• Title/Summary/Keyword: Viscosity Change

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HP-GPC Analysis for Characteristics Change of Asphalt Cement Due to Aging (노화(老化)에 의한 아스팔트 시멘트 형질변화(形質變化)의 HP-GPC 분석(分析))

  • Kim, Kwang Woo;Yeon, Kyu Seok;Choi, Joong Dae
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.12 no.4
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    • pp.49-57
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    • 1992
  • This study was conducted to evaluate physical property change of asphalt cement chromatograms (by HP-GPC) were experimentally obtained from 3 types of AC-20 virgin ACs, 5 and 24-hour artificially aged ACs, and naturally aged 4 ACs that were recovered from 4 different roads. Absolute viscosity, kinematic visoosity and penetration were the physical properties tested. THF was used for mobil phase and RI detector was used as a detector for Hp-GPC testing. Correlation between each physical property change and the chromatogram variation was evaluated. Each chromatogram was divided into ten-equal-time slices. The percentage areas of 10 slices and each physical property were used for statistical correlation evaluation. Statistical analysis results showed that eaoh physical property had a strong correlation with the chromatogram characteristics. Aging was identified as a mechanism of change of molecular size distribution - increasing large size molecules and reducing coresponding samll size molecules.

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Characteristics of the Concentration Process of Lactobacillus Cell Using a Ceramic Membrane (세라믹막을 이용한 Lactobacillus cell의 농축 공정의 특성)

  • Lee Yong Taek;Song Min-Ho
    • Membrane Journal
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    • v.14 no.3
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    • pp.192-200
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    • 2004
  • It is an anaerobic germ that Lactobacillus cell concentrated using ceramic membrane has high stability and long lifetime as compared with polymeric membrane. The effects of operating pressure, temperature, crossflow velocity on cell harvesting have been studied. Also the variation of flux and transmembrane pressure (TMP) with increasing concentration ratio and the change of TMP at constant concentration ratio (volumetric concentration factor: VCF) regarding the optimization have been examined. It showed that the permeate flux increased gradually with the increasing of transmembrane pressure, crossflow velocity, and volumetric concentration factor. The higher initial flux was due to the reduction of viscosity at elevated temperature. However, as operating time progressed, the effect of temperature was negligible since the effect of viscosity became minor. As a result, that operate in a constant concentration ratio, decreased degree could know that become slowly although the flux decreases according as operating time progressed. The flux is a very stable in the condition of constant VCF range. The yield of Latobaciilus (PS 406) which was cultivated at $37^{\circ}C$ was concentrated about 4.9{\times}10^9$ after operation.

Viscosity and Density Studies on the Second CMC of the Aqueous Solution of Dodecyl Pyridinium Chloride (粘性度 및 密度測定에 依한 Dodecyle Pyridinium Chloride 水溶液의 第二 CMC에 關한 硏究)

  • Young Won Youn;Kun Moo Lee
    • Journal of the Korean Chemical Society
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    • v.19 no.5
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    • pp.289-293
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    • 1975
  • According to the viscosity and density studies of an aqueous solution of dodecyl pyridinium chloride (DPC) it was shown that the 2nd critical micelle concentration (2nd cmc) existed in the solution in addition to the 1st cmc. The volume fraction ${\phi}_m$ of the hydrated micelle was calculated by using the following equation: ${\Pi}_{rm}=1+2.5{\phi}_m+14.1{\phi}_m^2$ It has been found that the increment of ${\phi}_m$ in the ${\phi}_m$ vs. $C_m$ curve decreased at near the 2nd cmc. And the partial specific volume ($\={v}$) of DPC obtained from the density measurement also decreased rapidly at near the 2nd cmc and remains constant value above the 2nd cmc. This may be attributed to a change in the micelle structure at the 2nd cmc caused by a variation in the type of aggregation and by a decrease in the counterion binding by the micelle.

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Biocompatibility for the Rat of Chitosan (키토산의 백서에서의 생체적합성)

  • 이석우;임윤택;공승대;류정욱;이우윤
    • KSBB Journal
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    • v.16 no.3
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    • pp.302-306
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    • 2001
  • The possibility of biomaterials prepared from natural polymer as a skin substitute was evaluated by measuring biocompatibility. Biodegradable films were prepared by solution blend method in the weight ratio of chitosan for the purpose of useful biomaterials. These films were inserted in the back of rat and their biodegradability was investigated by the film weight and hematology as a function of time for the biotransformation. The result of rat test showed that medium, high viscosity chitosan induced some suspects of inbiocompatibililty in the tissue by foreign body reaction 48 and 72 hours after implantation. Also, we prepared the official burn ointment which is made by low viscosity chitosan. This burn ointment was covered on the skin wound of artificial burn and their effect of healing was investigated by the evaluation of the naked eye and hematological change as a function of time. The result of rats test showed that burn ointments made from chitosan was effective reduction of inflammation than negative group.

