• Title/Summary/Keyword: Various starting materials

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Aging Characteristics of Al P/M Composites with Variation of Ceramic Contents

  • Min, Kyung-Ho;Chang, Si-Young;Kim, Deok-Soo;Kim, Ji-Soon;Kim, Young-Do
    • Proceedings of the Korean Powder Metallurgy Institute Conference
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    • 2006.09b
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    • pp.1065-1066
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    • 2006
  • The aging behavior of sintered Al composites with various ceramic contents was investigated. 2xxx series blended powder was used as the starting powder. Ceramic contents were 0wt.% and 5wt.%. The blended powders were compacted at 250MPa. The sintering process was performed at $620^{\circ}C$ for 60min in a $N_2$ atmosphere. Each part was solution-treated at $518^{\circ}C$ for 60min and aged at $180^{\circ}C$. The Rockwell hardness at the peak aging time increased with ceramic contents. However, the peak aging time at maximum hardness was reduced with increased ceramic contents.

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IRRADIATION EFFECTS OF HT-9 MARTENSITIC STEEL

  • Chen, Yiren
    • Nuclear Engineering and Technology
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    • v.45 no.3
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    • pp.311-322
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    • 2013
  • High-Cr martensitic steel HT-9 is one of the candidate materials for advanced nuclear energy systems. Thanks to its excellent thermal conductivity and irradiation resistance, ferritic/martensitic steels such as HT-9 are considered for in-core applications of advanced nuclear reactors. The harsh neutron irradiation environments at the reactor core region pose a unique challenge for structural and cladding materials. Microstructural and microchemical changes resulting from displacement damage are anticipated for structural materials after prolonged neutron exposure. Consequently, various irradiation effects on the service performance of in-core materials need to be understood. In this work, the fundamentals of radiation damage and irradiation effects of the HT-9 martensitic steel are reviewed. The objective of this paper is to provide a background introduction of displacement damage, microstructural evolution, and subsequent effects on mechanical properties of the HT-9 martensitic steel under neutron irradiations. Mechanical test results of the irradiated HT-9 steel obtained from previous fast reactor and fusion programs are summarized along with the information of irradiated microstructure. This review can serve as a starting point for additional investigations on the in-core applications of ferritic/martensitic steels in advanced nuclear reactors.

Preparation of PZT Powders by Hydrothermal Synthesis : Effects of Starting Materials and the Agitation of Substrate on Powder Characteristics (수열합성법에 의한 PZT 분말제조 : 출발물질과 기질의 교반이 분말특성에 미치는 영향)

  • Jung, S.T.;Lee, K.J.;Seo, K.W.
    • Applied Chemistry for Engineering
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    • v.8 no.2
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    • pp.292-300
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    • 1997
  • In this study PZT powders were prepared with shapes of cubic by hydrothermal synthesis with various starting materials, and the sintering characteristics of the powders were investigated. The particle shapes were cubic regardless of starting materials, but the mean size of particles formed using $Pb(NO_3)_2$, $Ti(OC_4H_9)_4$ and $Zr(OC_4H_9)_4$ was relatively smaller than that of particles prepared from other starting materials. Agitation of the feedstock during hydrothermal reaction results in decreasing the required reaction temperature for the formation of nuclei, and in increasing the size of product particles. XRD results showed that the major phase of PZT crystal powders was a tetragonal phase at the Zr to Ti ratio of 40 to 60, or a rhombohedral phase at its ratio of 60 to 40. The density of a sintered body made from the hydrothermal powders in PbO surrounding varied with sintering temperatures and with periods of sintering time. The experimental results also showed that the optimum sintering condition was at $1150^{\circ}C$ for a 2hr sintering, and that the density of a sintered body was $7.6g/cm^3$.

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Preparation and Properties of Hyperbranched Polymers

  • Kakimoto, Masa-Aki
    • Proceedings of the Polymer Society of Korea Conference
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    • 2006.10a
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    • pp.97-98
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    • 2006
  • After general introduction for hyperbranched polymers, hyperbranched polysiloxysilanes (HBPS) were introduced as new functional polymers. Vinyl terminated HBPS was synthesized starting from AB2 type monomer by hydrosilylation reaction. Vinyl group can be converted various functional groups such as carboxylic acid and alcohol. HBPS had strong interaction to inorganic surface. As an example of this phenomenon, silica gel bead for HPLC was modified with thermo sensitive polymers. The resulting bead was successfully applied to Green Chronatography.

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Preparation of the Mullite Fiber from Alkoxide by Sol-Gel Process (알콕사이드로부터 졸겔법에 의한 물라이트 섬유의 제조)

  • 김구대;정형진;이해욱
    • Journal of the Korean Ceramic Society
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    • v.28 no.2
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    • pp.153-159
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    • 1991
  • Polymeric alumina sol and polymeric silica sol were synthesized from aluminum sec-butoxide and tetraethyl orthosilicate, respectively as starting materials. A clear mullite sol was obtained by mixing these sols. When the mullite sol had a proper viscosity which was dependent on drying time, the fibers were fabricated by spinning. The optimum viscosity for fabrication of mullite fibers was 103-104 cps, and the fibers with various sizeswere made using the sols. The mullite was a major phase of the calcined fibers and the diameters of the fibers were about 50$\mu\textrm{m}$.

