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Crystal Structure Analysis of $LiN(D_xH_{1-x}){_4}SO_4$ by X-ray and Neutron Diffraction (X-선과 중성자 회절을 이용한 강유전체 단결정 $LiN(D_xH_{1-x}){_4}SO_4$의 결정구조 연구)

  • Kim, Shin-Ae;Kim, Seong-Hoon;So, Ji-Yong;Lee, Jeong-Soo;Lee, Chana-Hee
    • Journal of the Mineralogical Society of Korea
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    • v.20 no.4
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    • pp.351-356
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    • 2007
  • The crystal structure of $Li(ND_4)SO_4$ was analyzed by X-ray and neutron diffraction methods. The crystal is a deuterated $Li(NH_4)SO_4$ and one of the ferroelectric materials with hydrogen atoms. The crystal is orthorhombic at room temperature, $P2_1nb$, with lattice parameters of $a=5.2773(5)\;{\AA},\;b=9.1244(23)\;{\AA},\;c=8.7719(11)\;{\AA}$ and Z=4. Neutron intensity data were collected on the Four-Circle diffractometer (FCD) at HANARO in Korea Atomic Energy Research Institute and X-ray date were given by Prof. Y. Noda of Tohoku University Japan. The structure was refined by full-matrix least-square to final R value of 0.070 for 1450 observed reflections by X-ray diffraction and to final R=0.049 for 745 observed reflections by neutron diffraction. With X-ray data we obtained only one hydrogen atomic position. However, not only all atomic positions of four hydrogen atoms at $NH_4$ but also the occupation factors of D and H were refined with neutron data. From this results we obtained the average chemical structure of this sample, $LiND_{3.05}H_{0.95}SO_4$.

Evaluation of the operational efficiency of major coastal ports in China based on the PCA-DEA model (PCA-DEA 모델을 기반으로 한 중국 주요연안 항만의 운영 효율성 평가)

  • Haiqing Zhang;Hyangsook Lee
    • Journal of Korea Port Economic Association
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    • v.40 no.1
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    • pp.87-118
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    • 2024
  • Coastal ports play an essential role in developing a country and a city. Port efficiency is an important factor affecting port trade, and the importance of port efficiency for port performance has been recognized in previous literature. DEA (Data Envelopment Analysis) and SFA (Stochastic Frontier Analysis) are widely used in this field of research. However, these two methods are limited in selecting input and output variables. In addition, the literature studies on Chinese coastal ports mainly focus on the study of port clusters in local areas, which lacks a holistic approach and generally lacks up-to-date data. Therefore, to fill the gap in this area of research, this paper introduces a model combining principal component analysis and data envelopment analysis to analyze the operational efficiency of the top 17 coastal ports in China in terms of throughput based on the most recent data available in 2021. This paper identifies container throughput as the output variable, and 13 second indicators are selected as input variables from four primary indicators: land, capital, labor, and infrastructure. Four principal components were selected from 13 second indicators using PCA.After that, DEA (BBC) and DEA (CCR) were used to analyze the 17 ports, among which five were Shanghai, Ningbo-Zhoushan, Guangzhou, Xiamen, and Dongguan, respectively, DEA efficient, and the remaining 12 ports were non-DEA efficient. Finally, improvement directions for each port are derived, and brief suggestions are made. This paper provides some reference value for developing and constructing coastal ports in China.

Quality Characteristics and Volatile Flavor Compounds of Oriental Melon Wine Using Freeze Concentration (동결농축 참외와인의 품질 특성과 휘발성 향기 성분)

  • Hwang, Hee-Young;Hwang, In-Wook;Chung, Shin-Kyo
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.44 no.9
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    • pp.1347-1355
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    • 2015
  • In this study, the physicochemical properties, antioxidant capacities, and volatile flavor compounds of oriental melon wine prepared by freeze concentration after heat treatment (HA), ascorbic acid treatment (AAT), and heat and ascorbic acid treatment (HAAT) were investigated. During fermentation period, the melon wine by HAAT showed greater reduction of soluble solids and reducing sugar contents compared to other treatments. In addition, the melon wine treated with HAAT also showed a higher L value and lower browning index compared to other treatments. After aging, free sugar including fructose, and organic acids including citric acid, succinic acid, and malic acid were detected in all samples. For antioxidant activities and contents, HAAT treated wine showed greater antioxidant activities and total phenolic contents than those of others. In GC/MS analysis, a total of 33 volatile flavor compounds were identified. In the principal component analysis of volatile flavor compounds, principal components 1 and 2 represented 88.15% of the whole date distribution and showed opposite tendencies. Taken together, HAAT enhanced the antioxidant activities and sensory properties of oriental melon wine. Moreover, freeze concentration gave the different volatile flavor characteristics in oriental melon wine.