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Varietal Variation of Gelatinization and Cooking Properties in Rice having Different Amylose Contents (쌀 품종의 아밀로오스 함량에 따른 호화 및 취반 특성 비교)

  • Yoon, Mi-Ra;Oh, Sea-Kwan;Lee, Jeong-Heui;Kim, Dae-Jung;Choi, Im-Soo;Lee, Jeom-Sig;Kim, Chung-Kon
    • The Korean Journal of Food And Nutrition
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    • v.25 no.4
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    • pp.762-769
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    • 2012
  • In order to study the cooking characteristics of four rice cultivars of Seolhyangchal, Baegjinju, Ilpum and Haiami, we investigated the relationship between the textures of cooked rice and their physicochemical properties. Different levels in grain weight. length/width ratio and amylose content were observed among the four rice cultivars. There was no significant difference in the amylopectin chain length distribution among the cultivars. Water absorptions of rice grains during soaking were completed between 30 and 40 min, with Haiami showing the slowest absorption. Significant differences in the viscosity properties of rice flour were found by a Rapid Visco Analyser. Baegjinju with low amylose content had the highest viscosity in paste breakdown. According to the DSC results of rice starches, there were significant differences in the onset, peak and conclusion temperatures of the endothermic peak. Gelatinization enthalpy showed energy content changes between 4.20 and 6.97 J/g, with the lowest change in Haiami. Texture properties of cooked rice were assessed using a Texture Analyzer, which showed that the hardness of cooked rice was decreased with soaking than without soaking. However, this finding was not applicable for Haiami rice.

The Effect of Low Boiling Point Oxygenates on the Diesel Engine Performance and Emissions (저비점 함산소물질이 디젤기관의 성능과 배기배출물에 미치는 영향)

  • 김봉석;송용식;궁본등
    • Journal of Energy Engineering
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    • v.13 no.1
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    • pp.20-27
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    • 2004
  • In the study, the effect of low boiling point oxygenates in high viscous fuels on the exhaust emissions has been investigated for a single cylinder DI diesel engine. It was tested to estimated change of engine performance and exhaust emission characteristics for the base fuels and low boiling point oxygenates blended fuel which have six kinds of fuels and various mixed rates. The results of the study may be con eluded as follows By blending of various low boiling point oxygenated agents to lower grade fuels, significant improvements were simultaneously obtained in smoke, CO, PM, SOF and BSEC. Especially, these trends were remarkably obtained by retarding injection timing, by decreasing boiling point and increasing blending contents of additives in case of oxygenated agents rather than non-oxygenated agents. Also, it was revealed that when 20 vol.% DMM added to high viscosity fuels and injection timing was retarded, Nox-smoke trade off relationship was much better than that of ordinary diesel fuel. Thus, lower grade fuels with high viscosity could be expected to be used efficiently and cleanly in diesel operation by blending low boiling point oxygenates.

Phenyl modified silica sol-gel films for photonics (Photonic 재로로서 페닐실리카 코팅막의 특성)

  • Ahn, Bok-Yeop;Seok, Sang-Il;Kim, Joo-Hyeun;Lim, Mi-Ae
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2003.11a
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    • pp.131-131
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    • 2003
  • The advent of photonic technologies in the field of communications and data transmission has been heavily increasing the demand in integrated optical (IO) circuits capable of accomplishing not only simple tasks like signal, but also more sophisticated functions like all-optical signal routing or active multiplexing/demultiplexing. In the last decade, sol-gel technology has been widely used to prepare optical materials. Sol-gel processes show many promises for the development of low-loss, high-performance glass integrated optical circuits. However, crack formation is likely to occur during heat treatment in thick gel films. In order to overcome the critical thickness limitation, the organic-modified silicate has been widely used. In this case coating matrices have been prepared from the organo-silanes of T structures, acidic catalyst and the as-prepared gel films have been heat-treated below 200$^{\circ}C$ to avoid the crack formation and the degradation of organic components. However, the films prepared in the acidic condition and the low heat temperature make the films contain high OH groups which is the major optical loss function. In this work, C$\sub$6/H$\sub$5/SiO$\sub$1.5/ films were prepared on silicon substrate by sol-gel method using base catalyst in a PTMS/NH$_4$OH/H$_2$O/C$_2$H$\sub$5/OH system. The sol showed spinable viscosity at 50 wt% of solid content, and neglectable viscosity change with time. The films were crack-free and transparent after curing at 450 $^{\circ}C$, and highly condensed to minimize OH content in C$\sub$6/H$\sub$5/SiO$\sub$1.5/ networks. The effects of heat treatment of the films are characterized on the critical thickness, the chemical composition and the refractive indices by means of SEM, FT-IR, TGA, prism coupler, respectively.

