• Title/Summary/Keyword: VUV

검색결과 118건 처리시간 0.023초

Plasma and VUV Pretreatments of Polymer Surfaces for Adhesion Promotion of Electroless Ni or Cu Films

  • Romand, M.;Charbonnier, M.;Goepfert, Y.
    • 접착 및 계면
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    • 제4권2호
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    • pp.10-20
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    • 2003
  • This paper is relative to the electroless deposition of nickel or copper films on polyimide and polytetrafluoroethylene substrates. First, it is presented an original approach of the electroless process which consists in grafting nitrogenated functionalities on the polymer surfaces via plasma or VUV-assisted treatments operating in a nitrogen-based atmosphere ($NH_3$, $N_2$), and then in catalysing the grafted surfaces in an aqueous tin-free, Pd(+2)-based solution. Adhesion of the Pd(+2) catalytic species on polymer surfaces is explained by the formation of strong covalent bonds between these species and the grafted nitrogenated groups. Second, it is show how a fragmentation test performed in conjunction with electrical measurements can be used to characterize the practical adhesion of the electroless coatings deposited on flexible polymer substrates, and to evidence the influence of some experimental parameters (plasma treatment time and nature of the gas phase).

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N(2D) Product Velocity Mapped Imaging in the VUV Photolysis of Nitrous Oxide at 118.2 nm

  • Cosofret, Bogdan R.;Lambert, H. Mark;Houston, Paul L.
    • Bulletin of the Korean Chemical Society
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    • 제23권2호
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    • pp.179-183
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    • 2002
  • Resonance-enhanced multiphoton ionization with time-of-flight product imaging of the $N(^2D)$ atoms has been used to study the $N_2O$ photodissociation at 118.2 nm and the two-photon dissociation at 268.9 nm. These imaging experiments allowed the determination of the total kinetic energy distribution of the $NO(X^2{\prod})$ and $N(^2D_{5/2})$ products. The $NO(X^2{\prod})$ fragments resulting from the photodissociation processes are produced in highly vibrationally excited states. The two-photon photodissociation process yields a broad $NO(X^2{\prod})$ vibrational energy distribution, while the 118.2 nm dissociation appears to produce a vibrational distribution sharply peaked at $NO(X^2{\prod},\;{\nu}=14)$.

The dependence of the electrical characteristics of MgO on temperature in an AC PDP

  • Ha, Chang-Hoon;Jeong, Dong-Chul;Kim, Joong-Kyun;Whang, Ki-Woong
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2005년도 International Meeting on Information Displayvol.I
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    • pp.714-716
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    • 2005
  • We studied the dependence of the electrical characteristics of MgO protecting layer on temperature in an AC PDP cell. Careful measurements of the surface resistance of MgO were performed for the temperature range from room temperature to $100^{\circ}C$ with and without the VUV illumination. Experimental results show that the resistivity is affected by not only the temperature but also VUV irradiation. The measurement of wall charge distribution and the address discharge delay time as to the temperature show that the resistivity change of MgO may affect the wall voltage and consequently the discharge delay time.

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Synthesis and Optical Characteristics of Green-Emitting (Mg,Zn)$Al_2O_4:Mn^{2+}$ Phosphor for 3D- PDP Applications

  • Han, Bo-Yong;Yoo, Jae-Soo;Heo, Eun-Gi;Yoo, Young-Gil
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2009년도 9th International Meeting on Information Display
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    • pp.272-275
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    • 2009
  • A new green phosphor, ($Mg_{1-x-yZnx)$)$Al_2O_4:Mn^{2+}{_y}$ (0 x 0.6, 0.001 y 0.01), was synthesized by a flux-assisted solid reaction and its vacuum ultraviolet (VUV) excitation and emission characteristics were examined in this study. The chromaticity and peak intensity of the $(Mg_{0.79}Zn_{0.2})Al_2O_4:Mn^{2+}{_{0.01}}$ (x = 0.177, y = 0.745) phosphor were found to be more desirable than that of $Zn_2SiO_4:Mn^{2+}$ (x = 0.216, y = 0.72) phosphor as a green primary color.

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Analysis of Energy Flow and Barrier Rib Height Effect using Ray-Optics Incorporated Three-dimensional PDP Cell Simulation

  • Chung, Woo-Joon;Jeong, Dong-Cheol;Whang, Ki-Woon;Park, Jae-Hyeung;Lee, Byoung-Ho
    • Journal of Information Display
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    • 제2권4호
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    • pp.46-51
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    • 2001
  • Using ray-optics code incorporated with three-dimensional PDP cell simulation, we have analysed the energy flow in the PDP cell from the electric power input to the visible light output. Also, the visible light output profile and viewing angle distribution were obtained. We applied our code to the analysis of the barrier rib height effect on the visible light luminance and efficiency of the sustaining discharge. Although cells with higher barrier rib generate more VUV photons, less ratio of visible photons are emitted toward front panel due to the shadow effect. Thus, there exists optimal barrier rib height giving the highest visible luminance and efficiency. This kind of code can be a powerful tool in designing cell geometry.

