• Title/Summary/Keyword: VOC emission

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Long-term Changes in VOCs Emission of Finished Pine (Pinus rigida) Panels (도장처리 소나무 판재에서 방출되는 휘발성유기화합물의 경시변화)

  • Lee, Min;Lee, Sang-Min;Kang, Eun-Chang;Kang, Yeong-Seok;Park, Sang-Bum
    • Journal of the Korea Furniture Society
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    • v.27 no.4
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    • pp.335-342
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    • 2016
  • In previous study, volatile organic compounds (VOCs) emission characteristics were highly affected by coating materials for wood finishing. Natural based coating materials showed that about 15~46% lower TVOC emission than typical products. In this study, long-term changes of VOCs emission characteristics from pine panel with three types of coating treatments were determined. Non-treated pine panel emitted $604.7{\mu}g/m^2{\cdot}h$ of TVOC that contained 66% of NVOC ($399.7{\mu}g/m^2{\cdot}h$) at 0 month. After 10 month, TVOC reduced 88% and 93% reduction on NVOC was observed. Natural oil and waterborne stain treated pine panel showed 61% and 77% lower TVOC, respectively, than non-treated pine panel. However, TVOC from finished pine panels showed higher TVOC emission than non-treated pine panel. All samples satisfied the VOC emission regulation (below $4,000{\mu}g/m^2{\cdot}h$) by Korean Ministry of Environment. Toluene emission regulation (below $80{\mu}g/m^2{\cdot}h$) was passed on all sample without varnish treated pine panel at 0 month. According to HB qualification standard for construction materials by Korea Air Cleaning Association (KACA), wood is not qualified to get the best tag due to high TVOC emission. At the 10 months, only non-treated pine panel could get the best tag of HB from KACA.

Characteristics of the Emissions and Concentrations of Air Pollutants with Change in Traffic Volume during the Beach Opening Period in Busan (부산지역 해수욕장 개장시 교통량 변화에 따른 대기오염물질 배출량 및 농도 특성 분석)

  • Seo, Woo-Mi;Shon, Zang-Ho;Song, Sang-Keun
    • Journal of Environmental Science International
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    • v.21 no.9
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    • pp.1149-1162
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    • 2012
  • The impact of a considerable increase in traffic volume on the emission and concentrations of air pollutants was investigated at three beaches (Haeundae (HB), Gwanganri (GB), and Songjeong (SB)) in Busan during beach opening period (BOP) in 2011. During the BOP, passenger car was the major vehicle type, followed by taxi, and van. CO was the major contributor of total air pollutant emissions followed by NOx, VOC, and $PM_{10}$. For the temporal variation of the emission of air pollutants during the BOP, it was generally the highest in the afternoon followed by the evening and morning, except for SB. For the spatial variation of their emission, it was the highest at GB followed by SB and HB. The emissions of air pollutants during the BOP were generally higher than those during the Non-BOP, except for HB. In contrast, the significant impact of the traffic volume increase on the concentrations of air pollutants at monitoring sites near the three beaches during the BOP were not found compared to the Non-BOP due to the significant distances between monitoring sites of air pollutants and monitoring sites of traffic volume at the beaches.

A Prediction of Pollutant Emission Rate using Numerical Analysis and CFD in Double-Layered Building Materials (수치해석 및 CFD를 이용한 소형챔버내 복합건축자재의 오염물질 방출량 예측)

  • Kim, Chang-Nam;Leigh, Seung-Bok;Kim, Tae-Yeon
    • Proceedings of the SAREK Conference
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    • 2006.06a
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    • pp.277-282
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    • 2006
  • In order to predict the indoor air pollutant, the VOCs emission rate is used through small chamber in the design process. However, the small chamber method has limitations as the convective mass transfer coefficient, the most important factor when predicting VOCs contamination of indoor air, is different between the small chamber result and the measured data in the actual building. Furthermore, the existing studies which analyzed mass transfer coefficient in the small chamber were directed on the small chambers developed at the time and FLEC(Field and Laboratory Emission Cell), thus, are different from the current small chamber which has been changed with improvements. The purpose of this study is to determine the emission rate of pollutant in double-layered building materials through the CFD(Computational of Fluid Dynamics) and Numerical analysis based on the mass transfer coefficient on singled-layered building material by using the current small chamber widely used in Korea. Futhermore, this study used the new convective mass transfer coefficient($h_m'$) which indicates the existing convective mass transfer coefficient($h_m$) including VOC partition coefficient(k). Also, formaldehyde was selected as target pollutant.

