• Title/Summary/Keyword: V2C

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Electrolyte Effect on the Particle Characteristics Prepared by Soap-Free Emulsion Polymerization

  • Han, Seung-Tak;Lee, Kang-Seok;Shim, Sang-Eun;Saikia, Prakash J.;Choe, Soon-Ja;Cheong, In-Woo
    • Macromolecular Research
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    • v.15 no.5
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    • pp.403-411
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    • 2007
  • Monodisperse micron-sized polystyrene (PS) spheres were successfully obtained using a single stage soap-free emulsion method in aqueous media mixed with ethanol (co-solvent) containing NaCI as the electrolyte. The optimum conditions for preparing the monodisperse PS microspheres, using soap-free emulsion polymerization in a water/ethanol mixture with an electrolyte, were studied. The presence of the co-solvent and electrolyte controlled the particle dispersion stability during the polymerization. The microspheres formed using PS, with a weight-average diameter of $2.6{\mu}m$, coefficient of variation of 5.3% and zeta potential of -15.1 eV, were successfully obtained in the presence of 0.1 wt% NaCI, 10 wt% monomer, 0.1 wt% initiator and 95/5 (g/g) of a water/ethanol mixture reacted at $70^{\circ}C$ for 24 h.

Finite Dimension in Associative Rings

  • Bhavanari, Satyanarayana;Dasari, Nagaraju;Subramanyam, Balamurugan Kuppareddy;Lungisile, Godloza
    • Kyungpook Mathematical Journal
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    • v.48 no.1
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    • pp.37-43
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    • 2008
  • The aim of the present paper is to introduce the concept "Finite dimension" in the theory of associative rings R with respect to two sided ideals. We obtain that if R has finite dimension on two sided ideals, then there exist uniform ideals $U_1,U_2,\ldots,U_n$ of R whose sum is direct and essential in R. The number n is independent of the choice of the uniform ideals $U_i$ and 'n' is called the dimension of R.

Controlled Deformation of Microalloyed Steel by Precipitation and Recrystallization (미량원소첨가강의 석출 및 재결정에 의한 제어변형)

  • 조상현;김성일;유연철
    • Transactions of Materials Processing
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    • v.6 no.2
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    • pp.102-109
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    • 1997
  • The multistage deformation and stress relaxation were carried out to investigate the strain induced precipitation by torsion tests in the range of 1000~80$0^{\circ}C$, 0.05~5/sec for V-microalloyed steel. The starting temperature and time for the initiation of precipitation were determined by stress relaxation tests. The distribution of precipitates increased, as the strain rate increased and the mean size of precipitates was found to be about 10~30nm. The precipitation starting time$(P_s)$ decreased with increasing strain rate and the amount of pre-strain. The effect of deformation conditions on the no-recrystallization temperature$(T_nr)$ was also determined in the multistage deformation. $T_nr$ Tnr decreased with increasing the strain and strain rate. In the controlled rolling simulation, grain refinement and precipitation hardening effects could be achieved by the alternative large pass strain at the latter half pass stage under the condition of low temperature and high strain rate.

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Characterization of Bacillus cereus SH-7 Extracellular Protease

  • Yi, Hak-Kyu;Chun, Young-Jin;Kim, Han-Bok
    • Journal of Microbiology
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    • v.37 no.4
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    • pp.213-217
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    • 1999
  • An extracellular endopeptidase from Bacillus cereus SH-7 was purified to homogeneity. The protease was most active at pH 8 and $40{\circ}C$, respectively. The molecular mass of the protease was 40 kDa on SDS-PAGE, and 120 kDa by gel filtration, suggesting that the native enzyme is composed of three homogeneous subunits. The $K_m\;and\;V_{max}$ values of the protease for N-succinyl-$(Ala)_2$-Pro-Phe-p-nitroanilide were 11.11 mM and 170 nmol/mg of protein/min, respectively. The protease was also identified as a metalloprotease. The bioactivity of the SH-7 protease will need further study in the future.

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Transient and stable expression of hepatitis B surface antigen in tomato (Lycopersicon esculentum L.)

  • Srinivas, L.;Sunil Kumar, G.B.;Ganapathi, T.R.;Revathi, C.J.;Bapat, V.A.
    • Plant Biotechnology Reports
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    • v.2 no.1
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    • pp.1-6
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    • 2008
  • Cotyledonary leaves of tomato cv. Megha were transformed with the hepatitis B virus 's' gene, which encodes surface antigen. Six plant expression cassettes (pHBS, pHER, pEFEHBS, pEFEHER, pSHER and pEFESHER) were used to assay the possible expression levels by agroinfiltration. The maximum transient expression level of 489.5 ng/g D.W. was noted in pEFEHER-infiltrated cotyledonary leaves. Transgenic tomato plants with pEFEHBS and pEFEHER expression cassettes were regenerated and characterized by molecular analysis. The expression of the antigen in the fruits was confirmed by RT-PCR and ELISA analysis. This is the first report on the expression of hepatitis B surface antigen in tomato.

