• Bulletin of the Korean Chemical Society
• /
• 제15권11호
• /
• pp.933-939
• /
• 1994

Using an atom superposition and electron delocalization molecular orbital (ASED-MO) method, we have investigated the vibrational and chemisorptive properties of adsorbates on a Pt(100) surface during CO oxidation. The calculated vibrational stretching frequency for a predicted structure of $[CO{\cdot}{\cdot}{\cdot}O]^*$ complex is 1642 $cm^{-1}$. The CO bond stretches by 0.05 ${\AA}$ when adsorbed on one-fold site, and is tilted by 30 ${\AA}$ from the surface normal. We find the decrease in CO vibrational frequency on going from the one-fold to the high coordination sites. Binding at the two-fold site is predicted to be favored for $Pt_{18}(100)$ and at the 1-fold site for $Pt_{23}(100)$. From the calculations of the steric interactions, we have found that pre-adsorbed oxygen modifies the surface so that CO is adsorbed on the one-fold site ordered in a $(\sqrt{2}{\times}{\sqrt}{2})R45^{\circ}$. Our results are in good agreement with recent experimental findings of Hong et al. [J.Phys. Chem. 1993, 97, 1258].

• 한국철도학회:학술대회논문집
• /
• 한국철도학회 1999년도 추계학술대회 논문집
• /
• pp.558-565
• /
• 1999

Rubber wheel-type AGT has two major kinds of bogie; one is the bogie type and the other and passenger loads. This paper deals with the statics analysis for two types of bogie frame subjected to combined external forces, as well as independent ones specified in UIC 515-4. Furthermore, the dynamics analysis is performed under vibrational loading conditions so as to compare dynamic characteristics, Numerical results by using commercial packages, Ⅰ-DEAS and NASTRAN show that maximum stresses do not exceed the yielding level of material used for both bogies. From an overall viewpoint of strength, the bogie type turns out to be superior to the steering type except the case of a lateral loading. It is also observed that the steering type shows a be stiffened. It is strongly anticipated that vibrational fatigue analysis should be carried out under realistic loading conditions closely matching to situations such as running surface and lateral clearances along the guideway.

• 대한화학회지
• /
• 제52권3호
• /
• pp.322-327
• /
• 2008

HOOCl-H2O cluster에 대하여 안정한 구조와 결합에너지를 MP2/6-311G(d,p), MP2/6-311G(2d,2p)의 방법으로 계산하였고 vibrational frequency계산을 하여 HOOCl의 vibrational frequency와 비교하였다. Skew HOOCl-H2O cluster가 가장 안정한 cluster로 나타났고 결합에너지는 46~48 kJ/mol 정도이며 trans HOOCl-H2O cluster의 경우도 이보다 불안정하나 비교적 큰 결합에너지를 갖는 것으로 나타났다.

• Advances in aircraft and spacecraft science
• /
• 제3권3호
• /
• pp.317-330
• /
• 2016

Nowadays, the interest of aerospace and automotive industries on virtual testing of medium-frequency vibrational behavior of shallow shell structures is growing. The development of software capable of predicting the vibrational response in such frequency range is still an open question because classical methods (i.e., FEM, SEA) are not fully suitable for the medium-frequency bandwidth. In this context the Variational Theory of Complex Rays (VTCR) is taking place as an ad-hoc technique to address medium-frequency problems. It is a Trefftz method based on a weak variational formulation. It allows great flexibility because any shape function that satisfies the governing equations can be used. This work further develops such theory. In particular, orthotropic materials are introduced in the VTCR formulation for shallow shell structures. A significant numerical example is proposed to show the strategy.

• Journal of the Korean Wood Science and Technology
• /
• 제26권3호
• /
• pp.16-25
• /
• 1998

This study was carried out to compare vibrational properties and adsorption among shellac, cashew finished plate and untreated plate of Sitka spruce(Picea sitchensis Carr). By the method of statistical regression modeling, the fundamental resonance frequency of finished plate was higher than that of untreated plate. The fundamental resonance frequency of cashew finished plate was higher than that of shellac finished plate. By the method of modal analysis, mode frequency ratio of cashew finished plate was higher than that of shellac finished plate. Amounts of adsorption of finished plate was lower than that of untreated plate, and amount of adsorption of cashew finished plate was lower than that of shellac finished plate. It was clarified that the vibrational properties and adsorption of finished plate were superior to those of untreated plate. The vibrational properties and adsorption of cashew finished plate was superior to those of shellac finished plate.

