• Bulletin of the Korean Chemical Society
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• v.28 no.6
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• pp.1031-1034
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• 2007

The R- and Z-substituent effects for the gas-phase thermal decompositions of carbamates, R2NC(=O)- OCH2CH2Z, have been investigated theoretically at B3LYP level with 6-31G(d) and 6-31++G(d,p) basis sets. Both the Z- and R-substituent effects on reactivity (ΔH≠) were well consistent with experimental results, although the R-substituent effect was underestimated theoretically. No correlations were found between activation enthalpies and reaction enthalpies. The substituent effects on reactivity seemed to be complicated at a glance, but were understandable by concurrent electronic and steric factors. Variations of bond lengths at TS structures were well correlated with the Taft's σ* values and the TS structures became tighter as the Zsubstituent became a stronger electron-acceptor (δσ* > 0). However the effects of R-substituents on the TS structures were much smaller when compared to those of Z-substituents.

• Journal of the Korean Society for Advanced Composite Structures
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• v.5 no.3
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• pp.8-16
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• 2014

Torque control method and turn of nut method are specified as clamping method of high strength bolts in the steel construction specifications. Quality control of torque coefficient is essential activity because torque control method, which is presently adopted as clamping method in domestic construction sites, is affected by variation of torque coefficient. The clamping of torque shear bolt is based on KS B 2819. It was misunderstood that the tension force of the TS bolt was induced generally at the break of pin-tail specified. However, the clamping forces on slip critical connections do not often meet the intended tension, as it considerably varies due to torque coefficient dependent on the environmental factors and temperature variables despite the break of the pin tail.This study was focused to evaluate the effect of environmental factors and errors of installing bolts during tightening high strength bolts. The environmental parameters were composed of 'wet' condition, 'rust' condition, 'only exposure to air' condition. And the manufacture of trial product was planned to identify the induced force into the bolts. The algorithm for a trial product was composed of the relation between electricity energy taken from torque shear wrench and tension force from hydraulic tension meter.

• Journal of Advanced Marine Engineering and Technology
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• v.40 no.9
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• pp.774-779
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• 2016

This study was performed to study the possibility of TMCP's application for side shell plating curved structures through mechanical property testing to understand if the rules and regulations of DNV and the quality standard of IACS after line heating for TMCP steel and normalizing DH32 material steel could be satisfied. Experimental results showed that TMCP's strength was measured to YS = 385 MPa, 18% higher than the required 315 MPa and TS = 525 MPa, complying with the required range of between 440 and 570 MPa. The minus 20 degree impact test for the Charpy V-Notch complied with the required standard and in addition the hardness test satisfied the requirement of 'Hv10 = 130 ~ 320' by reaching an average of T : 216 and L : 275 respectively.