• Title/Summary/Keyword: Viscosity Change

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P2O5-ZnO-SiO2-R2O Glass Frit Materials for Hermetic Sealing of Dye-Sensitized Solar Cells

  • Lee, Hansol;Lee, Choon Yeob;Hwang, Jae Kwun;Chung, Woon Jin
    • Journal of the Korean Ceramic Society
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    • v.54 no.5
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    • pp.400-405
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    • 2017
  • $P_2O_5-ZnO-SiO_2-R_2O$ glasses were synthesized as a sealing material for large scale dye-sensitized solar cells (DSSC). Compositional effects of $P_2O_5$ and ZnO were examined by varying their contents. Their viscosity and glass stability at sintering temperatures of less than $550^{\circ}C$ were examined by flow button test. Glass transition temperature and structural change upon compositional change were investigated. Chemical stability against electrolyte was also examined by immersing the glasses in the electrolyte for 72 h at $85^{\circ}C$.

Temperature Characteristic Analysis according to Variation of Properties of Transformer Insulating Oil (변압기 절연유의 물성치 변화에 따른 온도특성해석)

  • Kim, Ji-Ho;Rhee, Wook
    • The Transactions of the Korean Institute of Electrical Engineers P
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    • v.63 no.4
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    • pp.327-332
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    • 2014
  • In this paper, the temperature distribution according to the property change of the insulating oil of the power transformer and max temperature were predicted through the ductility interpretation which heat-flow is coupled. By using CFD (Computation Fluid Dynamics) for the interpretation, the temperature distribution of 154kV the class single phase power transformer was predicted. The power loss causing the temperature rise of the transformer was changed to the heat source and we used as the input value for the heat-flow analysis. The temperature distribution was predicted according to the change of the density, specific heat, thermal conductivity and viscosity, that is the ingredient having an effect on the temperature rise of the transformer oil. The mineral oil of 4 kinds used in domestic and international based on the interpreted result was selected and the temperature distribution according to each load and Hot Spot temperature was predicted.

Evaluation of Internal Stress and Dislocation Velocity in Creep with 25Cr-20Ni Stainless Steels (25Cr-20Ni계 스테인리스강의 크리프 변형중 내부응력과 운동전위밀도의 평가)

  • Park, In-Duck;Ahn, Seok-Hwan;Nam, Ki-Woo
    • Proceedings of the KSME Conference
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    • 2004.04a
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    • pp.296-301
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    • 2004
  • By the purpose to investigate the change of internal stress and mobile dislocation density in creep, the stress relaxation test is carried out in the condition of each strain. Mobile dislocation density increased until it reached minimum creep rate and after that, it decreased and internal stress didn't have the change approximately until it reached minimum creep rate and after that, it decreased. The stress relaxation rate is fast and approached zero after 1.5 seconds after the beginning of the stress relaxation. And the larger the applied stress is, the larger the internal stress is. By the evaluation of mobility of dislocation, the dislocations glide viscously in STS31OJlTB but it is the dislocations glide viscously which N passes by cutting Cr atom rather than typical viscosity movement after calculating mobility of dislocation.

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Analysis of the strain energy release rate for time-dependent delamination in multilayered beams with creep

  • Rizov, Victor I.
    • Advances in materials Research
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    • v.11 no.1
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    • pp.41-57
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    • 2022
  • This paper is focused on delamination analysis of a multilayered inhomogeneous viscoelastic beam subjected to linear creep under constant applied stress. The viscoelastic model that is used to treat the creep consists of consecutively connected units. Each unit consists of one spring and two dashpots. The number of units in the model is arbitrary. The modulus of elasticity of the spring in each unit changes with time. Besides, the modulii of elasticity and the coefficients of viscosity change continuously along the thickness, width and length in each layer since the material is continuously inhomogeneous in each layer of the beam. A time-dependent solution to the strain energy release rate for the delamination is derived. A time-dependent solution to the J-integral is derived too. A parametric analysis of the strain energy release rate is carried-out by applying the solution derived. The influence of various factors such as creep, material inhomogeneity, the change of the modulii of elasticity with time and the number of units in the viscoelastic model on the strain energy release rate are clarified.