• 소음진동
• /
• 제9권3호
• /
• pp.517-524
• /
• 1999

Mathematical formulas for multi-dimensional isolation analysis via vibrational power transmission can be derived in a rather simple form when the wave effects of the isolators are completely neglected. With increase of frequency range of interest, however, the wave effects play a very important role and hence cannot be neglected. The formulas get involved accordingly. In this study, a method of equivalent stiffness modeling of the isolators to include the wave effects is proposed in such a way that not only the complexity of the mathematical expressions but also that of experiments of necessity can be reduced. This method is illustratively applied to a two-dimensional vibration isolation system with nonrigid source and base structures.

• 한국소음진동공학회:학술대회논문집
• /
• 한국소음진동공학회 1997년도 춘계학술대회논문집; 경주코오롱호텔; 22-23 May 1997
• /
• pp.229-234
• /
• 1997

The dynamic behavior of underground structures is complex due to the effects of vibrational characteristics of the structure and the rock. In this study, dynamic displacement responses at the structure surface by the elastic stress waves are considered as the vibrational characteristics, and evaluated by the form of the frequency spectrum. The variation of the vibrational characteristic is simulated by numerical analysis at the case of the structure has internal defections. The results reveals the possibility of the experimental detection of void existence and size. Furthermore, the verification of the dynamic response can be used for rating the stability of a tunnel.

• 한국소음진동공학회:학술대회논문집
• /
• 한국소음진동공학회 2001년도 춘계학술대회논문집
• /
• pp.194-201
• /
• 2001

The dynamic characteristic of the building using preflex composite beams is a low natural frequency due to long span. Therefore, both vibrational acceleration and the characteristic of natural frequency damage to people using the building, This study estimates a vibrational acceleration based on walking and natural frequency in five kinds of building. Recently, using methods of evaluating a serviceability are based on JIA, AISC, Eurocode, CSA, DIN and ISO. ed. The result of this study is content with foreign regulations and serviceability. However, considering of these results, the method of evaluating serviceability should be developed in the future.

• Bulletin of the Korean Chemical Society
• /
• 제31권12호
• /
• pp.3771-3776
• /
• 2010

The dynamics of the $CN^-$-ligated ferric cytochrome c (CytcCN) in $D_2O$ at 283 K following Q-band photoexcitation at 575 nm was observed using femtosecond time-resolved vibrational spectroscopy. The equilibrium vibrational spectrum of the CN stretching mode of CytcCN shows two overlapping bands: one main band (82%) at $2122\;cm^{-1}$ with $23\;cm^{-1}$ full width at half maximum (fwhm) and the other band (18%) at $2116\;cm^{-1}$ with $7\;cm^{-1}$ fwhm. The time-resolved spectra show bleaching of the CN fundamental mode of CytcCN and two absorption features at lower energies. The bleach signal and both absorption features are all formed within the time resolution of the experiment (< 200 fs) and decay with a life time of 1.9 ps. One transient absorption feature, appearing immediately red to the bleach signal, results from the thermal excitation of low-frequency modes of the heme that anharmonically couple to the CN fundamental mode, thereby shifting the CN mode to lower energies. The shift of the CN mode decays with a lifetime of 2 ps, equivalent to the time scale for vibrational cooling of the low-frequency heme modes. The other transient absorption feature, which is 3.3 times weaker than the bleach signal and shifted $27\;cm^{-1}$ toward lower energies, is attributed to the CN mode in an electronically excited state where the CN bond is weakened with a lowered extinction coefficient. These observations suggest that photoexcited CytcCN mainly undergoes ultrafast radiationless relaxation, causing photo-deligation of $CN^-$ from CytcCN highly inefficient. As also observed in $CN^-$-ligated myoglobin, inefficient ligand photodissociation might be a general property of $CN^-$-ligated ferric hemes.

• 한국음향학회지
• /
• 제18권7호
• /
• pp.39-44
• /
• 1999

직사각형 평판의 고유진동수와 진동모드를 연구하였다. 이중 퓨리에 사인시리즈를 직사각형 평판의 모달 변위함수로 사용하였으며, 다양한 경계조건을 가지는 자유진동 해석에 적용하였다. 유한급수 전개로써 근사해를 나타내는 고전적인 Ritz 방법을 이용해서 직사각형 평판의 고유진동수를 해석한 Leissa의 결과와 본 연구의 결과를 비교하였다. 그리고, 평판의 형상비에 따른 영향도 연구하였다. 자유경계 평판, 외팔평판, 고정평판, 그리고 모서리가 단순지지된 직사각형 평판의 진동형태를 가시화 하였다.