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Preparation of Polycrystalline Mullite Fiber Using the Sol-Gel Technique (졸-겔법에 의한 다결정 물라이트 섬유의 제조)

  • 김경용;김윤호;이수원;정형진;김구대
    • Journal of the Korean Ceramic Society
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    • v.26 no.6
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    • pp.795-801
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    • 1989
  • The polycrystalline mullite fiber was synthesized from various combination of starting materials including metal alkoxides and colloidal sol by the sol-gel process. The best spinnability was observed in the sol which showed shear thinning and hysteresis (i.e., thixotropic flow), indicating that the network structure was broken down as the shear rate increased. The mullite fiber was polycrystalline after firing and characterized by thermal analysis, XRD, FT-IR spectroscopy, rheological measurements, and SEM.

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NEW POLYIMIDES: SYNTHESIS, PROPERTIES AND POTENTIAL APPLICATION

  • Kravtsova, V.D.;Zhubanov, B.A.;Bekmagambetova, K.H.
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1998.06a
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    • pp.481-483
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    • 1998
  • The problem of production of new materials based on polyheteroarylenes and other polymers combining good mechanical and dielectric properties. radiation and chemical stability with heat- and thermal stability is related with the development of efficient synthesis technique of starting low-molecular compounds. Alicyclic dianhydrides are believed to be the promising monomers to synthesize various polymers.

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Preparation of PZT Fibers Using Triethanolamine Complexed Sol (Triethanolamine 착체졸을 이용한 PZT 섬유의 제조)

  • 박용일;이해욱;최용수;이종혁;김승현;김창은
    • Journal of the Korean Ceramic Society
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    • v.33 no.7
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    • pp.755-760
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    • 1996
  • Sol-gel processing was used to prepare PZT fibers. Titanium isopropoxide Zirconium n-butoxide and lead acetate trihydrate were used as starting materials and TEA(triethanolamine) was added to form stabilized Pb-Ti-Zr complex alkoxide, Effects of catalysts and various solvents on the state of precursor sol gelation reaction fiber spinnability pyrolysis and crystallization were also investiated.

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Crevice Corrosion Study of Materials for Propulsion Applications in the Marine Environment

  • Deflorian, F.;Rossi, S.;Fedel, M.;Zanella, C.;Ambrosi, D.;Hlede, E.
    • Corrosion Science and Technology
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    • v.14 no.6
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    • pp.288-295
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    • 2015
  • The present work addresses crevice and galvanic corrosion processes occurring at the cylinder head gasket/cylinder head interface and cylinder head gasket/cylinder liner interface of four-stroke medium-speed diesel engines for marine applications. The contact between these systems and the marine environment can promote formation of demanding corrosion conditions, therefore influencing the lifetime of the engine components. The electrochemical behavior of various metals and alloys used as head gasket materials (both ferrous alloys and copper alloys) was investigated. The efficacy of corrosion inhibitors was determined by comparing electrochemical behavior with and without inhibitors. In particular, crevice corrosion has been investigated by electrochemical tests using an experimental set-up developed starting from the requirements of the ASTM G-192-08, with adaptation of the test to the conditions peculiar to this application. In addition to the crevice corrosion resistance, the possible problems of galvanic coupling, as well as corrosive reactivity, were evaluated using electrochemical tests, such as potentiodynamic measurements. It was possible to quantify, in several cases, the corrosion resistance of the various coupled materials, and in particular the resistance to crevice corrosion, providing a basis for the selection of materials for this specific application.

Development and Application of Teaching and Learning Materials for Gifted Students in Elementary School (초등수학영재를 위한 교수학습 자료 개발 및 적용)

  • Kim, Sung Joon
    • East Asian mathematical journal
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    • v.37 no.4
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    • pp.443-460
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    • 2021
  • This study analyzes the characteristics of elementary math gifted classes through the development and application of teaching and learning materials. We used the guided reinvention methods including quasi-experiential perspectives. To this end, the applicability of Lakatos' quasi-empirical mathematical philosophy in elementary mathematics was examined, and the criteria for the development of teaching and learning materials for gifted students were presented, and then this study was conducted in this theoretical background. The subjects of the study were 21 elementary students at P University's Institute of Science and Gifted Education, and non-face-to-face real-time classes were conducted. Classes were divided into introduction, deployment1, deployment2, organization stages, and in each stage, small group cooperative learning was conducted based on group activities, and in this process, the characteristics of elementary mathematics gifted were analyzed. As a result of the study, elementary mathematics gifted students did not clearly present the essence of justification in the addition algorithm of fractions, but presented various interpretations of 'wrong' mathematics. They also showed their ingenuity in the process of spontaneously developing 'wrong' mathematics. On the other hand, by taking interest in new mathematics starting from 'wrong' mathematics, negative perceptions about it could be improved positively. It is expected that the development of teaching and learning materials dealing with various and original topics for the gifted students in elementary school will proceed through follow-up research.