Comparison of Agronomic Characteristics, Productivity and Feed Values of Summer Sowing Sorghum Hybrids in Gyeongbuk (경북지역에서 여름 파종 수수류 교잡종의 생육특성, 수량성 및 사료가치 비교)

  • Shin, Chung Nam;Ko, Ki Hwan;Kim, Jong Duk
    • Journal of The Korean Society of Grassland and Forage Science
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    • v.35 no.2
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    • pp.99-104
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    • 2015
  • This study was conducted to evaluate on agronomic characteristics, dry matter (DM) and digestible dry matter (DDM) yields of summer sowing sorghum hybrids (Sorghum bicolor (L) Moench) at Seongju in Gyeongbuk from 2013 to 2014. The experiment was arranged in randomized complete block design with three replications. Sorghum hybrids were seeded $31^{st}$ of July, 2013 and 2014. Sorghum hybrids were harvested on $3^{rd}$ November, 2013 and $5^{th}$ November, 2014. The observed average heading date was October 5, 8 and 9 for Sordan79, Sprint and SX17 respectively. The DM yield of 'SX17', 'Sordan79', and 'Sprint' was 24.2, 23,9 and 23.4 ton/ha, respectively and DM yield of those were significantly higher (p<0.05) than other three cultivars in 2013. DM yield of 'SX17', 'Sprint' and 'Sordan79' was 20.8, 20.0 and 19.3 ton/ha, respectively and DM yield of those was significantly higher (p<0.05) than other three cultivars in 2014. The DDM yield of 'SX17', 'Sordan79', and 'Sprint' was also higher (p<0.05) than other three cultivars in 2013 and 2014. ADF content of sorghum hybrids was low, whereas DDM was high. The results of this study indicated that traditional sorghum-sudangrass hybrids ('SX17', 'Sordan79') and sudan grass-sudangrass hybrid ('Sprint') than late flowering sorghum-sudangrass hybrid ('PACF8350') and sorghum-sorghum hybrids ('SS405', 'Sugar grazer') would be recommended for DM and DDM yields in the southern Korea.

Regional Asymmetries and Development Cooperation in MERCOSUR (남미공동시장의 역내 비대칭성과 지역개발협력)

  • Hyun, Min
    • Iberoamérica
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    • v.21 no.1
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    • pp.57-105
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    • 2019
  • This paper deals with the regional asymmetries of MERCOSUR and regional development cooperation for its solution. Through the formation of a common market, the countries of Southern Cone expected to grow evenly. However MERCOSUR had structural asymmetry from the beginning and exposed policy asymmetry over time. It is basically due to the overwhelming influences of Brazil on MERCOSUR. With regard to asymmetries, Paraguay calls for special and differential treatment. Uruguay wants equitable application of market liberalization. Argentine emphasizes production integration based on the development of value chains. In the issue of asymmetries, while Paraguay, Uruguay and Argentine act as petitioners, Brazil is capable of selecting the initiatives. Under these circumstances MERCOSUR has established FOCEM as regional redistribution mechanism. FOCEM has achieved some results as seen in Paraguay, but there are still problems such as financial limitations and lack of enforcement. In oder to activate the redistributive mechanism for regional integration and to coordinate the policies to resolve regional disparities, transnational governance is essential but all member countries are reluctant to it. To date, regional asymmetries or development gaps have persisted and disparities in individual countries remains a problem.

