• 제목/요약/키워드: Vinylidene fluoride

검색결과 204건 처리시간 0.03초

PVDF 극소형 수중 청음기의 제작 및 특성 평가 (Design and Fabrication of PVDF Miniature Hydrophone and its Characteristic Evaluation)

  • 현병국;이기욱;하강열;김무준;배종림
    • 한국음향학회:학술대회논문집
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    • 한국음향학회 2000년도 하계학술발표대회 논문집 제19권 1호
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    • pp.381-384
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    • 2000
  • 초음파 음장의 상대적인 변화를 측정하는데 사용하기 위한 극소형 수중 청음기를 제작하고 그 특성을 평가하였다. 압전체로서는 PVDF(Poly Vinylidene Di Fluoride) 고분자막을 사용하였으며, 수신 특성을 향상시키기 위해 임피던스 변환회로를 부가하였다. 본 논문에서는 설계된 수중 청음기의 초음파 수신특성을 Mason 등가회로에 의해 이론적으로 평가한 결과 및 극소형 수중 청음기의 제작 방법, 그리고 제작한 청음기의 초음파 수신 특성에 대하여 보고한다.

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P(VDF/TrFE)의 새로운 전이에 대한 실험적 증거 (Experimental Evidence for the Existence of a New Transition of a VDF and TrFE Copolymer)

  • 김갑진;이종순;조항원
    • 한국섬유공학회:학술대회논문집
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    • 한국섬유공학회 2002년도 봄 학술발표회 논문집
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    • pp.105-109
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    • 2002
  • vinylidene fluoride(VDF)와 trifluoroethylene(TrFE)의 공중합체 인 P(VDF/TrFE)는 전기활성을 갖는 강유전성 결정이므로 압전성 및 초전성 재료로 PVDF와 더불어 널리 사용되고 있다. 그러나 P(VDF/TrFE)는 어떤 온도 이상에서는 all-trans conformation을 하는 강유전 결정상이 전기적으로 불활성으로 되면서 PVDP의 $\alpha$-결정의 사슬배좌(trans-gauche)와 유사한 상유전 결정상으로 전이하는 상승 Curie 전이 온도 (T$^{\uparrow}$ $_{c}$ )가 존재하기 때문에 P(VDF/TrFF)의 압전재료로서의 적용온도 범위가 넓지 못하다는 단점이 있다. (중략)

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탄소나노섬유/PVDF-HFP 복합재로 코팅된 부직포의 역학적 및 전기적 특성 변화 (Mechanical and Electrical Properties of Nonwoven Coated with CNFs/PVDF-HFP Composite)

  • 이선희
    • 한국의류산업학회지
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    • 제13권2호
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    • pp.279-284
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    • 2011
  • In this study, the process of preparation nonwoven with coated carbon nano fibers (CNFs) /poly(vinylidene fluoride-co-hexafluoropropylene) (PVDF-HFP) composite solution is described. The various contents of CNFs/PVDF-HFP composite coated nonwoven were prepared and characterized by morphological, mechanical, and electrical methods. Nonwovens are coated with CNFs/PVDF-HFP composite solution and decreased the pick up ratio with increasing CNFs contents in range from 0% to 16%. In the results of SEM images, it was clear that the CNFs were evenly distributed in coated nonwoven by SEM images, the existence of CNFs in coated nonwoven was confirmed regularly. The mechanical properties of various contents of CNFs/PVDF-HFP coated nonwoven were examined. The tensile linearity and compression linearity increased with increasing CNFs contents. The electrical properties of the CNFs/PVDF-HFP coated nonwoven increased with increasing CNFs contents.

자동차용 플라스틱 연료튜브의 복합 벤딩에 대한 스프링백 (Spring Back on the Compound Bending of the Plastic Fuel Tube for Automobile)

  • 문찬용;박정식;정영득
    • 동력기계공학회지
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    • 제7권2호
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    • pp.51-55
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    • 2003
  • Recently the requirements for light weight and high performance of the automobile have increased. Especially, the plastic fuel tube makers have made their efforts to dove]op the various plastic fuel tube module with not only dimensional accuracy but also cost competitiveness. The experiment is performed to investigate spring backs for PA12 plastic fuel tubes in case of compound bending. In the experiment, steam bending process is adopted as bending method. In this study, the results we obtained are used to design the bending fixtures and the compound bending system.

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ZnO-나노와이어/PVDF 복합체를 압전 활성층으로 한 나노발전기 소자 (Nanogenerator Device Based on Piezoelectric Active Layer of ZnO-Nanowires/PVDF Composite)

  • 임영택;신백균
    • 한국전기전자재료학회논문지
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    • 제27권11호
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    • pp.740-745
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    • 2014
  • ZnO nanowires were grown by hydrothermal synthesis process and piezoelectric poly vinylidene fluoride (PVDF) was then coated on top of the ZnO-nanowires by spray-coating technique. The composite layer of ZnO-nanowires/PVDF was applied to an energy harvesting device based on piezoelectric-conversion mechanism. A defined mechanical force was given to the nanogenerator device to evaluate their electric power generation characteristics, where output current density and voltage were examined. Electric power generation property of the ZnO-nanowires/PVDF based nanogenerator device was compared to that of the nanogenerator device with ZnO-nanowires as single active layer. Effect of the ZnO-nanowires on improvement of power generation was discussed to examine its feasibility for the nanogenerator device.

