• Journal of Environmental Health Sciences
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• v.43 no.6
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• pp.509-515
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• 2017

Objectives: The purpose of this study was to assess the indoor levels of $PM_{10}$, VOCs and aldehydes in nail shop and hair salon. Methods: The field survey was conducted for 52 hair salons 52 nail shops, and 26 shop-in-shops in Seoul and Daegu city. The field technicians investigated characteristics of each shop including operating time, indoor volume, ventilation and so on. Indoor concentrations of $PM_{10}$, VOCs and aldehydes, indoor temperature and humidity were measured in 12 hair salons, 12 nail shops and 6 shop-in shops. MP Surveryor II (Graywolf, USA) was used to measure $CO_2$ concentration, temperature and humidity for 8 hours. $PM_{10}$ concentrations were measured by minivolume air sampler with Teflon quartz filter ($0.2{\mu}m$ pore size, ${\varphi}$ 47 mm, Graseby-Anderson TEF-DISKTM) for 6 hours. VOCs passive sampler (OVM 3500) was used to collect VOCs for 8 hours and analyzed by GC/MSD. Results: The $CO_2$ concentrations were $759.4{\pm}58.2$ ppm in nail shops, $731.0{\pm}72.5$ ppm in hair salons, and $656.4{\pm}31.2$ ppm in shop-in-shops. The $PM_{10}$ concentrations were $27.5{\pm}14.2{\mu}g/m^3$ in nail shops, $33.1{\pm}6.3{\mu}g/m^3$ in hair salons, and $39.0{\pm}26.9{\mu}g/m^3$ in shop-in-shops. TVOCs concentrations were $3085.4{\pm}1667.8{\mu}g/m^3$ in nail shops, $2131.1{\pm}617.3{\mu}g/m^3$ in hair salons, and $1550.3{\pm}529.0{\mu}g/m^3$ in shop-in-shops. TVOCs concentrations in nail shops were significantly higher than those in hair salons and shop-in-shops (p=0.002). Formaldehyde concentrations were $60.8{\pm}36.6{\mu}g/m^3$ in nail shops, $89.1{\pm}55.4{\mu}g/m^3$ in hair salons, and $45.1{\pm}22.5{\mu}g/m^3$ in shop-in-shops. Conclusion: TVOCs concentrations in nail shop were the highest among others. TVOC concentrations in all stores exceeded indoor air quality stand of indoor air quality control in public-use facilities, etc act.

• International Journal of Air-Conditioning and Refrigeration
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• v.13 no.2
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• pp.89-98
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• 2005

In this study, indoor VOCs concentration emitted from floor and furniture was measured after the installation of floor and furniture in a real residence. With the measured data, prediction method and predication equations for indoor concentration of each VOCs and BTEX were developed. The following conclusions were drawn from this study. First, according to the predicted results of concentration decrease of BTEX (benzene, toluene, ethylbenzene, m,p,o-xylene) after the installation of floor in a real residence, prediction equation can be expressed using exponential function. Second, in case of floor, more reliable prediction equation can be obtained by using cumulative value of indoor concentration than by using just hourly measured value directly. Indoor concentration of benzene can be expressed as $y=408.52(1­e^{-00031{\times}time})$ with $R^2$ of 0.94 which is significantly high value. Third, toluene showed the highest concentration in case of furniture installation indoors, and it needed the longest time for concentration decrease. However, other substances except toluene showed constant concentration throughout the measurement period. Fourth, in case of furniture installation indoors, prediction equation of toluene concentration decrease is estimated to be $y= 3616.3{\times}e^{(-0.1091{\times}time)}+513.96{\times}e^{(-0.0006{\times}time)}\;with\; R^2$ of 0.95 which is significantly high value.

• Proceedings of the SAREK Conference
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• 2008.06a
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• pp.742-747
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• 2008

Formaldehyde(HCHO) and total volatile organic compounds(VOCs) can cause adverse health effects to the building occupants and may contribute to symptoms of 'Sick Building Syndrome'. These chemical contaminants are emitted from furnishings and electronic equipments as well as building materials. The purpose of this study is to measure and analyze VOCs and HCHO emission concentration from furnitures composed of wood materials including various chemicals by the large chamber method. This paper presents experiment results on the emission concentration of TVOCs and HCHO released from furnitures, such as bed, kitchen, sofa and table by a large chamber($24m^3$). The temperature and air humidity in the chamber are controlled to $25{\pm}1{\circ}C$ and $50{\pm}5%$ for this experiment. When the air change rate is $0.5hr^{-1}$, the background concentrations within the large chamber are below $50{\mu}g/m^3$ for TVOC, $5{\mu}g/m^3$ for HCHO and individual VOCs. The study is investigated the characterization of the chemical emission TVOC and HCHO concentrations and unknown VOCs from 6 furnitures.

