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Characterization of Synthetic Na-beidellite (합성 Na-베이델라이트의 광물특성)

  • Ryu Gyoung-Won;Chae Soo-Chun;Bae In-Kook;Choi Sang-Hoon;Jang Young-Nam
    • Journal of the Mineralogical Society of Korea
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    • v.18 no.2
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    • pp.109-115
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    • 2005
  • Beidellite, a member of the smectite group, was synthesized hydrothermally from dickite. Physical and chemical properties of the synthetic Na-beidellite were characterized by the analytical methods of XRD, IR, TG, DTA, EDS, XRF and ICP. The result of Greene-Kelly test indicates that the synthesized smectite is Na-beidellite. IR spectrum of synthesized beidellite exhibited Al-O-H bending vibration at $818\;cm^{-1}\;and\;770\;cm^{-1}$ which was observed particularly in pure beidellite. TGA analysis revealed that the synthesized Na-beidellite comprises $16\;wt\%$ of water. DTA curve showed an endothermic peak at $117^{\circ}C$ due to dehydration reaction and peaks at $482^{\circ}C$ and $685^{\circ}C$ due to dehydroxylation reaction. The clay mineral was transformed to mullite and cristobalite at the temperature of $1028^{\circ}C$. The CEC value, Methylene Blue test and swelling capacity was determined to be $116\~118\;cmol/kg,\;84\~91\%,\;29\~32\;mL/2g$, respectively. The chemical composition of the synthesized phase was identified as $Na_{0.5}Al_{2.5}Si_{3.5}O_{10}(OH)_2$ from EDS and XRF analyses.

Preconcentration and Determination of Trace Cobalt and Nickel by the Adsorption of Metal-PDC Complexes on the Anion-Exchange Resin Suspension (금속-PDC 착물의 음이온교환 수지 상 흡착에 의한 흔적량 코발트와 니켈의 동시 예비농축 및 정량)

  • Han, Chul-Woo;In, Gyo;Choi, Jong-Moon;Kim, Sun Tae;Kim, Young-Sang
    • Analytical Science and Technology
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    • v.13 no.5
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    • pp.608-615
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    • 2000
  • A determination method of trace nickel and cobalt in water samples was studied and developed by adsorbing their complexes on ion exchange resin suspension. The analytical ions were formed as complexes with a ligand of APDC (ammonium pyrrolidinedithiocarbamate) and adsorbed on anion exchange resin of Dowex 2-X8. After the suspension was filtered out with membrane filter, the complexes were dissolved in HCl solution by an ultrasonic vibrator for ET-AAS determination. Several conditions were optimized as followings. pH of sample solution: 5.0, amount of ligand APDC: more than 430 times in mole ratio, the type and concentration of acid: 0.1 M HCl, and vibration time: 7 minutes. The addition of palladium in the HCl solution could improve the reproducibility and sensitivity by a matrix modification in the absorbance measurement. This procedure was applied for the analysis of three kinds of real water samples. The detection limits equivalent to 3 times standard deviation of blank were Co 0.36 ng/mL and Ni 0.27 ng/mL and recoveries in spiked samples were 99-102% for cobalt and 100-105% for nickel.

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The Effectiveness of Electroglottographic Parameters in Differential Diagnosis of Laryngeal Cancer (후두암 감별진단에 있어 성문전도(Electroglottograph) 파라미터의 유용성)

  • 송인무;고의경;전경명;권순복;김기련;전계록;김광년;정동근;조철우
    • Journal of the Korean Society of Laryngology, Phoniatrics and Logopedics
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    • v.14 no.1
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    • pp.16-25
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    • 2003
  • Background and Objectives : Electroglottography(EGG) is a non-invasive method of monitoring the vocal cord vibration by measuring the variation of physiological impedance across the vocal folds through the neck skin. It reveals especially the vocal fold contact area and is widely used for basic laryngeal researches, voice analysis and synthesis. The purpose of this study is to investigate the effectiveness of EGG parameters in differential diagnosis of laryngeal cancer. Materials and Methods : The author investigated 10 laryngeal cancer and 25 benign laryngeal disease patients who visited at the Department of Otolaryngology, Pusan National University Hospital. The EGG equipment was devised in the author's Department. Among various parameters of EGG, closed quotient(CQ), speed quotient(SQ), speed index(SI), Jitter, Shimmer, Fo were determined by an analysis program made with MATLAB 6.5$^{\circledR}$(Mathwork, Inc.). In order to differentiate various laryngeal diseases from pathologic voice signals, the author has used the electroglottographic parameters using the neural network of multilayer perceptron structure. Results : SQ, SI, Jitter and Shimmer values except those of CQ and Fo showed remarkable differences between benign and malignant laryngeal disease groups. From the artificial neural network, the percentage of differentiating the laryngeal cancer was over 80% in SQ, SI, Jitter, Shimmer except for CQ and Fo. These results indicated that it is possible to discriminate the benign and malignant laryngeal diseases by EGG parameters using the artificial neural network. Conclusion : If parameters of EGG which can reveal for the pathology of laryngeal diseases are additionally developed and the current classification algorithm is improved, the discrimination of laryngeal cancer will become much more accurate.

