• Wind and Structures
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• 제5권1호
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• pp.61-80
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• 2002

Wind tunnel aeroelastic model tests of the Commonwealth Advisory Aeronautical Research Council (CAARC) standard tall building were conducted using a three-degree-of-freedom base hinged aeroelastic(BHA) model. Experimental investigation into the effects of coupled translational-torsional motion, cross-wind/torsional frequency ratio and eccentricity between centre of mass and centre of stiffness on the wind-induced response characteristics and wind excitation mechanisms was carried out. The wind tunnel test results highlight the significant effects of coupled translational-torsional motion, and eccentricity between centre of mass and centre of stiffness, on both the normalised along-wind and cross-wind acceleration responses for reduced wind velocities ranging from 4 to 20. Coupled translational-torsional motion and eccentricity between centre of mass and centre of stiffness also have significant impacts on the amplitude-dependent effect caused by the vortex resonant process, and the transfer of vibrational energy between the along-wind and cross-wind directions. These resulted in either an increase or decrease of each response component, in particular at reduced wind velocities close to a critical value of 10. In addition, the contribution of vibrational energy from the torsional motion to the cross-wind response of the building model can be greatly amplified by the effect of resonance between the vortex shedding frequency and the torsional natural frequency of the building model.

• Journal of Advanced Marine Engineering and Technology
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• 제35권6호
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• pp.861-866
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• 2011

본 논문에서는 파도의 상하운동에 의해 발전되는 형발전시스템과 진동발전시스템이 결합된 하이브리드 발전방법을 제안한다. 선형발전시스템은 권선과 영구자석으로 구성되어있고, 파도의 상하운동속도를 직접적으로 사용하므로 파도의 주파수에 관계없이 안정적인 발전을 한다. 그리고 진동발전시스템은 진동시스템인 영구자석, 스프링과 발전시스템인 영구자석, 권선으로 구성되어 있다. 진동발전시스템은 파도의 주파수와 진동시스템의 고유진동수를 일치시킨 공진대역에서 구동함으로써 파도의 상하운동 속도보다 더 큰 속도를 이용하여 더 많은 전기에너지를 얻을 수 있다. 따라서 본 연구에서 제안한 하이브리드 파력발전방법은 공진영역에서 더 많은 전기에너지를 얻을 수 있을 뿐만 아니라 공진영역을 벗어난 대역에서도 안정적으로 발전할 수 있는 장점을 가짐을 알 수 있다.

• 한국소음진동공학회논문집
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• 제18권10호
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• pp.1082-1090
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• 2008

In this paper, a general solution for the vibrational energy and intensity distribution through a compliant and dissipative joint between plate structures is derived on the basis of energy flow analysis (EFA). The joints are modeled by four sets of springs and dashpots to show their compliancy and dissipation in all four degrees of freedom. First, for the EFA, the power transmission and reflection coefficients for the joint on coupled plate structures connected at arbitrary angles were derived by the wave transmission approach. In numerical applications, EFA is performed using the derived coefficients for coupled plate structures under various joint properties, excitation frequencies, coupling angles, and internal loss factors. Numerical results of the vibrational energy distribution showed that the developed compliant and dissipative joint model successfully predicted the joint characteristics of practical structures vibrating in the medium-to-high frequency ranges. Moreover, the intensity distribution of a compliant and dissipative joint is described.

• Bulletin of the Korean Chemical Society
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• 제27권7호
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• pp.1048-1052
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• 2006

Ab initio calculations of the structure, atomic charges and natural bond orbital (NBO) have been performed at HF/6-311G** and B3LYP/6-311G** levels for the title compound of dibenzothiazyl-disulfide. The calculated results show that the two nitrogen atoms have the biggest negative charges and they are the potential sites to react with the metallic ions, which make the title compound become a di-dentate ligand. Vibrational frequencies of the title compound have been obtained and compared with the experimental value and the comparison indicates that B3LYP/6-311G** level is better than HF/6-311G** level to predict the vibrational frequencies for the system studied here. For the title compound, electronic absorption spectra calculated by time?ependent density functional theory (TD-DFT) are more accurate than Hartree-Focksingle-excitation CI (CI-Singles) method. NBO analyses show that the electronic transitions are mainly derived from the contribution of bands $\pi\rightarrow\pi^{*}$. Thermodynamic calculated results show that the formation of the title compound from 2-mercaptobenzothiazole is a spontaneous process at room temperature with the change of free Gibbs being negative value.

