• Title/Summary/Keyword: Vapor condensation

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Effects of Temperature and Precursor-concentration on Characteristics of TiO2 Nanoparticles in Chemical Vapor Condensation Process -Part I: Real-time Particle Characterization by SMPS (화학기상응축 공정에서 TiO2 나노입자 특성에 미치는 반응온도와 전구체 농도의 영향 - Part I: SMPS를 이용한 실시간 입자특성 평가)

  • Lee, Chang-Woo;Yu, Ji-Hun;Im, Sung-Soon;Yun, Sung-Hee;Lee, Jai-Sung;Choa, Yong-Ho
    • Korean Journal of Materials Research
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    • v.13 no.5
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    • pp.323-327
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    • 2003
  • Properties of nanoparticles synthesized during gas phase reaction were studied in terms of particle behaviors using real-time particle characterization method. For this study, $TiO_2$ nanoparticles were synthesized in the chemical vapor condensation process(CVC) and their in-situ measurement of particle formation and particle size distribution was performed by scanning mobility particle sizer(SMPS). As a result, particle behaviors in the CVC reactor were affected by both of number concentration and thermal coagulation, simultaneously. Particularly, growth and agglomeration between nanoparticles followed two different ways of dominances from coagulations by increase of number concentration and sintering effect by increased temperature.

Design and Experiment of Lab-scale Contrail Generator (Lab-scale 비행운 발생장치 설계 및 시험)

  • Choi, Jaewon;Ock, Gwonwoo;Kim, Sangki;Kim, Hyemin
    • Journal of the Korean Society of Propulsion Engineers
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    • v.23 no.4
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    • pp.35-41
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    • 2019
  • Contrail is a kind of cloud that is formed during the flight by vapor condensation of engine exhaust in a cold atmospheric condition. Owing to the negative effects of contrails on the environment and in military applications, several studies for contrail mitigation had been performed in developed countries. The goal of this research is to design a lab-scale contrail generator, and to validate the contrail mitigation technology suggested by previous studies. The contrail generator was made using superheated vapor and a low temperature wind tunnel. Using this generator, the ineffectiveness of ethanol and surfactant suggested in the previous paper on contrail mitigation was found experimentally.

Electrical Measurement of SOx Dew Point (SOx노점의 전기적 측정)

  • Chun, Y.N.;Yong, K.J.;Chae, J.O.
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.7 no.4
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    • pp.600-610
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    • 1995
  • When combustion gas is cooled down below the dew point of sulfuric acid vapor in the heat recovery systems, condensation occurs. Since the condensed sulfuric acid solution causes low-temperature corrosion in materials, it is important to measure the SOx dew point by electric measurement. In this study, two kinds of probes having electric gaps of 1mm or 2mm were used. and experiments were carried out by the parameters of sulfuric acid vapor and water vapor concentration. The changes of electric current caused by sulfuric acid condensed on the surface of probe according to the cooling rate and the probe head surface temperature were sudied. The opimum cooling rate was decreased with the increasing of water vaper concentration regardless of sulfuric acid concentration. The sensitivity of electric current is improved for the narrower gap(1mm) of ring electrodes, but it rarely affects the SOx dew point measuring of different probes according to the change of cooling rate.

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Production of Nanosized WC Powder by Vapor Phase Reaction

  • Cho, Gi-Chul;Lee, Gil-Geun;Ha, Gook-Hyun;Kim, Byung-Kee
    • Proceedings of the Korean Powder Metallurgy Institute Conference
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    • 2006.09a
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    • pp.625-626
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    • 2006
  • In the present study, the focus is on the synthesis of nanosized WC powder by the chemical vapor condensation proces. The synthesized W-C system powder by the CVC process shows W2C, W, WO3 phases and can not shows WC phase. After recarburization heat treatment under mixture gas atmosphere of argon and hydrogen gases, the synthesized W-C system powder fully transformed to the pure WC. The synthesized WC powder after recarburization heat treatment has an average particle size of 20 nm. The nano-sized WC powder can be prepared by the combination of the CVC process and heat treatment methods.

