• Bulletin of the Korean Chemical Society
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• v.32 no.2
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• pp.625-629
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• 2011

A quantitative analysis of the decreasing rate of the monomer and increasing rate of the polymerization was made by monitoring radiation level increments using Raman spectroscopy within the therapeutic radiation range for a normoxic polymethacrylic acid gel dosimeter. The gel dosimeter was synthesized by stirring materials such as gelatin, distilled water, methacrylic acid, hydroquinone and tetrakis phosphonium chloride at $50^{\circ}C$, and the synthesized gel was contained in a 10- mm diameter and 32-mm high vial to conduct measurement. 24 hours after gel synthesis, it was irradiated from 0 Gy to 20 Gy by 2 Gy using a Co-60 radiotherapy unit. With use of the Cryo FE-SEM, structural changes in the 0 Gy and 10 Gy gel dosimeters were investigated. The Raman spectra were acquired using 532-nm laser as the excitation source. In accordance with fitting the changes in C-COOH stretching (801 $cm^{-1}$), C=C stretching (1639 $cm^{-1}$) and vinyl $CH_2$ stretching (3114 $cm^{-1}$) vibrational modes for monomer and $CH_2$ bending vibrational mode (1451 $cm^{-1}$) for polymer, sensitive parameter S for each mode was calculated. The values of S for monomer bands and polymer band were ranged in $6.0{\pm}2.6$ Gy and $7.2{\pm}2.3$ Gy, respectively, which shows a relatively good conformity of the decreasing rate of monomer and the increasing rate of polymerization within the range of error.

• The Journal of the Acoustical Society of Korea
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• v.25 no.3
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• pp.121-128
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• 2006

Korean pyeongyeong, a set of sixteen L-shape chime stones covering one and one third octaves, is a standard instrument in the Korean traditional court music. We analyze the vibrational mode frequencies in a pyeongyeong replica which is played at the National Center for Korean Traditional Performance Arts and pyeongyeong remains which are exhibited at King Sejong Memorial Museum. The modal shapes on the Whangjong, the 1st stone and Cheonghyurjong, the 16th stone mapped by scanning accelerometer, TV holography and STAR system. The nominal frequencies in pyeongyeong replica at the National Center for Korean Traditional Performance Arts increase linearly with the thickness of the stones and the tones are tuned in line with the musical scale of Sambunsonik. The sexagenary cycles on the pyeongyeong remains at King Sejong Memorial. which show the Year of product indirectly, are different each other and the tones are not tuned in scale. The relative frequency ratios of each modes on stones differ more than just-noticeable differences from those on the pyeongyeong replica. Modal shapes are same for the two stones regardless of the thickness.

• Proceedings of the Korean Vacuum Society Conference
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• 2016.02a
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• pp.143.2-143.2
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• 2016

The influence of electric field on CO adsorbed on Pt(111) was investigated with reflection-absorption infrared spectroscopy (RAIRS) in ultrahigh vacuum system. The ice film capacitor method was used to apply electric field to the amorphous ice film with CO on Pt(111). Two systems were compared by measuring the change of the CO stretching vibrational mode under applied electric field; one is CO on Pt(111), and the other is CO buried inside an ice film on Pt(111). By comparing them, we were able to calculate the additional effect of adsorption of CO on Pt(111) on peak shift. The CO adsorbed on Pt(111) has shown larger peak shift than CO adsorbed with H2O when we applied stronger electric field. Additionally, the differences were observable when the applied electric field exceeds $1{\times}10V/m^8$.

• Structural Engineering and Mechanics
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• v.43 no.3
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• pp.395-410
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• 2012

The visualizing energy flow and control in vibrating stiffened plates with a cutout are studied using finite element method. The vibration intensity, vibration energy and strain energy distribution of stiffened plates with cutout at different excitation frequencies are calculated respectively and visualized for the various cases. The cases of different size and boundaries conditions of cutouts are also investigated. It is found that the cutout or opening completely changes the paths and distributions of the energy flow in stiffened plate. The magnitude of energy flow is significantly larger at the edges near the cutout boundary. The position of maximum strain energy distribution is not corresponding to the position of maximum vibrational energy. Furthermore, the energy-based control using constrained damping layer (CDL) for vibration suppression is also analyzed. According to the energy distribution maps, the CDL patches are applied to the locations that have higher energy distribution at the targeted mode of vibration. The energy-based CDL treatments have produced significant attenuation of the vibration energy and strain energy. The present energy visualization technique and energy-based CDL treatments can be extended to the vibration control of vehicles structures.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2002.05c
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• pp.97-102
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• 2002

Bolt-tightened Langevin type vibrators using longitudinal mode of bar were designed and fabricated. In order to amplify the displacement of the tip of the vibrators, stacked ceramics were used and five different shapes of the horns were designed and fabricated. Resonant frequencies and vibrational characteristics of vibrators and horns were analyzed by ANSYS(finite element analysis computer program), and the displacements of tips of the horns were measured. As results, when the number of the stacked ceramics were increased, the displacements of the tips were increased and the driving voltages were decreased. Step1 horn(BLT-Stl) showed maximum displacement of 36.92[${\mu}m$] at 36.7[kHz] with 45[Vrms] and 0.11[A]. The displacement amplification ratio was about 5.2. But, the stress of step1 horn was concentrated on intersection, where two diameters meet. To lessen the stress, step3 shaped horn is recommended.