• Proceeding of Spring/Autumn Annual Conference of KHA
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• 2004.11a
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• pp.319-322
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• 2004

The purpose of this study is to evaluate the reduction effect of bake out on the concentration of indoor air pollutants by measuring the concentration of indoor pollutants(VOCs, HCHO) after the bake out. As a result of the study, bake out was considerably effective in reducing the concentration o( indoor air pollutants, showing relatively high reduction ratio around 40${\sim}$56%. However, continuous attention and control after the bake out is required for the prevention of the rise of the concentration by subsequent emission.

• Analytical Science and Technology
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• v.16 no.1
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• pp.1-11
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• 2003

This research examined the presence of hazardous materials in chemical workplace field using an integrated chemical/biological monitoring. Chemical workplace field air for volatile organic compounds (VOCs) analysis was collected using a collection tube packed with Tena.x TA adsorbent 400 mg. Workplace field air samples were analyzed by gas chromatography/mass spectrometry (GC/MS). Simultaneously, Tradescantia BNL 4430 clone was exposed in situ to monitor hazardous materials in chemical workplace field. GC/MS analysis showed the presence of various VOCs such as trichloroethylene, toluene, ethylbenzene, (m,p,o)-xylenes, styrene, 1,3,5-trimethylbenzene, and 1,2,4-trimethylbenzene. The results showed that in situ monitoring of VOCs with the Tradescantia-micronucleus (Trad-MCN) assay gave positive results in chemical workplace field and negative response at outdoor air. In conclusion, inhalation of these field air by workers may affect chronic demage to their health by inducing micronuclei formation in Tradescantia pollen mother cells. The combination of chemical/biological monitoring is very effective to evaluate hazardous materials in workplace field and can be alternatively used for screening hazardous materials.

• Journal of environmental and Sanitary engineering
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• v.16 no.4
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• pp.69-76
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• 2001

The catalytic oxidation of volatile organic compounds (VOCs), which were benzene and toluene, was studied in the supercritical carbon dioxide($SC-CO_2$) media. In $SC-CO_2$ media, the deep oxidation conversion of VOCs was increased with the temperature and pressure. The deep oxidation conversion in SC -$CO_2$ media is better than that in air media at same pressure condition. This can be explained by the solubility of VOCs in $SC-CO_2$. The many intermediates produced by the partial oxidation of VOCs were detected from off-line samples. The intermediates were Identified as benzene, toluene, benzaldehyde, phenol, naphthalene, 1,1`-biphenyl, benzoic acid, 3-methylphenol, 1,1'-(1,2-ethanediyl)bis- benzene, 1,1'-(1,2-ethene- diyl)bis-benzene, anthracene, and so on. The amount of intermediates was decreased as the molar radio of oxygen to carbon dioxide was decreased. When the molar ratio of oxygen to carbon dioxide was 1 : 16, the deep conversion was kept constant. Thus, the catalytic oxidation process in $SC-CO_2$ media can be combined on-line with supercritical fluid extraction of environmental matrices and supercritical regeneration of used adsorbent. Thus, the nontoxic $SC-CO_2$ media process was suggested as the new VOCs control technology.

• Journal of Environmental Science International
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• v.1 no.1
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• pp.41-46
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• 1992

To perform a long-term ambient sampling study at a residential site, an air sampler was constructed to collect 24-hour integrated air samples suitable for the volatile organic compounds (VOCs) analysis. It includes an esthetically acceptance due to proximity to homes, as fell as providing the required sampling specifications. The VOCs sampler accomodates four 5/8 "stainless steel(SS) traps packed with adsorbent(Tenax) and is capable of four flow rates in the range of 5 to 50 cc/min. Sintered metal filters(10 micrometer) were directly connected to the inlet of the trap adapters. Additional specifications include: 1) constructed of organically inert materials, 2) weatherproof, 3) battery operated, 4) collecting of VOCs at a breathing zone level, and 5) quiet operation with micro diaphragm pumps wrapped by the sponge. The pump/battery system was separated from the sampling shelter. Sound levels measured for this system were below permissible sound levels (NJDEP) at a residential site. The sampler has been successfully operated at both ground level in a residential area and on the roof of a one story elementary school.hool.