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INFRARED ABSORPTION MEASUREMENT DURING LOW-TEMPERATURE PECVD OF SILICON-OXIDE FILMS

  • Inoue, Yasushi;Sugimura, Hiroyuki;Takai, Osamu
    • Journal of the Korean institute of surface engineering
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    • v.32 no.3
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    • pp.297-302
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    • 1999
  • In situ measurement of infrared absorption spectra has been performed during low-temperature plasma-enhanced chemical vapor depositiion of silicon-oxide films using tetramethoxysilane as a silicon source. Several absorption bands due to the reactant molecules are clearly observed before deposition. In the plasma, these bands completely disappear at any oxygen mixing ratio. This result shows that most of the tetramethoxysilane molecules are dissociated in the rf plasma, even C-H bonds. Existence of Si-H bonds in vapor phase and/or on the film surface during deposition has been found by infrared diagnostics. We observed both a decrease in Si-OH absorption and an increase in Si-O-Si after plasma off, which means the dehydration condensation reaction continues after deposition. The rate of this reaction is much slower than the deposition ratio of the films.

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External Condensation Heat Transfer Coefficients of R22 Alternative Refrigerants and R134a According to the Saturated Vapor Temperature Change on an Enhanced Tube (열전달 촉진관에서 R22 대체냉매 및 R134a의 포화증기 온도변화에 따른 외부 응축 열전달계수에 관한 연구)

  • Yoo Gil-Sang;Hwang Ji-Hwan;Park Ki-Jung;Jung Dongsoo
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.17 no.11
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    • pp.981-989
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    • 2005
  • In this study, external condensation heat transfer coefficients (HTCs) are measured on a low fin tube and Turbo-C tubes at the saturated vapor temperature of $30^{\circ}C$, $39^{\circ}C$, and $50^{\circ}C$ for R22, R410A, R407C and R134a with the wall subcooled at $3{\~}8^{\circ}C$. The HTCs of all refrigerants decreased as increasing the saturation temperature from $30^{\circ}C$ to $50^{\circ}C$. This trend is due to better thermodynamic properties of the liquid phase at low temperature Beatty and Katz's prediction yielded a $20.0\%$ deviation for the low fin tube data. The heat transfer enhancement factors for the 26 fpi low fin tube and Turbo-C tubes are 4.0${\~}$5.5 and 3.0${\~}$8.1 respectively for the refrigerants tested. Finally the performance of Turbo-C tube is better than that of the low fin tube.

Removal Efficiency of Water Contents using Inertial Impaction Separator with Change in Relative Humidity (입구 습도 변화에 따른 관성 충돌 방식의 액적 분리장치의 수분제거효율 변화)

  • Song, Dong Keun;Lee, Sin Young;Hong, Won Seok;Shin, Wanho;Kim, Gyujin;Kim, Hanseok
    • Particle and aerosol research
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    • v.9 no.4
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    • pp.247-252
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    • 2013
  • Removal of water contents in a gas is needed in industrial field of gas processing related on energy production/conversion, and environmental treatment. Inertial separators are economic devices for separating droplets from the gas stream. For design and incorporation of inertial pre-treatment separator, characteristics of removal of water contents with various operation conditions are needed. In this study, removal efficiency of water droplets at various flowrates (5-14 SCMM) and relative humidity (R.H.) conditions (40%, and 90%) has been investigated. At low R.H. condition, the removal characteristic is similar to the removal of solid particles. But, droplet growth resulting from the condensation of water vapor at high R.H. condition, is significant and it made increase in removal efficiency of droplet phase of water contents. For rapid removal of water contents, an effective method to enhancing condensation growth of water droplets is highly needed.

