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Flux Decline and Fouling Mechanism of Si Colloidal Solution During the Ultra-Filtration (환외여과에 있어서 Si 콜로이드 용액의 투과유속 감소 및 오염특성)

  • Nam, Suk-Tae;Jeon, Jae-Hong;Lee, Seok-Ki;Choi, Ho-Sang
    • Clean Technology
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    • v.5 no.2
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    • pp.25-35
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    • 1999
  • Behavior of permeate flux decline was examined through the hollow fiber membrane in ultrafiltration system for Si colloidal solution. Flux decline with time was due to the growth of Si cake deposited on the membrane surface and the pore blocking by Si particles for the hollow fiber membrane. At the pseudo steady state of operation, the permeate flux of dead-end flow was 60 % to that of the cross flow. The ratio of permeate flux to the pure water flux, $J/J_w$, decreased with increasing the trans-membrane pressure, from 64.2 % for $0.5kg_f/cm^2$ to 45.7 % for $2.0kg_f/cm^2$. When the feed flow rate was 3 L/min, the pore blocking model was dominant at the initial period of filtration and was followed by the cake filtration model. And with increasing the feed flow rate from 1 L/min to 3 L/min, $R_c$ was $1.79{\times}10^{12}{\sim}2.34{\times}10^{12}m^{-1}$ which was the about 40 % decreased value to that of the 1 L/min while $R_p$ was not changed and was $1.71{\times}10^{12}m^{-1}$ approximately.

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Development of an On-line Measurement Method for Clean Biofuel Based on Near Infrared Spectroscopy and Chemometrics (근적외선 분광학과 화학계량학에 기반한 청정 바이오연료 실시간 품질 측정 기술 개발)

  • Cho, Hyeong-Su;Ryu, Jun-Hyung;Liu, J. Jay
    • Clean Technology
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    • v.17 no.3
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    • pp.215-224
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    • 2011
  • It is an important issue to develop quality assessing system for biofuel for the purpose of accelerating the mass production of biofuel. It is particularly challenging to conduct testing method in the mass production of bioethanol while meeting quality specifications such as ASTM (American Society for Testing & Materials) D4806-10. In order to address this challenge, this paper proposes on-line spectroscopic quality assesment system based on Near Infrared spectrum and Partial Least Squares method in Chemometrics. As a result of testing a number of preprocessing methods and Partial Least Squares, it was found out that Savitzky-Golay method showed the best performance in terms of spectrum correction, noise reduction, and model maintenance. The proposed system allows us to assess multiple quality components continuously using spectroscopic facilities with the cheap cost. Since the value of R2 is more than 0.99, it is possible to replace the laboratory analysis.

A Study on Synthesis and Hydrolysis of the Maleated Polyethylene Wax (무수말레인산으로 그라프트된 폴리에틸렌 왁스의 중합과 가수분해에 대한 연구)

  • Yu, Si-Won;Choi, Joong-So;Na, Jae-Sik
    • Clean Technology
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    • v.19 no.4
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    • pp.393-400
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    • 2013
  • In this study, Polyethylene wax, which was produced in manufacturing process of high density polyethylene was grafted with maleic anhydride (MAH). The influences of reaction parameters on the graft polymerization as well as the effect of hydrolysis of the anhydride functions were investigated. The results show that the grafting degree increased and conversion of maleic anhydride decreased with an increase in MAH monomer content. This means the highest grafting efficiency for the reaction can be met when MAH monomer content is about 15 wt%. DCP (dicumyl peroxide) and DTBP (di-tert-butyl peroxide) have been used as the initiator and the highest yield of grafting was obtained when the initiator content is about 0.5 wt%. However, It can be seen that the gel content values of this polyethylene wax grafted MAH were below 2%. It was also observed that the grafting degree increased with an increase in reaction temperature and the maximum value was reached 2 hours later. Although MAH functions grafted onto polyethylene wax were mainly in the carboxylic acid forms, some anhydride form of MAH appeared in over 5% of grafting degree. As a result of hydrolysis reaction, it was observed that the conversion of anhydride group into carboxylic acid group was reached up to 10%.

Desorption Characteristics for Previously Adsorbed Gold and Copper-Cyanide Complexes onto Dowex21K XLT Resin Using Mixed Solvent with HCl and Acetone (염산과 아세톤의 혼합용매를 이용한 Dowex21K XLT 수지에 흡착된 금과 구리-시안 착화합물의 탈착 특성)

  • Jeon, Choong
    • Clean Technology
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    • v.19 no.4
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    • pp.487-491
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    • 2013
  • To efficiently desorb gold and copper-cyanide complexes adsorbed onto Dowex21K XLT resin, the mixed solvent with HCl and acetone which is a kind of dipolar aprotic solvent was used as a desorbing agent. The desorption efficiency for gold-cyanide complex was the highest as about 94% when the mixing ratio of HCl and acetone based on volume was the 7:3, however, the value decreased as the ratio of acetone increased. In the case of copper-cyanide complex, most of them was desorbed when the amount of HCl was relatively higher than that of acetone, however, desorption efficiency decreased as the ratio of acetone increased. The desorption efficiency for gold and copper-cyanide complexes was the 94 and 100%, respectively at the 0.6 M of HCl with the 7 (HCl) : 3 (Acetone) of mixing ratio and desorption efficiency for gold-cyanide complex not increased any more even though higher HCl concentration was used. And the desorption efficiency for gold and copper-cyanide complexes was about 100% at the S/L raio ${\leq_-}1.0$ whereas desorption efficiency for gold-cyanide complex was very low as about 20-29% at the S/L ratio > 1.0. Also, most of desorption process for gold and copper-cyanide complexes was completed within 120 min.

