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Structural and Optical Properties of Copper Indium Gallium Selenide Thin Films Prepared by RF Magnetron Sputtering

  • Kong, Seon-Mi;Fan, Rong;Kim, Dong-Chan;Chung, Chee-Won
    • Proceedings of the Korean Vacuum Society Conference
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    • 2011.02a
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    • pp.158-158
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    • 2011
  • $Cu(In_xGa_{1-x})Se_2$ (CIGS) thin film solar cell is one of the most promising solar cells in photovoltaic devices. CIGS has a direct band gap which varied from 1.0 to 1.26 eV, depending on the Ga to In ratio. Also, CIGS has been studying for an absorber in thin film solar cells due to their highest absorption coefficient which is $1{\times}10^5cm^{-1}$ and good stability for deposition process at high temperature of $450{\sim}590^{\circ}C$. Currently, the highest efficiency of CIGS thin film solar cell is approximately 20.3%, which is closely approaching to the efficiency of poly-silicon solar cell. The deposition technique is one of the most important points in preparing CIGS thin film solar cells. Among the various deposition techniques, the sputtering is known to be very effective and feasible process for mass production. In this study, CIGS thin films have been prepared by rf magnetron sputtering method using a single target. The optical and structural properties of CIGS films are generally dependent on deposition parameters. Therefore, we will explore the influence of deposition power on the properties of CIGS films and the films will be deposited by rf magnetron sputtering using CIGS single target on Mo coated soda lime glass at $500^{\circ}C$. The thickness of CIGS films will be measured by Tencor-P1 profiler. The optical properties will be measured by UV-visible spectroscopy. The crystal structure will be analyzed using X-ray diffraction (XRD). Finally the optimal deposition conditions for CIGS thin films will be developed.

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Sol-gel 법으로 제작된 $ZrO_2$ 박막의 분광타원편광분석 연구

  • Kim, Tae-Jung;Yun, Jae-Jin;Hwang, Sun-Yong;Kim, Yeong-Dong;Hwang, Su-Min;Lee, Seung-Muk;Ju, Jin-Ho
    • Proceedings of the Korean Vacuum Society Conference
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    • 2011.02a
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    • pp.177-177
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    • 2011
  • Complementary metal-insulator-metal capacitor에서 $SiO_2$는 절연체로 널리 사용되고 있었으나, 반도체 소자의 고직접화로 인한 선폭의 감소로 터널링 효과에 의해 누설전류가 증가하여, 대체 물질에 대한 연구가 활발히 진행되고 있다. 그 중 $ZrO_2$는 고유전율, wide bandgap, 열안정성의 특징을 가지고 있어 대체 물질로 주목 받고 있다. $ZrO_2$ 박막 제작에는 sputter, atomic layer deposition 등의 진공증착을 이용한 방법과 용액을 이용한 sol-gel 법이 있다. 화학용액을 이용한 sol-gel 법은 소자의 패턴을 프린트 할 수 있는 장점과 상대적으로 값싼 공정으로 인해 최근 주목 받고 있지만, 진공증착법에 비해서 연구가 전무한 실정이다. 본 연구에서는 sol-gel 법에 의해 프린트된 $ZrO_2$ 박막의 광특성을 분광타원편광분석법으로 연구하였다. Si 기판위에 0.1 M의 $ZrO_2$ sol을 입힌 뒤에 $300{\sim}700^{\circ}C$의 온도에서 열처리 하였다. 분광타원 편광분석기로 1.12~6.52 eV 에너지 영역에서 측정하였고, $ZrO_2$ 박막의 광특성 분석을 위해서 Tauc-Lorentz 모델을 이용하였다. 그 결과 고온에서의 열처리로 인해 효율이 높아서 소자로 이용할 수 있는 tetragonal 구조를 가진 $ZrO_2$ 박막이 형성됨을 분석할 수 있었다. 본 연구는 sol-gel법으로 제작된 $ZrO_2$ 박막의 고직접, 고속 소자응용성과 비파괴적인 광특성 분석법을 제시하고 있다.