• Journal of Environmental Health Sciences
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• v.44 no.3
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• pp.250-258
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• 2018

Objectives: The study examined indoor air quality during daytime and commute times in underground parking lots in five apartments located in northern Gyeonggi province. Methods: This study examined the temporal characteristics of $PM_{10}$, $CO_2$, CO, HCHO and VOCs in the indoor air quality of the underground parking lots in five apartments. Results: $PM_{10}$ concentration in daytime were ranged from 37.4 to $69.9{\mu}g/m^3$ which complied with the indoor air quality maintenance standard ($200{\mu}g/m^3$) and Gyeonggi province ordinance standard ($180{\mu}g/m^3$). However $PM_{10}$ concentrations in commuting time were in range of $447.3{\sim}944.0{\mu}g/m^3$ that exceeded for both criteria. The $CO_2$, CO and HCHO concentrations complied with the standard. The VOCs indicated high tendency in the order of toluene, xylene, ethylbenzene and benzene. This tendency was more apparent in commuting time than daytime. Conclusion: All indoor parking lots of five apartments were equipped with ventilators. However the most apartment residents did not operate blowers to save electricity and the lack of interest for indoor air quality. In order to improve the indoor air quality of underground parking lots in apartment, operating ventilation system during commuting time is recommended.

• 한국연소학회:학술대회논문집
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• 1998.10a
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• pp.31-36
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• 1998

An experimental study has been performed to characterize fundamental aspects of VOCs removal using non-thermal palsma technique. The removed VOCs in the present study are toluene ($C_6H_5CH_3$), ethene ($C_2H_4$), propene ($C_3H_6$) which are typical air pollutants generated from industry and automobile engines. The non-thermal plasma used in the present experiments has been produced in a wire-cylinder reactor with pulsed corona or a packed-bed reactor filled with ceramic bead. These differently generated non-thermal plasma have been visualized with an intensified CCD. The images of non-thermal plasma have been used for optimal design of a corona reactor used in the present study. The experimental results show that the removal efficiencies of VOCs with non-thermal plasma are dependant on the reactivity of VOCs with OH, O, and $O_3$. The results also show that the removal efficiencies of VOCs decrease significantly when VOCs are treated with NO that is also oxidized in the presence of OH, O, and $O_3$.

• Journal of Korean Society for Atmospheric Environment
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• v.30 no.6
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• pp.586-599
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• 2014

During the last two decades, indoor air quality and volatile organic compounds (VOCs) have been of concern in Korean society due to their nature of potential health impacts. In order to investigate the pollution levels of VOCss in indoor environments, establishment of a solid test method for monitoring the airborne VOCss is essential. In Korea, a method based on adsorbent sampling and GC analysis coupled with thermal desorption was proclaimed as the Korea Standard Method for Indoor Air Quality Test. This study was carried out to examine some inherent problems of the VOCs measurement method. The VOCs method does not describe in detail preparing the standard samples. The standard samples may be prepared by impregnation of either liquid standard solutions or a mixture of standard gases. In this study, we investigated the optimal temperature condition for transferring the liquid standards onto a standard adsorbent tube. As a result, keeping the impregnation temperature at $250^{\circ}C$ will be recommended in regard of the boiling points of multiple target analytes and the thermal stability of the adsorbent. We also demonstrated some problems associated with handling of a syringe used for transferring the standard solutions onto the adsorbent tubes, and a best way to get rid of the syringe problems was suggested. Finally, a number of field works were conducted to evaluate the performance of adsorbent sampling methods. Comparison of different adsorbent tubes, i.e. tube packed with single sorbent (Tenax) and double sorbents (Tenax with Carbotrap), revealed that 30 to 40% differences between the two groups, implying that sampling efficiency is depending on the volatility and the strength of adsorbents. However, duplicate precisions for VOCs sampling with a same type of adsorbent and at same flow rates appeared to be satisfactory to be all within 20%, which is a quality control guideline. Distributed volume precisions were also found to be within a guideline value, 25%, although the precision was in general inferior to the duplicate precision. The Korea indoor VOCs test method should be more refined and improved in many aspects, particularly procedure and instrumentation for preparing the standard samples and specification of quality control assessment.