A Study on Rheological Properties of Cement Paste using Expansive Additives by Kind & Replacement Ratio (팽창재 종류 및 치환율에 따른 시멘트 페이스트의 레올로지 특성)

  • Park, Chun-Young;Kang, Byeung-Hee
    • Journal of the Korea Institute of Building Construction
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    • v.8 no.2
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    • pp.99-106
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    • 2008
  • To improve concrete tensile strength and bending strength, New plan that have more economical and simple manufacture process is groped. By an alternative plan, chemical pre-stressed concrete is presented. In this study, we analyzed the rheological properties of cement paste with the kind and replacement ratio of k-type CSA type expansive additives that is used mainly in domestic. and we suggested that the algorithm of a mixing plan in the chemical pre-stressed concrete and from this, we presented the basic report for the right mixing plan. From the results, Flow increased more or less according to use of expansive additives. This phenomenon was observed by increasing paste amount that shows as substitution for expansive additives that specific gravity is smaller than that of cement. As linear regression a result supposing paste that mix expansive additives by Bingham plastic fluid. The shear rate and shear stress expressed high interrelationship. therefore, flow analysis of quantitative was available. The plastic viscosity following to replacement ratio of expansive additives is no change almost, the yield value is decreased in proportion to the added amount of expansive additives. Through this experiment, we could evaluate rheological properties of cement paste using the expansive additives. Hereafter by an additional experiment, we must confirm stability assessment of material separation by using the aggregate with the kind and replacement ratio of expansive additives.

Application of Rats According to Molecular Weight of Chitosan (키토산의 분자량에 따른 랫드에서의 적용)

  • Jung, Duck-Chae;Lee, Ki-Chang;Yoon, Cheol-Hun;Kim, Pan-Gyi;Shin, Dong-Hwan
    • Journal of Environmental Health Sciences
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    • v.25 no.3
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    • pp.58-63
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    • 1999
  • Biodegradable films were prepared by solution blend method in the weight ratio of chitosan for the purpose of useful biomaterials. The possibility of biomaterials prepared from natural polymer as a skin substitute was evaluated by measuring biocompatibility. These films were inserts in the back of rat and their biodegradability was investigated by the film weight and hematology as a function of time for the biotransformation. The result of rat test showed that medium, high viscosity chitosan induced some suspects of inbiocompatibility in the tissue by goreign body reaction 48 and 72 hours after implantation. Also, we prepared the official burn ointment which is made by low viscosity chitosan. This burn ointment was covered on the skin wound of artificial burn and their effect of healing was investigated by the evaluation of the naked eye and hematological change as a function of time. The result of rats test showed that burn ointments made from chitosan was effective reductio of inflammation than negative group.

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Decomposition of Thickener in Grease by Water Contamination (수분오염에 따른 그리스 내 증주제 분해 연구)

  • Lim, Young-Kwan;Ham, Song-Yee;Lee, Joung-Min;Jeong, Choong-Sub
    • Tribology and Lubricants
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    • v.28 no.1
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    • pp.33-37
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    • 2012
  • Automotive wheel bearing grease helps to reduce stresses and prevent wear of wheel bearings. But it is easily contaminated by water and other contaminants. Previously, our research group reported the change of grease physical properties such as dropping point, work penetration and oxidation work stability, water washout characteristics, leakage tendency, oil separation, evaporation loss and rust protection by water contamination. In this paper, we analyzed the physical characteristics of grease such as lubricity, viscosity and total acid number to investigate the mechanism of thickener decomposition. In water contaminated grease, the total acid number and wear scar were increased, the viscosity was decreased due to the decomposition of lithium complex thickener.