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The Quality Characteristics of Chunggujang Prepared by Bacillus Subtilis NRLSI IV on the Different Inoculum Levels and Fermentation Times (Bacillus Subtilis NRLSI IV로 제조한 청국장의 접종포자농도와 발효시간에 따른 품질 특성)

  • Kim Kyung-Mi;Kim Haeng-Ran;Park Hong-Ju
    • The Korean Journal of Community Living Science
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    • v.17 no.3
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    • pp.123-131
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    • 2006
  • To compare the quality characteristics, chunggugjang was prepared with Bacillus subtilis NRLSI IV on the different inoculum levels$(10^2,\;10^4,\;10^6,\;and\;10^8 CFU/ml)$ and fermentation times(0, 12, 24, 36, and 48 hours). Although significant change in total nitrogen content was not found, the content of amino type, soluble and ammonia type nitrogen was generally increased according to the increase in fermentation time. Decomposition rate of nitrogen was also increased by fermentation time and nitrogen solubility was the highest value(62-75.9%) at 48 hour fermentation. In results of color changes, it was found that L and a value were decreased but there was no significant changes in b value as fermentation time was increased. In chunggugjang made with long fermentation time, hardness was decreased and relative viscosity of viscous substance was gradually decreased after little increase at initial fermentation time. The effect of inoculum level on hardness and relative viscosity were similar to that of fermentation time, i.e. the decrease of these at high inoculum level. In activity of V-GTP, 36 hour incubation could produce the highest value whereas no effect of inoculum level was found during fermentation except at 48 hour. In chunggugjang made with $10^2CFU/mL$ of Bacillus subtilis NRLSI IV, the content of glucose, sucrose, raffinose and stachyose was dramatically decreased at initial fermentation time and that of phytic acid, oxalic acid, citric acid, tartaric acid and malic acid was also decreased during fermentation, although the increase in acetic acid was found.

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A Study on the Possibility of Produced by Supercritical Fluid Extraction from Lycii Fructus Seed for Cosmetic Ingredients (구기자 종자 초임계유체 추출물의 화장품소재로서의 가능성 평가)

  • Kim, Bo-Ae
    • Journal of the Korean Applied Science and Technology
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    • v.34 no.3
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    • pp.623-630
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    • 2017
  • The purpose of this study was to investigate the possibility of applying cosmetic material about extracted from Lycii Fructus seed supercritical fluid. This study was conducted to evaluate the anti-melanogenesis effect and antimicrobial activity about the extracts from Lycii Fructus seed. These researches studied for emulsion physical stability of pH, viscosity, particle size from emulsion containing Lycii Fructus seed extract. As a result, the supercritical fluid extract from Lycii Fructus seed significantly inhibited melanin synthesis by 81.86 % at the concentration $750{\mu}g/mL$. Antimicrobial effects of extract was determined against Staphylococcus aureus, Candida albicans, Escherichia coli. except by Staphylococcus epidermidis. The physical stability of viscosity and pH on the emulsion containing Lycii Fructus seed extract were stable for 28 days. Emulsion containing Lycii Fructus seed extract did not change particles at observation into optical microscope. These results suggest that extracts from Lycii Fructus seed may have value as the potential cosmetic formulation.

Particle Motion Interpolation Method for Mitigating the Occurrence of Unnatural Wave Breaking in Fluid Simulation (유체 시뮬레이션에서 부자연스러운 쇄파의 발생을 완화하기 위한 파티클 움직임 보간 방법)

  • Sung, Su-Kyung;Lee, Eun-Seok;Shin, Byeong-Seok
    • Journal of Korea Game Society
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    • v.14 no.3
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    • pp.55-62
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    • 2014
  • In particle-based fluid simulation, applying sudden power to particle raise unnatural flow when wave is breaking. To solve this problem, we have used an linear interpolation technique that interpolate between fluid particle by subdividing the time interval in the previous work. Acceleration vector of the particle with increased pressure in boundary could change smoothly. However, particle looks like flow with viscosity because the number of the minimum samples to interpolate increases. We propose an weighted-interpolation technique to represent the realistic movement of fluid. it is accumulating that has added and assigned different weights to the previous acceleration vector and current one repeatedly. weighted-interpolation technique using less minium samples to flow than linear interpolation, so it can solve the problem which particle looks like flow with viscosity.