A Very Early-Maturing Italian Ryegrass (Lolium multiflorum Lam.) New Variety, 'Green farm II' (이탈리안 라이그라스 신품종 '그린팜 2호'의 생육특성과 수량성)

  • Ji, Hee Chung;Choi, Gi Jun;Lee, Sang Hyun;Kim, Ki-Yong;Lee, Ki Won;Park, Nam Gun;Lee, Eun Sup
    • Journal of The Korean Society of Grassland and Forage Science
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    • v.33 no.1
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    • pp.10-14
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    • 2013
  • This experiment was carried out to breed an early maturing variety of Italian ryegrass (Lolium multiflorum Lam.) in the Grassland and Forage Crops Division, National Institute of Animal Science, RDA, Cheonan from 2009 to 2011. A new variety, 'Green farm II' is a diploid with green leaves and has a semi-erect growth habit in late autumn and erect growth habit in early spring, respectively. 'Green farm II' was on the $28^{th}$ of April in the heading date as an early-maturing variety. 'Green farm II' was also wider by 0.6 mm in flag leaf width, shorter by 1 cm in flag leaf length and shorter by 1 cm in plant length than those of the control variety, 'Florida 80', respectively. 'Green farm II' was thicker by 0.7 mm in stem thickness and strong in winter hardness. Dry matter (DM) yield (11,452 kg/ha) of 'Green farm II' was similar to that of 'Florida 80'. In vitro dry matter digestibility (IVDMD), total digestible nutrients (TDN), and relative feed value (RFV) of 'Green farm II' were 70.6%, 63.9%, and 114% higher than those of 'Florida 80', respectively. Acid detergent fiber (ADF) and neutral detergent fiber (NDF) of 'Green farm II' were 31.7% and 52.6% which were 3.5% and 6.4% lower than those of 'Florida 80', respectively.

Effects of N, $P_{2}O_{5}$ and $K_{2}O$ Top Dressing at Panicle Initiation Stage of Rice Plants in Differently Fertilized Soil (수년간 질소, 인산 및 가리를 시용하지 않은 답토양에서 그들의 수비가 수도의 수량 및 수량구성형질에 미치는 영향)

  • Jung-Il Lee;Eun-Woong Lee
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.25 no.2
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    • pp.23-30
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    • 1980
  • Experiments were conducted to know N, P, and K top dressing effects on yield and other agronomic characters of rice plants grown in 5-year differently fertilized soils. Four levels of nitrogen, 0, 1.2, 2.4, and 3.6kg/10a, were applied 32 days before heading in 5-year non-fertilized and PK applied plots. Four levels of P_2 $O_{5}$ and K_2 O of 0, 4, 8 and 12kg/l0a were applied 40 days before heading in 5-year NK and NP applied plots, respectively. 1. Heading was delayed by seven days in 5-year non-fertilized and PK applied plots compared to NK, NP, or NPK applied plots where nitrogen was applied as basal. However, in 5-year non-fertilized and PK applied plots heading was delayed from 1 to 4 days as amounts of nitrogen top dressing increased. Phosphorus and potassium did not affect heading date of rice plants. 2. In 5-year non-fertilized plot grain yield increased as amounts of nitrogen top dressing increased up to 2.4kg/l0a due to both increased number of panicles per hill and spikelets per panicle. However, in 5-year PK applied plot amounts of nitrogen top dressing did not affect grain yield; the number of panicle per hill increased, but the percentage of ripened grains and grain weight tended to decrease as nitrogen levels increase. 3. The number of panicle/maximum tillers ratio in percentage increased markedly as amounts of nitrogen top dressing increased in 5-year non-fertilized and PK applied plots with maximum value of 130% on the basis of maximum tillers at vegetative stage. 4. Top dressing of phosphorus and potassium did not affect yield and other agronomic characters in NK and NP applied plots.

