• Title/Summary/Keyword: V5.2

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Effect of V2O5 Addition on the Microstructure and Electrical Properties of Pb(In1/2Nb1/2)O3-PbTiO3 Ceramics (Pb(In1/2Nb1/2)O3-PbTiO3계의 미세구조와 전기적 물성에 미치는 V2O5 첨가의 영향)

  • 박현욱;이응상
    • Journal of the Korean Ceramic Society
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    • v.25 no.4
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    • pp.335-340
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    • 1988
  • The change in microstructure and the electrical properties of Pb(In1/2Nb1/2)O3-PbTiO3 Ceramics caused by V2O5 addition were studied. The results are ; 1. interability was increased because the mass transport through the second phase formed by V2O5 addition increased. 2. ith addition of V2O5, tetragonality and Curie temperature increased. The maximum value of kp was observed when 0.5wt% of V2O5 was added. 3. he second phase formed by V2O5 accelerated the grain growth, and existed in grain boundary. Electrical properties were changed by corelations between tetragonality and the amount of second phase.

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A Study on the Optical Properties of Lithium Injection in V$_2$O$_{5}$ Electrochromic Thin Films (리튬이 주입된 전기변색 V$_2$O$_{5}$ 박막의 광 특성에 관한 연구)

  • Ha, Seung-Ho;Cho, Bong-Hee;Kim, Young-Ho
    • Korean Journal of Materials Research
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    • v.5 no.7
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    • pp.802-807
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    • 1995
  • The electrochromic properties of vacuum deposited V$_2$O$_{5}$ thin films as a function of crystallinity and film thickness have been systematically investigated. The as-deposited films have slightly yellow appearance. V$_2$O$_{5}$ films deposited at higher substrate temperature(>14$0^{\circ}C$) are found to be crystalline while those deposited at low substrate temperature are amorphous. The optical modulation on lithium ion injection indicates that V$_2$O$_{5}$ films exhibit anodic coloration in the 300~500 nm wavelength range and cathodic coloration in the 500~1100nm wavelength range independent of crystallinity and film thickness. The optical band gap energy of crystalline and amorphous Li$_{x}$ VV$_2$O$_{5}$ films shifts to higher energies by 0.17 eV and 0.75 eV, respectively, with increasing lithium ion injection up to x=0.6. The coloration efficiency of amorphous Li$_{x}$ V$_2$O$_{5}$ exhibits very little dependence on film thickness and lithium ion injection amounts in the near-infrared while it increases significantly with increasing film thickness and decreasing lithium ion injection amounts in the blue and near-UV due to the shift in absorption edge below around 500nm. However, the coloration efficiency of crystalline Li$_{x}$ V$_2$O$_{5}$is relatively independent of film thickness and lithium ion injection in the 300~1100 nm wavelength range.

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Heterologous Expression of Human SLC1A5v2 as a Functional Glutamine Transporter in Escherichia coli

  • E Young Kim;Ji Won Park;Ok Bin Kim
    • Microbiology and Biotechnology Letters
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    • v.51 no.1
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    • pp.37-42
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    • 2023
  • Neutral and non-essential amino acid, glutamine (Gln), plays an essential role in supplying nitrogen to all the amino acids and nucleotides in the mammalian body. Gln is also the most important carbon source that provides intermediates for gluconeogenesis and fatty acid synthesis and supplements the tricarboxylic acid cycle in fast-growing cancer cells. Among the known 14 Gln transporter genes, soluted carrier family 1 member 5 (SLC1A5) has been reported to be closely associated with cancer cell growth. Three variants (v1, v2, and v3) have been derived from SLC1A5. Here, we established a heterologous gene expression system for the active form of human SLC1A5 variant-2 (hSLC1A5v2) in Escherichia coli. v2 is the smallest variant that has not yet been studied. Four expression systems were investigated: pBAD, pCold, pET, and pQE. We also addressed the problem of codon usage bias. Although pCold and pET overexpressed hSLC1A5v2 in E. coli, they were functionally inactive. hSLC1A5v2 using the pBAD system was able to catalyze the successful transport of Gln, even if it was not highly expressed. Initial activity of hSLC1A5v2 for [14C] Gln uptake in E. coli reached up to 6.73 μmole·min-1·gDW-1 when the cell was induced with 80 mM L-arabinose. In this study, we demonstrated a heterologous expression system for the human membrane protein, SLC1A5, in E. coli. Our results can be used for the functional comparison of SLC1A5 variants (v1, v2, and v3) in future studies, to facilitae the developement of SLC1A5 inhibitors as effective anticancer drugs.