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A Process Optimization of HVOF on ALBC3 by Experiments Design (실험계획법을 이용한 ALBC3에 대한 고속화염용사의 최적 공정 설계)

  • Kim, Young-Moon;Lim, Byung-Chul;Kim, Min-Tae;Park, Sang-Heup
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.17 no.4
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    • pp.448-453
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    • 2016
  • Erosion and abrasion caused by cavitation damage occur in fluid equipment, such as ships or impellers. Similarly, the equipment damage from noise and vibration can shorten its life. This study analyzed the importance of the parameter characteristics of the process optimization of HVOF (High Velocity Oxygen Fuel spraying), which is generally used in a variety of industries for enhancing the resistibility from the cavitation phenomenon. The surface of the ALBC3 substrate was coated with an amorphous powder as a filler metal according to the experimental design using the Taguchi method, and then the characteristics with each parameter were analyzed using a porosity measurement test. The optimal process conditions was a combustion pressure of 80psi, coating distance of 270mm, gun speed of 200mm/s, and powder feed rate of 25g/min as a result of the HVOF coating by applying the experimental design. The combustion pressure, coating distance and powder feed rate were more than 25% and indicated a similar contribution rate, but the contribution rate of the gun speed was 19%, which was slightly less than the others. The contribution rate with each parameter was only slightly significant. On the other hand, all four parameters were found to be important in the contribution rate aspects of the HVOF coating process.

Performance Improvement of Overpass Bridge by Weight Reduction (고가교 경량화에 따른 성능개선)

  • Kim, Sung Bae;Nam, Sang Hyeok;Kim, Jang-Ho Jay
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.15 no.2
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    • pp.51-60
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    • 2011
  • In this study, structural safety capacity analysis of the overpass railway bridge between Konkuk Univ. and Guui station railroad has been performed. The overpass is expected to have suffered durability reduction by deterioration. The weight reduction of the overpass has been implemented to prevent further durability reduction and to improve performance capacity. To reduce the weight, 3 procedures of replacing concrete soundproofing wall to light-weight soundproofing wall, replacing gravel ballast to concrete ballast, and reducing the weight of trough have been performed. The analysis of static/dynamic behaviors and improved capacity of the light-weighted overpass bridge has been performed. The structural safety verification of the improved structure has been implemented by using rating factors of load carrying capacity of PSC I girder. The results have shown that the deflection has been reduced by 2.6mm and tensile strength has been improved by 1.07MPa, which indicate that the structural capacity has effectively been improved. Also, the natural frequency has improved by approximately 30% where vibration reduction and dynamic behavior improvement have been achieved. Moreover, in the rating factor evaluation based on analysis and test results, an improvement from 1.82 to 1.93 has been observed. Therefore, weight reduction method for the overpass is effective considering overall results.

A Study on Depth Data Extraction for Object Based on Camera Calibration of Known Patterns (기지 패턴의 카메라 Calibration에 기반한 물체의 깊이 데이터 추출에 관한 연구)

  • 조현우;서경호;김태효
    • Proceedings of the Korea Institute of Convergence Signal Processing
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    • 2001.06a
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    • pp.173-176
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    • 2001
  • In this thesis, a new measurement system is implemented for depth data extraction based on the camera calibration of the known pattern. The relation between 3D world coordinate and 2D image coordinate is analyzed. A new camera calibration algorithm is established from the analysis and then, the internal variables and external variables of the CCD camera are obtained. Suppose that the measurement plane is horizontal plane, from the 2D plane equation and coordinate transformation equation the approximation values corresponding minimum values using Newton-Rabbson method is obtained and they are stored into the look-up table for real time processing . A slit laser light is projected onto the object, and a 2D image obtained on the x-z plane in the measurement system. A 3D shape image can be obtained as the 2D (x-z)images are continuously acquired, during the object is moving to the y direction. The 3D shape images are displayed on computer monitor by use of OpenGL software. In a measuremental result, we found that the resolution of pixels have $\pm$ 1% of error in depth data. It seems that the error components are due to the vibration of mechanic and optical system. We expect that the measurement system need some of mechanic stability and precision optical system in order to improve the system.