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Relationship between the Caries Experience of Korean School Children and the Distribution of Streptococcus mutans in Dental Plaque (한국아동(韓國兒童)의 치아우식경험과 치면상(齒面上) Streptococcus mutans 분포(分布)에 대(對)한 연구(硏究))

  • Kim, Kack-Kyun;Choe, Son-Jin;Lim, Chang-Yoon;Chang, Woo-Hyun
    • The Journal of the Korean Society for Microbiology
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    • v.18 no.1
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    • pp.11-21
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    • 1983
  • Various investigations have been carried out to elucidate the causative relationship between specific oral bacterial species and dental caries since it was first demonstrated that selected streptococoal species produced dental caries in germfree rats when fed a high-sucrose diet. Now, S. mutans is considered to play an important role in the development of dental caries in animals and humans, and only a limited number of species of bacteria other than S. mutans are occasionally found to be cariogenic in experimental animals. In this regard, association of the number of S. mutans in approximal plaque with caries experience (DMFT) was studied from 137 Korean school children($10{\sim}11$ year old). Biotypes of the collected strains of S. mutans were determined, and their relationship with caries status was also examined. The following results were emerged from the study. 1. S. mutans was detected in the plaques of all children. 2. Statistically significant positive correlation(r=0.445, p<0.001) was found between the caries experience(DMFT) and the number of S. mutans in approximal plaques. 3. The number of S. mutans were significantly higher(p<0.001) in plaques removed from carious surface than from sound surface. 4. The most frequent biotype was biotype I(78.8%), followed by IV(33.1%) and V(09.5%). Biotype II was isolated in the plaque of two children(1.7%) only. 5. There was no apparent relation of specific biotypes to carious status.

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Changes in Phosphate Transporter Activity Evaluated by Phosphonoformic Acid Binding in Cadmium-Exposed Renal Brush-Border Membranes

  • Chung, Jin-Mo;Ahn, Do-Whan;Kim, Kyoung-Ryong;Park, Yang-Saeng
    • The Korean Journal of Physiology and Pharmacology
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    • v.3 no.5
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    • pp.513-519
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    • 1999
  • Direct exposure of renal tubular brush-border membranes (BBM) to free cadmium (Cd) causes a reduction in phosphate (Pi) transport capacity. Biochemical mechanism of this reduction was investigated in the present study. Renal proximal tubular brush-border membrane vesicles (BBMV) were isolated from rabbit kidney outer cortex by Mg precipitation method. Vesicles were exposed to $50{\sim}200\;{\mu}M\;CdCl_2$ for 30 min, then the phosphate transporter activity was determined. The range of Cd concentration employed in this study was comparable to that of the unbound Cd documented in renal cortical tissues of Cd-exposed animals at the time of onset of renal dysfunction. The rate of sodium-dependent phosphate transport $(Na^+-Pi\;cotransport)$ by BBMV was determined by $^{32}P-Iabeled$ inorganic phosphate uptake, and the number of $Na^+-Pi$ cotransporters in the BBM was assessed by Pi-protectable $^{14}C-labeled$ phosphonoformic acid $([^{14}C]PFA)$ binding. The exposure of BBMV to Cd decreased the $Na^+-Pi$ cotransport activity in proportion to the Cd concentration in the preincubation medium, but it showed no apparent effect on the Pi-protectable PFA binding. These results indicate that an interaction of renal BBM with free Cd induces a reduction in $Na^+-Pi$ cotransport activity without altering the carrier density in the membrane. This, in turn, suggest that the suppression of phosphate transport capacity $(V_{max})$ observed in Cd-treated renal BBM is due to a reduction in $Na^+-Pi$ translocation by existing carriers, possibly by Cd-induced fall in membrane fluidity.

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Surface Characteristics of Anodized and Hydrothermally-Treated Ti-6Al-7Nb Alloy (양극산화와 열수처리한 Ti-6Al-7Nb 합금의 표면 특성)