The Shear Strength Characteristics of Weathered Granite Soil in Unsaturated State (불포화(不飽和) 화강암질풍화토(花崗岩質風化土)의 전단강도(剪斷强度) 특성(特性))

  • Cho, Seong Seup;Kang, Yea Mook;Chee, In Taeg
    • Korean Journal of Agricultural Science
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    • v.12 no.1
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    • pp.86-100
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    • 1985
  • In order to investigate the strength characteristics of weathered granite soils in unsaturated state, the five physically different weathered granite soils and the common soil (sandy loam) were examined. The disturbed and the undisturbed material were prepared for triaxial compression test. The following conclusions were drawn from the study; 1. Dry density of the undisturbed soil samples was lower than maximum dry density determined from the compaction test and it showed the higher value at the well graded soil. 2. The failure strength of the samples decreased with the increase of moisture content of the soil and these results were highly pronounced at the common soil sample having a good cohesive property. 3. On weathered granite soils, the cohesion was lower measured and the internal friction angle highly, the decrease rate at internal friction angle with increase of moisture content of the soil was more significant than that of cohesion 4. The modulus of deformation of the samples decreased with increase of moisture content of the soil and these phenomena were highly pronounced at the weathered granite soils than common soil. 5. The failure strength of the samples increased with in crease of confining pressure and effect of confining pressure on failure strength was highly significant at the lower moisture content of the soil.

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Genome wide association test to identity QTL for dressing percentage in Hanwoo (전장 유전체 관련성 분석을 통한 한우 도체수율 관련 양적형질좌위 탐색)

  • Lee, Seung Hwan;Lim, Dajeong;Dang, Chang Gwan;Chang, Sun Sik;Kim, Hyeong Cheul;Jeon, Gi Jun;Yeon, Seong Hum;Jang, Gul Won;Park, Eung Woo;Oh, Jae Don;Lee, Hak Kyo;Lee, Jun Heon;Kang, Hee Sul;Yoon, Duhak
    • Korean Journal of Agricultural Science
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    • v.40 no.2
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    • pp.155-162
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    • 2013
  • Genome-wide association study was performed on data from 266 Hanwoo steers derived from 66 sire using bovine 10K mapping chip in Hanwoo (Korean Cattle). SNPs were excluded from the analysis if they failed in over 5% of the genotypes, had median GC scores below 0.6, had GC scores under 0.6 in less than 90% of the samples, deviated in heterozygosity more than 3 standard deviations from the other SNPs and were out of Hardy-Weinberg equilibrium for a cutoff p-value of $1^{-15}$. Unmapped and SNPs on sex chromosomes were also excluded. A total of 4,522 SNPs were included in the analysis. To test an association between SNP and QTL, GWAS for five genetic mode (additive, dominant, overdominant, recessive and codominant) was implemented in this study. Three SNPs (rs29018694, ss46526851 and rs29018222) at a threshold p< $1.11{\times}10^{-5}$ were detected on BTA12 and BTA21 for dressing percentages in codominant and recessive genetic mode. The G allele for rs29018694 has 4.9% higher dressing percentage than A allele, while the T allele for ss46526851 has 2.57 % higher dressing percentage than C allele. Therefore, rs29018694 SNP showed a bigger effect than the other two SNPs (ss46526851 and rs29018222) in this study. In conclusion, this study identifies three loci with moderate effects and many loci with infinitesimally small effect across genome in Hanwoo.

Effects of fruit bags and bagging time on fruit quality indices at harvest time in 'Wonhwang' and 'Whasan' pears (봉지종류 및 괘대시기가 '원황' 및 '화산' 배 과실의 수확기 품질에 미치는 영향)

  • Jung, Ok-Kun;Lee, Ug-Yong;Ahn, Young-Jik;Lee, Hyuk-Jae;Hwang, Yong-Soo;Chun, Jong-Pil
    • Korean Journal of Agricultural Science
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    • v.40 no.2
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    • pp.107-113
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    • 2013
  • We tested fruits quality and skin coloration of two pear cultivar 'Wonhwang' and 'Whasan' produced by bagging with different kinds of paper bags in the Cheonan area, Chungnam Province, Korea. The fruits were bagged at 35, 45, 55 or 65 days after full bloom (DAFB) with 3 kinds of double layer paper bag which consisted of grey color, yellow color and newspaper for outer layer. The great extent of light interruption was observed in grey colored outer paperbag among three kinds of paperbag which showed only 0.46% of lowest light transmittance when compared with 43.7% and 40.0% of yellow paper and newspaper, respectively. The development of skin redness ($a^*$) increased with the delay of bagging time in two pear cultivars. But the fruits treated at 65 DAFB showed uneven coloration and excessive development of redness which represented low fruit external appearance value. Uniform flesh firmness was attained at the fruits bagged with grey outer color paperbag regardless of bagging time, although the fruit quality indices including soluble solids and titratable acidity did not change significantly by using different kind of fruit bags and bagging time in two pear cultivar. Based on our results, it was explained that the grey-colored fruit bag had positive effect on the development of skin coloration without any detrimental effect on fruit quality factors in 'Wonhwang' and 'Whasan' pears.