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Growth Characteristics and Productivity of New Orchardgrass(Dactylis glomerata L.) Variety "Korditwo" (오차드그라스 신품종 "코디투"의 생육특성과 수량성)

  • Ji, Hee-Chung;Choi, Gi-Jun;Sung, Byung-Ryul;Seo, Sung;Kim, Ki-Young;Lee, Joung-Kyong;Kim, Won-Ho;Park, Hyung-Soo;Moon, Chung-Sup
    • Journal of The Korean Society of Grassland and Forage Science
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    • v.28 no.1
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    • pp.1-6
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    • 2008
  • Korditwo is a new orchardgrass(Dactylis glomerata L.) variety developed by the National Institute of Animal Science(NIAS) in 2005. To develope the new variety of orchardgrass, 5 superior clones, Dg8533, Dg9518, EDg9133, U8504 and U8519, were selected and polycrossed for seed production. That synthetic variety was designated newly as "Korditwo", and it's agronomic growth characteristics and forage productivity were examined at Suwon from 2001 to 2002, and regional yield trials were conducted in Suwon, Pyungchang, Youngju, Iksan, and Jeju from 2003 to 2005, respectively. "Korditwo" showed medium type growth habit in fall and spring and short in length of flag leaf and upper internode. Plant height of "Korditwo" was similar to that of standard variety, "Ambassador" and heading date was 4 days later than 14th May compared to Ambassador. Characteristics such as winter hardiness, lodging tolerance, disease resistance of "Korditwo" were stronger or better than those of Ambassador, specially in winter hardiness and lodging tolerance. "Korditwo" showed 10% higher dry matter yield(11.3 ton/ha) compared to Amabassador. Nutritive value was appeared to be similar in both varieties.

Growth Characteristics and Productivity of New Orchardgrass(Dactylis glomerata L.) Variety 'Kordi' (오차드그라스 신품종 '코디'의 생육특성과 수량성)

  • Rim Y. W.;Choi G. J.;Sung B. R.;Lim Y. C.;Kim M. J.;Park G. J.;Kim K. Y.;Chung J. W.;Go S. B.
    • Journal of The Korean Society of Grassland and Forage Science
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    • v.24 no.3
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    • pp.261-264
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    • 2004
  • New orchardgrass(Dactylis glomerata L.) variety named as 'Kordi' was developed by the National Livestock Research Institute(NLRI) in 2003. Five superior clones on selected to develope the new variety of orchardgrass, and polycrossed for synthetic seed production. Synthetic seeds were examined on the agronomic growth characteristics and forage production at Suwon from 1995 to 1998, and regional trials were conducted in Suwon, Pyungchang and Jeju from 2001 to 2003 and Icsan in 2003, respectively. 'Kordi' showed semi-erect growth habit in fall and spring, and long type in length of flag leaf and short in upper internode. Plant height of 'Kordi' was little short compared to that of standard variety, Ambassador, and heading date was delayed about 3 days as 14th May compared to Ambassador. Characters such as winter hardiness. lodging tolerance, regrowth, disease resistance of 'Kordi' were stronger or better than those of Ambassador. 'Kordi' showed $10\%$ higher dry matter yield as 15,174 kg/ha compared to Ambassador. Nutritive value was appeared to be similar in both varieties.

Growth Characteristics and Productivity of New Orchardgrass(Dactylis glomerata L.) Variety “Jangbeol 101” (오차드그라스 신품종 “장벌 101호”의 생육특성과 수량성)

  • 임용우;최기준;성병렬;임영철;김맹중;박근제;김기용;정종원;박남건
    • Journal of The Korean Society of Grassland and Forage Science
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    • v.23 no.3
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    • pp.203-206
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    • 2003
  • New orchardgrass(Dactylis glomerata L.) variety named as “Jangbeol 101” was developed by the National Livestock Research Institute(NLRI) in 2002. To develope the new variety of orchardgras, 5 superior clones were selected and polycrossed for seed production. Synthetic seeds were examined on the agronomic growth characteristics and forage production at Suwon from 1995 to 1998, and regional trials were conducted in Suwon, Namwon and Pyungchang from 1999 to 2002 and Jeju from 2000 to 2002, respectively. “Jangbeol 101” showed semi-erect growth habit in fall and spring and medium type in length of flag leaf and upper internode. Plant height of “Jangbeol 101” was short compared to that of standard variety, “Ambassador” and heading date was delayed about 2 days as 14th May compared to Ambassador. Characters such as winter hardiness, regrowth, moisture tolerance, disease resistance of “Jangbeol 101” were stronger or better than those of Ambassador. “Jangbeol 101” showed 9% higher dry matter yield as 12,374 kg/ha compared to Amabassador. Nutritive value was appeared to be similar in both varieties.