  • Kim, Moon-Young;Song, Kwang-Yeob;Bae, Tae-Sung
    • Journal of Dental Rehabilitation and Applied Science
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    • v.22 no.1
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    • pp.101-110
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    • 2006
  • This study was performed to investigate the surface properties and in vitro biocompatibility of electrochemically oxidized Ti-6Al-7Nb alloy by anodic spark discharge technique. Discs of Ti-6Al-7Nb alloy of 20 mm in diameter and 2 mm in thickness were polished sequentially from #300 to 1000 SiC paper, ultrasonically washed with acetone and distilled water for 5 min, and dried in an oven at $50^{\circ}C$ for 24 hours. Anodizing was performed using a regulated DC power supply. The applied voltages were given at 240, 280, 320, and 360 V and current density of $30mA/cm^2$. Hydrothermal treatment was conducted by high pressure steam at $300^{\circ}C$ for 2 hours using a autoclave. Samples were soaked in the Hanks' solution with pH 7.4 at $36.5^{\circ}C$ during 30 days. The results obtained were summarized as follows; 1. The oxide films were porous with pore size of $1{\sim}5{\mu}m$. The size of micropores increased with increasing the spark forming voltage. 2. The main crystal structure of the anodic oxide film was anatase type as analyzed with thin-film X-ray diffractometery. 3. Needle-like hydroxyapatie (HA) crystals were observed on anodic oxide films after hydrothermal treatment at $300^{\circ}C$ for 2 hours. The precipitation of HA crystals was accelerated with increasing the spark forming voltage. 4. The precipitation of the fine asperity-like HA crystals were observed after being immersed in Hanks' solution at $37^{\circ}C$. The precipitation of HA crystals was accelerated with increasing the spark forming voltage and the time of immersion in Hanks' solution. 5. The Ca/P ration of the precipitated HA layer was equivalent to that of HA crystal as increasing the spark forming voltage and the time of immersion in Hanks' solution.

MOLECULAR CLOUDS WITH PECULIAR VELOCITY IN THE OUTER LOCAL ARM

  • Kang, Mi-Ju;Lee, Young-Ung
    • Journal of The Korean Astronomical Society
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    • v.39 no.4
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    • pp.107-114
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    • 2006
  • We conducted an analysis of a selected region from the FCRAO $^{12}CO$ Outer Galaxy Survey. The selected region is located between galactic longitude $117^{\circ}$ and $124^{\circ}$ with the velocity of -23 km $s^{-1}. Molecular clouds in this region show a peculiar velocity field, protruding from the Local Arm population. The selected region is divided into 7 clouds by spatial location. Though we were not able to identify the direct driving source for peculiar velocity of our target region, we find that there are several internal YSOs or star forming activities; there are many associated sources like an outflows, a high-mass protostellar candidate and $H_2O$ maser sources. We attribute the driving energy source to older generation of episodic star formation. Masses of main clouds(cloud 1-4) estimated using a conversion factor from $^{12}CO$ luminosity are larger than $10^4M_{\odot}$. Other components have a small mass as about $10^3M_{\odot}$. Among main clouds, cloud 2 and 4 seem to be marginally gravitational bound systems as their ratio of $M_{CO}$ to $M_{VIR}$ is about $2{\sim}3$, and the internal velocity dispersion is larger than the centroid velocity dispersion. Total mass estimated using a conversion factor from $^{12}CO$ luminosity is $7.9{\times}10^4M_{\odot}$.

Improved Ultrastructural Preservation of Retinal Cells in Drosophila melanogaster (초고압동결장치를 이용한 초파리 레티나 세포의 향상된 미세구조)

  • Mun, Ji-Young;Park, Se-Jin;Han, Sung-Sik
    • Applied Microscopy
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    • v.37 no.3
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    • pp.175-183
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    • 2007
  • The Drosophila retinal cell is widely used to study cell development and cell signaling processes. In the past decades, conventional chemical fixation had been used to study the structure of retinal cells in Droscphila. Rapid freezing methods are superior to chemical fixation methods due to their fixation speed. Some Drosophila tissues, such as the eyes, should not be freezed due to their surrounding cuticle layer. Therefore, in the case of the Drosophila retina, the benefits of high pressure freezing and freeze substitution (HPF-FS) had not been verified. In this study, a retinal cell from Drosophila melanogaster had been studied by using the HPF-FS method. Compared to chemical fixation, the preservation of the cytoplasm in the HPF-FS sample was improved on the whole. The HPF-FS cell membranes were smoother than that of chemical fixation. In addition, HPF-FS preserved the mitochondria structures very well. These results of the present study suggest that HPF-FS is superior to other fixation methods for the preservation of the retinal cell structure.