Nonlinear Analysis of PSC Girders with External Tendons (외부강선으로 긴장된 PSC 거더의 비선형 해석)

  • Choi, Kyu-Chon;Lee, Jae-Seok
    • Journal of the Computational Structural Engineering Institute of Korea
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    • v.23 no.3
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    • pp.303-314
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    • 2010
  • A study for the nonlinear analysis method of prestressed concrete(PSC) girders with external tendons is presented. The PSC girders with external tendons show the complex nonlinear behavior due to the slip of external tendons at deviator and the change of eccentricity between the girders and external tendons. The external tendon between anchorage-deviator or deviator-deviator is modeled as an assemblage of the curved elements. The slip effect of the external tendon at deviator is taken into account using the force equilibrium relationship between the friction force and the driving force at each deviator. The finite element model and analysis method of the external tendon suggested herein are integrated in the nonlinear analysis program of segmentally erected PSC frames developed by the authors. The proposed analysis method is verified through the comparison of the analysis and experimental results obtained from other investigators. From the ultimate analysis results of PSC beams with external tendons having different number of deviators, the yielding and ultimate loads of PSC beams found to be increased as the number of deviators are increased. In addition, the ultimate capacity of the PSC beam increases according to the increase of friction coefficient between deviator and external tendon, whereas found to decease over the certain value of friction due to the effect of the moment transmitted to the member by the friction force exerted from the external tendon.

An Criterion to Minimize FE Mesh-Dependency in Concrete Plate under Impact Loading (충격하중을 받는 판형콘크리트 구조물의 요소의존성 최소화 기준식)

  • Kwak, Hyo-Gyoung;Gang, Han-Gul;Park, Lee-Ju
    • Journal of the Computational Structural Engineering Institute of Korea
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    • v.27 no.3
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    • pp.147-154
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    • 2014
  • In the context of an increasing need for safety in concrete structures under blast and impact loading condition, the behavior of concrete under high strain rate condition has been an important issue. Since concrete subjected to impact loading associated with high strain rate shows quite different material behavior from that in the static state, several material models are proposed and used to describe the high strain rate behavior under blast and impact loading. In the process of modelling high strain rate conditions with these material models, mesh dependency in the used finite element(FE) is the key problem because simulation results under high strain-rate condition are quite sensitive to applied FE mesh size. This paper introduces an criterion which can minimize the mesh-dependency of simulation results on the basis of the fracture energy concept, and HJC(Holmquist Johnson Cook) model is examined to trace sensitivity to the used FE mesh size. To coincide with the purpose of the perforation simulation with a concrete plate under a projectile(bullet), the residual velocities of projectile after perforation are compared. The analytical results show that the variation of residual velocity with the used FE mesh size is quite reduced and accuracy of simulation results are improved by applying a unique failure strain value determined according to the proposed criterion.

Comparative Study of Finite Element Analysis for Stresses Occurring in Various Models of the Spent Nuclear Fuel Disposal Canister due to the Accidental Drop and Impact on to the Ground (추락낙하 사고 시 지면과의 충돌충격에 의하여 다양한 고준위폐기물 처분용기모델에 발생하는 응력에 대한 유한요소해석 비교연구)

  • Kwon, Young-Joo
    • Journal of the Computational Structural Engineering Institute of Korea
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    • v.30 no.5
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    • pp.415-425
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    • 2017
  • Stresses occur in the spent nuclear fuel disposal canister due to the impulsive forces incurred in the accidental drop and impact event from the transportation vehicle onto the ground during deposition in the repository. In this paper, the comparative study of finite element analysis for stresses occurring in various models of the spent nuclear fuel disposal canister due to these impulsive forces is presented as one of design processes for the structural integrity of the canister. The main content of the study is about the design of the structurally safe canister through this comparative study. The impulsive forces applied to the canister subjected to the accidental drop and impact event from the transportation vehicle onto the ground in the repository are obtained using the commercial rigid body dynamic analysis computer code, RecurDyn. Stresses and deformations occurring due to these impulsive forces are obtained using the commercial finite element analysis computer code, NISA. The study for the structurally safe canister is carried out thru comparing and reviewing these values. The study results show that stresses become larger as the wall encompassing the spent nuclear fuel bundles inside the canister becomes thicker or as the diameter of the canister becomes larger. However, the impulsive force applied to the canister also becomes larger as the canister diameter becomes larger. Nonetheless, the deformation value per unit impulsive force decreases as the canister diameter increases. Therefore, conclusively the canister is structurally safe as the diameter increases.