• Title/Summary/Keyword: VOCs in air

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Efficiency Evaluation of Adsorbents for the Removal of VOC and NO2 in an Underground Subway Station

  • Son, Youn-Suk;Kang, Young-Hoon;Chung, Sang-Gwi;Park, Hyun-Ju;Kim, Jo-Chun
    • Asian Journal of Atmospheric Environment
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    • v.5 no.2
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    • pp.113-120
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    • 2011
  • Adsorbent combination studies have been carried out to remove nitrogen dioxide ($NO_2$) and volatile organic compounds (VOCs: BTEX) out of a subway environment characterized by high flow and low concentration. Optimal conditions for the high removal efficiency of the concerned target compounds were obtained through testing a series of control factors such as adsorbent sorts, thicknesses, and superficial velocity. It was found that the efficiencies increased as the specific surface area of activated carbon and its thickness increased, and external void fraction decreased. Furthermore, mixed activated carbon with granular and constructed contents was extensively tested to reduce pressure drop through the carbon bed. It was found that the performance of higher contents of granular activated carbon was better than that of higher contents of the constructed carbon. When the mixed carbon was applied to the subway ventilation system in order to eliminate $NO_2$ and VOC simultaneously, the removal efficiencies were found to be 75% and 85%, respectively.

Removal Characteristics of Soot and NO by Nonthermal Plasma and Radical in a Diesel Engine (비열플라즈마와 라디칼을 이용한 디젤엔진의 매연 및 NO 제거 특성)

  • Jang, Yeong-Jun;Choe, Seung-Hwan;Kim, Gyu-Bo;Jeon, Chung-Hwan
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.26 no.4
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    • pp.547-554
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    • 2002
  • We are facing the serious environmental pollution difficulties such as acid rain, green house effects, etc. The gaseous matter NOx, SOx, VOCs which are regarded as main factors for these current pollutions are mainly emitted from power plants and vehicles. Therefore several leading countries are regulating the emissions strictly, especially the exhaust emissions from a Diesel engine without an aftertreatment device. The objective of this study is to find out soot and NO removal characteristics focused on the emissions of a Diesel engine by using nonthermal plasma for each engine speeds and loads. Electrostatic precipitator(wire-to-plate type reactor) is used for soot removal. Radicals generated from outer air and put into a mixing chamber in the end of exhaust line are used for NO removal. Concentration of exhaust emissions is analyzed from the gas analyzer(KaneMay) and FTIR to estimate by-products.

Soybean-based Green Adhesive for Environment-friendly Furniture Material

  • Jeon, Ji-Soo;Lee, Jeong-Hun;Kim, Su-Min
    • Journal of the Korea Furniture Society
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    • v.22 no.3
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    • pp.174-182
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    • 2011
  • Over the last decade, Sick Building Syndrome has become a significant social issue in Korea and many methods have been considered to maintain comfortable indoor air quality. To reduce toxic substances emitted from wood composite products, the source control is an efficient method through the reduction of formaldehyde content by using natural material-based adhesives for composite wood products production. Among alternative materials, soybean protein is considered an appropriate natural material to replace formaldehyde-based resin and many efforts have been made to produce new products, such as soap, shampoo, ink, resin, adhesive and textile through changing the chemical or physical properties of soybean. To process soybeans into these useful products, the beans are dehulled and the oil is removed by crushing at very high pressure or by solvent extraction. For use soybean as an adhesive, it is processed at temperatures below $70^{\circ}C$ to preserve the alkaline solubility of the proteins. In addition, soybean-based adhesive is undergone treatment process to improve mechanical properties using urea, urease inhibitor N-(n-butyl) thiophosphoric triamide and sodium dodecyl sulfate. The modified soybean-based adhesive exhibited sufficient mechanical properties to use as an adhesive for composite wood products. This paper is a review article to discuss the possibilities of soybean-based adhesive for environment-friendly furniture materials.

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Development and efficiency evaluation of 30kW scale syngas cogeneration system (30kW 급 합성가스 열병합 시스템 개발 및 효율 성능평가)

  • Park, Il-Gun;Kim, Sang-Tae;Noh, Gwi-Sung
    • Journal of the Korean Applied Science and Technology
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    • v.36 no.4
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    • pp.1427-1433
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    • 2019
  • In this paper, Gas engine was tested for the energy of synthesis gas. As excess air ratio increase 1, 1.1, 1.2, 1.3, 1.4, 1.5, 1.6 in 1800 rpm and synthesis gas, thermal efficiency generally decrease and power generation was 34 kWm at λ 1.4. And excess air ratio increase 1, 1.1, 1.2, 1.3, 1.4 in power generation 34 kWm, thermal efficiency generally increase 34.2%, 36.9%, 37.2%, 37.4%, 38.1%. Total efficiency through power generation consumes 38.7 kg/h of fuel at 30 kWe load and recovers 57.3% of waste heat by recovering 57.3 kW of waste heat through 32.1% power generation efficiency and heat recovery from cooling water and exhaust gas. The total efficiency was 85.8%.