Magnetic Properties of Chip Inductors Prepared with V2O5-doped Ferrite Pastes (V2O5 도핑한 페라이트 페이스트로 제조된 칩인덕터의 자기적 특성)

  • Je, Hae-June
    • Journal of the Korean Magnetics Society
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    • v.13 no.3
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    • pp.109-114
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    • 2003
  • The purpose of this study Is to investigate the effect of $V_2$O$_{5}$ addition on the microstructures and magnetic properties of 7.7${\times}$4.5${\times}$1.0 mm sized multi-layer chip inductors prepared by the screen printing method using 0∼0.5 wt% $V_2O_{5}$-doped NiCuZn ferrite pastes. With increasing the $V_2O_{5}$ content, the exaggerated grain growth of ferrite layers was developed due to the promotion of Ag diffusion and Cu segregation into the grain boundaries oi ferrites, which affected significantly the magnetic properties of the chip inductors. After sintering at $900^{\circ}C$, the inductance at 10 MHZ of the 0.5 wt% $V_2O_{5}$-doped chip inductor was 3.7 ${\mu}$H less than 4.2 ${\mu}$H of the 0.3 wt% $V_2O_{5}$-doped one, which was thought to be caused by the residual stress at the ferrite layers increased with the promotion of Ag diffusion and Cu segregation. The quality factor of the 0.5 wt% $V_2O_{5}$-doped chip inductor decreased with increasing the sintering temperature, which was considered to be caused by the electrical resistivity of the ferrite layer decreased with the promotion of Ag/cu segregation at the grain boundaries and the growth of the mean grain size of ferrite due to exaggerated grain growth of ferrite layers.

Application Analysis of Vitex rotundifolia by Difference of the Shallow-Extensive Green Roof System (저관리 옥상녹화의 식재기반 시스템 차이에 따른 순비기나무의 활용성 평가)

  • Park, Jun-Suk;Ju, Jin-Hee;Kim, Won-Tae;Yoon, Young-Han
    • Journal of the Korean Society of Environmental Restoration Technology
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    • v.13 no.4
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    • pp.10-17
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    • 2010
  • The objectives of this study were to compare the growth of Vitex rotundifolia as affected by the difference of soil depth and mixture ratio in a shallow-extensive green roof module system, and to identify the level of soil thickness and mixture ratio as suitable growing condition to achieve the desired plant growth in green roof. Different soil thickness levels were achieved under 7cm, 15cm and 25cm of shallow-extensive green roof module systems made by woody frame of $500{\times}500{\times}300mm$. Soil mixture ratio were eight types for perlite : peatmoss : leafmold = 7 : 1 : 2 (v/v/v, $P_7P_1L_2$), perlite : peatmoss : leafmold = 6 : 2 : 2 (v/v/v, $P_6P_2L_2$), perlite : peatmoss : leafmold = 5 : 3 : 2 (v/v/v, $P_5P_3L_2$), perlite : peatmoss : leafmold = 4 : 4 : 2 (v/v/v, $P_4P_4L_2$), only sand ($S_{10}$), sand : leafmold = 7 : 3 (v/v, $S_7L_3$), sand : leafmold = 5 : 5 (v/v, $S_5L_5$) and only leafmold ($L_{10}$). The growth response of Vitex rotundifolia had fine and sustain condition in $P_6P_2L_2$, $P_5P_3L_2$ and $P_4P_4L_2$., Especially, in case of $P_6P_2L_2$, growth response appeared to be good even in soil thickness 7cm, which showed low survival rates of Vitex rotundifolia in other soil mixtures. Tree height, root diameter, photosynthesis and chlorophyll contents tended to increase with increased soil thickness.

Solid-State 51V NMR and Infrared Spectroscopic Study of Vanadium Oxide Supported on $ZrO_2-WO_3$

  • 손종락;이만호;도임자;배영일
    • Bulletin of the Korean Chemical Society
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    • v.19 no.8
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    • pp.856-862
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    • 1998
  • Vanadium oxide catalyst supported on ZrO2-WO3 was prepared by adding the Zr(OH)4 powder into a mixed aqueous solution of ammonium metavanadate and ammonium metatungstate followed by drying and calcining at high temperatures. The characterization of prepared catalysts was performed using solid-state 51V NMR and FTIR. In the case of calcination temperature at 773 K, for the samples containing low loading V2O5 below 18 wt % vanadium oxide was in a highly dispersed state, while for samples containing high loading V2O5 equal to or above 18 wt % vanadium oxide was well crystallized due to the V2O5 loading exceeding the formation of monolayer on the surface of ZrO2-WO3. The ZrV2O7 compound was formed through the reaction Of V2O5 and ZrO2 at 873 K and the compound decomposed into V2O5 and ZrO2 at 1073 K, which were confirmed by FTIR and 51V NMR.