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Dynamic Behavior Character of Vessel Using DGPS and Motion Sensor (DGPS와 Motion Sensor를 이용한 선박 동적 거동특성)

  • Choi, Chul-Eung;Kim, Youn-Soo
    • Journal of Korean Society for Geospatial Information Science
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    • v.12 no.4 s.31
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    • pp.35-43
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    • 2004
  • Multibeam Echosounder system is the latest technology of a hydrographic survey utilized in producing an electronic nautical chart, obtaining a DEM with high precision, making a moving image by Swath surveying a wide area. As a fundamental study for improving the precision of MBES, we compared and analyzed measurements of DGPS and Motion sensor, and studied for the dynamic characteristics of vessel's movements. DGPS was installed in front and in the rear and on both side or the vessel and surveyed. The receiving precision of surveyed GPS results was obtained to the satisfactory extent that was possible to valuate the accuracy of Motion sensor as 0.0016$^{\circ}$ of the roll value and 0.0009$^{\circ}$ of the pitch value. The relationship between the values of heading, pitch, and roll in Motion sensor and the data of DGPS was proportional correlation. In addition, it is considered that deviations by elements like rapid turning and vibration of the vessel will be occurred, although the correlation of each deviation according to each amount or change is proportional. It is suitable that GPS installs in the central line of the vessel that is less affected than other places by waving because the amount of change in the tide level obtained from GPS survey and the value of heave are similar with the values taken by Motion sensor, and the velocity of GPS is different from installed places. The accuracy of the final result from MBES could be affected by the values of gyro and Motion sensor inputted to MBES processor because there were intervals of 15s and 13s of receiving time in gyro and Motion sensor respectively compared with the real-time measurements of DGPS.

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Identification of Dynamic Characteristics Using Vibration Measurement Data of Saemangeum Mangyeong Offshore Observation Tower and Numerical Model Updating by Pattern Search Method (새만금 만경해상관측타워의 진동계측자료를 이용한 동특성 분석과 패턴서치 방법에 의한 수치해석모델 개선)

  • Park, Sangmin;Yi, Jin-Hak;Cho, Cheol-Ho;Park, Jin-Soon
    • Journal of Korean Society of Coastal and Ocean Engineers
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    • v.32 no.5
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    • pp.285-295
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    • 2020
  • In the case of small observation towers located at sea, it is necessary to confirm the change in dynamic characteristics due to the influence of environmental loads. In this study, the dynamic characteristics were analyzed and the numerical analysis model was designed through field dynamic response measurement on the Mangyeong Offshore Observation Tower (Mangyeong Tower) located near the Saemangeum Embankment. As a result of the measurement, the natural frequency was found to increase slowly as the tide level is lowered. In addition, it was confirmed that the same mode has two frequencies, which was judged to be a phenomenon in which the natural frequency was partially increased when the pile and the ground contacted by scouring. For numerical analysis, the upper mass, artificial fixity point, scour depth and fluid influences are reflected in the structural characteristics of the Mangyeong Tower. In addition, the model updating from the estimated natural frequency and pattern search algorithm was performed. From the model updating, it is expected that it can be applied to future studies on stability of Mangyeong Tower.

Analysis of the railway noise prediction result using Schall03 in noise mapping (소음지도 작성 시의 Schall03에 의한 철도소음 예측결과 분석)

  • Koh, Hyoin;Jang, Jinwon;Jang, Seungho;Hong, Jiyoung
    • Journal of Environmental Impact Assessment
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    • v.25 no.3
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    • pp.175-189
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    • 2016
  • The guideline for railway noise mapping is notificated in the administration law for noise/vibration which is announced by the ministry of environment, Korea. Here input parameters for the railway sound sources are proposed for each prediction models. In case of the application of the vehicle characteristics it is suggested to choose "0(%)" for the disc brake parameter. However new trains have been in revenue service since the announcement of the guideline, an investigation of the effect of the input parameters of the foreign railway prediction models on the prediction results of korean railway systems are needed. In this paper the sound prediction results are analyzed with a focus on the input parameters such as disc brake percentage, rail roughness, rail joints. Schall03 is used for the railway noise prediction which has been using most frequently in Korea. The results are shown and discussed.

Investigation of Axially Loaded Jacked Pile Behavior by Pile Load Test (말뚝재하시험을 통한 압입강관말뚝의 연직지지거동 분석)

  • Baek, Sung-Ha;Do, Eun-Su;Kim, Seok-Jung
    • Journal of the Korean Geotechnical Society
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    • v.34 no.7
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    • pp.39-49
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    • 2018
  • Jacked pile that involves the use of hydraulic jacks to press the piles into the ground is free from noise and vibration, and is possibly installed within a limited construction area. Thus, as an alternative to conventional pile driving methods, pile jacking could become widely accepted for the construction projects in urban area (e.g., reconstruction or remodeling construction projects). Great concern has arisen over the prediction of axially loaded jacked pile behavior. Against this background, a series of pile load tests were hence conducted on a jacked steel pipe pile installed in weathered zone (i.e., weathered soil and weathered rock). From the test results, base resistance and shaft resistance for each test condition were evaluated and compared with the values predicted by the previous driven pile resistance assessment method. Test results showed that the previous driven pile resistance assessment method highly underestimated both the base and shaft resistances of a jacked pile; differences were more obviously observed with the shaft resistance. The reason for this discrepancy is that a driven pile normally experiences a larger number of loading/unloading cycles during installation, and therefore shows significantly degraded stiffness of surrounding soil. Based on the results of the pile load tests, particular attention was given to the modification of the previous driven pile resistance assessment method for investigating the axially loaded jacked pile behavior.