Emission Factor of Hazardous Air Pollutants in Gas-phase from Light Commersial Vehicle using PEMS on Real-road Driving (실도로 주행에서 PEMS를 이용한 소형 경유 상용차의 가스 상 유해대기오염물질 배출계수 연구)

  • Lim, Ji Hye;Han, Sang Woo;Kim, Jeong;Jang, Young Kee;Chon, Mun Soo;Hwang, Sung Chul;Kim, Joung Hwa;Jung, Sung Woon;Kim, Jeong Soo;Han, Jin Seok
    • Journal of Korean Society for Atmospheric Environment
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    • v.34 no.2
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    • pp.191-206
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    • 2018
  • In this study, the HAPs(Harzard Air Pollutants) emission factor level of Starex and Grand Carnival was tested using PEMS (Portable Emissions Measurement System) on real road driving. As a result of RDE (Real Driving Emission test), the overall vehicle speed pattern showed similar characteristics. The real-road driving test at constant speed revealed emission factor is inversely proportional relationship to constant speed. Results of accelerating with speed limit on the real-road were shown as followings; Uran (less than 45 km/h)>Rural (<45 km/h, less than 80 km/h)>Motorway (>80 km/h). Moreover, the sudden acceleration and deceleration in driving at high speed was the increasing factor to the HAPs emission factor. This tendency is considered to be influenced by the operating environment on real roads.

An Ozone-based Advanced Oxidation Process for an Integrated Air Pollution Control System (복합대기오염 저감 시스템을 위한 오존 고속산화 기반 고도산화공정)

  • Uhm, Sunghyun;Hong, Gi Hoon;Hwang, Sangyeon
    • Applied Chemistry for Engineering
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    • v.32 no.3
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    • pp.237-242
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    • 2021
  • Simultaneous removal technologies of multi-pollutants such as particulate matters (PMs), NOx, SOx, VOCs and ammonia have received consistent attention due to the enhancement of pollutant abatement efficiency in addition to the stringent environmental regulation and emission standard. Pretreatment of insoluble NO by an ozone oxidation can be considered to be more effective route for saving space occupation as well as operation cost in comparison with that of traditional selective catalytic reduction (SCR) process. Moreover the primary advantage of ozone oxidation process is that the simultaneous removal with acidic gas including SOx is also available. Herein, we highlight recent studies of multi-pollutant abatement via ozone oxidation process and the promising research topics for better application in industrial sectors.

Development of a building materials database; Volatile organic compounds, formaldehyde emission rates and chemical compositions (건축자재의 오염물질 방출 데이터베이스 개발; 휘발성유기화합물, 폼알데하이드 방출강도 및 화학조성)

  • Yu, Young-Jae;Lee, Chul-Won;Kim, Man-Goo
    • Analytical Science and Technology
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    • v.22 no.1
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    • pp.57-64
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    • 2009
  • A material database has been developed for VOCs and formaldehyde emitted from building materials in this study. New classification system has been made by correlating the classification methods used in Korean Air Cleaning and Environmental Protection Agency. The developed databases include emission rates of TVOC, 5VOC and formaldehyde emitted from each building material. In addition, the databases can be used as an input variable to estimate indoor air quality (IAQ) using computer simulation since they also contain chemical component and general imformation. Box plot was used to do statistical analysis for emission rates of formaldehyde and TVOCs from different types of building materials. Also we confirmed the building materials worsening IAQ by categorizing the emission characteristic of different types of pollutants.

Inhalation and Dermal Exposures to Chloroform while Bathing (목욕시 Chloroform에 대한 흡기 및 피부 접촉 노출)