Classification of Livestock Raising Area and Spatial Mobility (가축사육의 지역분류와 공간이동에 관한 연구)

  • 김재환;박치호;강희설;곽정훈;최동윤;최희철
    • Journal of Animal Environmental Science
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    • v.7 no.1
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    • pp.45-56
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    • 2001
  • The following statistics are the results of a survey that analyzed the classification of livestock area and spatial mobility based upon the number of livestock and an area of 151 towns and cities from 1975 to 1995. 1. As a results of analysis about the degree of location concentration using C.V., Korean native cattles (HanWoo) and swines are becoming more centralized while dairies and chickens are becoming decentralized. 2. 49 regions, that is 32.5%, were classified as growing regions, 30 regions (19.9%) were stagnant regions and 72 regions (47.7%) were withering regions. The classification was based upon the calculation according to the numbers of converted grown animals and growth index. Kyonggi-do and Chungchongnam-do, specifically, took up 26.6% and 24.5% of the developing regions which shows that these two regions are the dominant regions for livestock. 3. Kyongsangbuk-do and Chungchongnam-do play significant roles for overall livestock, and Chollanam-do is considering a transition from swines to Korean native cattles and Kyongsangbuk-do is shifting from Korean native cattles to swines.

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High Temperature Oxidation of Ti-15Mo-5Zr-3Al Alloy (Ti-15Mo-5Zr-3Al 합금의 고온산화)

  • 우지호;김종성;백종현;이동복
    • Journal of Surface Science and Engineering
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    • v.31 no.5
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    • pp.278-285
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    • 1998
  • Alloys of Ti-15Mo-5Zr-3Al(wt%) were oxidized in air between 700 and $900^{\circ}C$. It was found that the oxidation resistance is much better than that of either commercially available pure Ti-6Al-4V(wt%) alloys. The oxide scales were primarily composed of thick Ti-ox-ides which were formed by the inward diffusion of oxygen from the atmosphere. At higher temperatures a thin $\alpha$-$Al_2O_3$ layer was formed on Ti-oxides owing to the outward diffusion of Al from the base alloys. Molybdenum, the noblest metal among the alloy components, was predominantly present behind the oxide-substrate interface. Zirconium, an oxygen active metal, was present at both the oxide layer and the substrate.

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Catalytic Properties of Phospholipase D using Phosphatidic Acid as an Activator

  • Eun-hie Koh;Myung-Un Chol;Kwanyoung Jung
    • Bulletin of the Korean Chemical Society
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    • v.10 no.6
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    • pp.595-599
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    • 1989
  • The effects of phosphatidic acid(PA) on the activity of phospholipase D were examined in detail. The enzyme activity was examined in the liposome system containing phosphatidylcholine and PA, which was suspended in a desired buffer solution by ultrasonication. The substrate of large unilamella vesicle (LUV) state by ultrasonication was more effective on the enzyme activity than that of multilamella vesicle(MLV) by water-bath type sonication. The most effective molar ratio of PC-PA liposome for enzyme activity was found to be 1:0.7. The other optimum conditions were found 5 mM $Ca^{2+}$ ion, pH 6.6, and incubation temperature of $27^{\circ}C. K_m \;and \;V_{max}$ values were estimated to be 1.43 mM and 0.8 $nmole/min/{\mu}g$ protein respectively. These properties in a PC-PA liposome system were compared with those in a PC-SDS mixed micelle system. The effects of other phospholipids and organic phosphates on the enzyme activity were also examined.

Analysis of Ginsenosides by Thermospray LC/MS (열분무 LC/MS에 의한 인삼사포닌의 분석)

  • Park, Man-Ki;Park, Jeong-Hill;Hwang, Gwi-Seo;Lee, Mi-Young;Park, In-Jeong
    • Journal of Ginseng Research
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    • v.19 no.2
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    • pp.134-137
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    • 1995
  • Ginseng saponins were analyzed by thermospray (TSP) LCMS method using ODS column and with acetonitrile/ammonium acetate solution. Optimal condition for TSP Lchfs was found as follows: capillary temperature: 33$0^{\circ}C$ repelled voltage: 200 V, and concentration of ammonium acetate: 0. 05 M. Panaxadiol and panaxatriol type saponins showed characteristic fragment ions. The calibration curve of ginseng saponin showed good linearity with a correlation coefficient of 0.99. Detection limits using selected ion monitoring (SIM) technique were improved by 10~200 times compared to conventional HPLCnnr detection method.

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Synthesis and Characterization of Novel Polyurethanes Based on 4-{(4-Hydroxyphenyl)iminomethyl} phenol

  • Raghu, A.V.;Jeong, Han-Mo;Kim, Jae-Hoon;Lee, Yu-Rok;Cho, Youn-Bok;Sirsalmath, Kiran
    • Macromolecular Research
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    • v.16 no.3
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    • pp.194-199
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    • 2008
  • Four novel polyurethanes were prepared from 4-{(4-hydroxyphenyl)iminomethyl} phenol by reactions with two aromatic diisocyanates, 4,4'-diphenylmethane diisocyanate and toluene 2,4-diisocyanate, and two aliphatic diisocyanates, isophorone diisocyanate and hexamethylene diisocyanate. The polyurethanes formed were characterized by UV-vis, fluorescence, FT-IR, $^1H$-NMR, $^{13}C$-NMR, differential scanning calorimetry, thermogravimetry, and X-ray diffraction. The polymers were semi-crystalline and all polymers were soluble in polar aprotic solvents.