Ultrasonic Characterization of Fluid Mud: Effect of Temperature (부유퇴적물의 초음파 특징: 온도의 효과)

  • Kim, Gil-Young;Kim, Dae-Choul;Kim, Jeong-Chang
    • The Journal of the Acoustical Society of Korea
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    • v.23 no.4E
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    • pp.140-145
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    • 2004
  • A laboratory study was carried out to investigate the change of ultrasonic velocity as a function of temperature for fluid mud (i.e., suspension). Pulse transmission technique with ultrasonic wave was used for ultrasonic velocity measurement. The five samples for fluid mud were prepared for concentration range of $30.6{\%}\;(1.24\;g/cm^{3}\;in\;density),\;23.3{\%}\;(1.19\;g/cm^{3}),\;11.5{\%}(1.10\;g/cm^{3}),\;7.8{\%}\;(1.08\;g/cm^{3}),\;and\;3.8{\%}\;(1.05\;g/cm^{3})$ by weight. The ultrasonic velocity in fluid mud was investigated to increase $(approximately\;2.83\;to\;4.95\;m/s/^{\circ}C)$ with increasing temperature, due to the effect of viscosity and compressibility of water with changing temperature. But the increasing rate tends to decrease at temperature higher than $30^{\circ}C,$ caused by the effect of viscosity. The concentration of fluid mud more affect to the ultrasonic velocity at higher temperature range than that at lower temperature. Overall the temperature effect on the ultrasonic velocity in fluid mud was a similar rate as for distilled water and seawater, suggesting fluid mud significantly depends on the behavior of water.

A Study on the Synthesis and Properties of Water-Dispersion Polyurethane for Garment Coating Using Nonionic Polyol (비이온 폴리올을 이용한 Garment 코팅용 수분산 폴리우레탄의 합성 및 물성에 관한 연구)

  • Lee, Joo-Youb
    • Journal of the Korean Applied Science and Technology
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    • v.34 no.1
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    • pp.83-90
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    • 2017
  • The polyurethane resin used for the garment skin leather surface coating was synthesized by varying the content of polyethylene glycol (PEG) in [NCO] / [OH] mole % ratio. The mechanical properties of the synthesized polyurethane resin were analyzed by SEM, FT-IR, UTM. As the [NCO] / [OH] mole % ratio of nonionic poly ethylene glycol (PEG) increased, there was no change in flexural resistance (dry, wet) and abrasion resistance and tensile strength measurement value were lowered. In contrast, the elongation property values were increased. The result of viscosity measurement showed that the viscosity became thinner with increasing [NCO] / [OH] mole % of PEG.

Transport Properties of Ar-Kr Mixtures: A Molecular Dynamics Simulation Study

  • Min, Sun-Hong;Son, Chang-Mo;Lee, Song-Hi
    • Bulletin of the Korean Chemical Society
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    • v.28 no.10
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    • pp.1689-1696
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    • 2007
  • Equilibrium molecular dynamics (EMD) simulations are used to evaluate the transport coefficients of argonkrypton mixtures at two liquid states (state A: 94.4 K and 1 atm; state B: 135 K and 39.5 atm) via modified Green-Kubo formulas. The composition dependency of the volume at state A obeys close to the linear model for ideal liquid mixture, while that at state B differs from the linear model probably due to the high pressure. The radial distribution functions for the Ar-Kr mixture (x = 2/3) show a mixing effect: the first peak of g11 is higher than that of g(r) for pure Ar and the first peak of g22 is lower than that of g(r) for pure Kr. An exponential model of engineering correlation for diffusion coefficient (D) and shear viscosity (η) is superior to the simple linear model for ideal liquid mixtures. All three components of thermal conductivity (λpm, λtm, and λti) at state A and hence the total thermal conductivity decrease with the increase of x. At state B, the change in λtm is dominant over those in λpm and λti, and hence the total thermal conductivity decrease with the increase of x.