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라포나이트-X(X = Eu, Tb) 형광체의 합성 및 열적 안정성과 발광특성 연구 (Synthesis, photoluminescence and thermal properties of laponite-X (X = Eu, Tb) phosphors)

  • 김표라;손동민;이한나;김유혁
    • 한국결정성장학회지
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    • 제19권4호
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    • pp.196-201
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    • 2009
  • 본 연구에서는 라포나이트의 발광 기능성을 부여하기 위하여 수용액에서 라포나이트의 층간에 존재하는 Na 이온을 Eu 및 Tb 이온으로 치환하여 동결 건조 후 소성하여 라포나이트-X(X=Eu, Tb) 형광체를 제조하였다. 합성된 형광체의 열적 안정성을 조사하기 위하여 여러 온도에서 소성하여 XRD로 결정구조를 분석한 후 형광체가 $600^{\circ}C$까지 안정하고 $700^{\circ}C$ 이후에는 새로운 결정상이 형성됨을 확인할 수 있었다. 합성된 형광체의 발광 특성은 UV 및 VUV 여기 광원하에서 조사하였으며 적색 및 녹색 발광 특성은 $300^{\circ}C$$500^{\circ}C$에서 각각 $Eu^{3+}$$Tb^{3+}$에 기인하는 발광 피이크로 확인 할 수 있었다.

Influence of gas mixture He-Ne-Xe on the vacuum ultraviolet intensity in ac-PDPs.

  • Yoo, N.L.;Jung, K.B.;Lee, J.H.;Lee, S.B.;Han, Y.K.;Jeong, S.H.;Lee, H.J.;Son, C.G.;Lim, J.E.;Oh, P.Y.;Moon, M.W.;Jeoung, J.M.;Ko, B.D.;Cho, G.S.;Uhm, H.S.;Choi, E.H.
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2005년도 International Meeting on Information Displayvol.II
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    • pp.1221-1224
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    • 2005
  • The improvement of luminance and luminous efficiency is the one of the most important parts in AC-PDPs. To achieve high luminance and luminous efficiency, high VUV emission efficiency is needed. We measured the emission spectra of the vacuum ultraviolet(VUV) rays in surface discharge AC-PDP with ternary gas mixture of He-Ne-Xe. The influence of He-Ne-Xe gas-mixture ratio on excited $Xe^{\ast}$ resonant atoms and $Xe_2\;^{\ast}$ dimers has been investigated. It is found that luminous efficiency of ternary gas mixture, He-Ne-Xe, is shown to be much higher than that of binary gas mixture of Ne-Xe. For improving discharge luminous efficiency, we have studied VUV emission characteristics of ternary gas mixture, He(50%)-Ne-Xe and He(70%)-Ne-Xe with Xe concentration and filling gas pressure.

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조합화학을 이용한 (Gd0.74Y0.11Tb0.15P1.15)Oδ 형광체 합성 및 발광특성 (Synthesis of (Gd0.74Y0.11Tb0.15P1.15)OδPhosphors Using Combinatorial Chemistry)

  • 이재문;유정곤;박덕현;김지식;손기선
    • 한국세라믹학회지
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    • 제41권5호
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    • pp.381-387
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    • 2004
  • 현재 상용화되어 있는 PDP용 형광체의 물성에 있어서 청색 형광체는 열화, 색도변화, 휘도, 그리고 녹색 형광체는 잔광시간과 색순도, 적색 형광체의 경우에는 색순도에 대한 개선이 필요한 것으로 알려져 있다. 그 중 녹색 형광체로 Willemite 구조의 ZnSiO:Mn 형광체의 경우 발광효율은 우수하나 반면에 잔광시간이 길고 색순도(color purity)가 좋지 않다는 단점을 가지고 있다. 따라서 본 연구에서는 미세조정 조합화학기법을 이용하여 PDP에 적합한 새로운 고효율 형광체를 개발하였다. 화학적으로 정량인 가돌리늄 인산염(gadolinium phosphorous) 대신 인산을 과잉으로 첨가하여 탐색한 다음 과잉인산(excess phosphorous) 첨가 조성을 유지한 채로 가돌리늄(gadolinium)의 일정분율을 이트륨(yttrium)으로 치환하였다. 그 결과 최적 형광체 조성은 (G $d_{0.74}$ $Y_{0.11}$T $b_{0.15}$) $P_{1.15}$ $O_{{\delta}}$이였으며, 현재 상용화된 Z $n_2$ $SiO_4$:Mn 형광체에 비해 상대적으로 높은 발광효율을 나타내었으며, 잔광시간도 줄일 수 있게 되었다.