Carbon Nanotube의 첨가에 의한 PZT/PVDF 압전소자의 상전이와 출력 효율 개선 (Phase Transition and Improvement of Output Efficiency of the PZT/PVDF Piezoelectric Device by Adding Carbon Nanotubes)

  • 임영택;이선우
    • 한국전기전자재료학회논문지
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    • 제31권2호
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    • pp.94-97
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    • 2018
  • Lead zirconate titanate/poly-vinylidene fluoride (PZT/PVDF) piezoelectric devices were fabricated by incorporating carbon nanotubes (CNTs), for use as flexible energy harvesting devices. CNTs were added to maximize the formation of the ${\beta}$ phase of PVDF to enhance the piezoelectricity of the devices. The phase transition of PVDF induced by the addition of CNTs was confirmed by analyzing the X-ray diffraction patterns, scanning electron microscopy images, and atomic force microscopy images. The enhanced output efficiency of the PZT/PVDF piezoelectric devices was confirmed by measuring the output current and voltage of the fabricated devices. The maximum output current and voltage of the PZT/PVDF piezoelectric devices was 200 nA and 350 mV, respectively, upon incorporation of 0.06 wt% CNTs.

초미세기공을 지니는 탄소분자체의 수소저장거동 (Preparation and Characterization of Ultramicroporous Carbons for Hydrogen Storage)

  • 이슬이;박수진
    • 한국신재생에너지학회:학술대회논문집
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    • 한국신재생에너지학회 2011년도 춘계학술대회 초록집
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    • pp.158.1-158.1
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    • 2011
  • In this work, we prepared ultramicroporous carbons (UC) prepared by pyrolyzing poly(vinylidene fluoride) with different carbonization temperatures, and investigated the hydrogen storage behaviors. The surface functional groups and specific elements of UC were confirmed by Fourier-transform infrared spectroscopy (FT-IR) and X-ray photoelectron spectroscopy (XPS), respectively. Textural properties were analyzed using $N_2$ adsorption isotherms at 77 K. The hydrogen storage capacity of the UC samples were investigated by BEL-HP at 298 K/10 MPa. From the results, it was found that the hydrogen storage capacity was enhanced with increasing of specific surface area, resulting from the formation of ultramicropore on the UC.

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Polymer Films with Electrospray Deposition, model and experiment

  • Rietveld Ivo B.;Kobayashi Kei;Yamada Hirofumi;Matsushige Kazumi
    • 한국고분자학회:학술대회논문집
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    • 한국고분자학회 2006년도 IUPAC International Symposium on Advanced Polymers for Emerging Technologies
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    • pp.284-284
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    • 2006
  • Electrospray deposited films of poly(vinylidene fluoride) were prepared with various conditions. A model has been developed, which provides the state of the electrosprayed droplet at impact. With a combination of the experimental films and the model calculations, it can be shown that growth rate, the increase of the sprayed solution on the substrate per second, defines the film morphology in electrospray deposition. Growth rate indicates which factors play the main role in the film formation process. The most important factors are liquid flow, surface tension and shear rate. The model can calculate the shear rate and it is shown that PVDF, and most likely polymers in general, has a large range of growth rates, where the morphology only depends on the shear rate of the depositing droplet. This method can also be used to describe electrospray deposition of other compounds.

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Ionic Polymer-Metal Composite Actuator with Increased Air-Operating stability by Using Ionic Liquids

  • Lee, Jang-Yeol;Han, Man-Jae;Lee, Sung-Won;Park, Sun-Jin;Yoon, Bye-Ri;Jho, Jae-Young
    • 한국고분자학회:학술대회논문집
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    • 한국고분자학회 2006년도 IUPAC International Symposium on Advanced Polymers for Emerging Technologies
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    • pp.246-246
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    • 2006
  • Ionic polymer-metal composite (IPMC) soaked with various ionic liquids was prepared by using polystyrene sulfonic acid-grafted poly(vinylidene fluoride-co-hexafluoropropylene) as ion-exchange membrane (IEM). The prepared IPMCs were effectively deformed three times larger and actuated for 300 times longer than those of Nafion with water at the same applied conditions. The experimental results indicated than the increase in the bending capability can be caused by the increase in the improved properties of the IEMs and ionic liquids such as uptake content and ionic conductivity. And air-operating stability of the IPMCs is appreciably governed by various physical and electrochemical properties of soaked solvents in IEMs.

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Recent Development in Polymer Ferroelectric Field Effect Transistor Memory

  • Park, Youn-Jung;Jeong, Hee-June;Chang, Ji-Youn;Kang, Seok-Ju;Park, Cheol-Min
    • JSTS:Journal of Semiconductor Technology and Science
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    • 제8권1호
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    • pp.51-65
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    • 2008
  • The article presents the recent research development in polymer ferroelectric non-volatile memory. A brief overview is given of the history of ferroelectric memory and device architectures based on inorganic ferroelectric materials. Particular emphasis is made on device elements such as metal/ferroelectric/metal type capacitor, metal-ferroelectric-insulator-semiconductor (MFIS) and ferroelectric field effect transistor (FeFET) with ferroelectric poly(vinylidene fluoride) (PVDF) and its copolymers with trifluoroethylene (TrFE). In addition, various material and process issues for realization of polymer ferroelectric non-volatile memory are discussed, including the control of crystal polymorphs, film thickness, crystallization and crystal orientation and the unconventional patterning techniques.