  • 조완근
    • Journal of Environmental Science International
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    • v.7 no.3
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    • pp.301-310
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    • 1998
  • Recently, bathes have been suspected to an Important source of indoor exposure to volatile organic compounds(VOCs). Two experiments were conducted to evaluate chloroform exposure and corresponding body burden by exposure routes while bathing. Another experiment was conducted to ekamine the chloro- form dose during dermal exposure and the chloroform decay In breath after dermal exposure. The chioroform dose was determined based on exhaled breath analysis. The ekamine breath concentration measured after normal baths (2.8 Vg/$m^3$) was approxidmately 13 tomes higher that measured prior to normal bathes (0.2 ug/$m^3$). Based on the means of the normalized post exposure chloroform breath concentration. the dermal exposure was estimated to contribute to 74% of total chloroform body burden while bathing. The Internal dose from bathing (Inhalation plus dermal) was comparable to the dose ostimated Srom dally water Ingestion. The rusk associated 10 a weekly, 30-min bath was estimated to be 1 x 10.5, while the rusk firom dally Ingestion of tap water was to be $0.5{\times}0^{-5} for 0.151 and 6.5{\times}10^{-5}$ for 2. 0 1. Chloroform breath concentration Increased gradually during the 60 minute dermal exposure. The breath decay after the dermal exposure showed two-phase mechanism, with early raped decay and the second slow decay. The mathematical model was developed to describe the relationship between water and air chloroform concentrations, with $R^2$ : 0.4 and p<0.02.

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Effect of the Thermal Etching Temperature and SiO2/Al2O3 Ratio of Flexible Zeolite Fibers on the Adsorption/desorption Characteristics of Toluene

  • Ji, Sang Hyun;Yun, Ji Sun
    • Korean Journal of Materials Research
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    • v.29 no.3
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    • pp.143-149
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    • 2019
  • To develop flexible adsorbents for compact volatile organic compound (VOC) air purifiers, flexible as-spun zeolite fibers are prepared by an electrospinning method, and then zeolite particles are exposed as active sites for VOC (toluene) adsorption on the surface of the fibers by a thermal surface partial etching process. The breakthrough curves for the adsorption and temperature programmed desorption (TPD) curves of toluene over the flexible zeolite fibers is investigated as a function of the thermal etching temperature by gas chromatography (GC), and the adsorption/desorption characteristics improves with an increase in the thermal surface etching temperature. The effect of acidity on the flexible zeolite fibers for the removal of toluene is investigated as a function of the $SiO_2/Al_2O_3$ ratios of zeolites. The acidity of the flexible zeolite fibers with different $SiO_2/Al_2O_3$ ratios is measured by ammonia-temperature-programmed desorption ($NH_3-TPD$), and the adsorption/desorption characteristics are investigated by GC. The results of the toluene adsorption/desorption experiments confirm that a higher $SiO_2/Al_2O_3$ ratio of the flexible zeolite fibers creates a better toluene adsorption/desorption performance.

A Survey on Characteristics of Distribution for Indoor Air Pollutants in Museum Environments (박물관내 실내공기오염물질의 분포 특성 실태조사)

  • Kim, Yoon-shin;Roh, Young-man;Yoon, Young-hun;Lee, Cheol-min;Kim, Ki-yeon;Kim, Jong-cheol;Jeon, Hyoung-jin;Sim, In-suk
    • 보존과학연구
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    • s.28
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    • pp.91-104
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    • 2007
  • The goal of this study was to provide basic data for arrangement of management in museum environment. We investigated characteristics of distribution on indoor air pollutants at exhibition halls and storages in museums between July and August, 2007. The monitoring carried out at three cultural sites, Pusan, Daejeon and Kyungjoo which is possessed their own exhibition hall and storage in Museums. We adopt the several pollutants for this survey such as $PM_{10}$, $PM_{2.5}$ $CO_2$, Formaldehyde, TBC, CO, $NO_2$, Rn, VOCs, $O_3$ and followed the standard method of Ministry of Environment, Korea for sampling and analysis, respectively. The results of this survey revealed that average concentration of $PM_{10}$ and $PM_{2.5}$ in storages were $117.3{\mu}g/m^3$ and $92.6{\mu}g/m^3$, respectively. The average concentration in storages of gases pollutants and microorganism such as $CO_2$, Formaldehyde, $NO_2$, Rn, TVOC, $O_3$, and TBC showed as: 788.8ppm, $30.7{\mu}g/m^3$, 0.4ppm, 6.4ppb, $1.3pCi/{\ell}$, $1,374.9{\mu}g/m^3$, 2.4ppb, and $119.4cfu/m^3$, respectively. In addition, average concentration of $PM_{10}$ and $PM_{2.5}$ in exhibition halls were $49.5{\mu}g/m^3$ and $56.1{\mu}g/m^3$, respectively. The average concentration in exhibition halls of gases pollutants and microorganism such as $CO_2$, Formaldehyde, $NO_2$, Rn, TVOC, $O_3$, and TBC showed as: 475.2ppm, $94.1{\mu}g/m^3$, 0.3ppm, 12.4ppb, $0.3pCi/{\ell}$, $1,179.1{\mu}g/m^3$, 5.2ppb, 2.4ppb, and $24.8cfu/m^3$, respectively.

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