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A comparison study on Isoprene emission rates from various Oak trees (참나무 수종별 Isoprene 배출속도 비교)

  • 김조천;임용재;선우영;김기준;홍지형
    • Proceedings of the Korea Air Pollution Research Association Conference
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    • 2003.11a
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    • pp.94-95
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    • 2003
  • 인간의 활동에 의해 생성되고 배출되는 휘발성유기화합물질(VOCs : Volatile Organic Compounds)들의 대기화학적 역할과 그 중요성은 최근 많은 나라에서 커다란 관심의 대상이 되고 있다. 산림은 대기 중으로 유입되는 자연 VOC(NVOC)의 주요 배출원이다. 우리나라의 경우 산림과 농경지가 각각 전국토의 65%, 20%를 차지한다는 점을 감안하면 산림이 NVOC의 주요 배출원일 것으로 추정할 수 있으며 특히, 반응성이 강한 탄화수소의 배출원이란 점은 중요한 의미를 지닌다. 전 세계적으로 NVOC의 배출량이 인위적인 것의 약 7배 정도에 이를 것으로 추정되고 있다. (중략)

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Emission Characteristics of VOCs Using GIS (GIS를 이용한 휘발성유기화합물의 배출특성)

  • 정장표;이승훈;이승묵
    • Proceedings of the Korea Air Pollution Research Association Conference
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    • 2000.04a
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    • pp.62-64
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    • 2000
  • 최근 급속한 경제성장으로 인한 국민복지의 향상과 생활공간의 확대 등으로 인한 인간활동에서 발생된 인위적 화학물질은 여러 형태로 대기로 배출되고, 또한 여러 가지 화학반응을 일으켜 환경오염의 유발 및 악화를 초래한다. 그 중에서도 자동차 보급의 급증으로 인한 유류 및 유기용제의 사용 확대로 VOCs (Volatile Organic Compounds)의 배출량이 증가하고 있으며, 이로 인하여 여러 가지 형태의 대기오염피해가 가중되고 있는 실정이다. VOCs는 오존전구물질 뿐만 아니라, 인체 위해도에 크게 기여하고 있다. (중략)

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Application of Field and Laboratory Emission Cell (FLEC) to Determine Formaldehyde and VOCs Emissions from Wood-Based Composites

  • Kim, Sumin;Kim, Jin-A;Kim, Hyun-Joong
    • Journal of the Korean Wood Science and Technology
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    • v.35 no.5
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    • pp.24-37
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    • 2007
  • The Korean Ministry of Environment started controlling indoor air quality (IAQ) in 2004 through the introduction of a law regulating the use of pollutant emitting building materials. The use of materials with formaldehyde emission levels above $1.25 mg/m^2{\cdot}h$ (JIS A 1901, small chamber method) has been prohibited. This level is equivalent to the $E_2$ grade ($>5.0mg/{\ell}$) of the desiccator method (JIS A 1460). However, the $20{\ell}$ small chamber method requires a 7-day test time to obtain the formaldehyde and volatile organic compound (VOC) emission results from solid building interior materials. As a approach to significantly reduce the test time, the field and laboratory emission cell (FLEC) has been proposed in Europe with a total test time less than one hour. This paper assesses the reproducibility of testing formaldehyde and TVOC emissions from wood-based composites such as medium density fiberboard (MDF), laminate flooring, and engineered flooring using three methods: desiccator, perforator and FLEC. According to the desiccator and perforator standards, the formaldehyde emission level of each flooring was ${\le}E_1$ grade. The formaldehyde emission of MDF was $3.48 mg/{\ell}$ by the desiccator method and 8.57 g/100 g by the perforator method. To determine the formaldehyde emission, the peak areas of each wood-based composite were calculated from aldehyde chromatograms obtained using the FLEC method. Formaldehyde, acetaldehyde, propionaldehyde, butyraldehyde and benzaldehyde were detected as aldehyde compounds. The experimental results indicated that MDF emitted chloroform, benzene, trichloroethylene, toluene, ethylbenzene, m,p-xy-lene, styrene, and o-xylene. MDF emitted significantly greater amounts of VOCs than the floorings did.

