatalytic activities were evaluated by the photocatalytic oxidation of methylene blue (MB) solution. It was found that the prepared Fe-AC/Ti$O_2$ composites have an excellent photocatalytic under visible light irradiation. A small amount of Fe ions in the AC/Ti$O_2$ composites could obviously enhance their photocatalytic activity. The high activities of the Fe-AC/Ti$O_2$ composites could be attributed to the results of the synergetic effects of the enhancement of the Fe element, the photocatalytic activity of Ti$O_2$, and the adsorption of AC.