• Bulletin of the Korean Chemical Society
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• 제28권6호
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• pp.1031-1034
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• 2007

The R- and Z-substituent effects for the gas-phase thermal decompositions of carbamates, R2NC(=O)- OCH2CH2Z, have been investigated theoretically at B3LYP level with 6-31G(d) and 6-31++G(d,p) basis sets. Both the Z- and R-substituent effects on reactivity (ΔH≠) were well consistent with experimental results, although the R-substituent effect was underestimated theoretically. No correlations were found between activation enthalpies and reaction enthalpies. The substituent effects on reactivity seemed to be complicated at a glance, but were understandable by concurrent electronic and steric factors. Variations of bond lengths at TS structures were well correlated with the Taft's σ* values and the TS structures became tighter as the Zsubstituent became a stronger electron-acceptor (δσ* > 0). However the effects of R-substituents on the TS structures were much smaller when compared to those of Z-substituents.

• 복합신소재구조학회 논문집
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• 제5권3호
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• pp.8-16
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• 2014

Torque control method and turn of nut method are specified as clamping method of high strength bolts in the steel construction specifications. Quality control of torque coefficient is essential activity because torque control method, which is presently adopted as clamping method in domestic construction sites, is affected by variation of torque coefficient. The clamping of torque shear bolt is based on KS B 2819. It was misunderstood that the tension force of the TS bolt was induced generally at the break of pin-tail specified. However, the clamping forces on slip critical connections do not often meet the intended tension, as it considerably varies due to torque coefficient dependent on the environmental factors and temperature variables despite the break of the pin tail.This study was focused to evaluate the effect of environmental factors and errors of installing bolts during tightening high strength bolts. The environmental parameters were composed of 'wet' condition, 'rust' condition, 'only exposure to air' condition. And the manufacture of trial product was planned to identify the induced force into the bolts. The algorithm for a trial product was composed of the relation between electricity energy taken from torque shear wrench and tension force from hydraulic tension meter.

• Journal of Advanced Marine Engineering and Technology
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• 제40권9호
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• pp.774-779
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• 2016

본 연구에서는 선박의 곡 외판 구조에 TMCP 강재의 사용 범위 확대 가능성을 연구하고자 노말라이징강 및 TMCP 강 DH32 재질 강재에 선상가열 후 기계적 물성 시험을 실시하여 DNV 선급 및 IACS 규정의 품질 요구 기준에 적합한지 연구하였다. TMCP강재 인장시험에서 요구기준 YS = 315 MPa 대비 385 Mpa로서 약 18% 높게 나타났고, TS = 440 ~ 570 MPa 기준 대비 525 MPa로 요구 기준에 적합하였다. 샤르피 V-노치 $-20^{\circ}C$ 충격시험에서도 요구 기준에 적합하였으며 경도시험에서 평균 T : 216, L : 275로서 규정인 Hv10 = 130 ~320 범위에 만족 하였다.