Emission Reduction of Air Pollutants Produced from Chemical Plants

  • Lee, Byeong-Kyu;Cho, Sung-Woong
    • Journal of Korean Society for Atmospheric Environment
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    • v.15 no.E
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    • pp.29-38
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    • 1999
  • This study identified emission sources and emissions of air pollutants such as volatile organic compounds (VOCs), solvents, and acid gases produced from chemical plants. We collected air samples from various processes, reactors and facilities using VOC detectors and workers' experience. We identified chemical structures and emission concentrations of air pollutants. We analyzed total emissions of air pollutants emitted from the chemical plants. Also, we developed some emission reduction technologies based on chemical types and emission situations of the identified air pollutants. For reduction of air emissions of acid gases, we employed a method improving solubility of pollutants by reducing scrubber operation temperature, increasing surface area for effective contact of gas and liquid, and modifying or changing chemicals used in the acid scrubbers. In order to reduce air emissions of both amines and acid gases, which have had different emission sources each other but treated by one scrubber, we first could separate gas components. And then different control techniques based on components of pollutants were applied to the emission sources. That is, we first applied condensation and then acid scrubbing method using H2SO4 solution for amine treatment. However, we only used an acid scrubbing method using H2O and NaOH solution for acid gas treatment. In order to reduce air emissions of solvents such as dimethylformamide and toluene, we applied condensation and activated carbon adsorption. In order to reduce air emissions of mixture gases containing acid gases and slovents, which could not be separated in the processes, we employed a combination of various air pollution control devices. That is, the mixture gases were passed into the first condenser, the acid scrubber, the second condenser, and the activated carbon adsorption tower in sequence. In addition, for improvement of condensation efficiency of VOCs, we changed the type of the condensers attached in the reactors as a control device modification. Finally, we could successfully reduce air emissions of pollutants produced from various chenmical processes or facilities by use of proper control methods according to the types and specific emission situations of pollutants.

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Evaluation and Improvement of Diesel Retrofit Program in Gyeonggi-do (경기도 운행차 저공해화 사업의 성과분석 및 발전방안)

  • Kim, Dong-Young;Choi, Min-Ae
    • Journal of Korean Society for Atmospheric Environment
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    • v.28 no.2
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    • pp.203-210
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    • 2012
  • The purpose of this study is to evaluate the diesel retrofit program which have been proceeded for the last 7 years in Gyeonggi-do. Diesel retrofit programs in Gyeonggi-do consist of the attachment of DPF (Diesel Particulate Filter), p-DPF (partial-DPF) and DOC (Diesel Oxidation Catalyst), switching to LPG engine, scraping an old cars. Emission reduction by diesel retrofit program was estimated $N_2O$ 8,313.4 ton/year, PM10 3,626.4 ton/year, VOC 8,078.5 ton/year in 2010. The benefit-cost analysis shows that the 964 billion wons of benefits are greater than the 853 billion wons of total costs. Diesel retrofit programs could be one of the most effective measures to improve PM10 concentration in metropolitan area. But retrofit programs also need to be properly maintained by each vehicle.

GHG-AP Integrated Sink/Emission Inventories and Environmental Value Analysis in Vegetation Sector of Seoul (서울시 식생부문 온실가스-대기오염 통합 흡수/배출량 인벤토리 및 환경가치분석)

  • Jung, Jaehyung;Kwon, O-Yul
    • Journal of Korean Society for Atmospheric Environment
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    • v.31 no.1
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    • pp.72-82
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    • 2015
  • We constructed greenhouse gas (GHG) and air pollution (AP) integrated sink/emission inventories and evaluated the environmental value for the vegetation sector in Seoul during year 2010. The data of vegetation, classified into four sectors of cultivated land, forest land, park and street tree, were obtained from Statistics Korea and Seoul City. Based on the previous studies, only $CO_2$ was chosen as GHG sink by vegetation. $NO_2$ and $SO_2$ were chosen as AP sink by vegetation, while isoprene, monoterpene, other VOC (OVOC) and NH3 were chosen as AP emission from vegetation. Estimation methodology and sink/emission factors were gathered from reports and published literatures. Estimated GHG sink by vegetation during year 2010 was 12,987,173 $tonCO_{2eq}$, of which approximately 1/4 was from pure vegetation and the remaining 3/4 from vegetation soil. AP sink and emission were estimated to be 23,309 tonAP and 2,629,797 tonAP, respectively. The analysis by administrative districts in Seoul revealed that among 25 districts, Seocho-gu, Nowon-gu, Eunpyeong-gu, Gwanak-gu and Gangbuk-gu were the major districts in GHG and AP sink/emission inventories for vegetation sector. Environmental value of vegetation as a function of GHG and AP sink, was estimated as 800 billion won, corresponding to 5% of the total cost of the forest land in Korea evaluated as a public function.