Study on R-l34a, R-407C, and R-410A Condensation Performance in the Oblong Shell and Plate Heat Exchanger (오블롱 셀 플레이트 열교환기에서의 R-l34a, R-407C, R-410A의 응축성능에 관한 실험적 연구)

  • Park, Jae-Hong;Kim, Young-Soo
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.28 no.12
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    • pp.1535-1548
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    • 2004
  • Condensation heat transfer experiments were conducted with the oblong shell and plate heat exchanger without oil in a refrigerant loop using R-l34a, R-407C and R-410A. An experimental refrigerant loop has been developed to measure the condensation heat transfer coefficient h$_{r}$ and frictional pressure drop $\Delta$p$_{f}$ of the various refrigerants in a vertical oblong shell and plate heat exchanger. The effects of the refrigerant mass flux(40∼80kg/$m^2$s), average heat flux(4∼8kW/$m^2$), refrigerant saturation temperature(30∼4$0^{\circ}C$) and vapor quality of refrigerants on the measured data were explored in detail. Similar to the case of a plate heat exchanger, even at a very low Reynolds number, the flow in the oblong shell and plate heat exchanger remains turbulent. A comparison of the performance of the various refrigerants revealed that R-410A had the highest heat transfer performance followed by R-l34a, and R-407C had the lowest performance of the refrigerants tested. The pressure drops were also reported in this paper. The pressure drops for R-410A were approximately 45% lower than those of R-l34a. R-407C had 30% lower pressure drops than R-l34a. Experimental results were compared with several correlations which predicted condensation heat transfer coefficients and frictional pressure drops. Comparison with the experimental data showed that the previously proposed correlations gave unsatisfactory results. Based on the present data, empirical correlations of the condensation heat transfer coefficient and the friction factor were proposed.tor were proposed.sed.

Synthesis of Nanosized TiO$_2$ Powder by Chemical Vapor Condensation Process(1) (화학기상응축법에 의한 TiO$_2$ 나노분말의 합성 (1))

  • 김신영;유지훈;이재성;김종렬;김병기
    • Journal of the Korean Ceramic Society
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    • v.36 no.7
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    • pp.742-750
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    • 1999
  • Nanosized TiO2 powders were synthesized using the chemical vapor conduensation (CVC) process with various precursor feeding rates (0.37 and 0.752 ml/min) and oxygen flow rates(1-2slm) conditions and powder characteristics were investigated in terms of formation of nanosized powder varying with the above processing conditions. For this study the main thermodynamic and fluid dynamic factors -supersaturation ratio collision frequency and residence time-were theoretically established and compared to the characteristics of formed TiO2 powder. The loosely combined anatase phase powders (including less than 3%of rutile phase) having 20-30nm crystallite size were obtained at overall conditions. The particle size and th degree of agglomeration for a precursor flow rate of 0.376 ml/min turn out to be smaller than for a flow rate of 0.742ml/min. And the decreasing of particles size and particle size distribution were observed with increasing oxygen flow rate as the residence time and collision frequency were reduced by increasing oxygen flow rate,. It appears that further scrutiny is needed to elucidate the influence of the individual thermodynamic and kinetic parameters mdependently.

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Variation of Vapor Pressure Deficit and Condensation Flux of Air Heating Plastic Greenhouse Installed with Two Layers Thermal Curtain in Winter (이층커튼 온풍난방 플라스틱온실의 겨울철 포차 및 결로량 변화)

  • Lee, Hyun-Woo;Kim, Young-Shik;Sim, Sang-Youn;Lee, Jong-Won
    • Journal of Bio-Environment Control
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    • v.22 no.1
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    • pp.35-41
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    • 2013
  • This study was conducted to provide data necessary for reducing the condensation on greenhouse covering in winter season. The variation of VPD (Vapor Pressure Deficit) and condensation flux was analyzed in experimental tomato greenhouse. VPD values in experimental plastic greenhouse were greater than 0.2 kPa of disease prevention threshold, and lower than 0.5 kPa of threshold for dehumidification. The surface temperature of inside covering was slightly higher than the average temperature of outside and above curtain, and changed according to outside temperature. The humidity above curtain was nearly 100% and good condition for condensation. The humidity below curtain was 75~90% and comparatively stable condition for growing. The condensation flux value in experimental greenhouse corresponded with result of Seginer and Kantz (1986).