• Bulletin of the Korean Chemical Society
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• v.30 no.4
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• pp.913-916
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• 2009

Femtosecond vibrational spectroscopy was used to probe the dynamics of CO rebinding to hemoglobin (Hb), denatured by 4.0 M GdnHCl in $D_2O# at 283 K, after photolysis of HbCO. The stretching mode of $^{13}CO$ bound to the denatured $Hb^{13}CO$ showed a single band centered at 1922 $cm^{-1}$, indistinguishable from that of denatured $Mb^{13}CO$. Geminate rebinding of CO to the denatured Hb was accelerated more than 1000 times, suggesting that the native structure of the Hb is required to suppress efficient geminate rebinding of CO, as is the case in Mb. The geminate yield and rate for CO rebinding are almost the same in both the denatured Hb and Mb. Similarity in the equilibrium spectrum and rebinding dynamics of CO indicates that the state of the denatured Hb is very similar to that of the denatured Mb. In the denatured Hb, quaternary contact of the protein is likely severed, with the denatured protein existing as an independent subunit much like Mb.

• Bulletin of the Korean Chemical Society
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• v.34 no.2
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• pp.465-469
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• 2013

Proton transfer reaction is one of the most fundamental processes in chemistry and life science. Excited state intramolecular proton transfer (ESIPT) has been studied as a model system of the proton transfer, since it can be conveniently initiated by light. We report ESIPT reaction dynamic of 1-hydroxy-anthraquione (1-HAQ) in solution by highly time-resolved fluorescence. ESIPT time of 1-HAQ is determined to be $45{\pm}10$ fs directly from decay of the reactant fluorescence and rise of the product fluorescence. High time resolution allows observation of the coherent vibrational wave packet motion in the excited state of the reaction product tautomer. The coherently excited vibrational mode involves large displacement of the atoms, which shortens the distance between the proton donor and the acceptor. With the theoretical analysis, we propose that the ESIPT of 1-HAQ proceeds barrierlessly with assistance of the skeletal vibration, which in turn becomes excited coherently by the ESIPT reaction.

• Journal of the Korean Chemical Society
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• v.50 no.2
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• pp.107-115
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• 2006

Complexes of Sn(II) with L1 = acac-o-phdnH2 [N,N'-o-phenylene bis(acetylacetoneimine)], L2 = acac-m-phdnH2 [N,N'-m-phenylene bis(acetylacetoneimine)] and L3 = acac-p-phdnH2 [N,N'-p-phenylene bis(acetylacetoneimine)] have been prepared and characterized by elemental analyses, vibrational, electronic spectra and thermal studies (TGA and DTA). Vibrational spectra indicated the coordination mode of imine and carbonyl oxygen for ligands giving (ONNO) that belong to C2V point group symmetry. The [Sn(L3)] complex has a maximum activation energy and [Sn(L2)] complex has a minimum activation energy.

• Advances in concrete construction
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• v.11 no.3
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• pp.255-260
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• 2021

Vibration of protein microtubules is investigated based upon Orthotropic Elastic Shell Model, considering the effect of thermal stresses. The complete analytical formulas of thermal vibration for microtubules are obtained. It is observed that the effects of thermal stresses on the vibrational frequency mode are more significant when the longitudinal and circumferential wave vectors are large enough. But when the length of wave vector reduces to 5 nm, these effects have no significant effects. The present results well agree with the lattice vibrations of microtubules. Moreover, the results show that the effects of thermal stresses due to small change in temperature are not so significant but with the increase in temperature its effects are obvious.

• Structural Engineering and Mechanics
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• v.84 no.1
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• pp.77-83
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• 2022

In the last ten years, many researchers have studied the vibrations of carbon nanotubes using different beam theories. The nano- and micro-scale systems have wavy shape and there is a demand for a powerful tool to mathematically model waviness of those systems. In accordance with the above mentioned lack for the modeling of the waviness of the curved tiny structure, a novel approach is employed by implementing the Timoshenko-beam model. Owing to the small size of the micro beam, these structures are very appropriate for designing small instruments. The vibrations of double walled carbon nanotubes (DWCNTs) are developed using the Timoshenko-beam model in conjunction with the wave propagation approach under support conditions to calculate the fundamental frequencies of DWCNTs. The frequency influence is observed with different parameters. Vibrations of the double walled carbon nanotubes are investigated in order to find their vibrational modes with frequencies. The aspect ratios and half axial wave mode with small length are investigated. It is calculated that these frequencies and ratios are dependent upon the length scale and aspect ratio.