The Characteristics of Cultural Conditions for the Mycelial Growth and Fruiting Body Formation of Paecilomyces sinclairii (매미눈꽃동충하초(Paecilomyces sinclairii)의 균사 생장과 자실체 형성 조건의 특성)

  • Shim, Sung-Mi;Lee, Kyung-Rim;Im, Kyung-Hoan;Lee, U-Youn;Lee, Min-Woong;Lee, Tae-Soo
    • The Korean Journal of Mycology
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    • v.31 no.1
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    • pp.8-13
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    • 2003
  • The fruiting body of Paecilomyces sinclairii was collected in Baekyangsa, Jeollanam-Do, Korea. Cultural conditions for the mycelial growth and fruiting body formation were investigated. Its optimum mycelial growth was obtained at 25℃ and pH 8 on potato dextrose agar and Hamada media among the various media tested. The carbon and nitrogen sources for the optimum mycelial growth were dextrin and glutamine, respectively. The optimum C/N ratio was about 20:1 in case that 1% glucose was supplemented to the basal medium as a carbon source. The favorable mycelial growth was obtained from corn meal extract medium mixed with 30% (w/v) milk solution. The maximum fruiting body was formed in unpolished rice medium supplemented with 20% (w/w) silkworm pupae at $25^{\circ}C$ under 500lux.

Optimization of Drive-in Temperature at Doping Process for Mono Crystalline Silicon Solar Cell (단결정 실리콘 태양전지의 도핑 최적화를 위한 확산 온도에 대한 연구)

  • Cho, Sung-Jin;Song, Hee-Eun;Yoo, Kwon-Jong;Yoo, Jin-Soo;Han, Kyu-Min;Kwon, Jun-Young;Lee, Hi-Deok
    • Journal of the Korean Solar Energy Society
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    • v.31 no.1
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    • pp.37-43
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    • 2011
  • In this paper, the optimized doping condition of crystalline silicon solar cells with $156{\times}156\;mm^2$ area was studied. To optimize the drive-in temperature in the doping process, the other conditions except variable drive-in temperature were fixed. These conditions were obtained in previous studies. After etching$7\;{\mu}m$ of the surface to form the pyramidal structure, the silicon nitride deposited by the PECVD had 75~80nm thickness and 2 to 2.1 for a refractive index. The silver and aluminium electrodes for front and back sheet, respectively, were formed by screen-printing method, followed by firing in 400-425-450-550-$850^{\circ}C$ five-zone temperature conditions to make the ohmic contact. Drive-in temperature was changed in range of $830^{\circ}C$ to $890^{\circ}C$to obtain the sheet resistance $30{\sim}70\;{\Omega}/{\box}$ with $10\;\Omega}/{\box}$ intervals. Solar cell made in $890^{\circ}C$ as the drive-in temperature revealed 17.1% conversion efficiency which is best in this study. This solar cells showed $34.4\;mA/cm^2$ of the current density, 627 mV of the open circuit voltage and 79.3% of the fill factor.

Effects of GMA Welding Conditions on the Bead Shape of Hardfacing Overlay Welding (하드페이싱 오버레이용접 비드형상에 미치는 GMA 용접조건의 영향)

  • Han, Kyu-Ho;Kim, Jun-Ki;Kim, Cheol-Hee;Kim, Jeong-Han;Nam, See-Hwan;Jeon, Chi-Jung
    • Journal of Welding and Joining
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    • v.25 no.5
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    • pp.58-63
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    • 2007
  • The relationship between GMA welding conditions and the bead shape of overlay weld was studied by using ${\Phi}1.6mm$ hypo-eutectic metal-cored wire designed for hardfacing against the severe metal-to-metal wear. As the welding voltage increased, the dilution also increased but the sudden drop of dilution was observed at $30{\sim}33V$. It was considered to be due to the decrease of penetration resulting from the change of transfer mode, from short circuit to spray. It was also found that the behavior of penetration with welding current was dependant on the transfer mode. The short circuit mode exerted the penetration to decrease while the spray mode did it to increase with increase of welding current. The former was considered to be responsible for the remarkable decrease in dilution at low welding voltage region. The change of transfer mode also had an effect on the behavior of bead width with welding current but it did not on the bead spreadability defined as W/H ratio. It was considered that the optimal welding conditions for multi-pass overlay welding could be obtained from the bead spreadability suitable for bead lapping and the dilution as low as possible in the spray transfer mode.