• Bulletin of the Korean Chemical Society
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• 제31권7호
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• pp.1875-1880
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• 2010

A dicycle pyrazoline derivative, 1-phenyl-5-(p-fluorophenyl)-3,4-($\alpha$-p-fluoro-tolylenecyclohexano) pyrazoline, was synthesized and characterized by elemental analysis, IR, UV-vis, fluorescence spectra and X-ray single crystal diffraction. Density function theory (DFT) calculations were performed by using B3LYP method with 6-$311G^{**}$ basis set. The optimized geometry can well simulate the molecular structure. Vibrational frequencies were predicted, assigned and compared with the experimental values, which suggest that B3LYP/6-$311G^{**}$ method can well predict the IR spectra. Both the experimental electronic absorption spectra and the predicted ones by B3LYP/6-$311G^{**}$ method reveal three electron-transition bands, with the theoretical ones having some red shifts compared with the experimental data. Natural bond orbital analyses indicate that the absorption bands are mainly derived from the contribution of n $\rightarrow\pi^*$ and $\pi\rightarrow\pi^*$ transitions. Fluorescence spectra determination shows that the title compound can emit blue-light at about 478 nm. On the basis of vibrational analysis, the thermodynamic properties of title compound at different temperature have been calculated, revealing the correlations between $C^0_{p,m}$, $S^0_m$, $H^0_m$ and temperature.

• Bulletin of the Korean Chemical Society
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• 제35권9호
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• pp.2774-2780
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• 2014

A dynamics study of relaxation and fragmentation of icosahedral argon cluster with a vibrationally excited $Ar_2^+$ (${\nu}$) is presented. Local translation is shown to be responsible for inducing energy flow from the embedded ion to host atoms and fragmentation of the cluster consisting of various low frequency modes. The total potential energy of $(Ar_2^+)Ar_{12}$ is formulated using a building-up procedure of host-guest and host-host interactions. The time dependence of ion-to-host energy transfer is found to be tri-exponential, with the short-time process of ~100 ps contributing most to the overall relaxation process. Relaxation timescales are weakly dependent on both temperature (50-300 K) and initial vibrational excitation (${\nu}$ = 1-4). Nearly 27% of host atoms in the cluster with $Ar_2^+$ (${\nu}$ = 1) fragment immediately after energy flow, the extent increasing to ~43% for ${\nu}$ = 4. The distribution of fragmentation products of $(Ar_2^+)Ar_{12}{\rightarrow}(Ar_2^+)Ar_n+(12-n)Ar$ are peaked around $(Ar_2^+)Ar_8$. The distribution of dissociation times reveals fragmentation from one hemisphere dominates that from the other. This effect is attributed to the initial fragmentation causing a sequential perturbation of adjacent atoms on the same icosahedral five-atom layer.

• Bulletin of the Korean Chemical Society
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• 제31권12호
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• pp.3553-3560
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• 2010

A new hydrazone derivative compound has been synthesized and characterized by IR, $^1H$-NMR, $^{13}C$-NMR and UV-vis. spectroscopy techniques, elemental analysis and single-crystal X-ray diffraction (XRD). The new compound crystallizes in monoclinic space group C2/c. In addition to the crystal structure from X-ray experiment, the molecular geometry, vibrational frequencies and frontier molecular orbitals analysis of the title compound in the ground state have been calculated by using the HF/6-31G(d, p), B3LYP/6-311G(d, p) and B3LYP/6-31G(d, p) methods. The computed vibrational frequencies are used to determine the types of molecular motions associated with each of the observed experimental bands. To determine conformational flexibility, molecular energy profile of (1) was obtained by semi-empirical (AM1) calculation with respect to a selected degree of torsional freedom, which was varied from $-180^{\circ}$ to $+180^{\circ}$ in steps of $10^{\circ}$. Molecular electrostatic potential of the compound was also performed by the theoretical method.

• 한국정보디스플레이학회:학술대회논문집
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• 한국정보디스플레이학회 2006년도 6th International Meeting on Information Display
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• pp.611-614
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• 2006

Sum-frequency vibrational spectroscopy (SFVS) has been used to study the molecular orientations at the polymer surfaces for liquid crystal alignment. Various molecular orientations appear at the surface depending on various types of surface treatments and polymers.

• 과학과기술
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• 제8권12호통권79호
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• pp.61-64
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• 1975

An expression for the vibrational frequency of diatomic molecular is obtained by using molecular gas temperature T and molecular gas mean-free path λ. And when λ/T →2.59, beca use of the damped vibration, a diatomic molecular gas is Impeded about transportation. If transfortation is not attained with this condition, rectilinear motion of a diatomic molecular gas can't maintain for the equilibrium state.

• 한국정밀공학회:학술대회논문집
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• 한국정밀공학회 2010년도 추계학술대회 논문집
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• pp.767-768
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• 2010