The fabrication of $TiO_2-V_2O_5$ ceramic humidity sensors and their characteristics ($TiO_2-V_2O_5$ 세라믹 습도감지소자의 제조 및 그 특성)

  • 이성필;임재영;고성택
    • Electrical & Electronic Materials
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    • v.6 no.2
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    • pp.129-136
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    • 1993
  • 습도 감지소자의 물질 중 이온형의 대표적인 물질인 TiO$_{2}$ 습도 센서와 TiO$_{2}$에 V$_{2}$O$_{5}$를 첨가한 TiO$_{2}$-V$_{2}$O$_{5}$ 세라믹 습도센서를 제작하고 V$_{2}$O$_{5}$함량의 변화, 열처리 온도 및 열처리 시간에 따른 습도감지 특성 및 동작온도에 따른 특성 등을 조사하였으며 XRD와 SEM으로 그 원인을 규명하였다. TiO$_{2}$에 V$_{2}$O$_{5}$를 첨가하면 선형성이 좋아지는 것을 알 수 있었고 제작한 시료 중 V$_{2}$O$_{5}$의 함량이 1mol% 열처리 조건이 1000.deg.C, 1시간인 소자는 동작온도 40.deg.C에서 약 95%의 감도를 나타내었다.

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Temperature-dependent photoluminescence properties of amorphous and crystalline V2O5 films (비정질과 결정질 V2O5 박막의 온도에 따른 발광특성)

  • Kang, Manil;Chu, Minwoo;Kim, Sok Won
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.24 no.5
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    • pp.202-206
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    • 2014
  • In order to investigate the photoluminescence (PL) properties of $V_2O_5$ films, amorphous and crystalline films were prepared by using RF sputtering system, and the PL spectra of the films were measured at the temperatures ranging from 300 K to 10 K. In the amorphous $V_2O_5$ film grown at room temperature, a PL peak centered at ~505 nm was only observed, and in the crystalline $V_2O_5$ film, two peaks centered at ~505 nm and ~695 nm, which is known to correspond to oxygen defects, were revealed. The position of PL peak centered at 505 nm for both the amorphous and crystalline $V_2O_5$ films showed a strong dependence on temperature, and the positions were 2.45 eV at 300 K and 2.35 eV at 10 K, respectively. The PL at 505 nm was due to the band energy transition in $V_2O_5$, and also, the reduction of the peak position energy with decreasing temperature was caused by a decrement of the lattice dilatation effect with reducing electron-phonon interaction.

Study on the Electrical Conductivity and Catalytic Property by Structural Change of 70V2O5-10Fe2O3-13P2O5-7B2O3 Glass with Crystallization

  • Jeong, Hwa-Jin;Cha, Jae-Min;Ryu, Bong-Ki
    • Journal of the Korean Ceramic Society
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    • v.54 no.5
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    • pp.406-412
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    • 2017
  • $70V_2O_5-10Fe_2O_3-13P_2O_5-7B_2O_3$ glasses were prepared to study the electrical conductivity and catalytic properties of the structural change with crystallization. The structural changes were analyzed by determining the molecular volume from the sample density; using X-Ray Diffraction (XRD) analysis, which indicated that $V_2O_5$, $VO_2$ and $B_2O_3$ crystals in heat-treated more than 1h samples. Especially a new crystalline phase of non-stoichiometric $Fe_{0.12}V_2O_5$ was formed after 6 h heat treatment. The V-O bonding change after crystallization was analyzed by Fourier Transform Infrared Spectroscopy (FTIR); V ion change from $V^{5+}$ to $V^{4+}$ was shown by XPS. Conductivity and catalytic properties were examined based on the polaronic hopping of V and Fe ions, which exhibited different valence states with crystallization.

A Study on the Characteristics of Semiconductor Oxides with V2O5 (V2O5가 첨가된 반도체 산화물의 특성개선연구)

  • Lee, Don-Kyu
    • Journal of IKEEE
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    • v.22 no.4
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    • pp.965-969
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    • 2018
  • In the dye-sensitized solar cell, the semiconductor oxide plays an important role in the generation and transport of electrons, and thus extensive research on this has been continuously carried out. In this study, the characteristics of dye-sensitized solar cell are studied by fabricating semiconductor oxide doped with $V_2O_5$. The $TiO_2$ paste with $V_2O_5$ is prepared by the screen printing method of the sol - gel process and the surface and electrical properties are measured. The addition of $V_2O_5$ increased grain size and improved the open circuit voltage, short circuit current, charge factor and conversion efficiency of the dye sensitized solar cell.