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Partial Molal Volume and Viscosity of Tetraethylammonium Chloride in Dimethyl Sulfoxide-Water Mixtures (Dimethyl Sulfoxide-물 混合溶媒中에서 Tetraethylammonium Chloride의 分몰容積 및 粘度에 관한 硏究)

  • Cho Byung Rin;Lee Yong Ja;Lee Ikchoon
    • Journal of the Korean Chemical Society
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    • v.19 no.1
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    • pp.3-10
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    • 1975
  • The partial molal volumes and relative viscosities of tetraethylammonium chloride in a series of dimethyl sulfoxide (DMSO)-water mixtures were measured at $30^{\circ}C$. A maximum structuredness of solvent, that leads to a minimum viscosity A-coefficient and a maximum viscosity B-coefficient of the Jones-Dole equation(${\eta}_r=1+AC^{1/2}$ + BC), was found at 0.2${\sim}$0.3 mole fraction of DMSO. The solvent structure, that leads to a minimum partial molal volume due to the maximum electrostrictive effect of chloride ion and to a minimum viscosity B-coefficient, was found at 0.4${\sim}$0.5 mole fraction of DMSO. An approximate relationship between the limiting effective flowing volume, $V_e^{\circ}$, and the B-coefficient was found to be B = 2.5 $V_e^{\circ}$ in the Einstein equation.

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Effects of Addition of Apple pomace to sawdust substrate on the Growth and Development of Flammulina velutipes (사과가공부산물 첨가배지가 팽이버섯(Flammulina velutipes)의 균사생장과 자실체에 미치는 영향)

  • Jo, Woo-Sik;Yun, Yeong-Seok;Rew, Young-Hyun;Park, Sun-Do;Choi, Boo-Sull
    • The Korean Journal of Mycology
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    • v.24 no.3 s.78
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    • pp.223-227
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    • 1996
  • The effects of addition of dried apple pomace to sawdust substrate on the growth of Flammulina velutipes were investigated during the period of 2 years $(1994{\sim}1995)$. Dried apple pomace used in this study consisted of 44.6% C, 0.54% N, 0.16% CaO, 0.16% $P_2O_5$, 0.11% MgO and 1.29% $K_2O$ (pH 4.4). The addition of 15% apple pomace (v/v) increased the yield of the mushroom fruitbody by 9%, and period of primordia formation was similar regardless of the treatments. In economical analysis, the addition of 15% apple pomace (v/v) increased 29% compared to the control treatment in relative income.

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Evaluation of Thrombolytic Effect of Streptokinase-Dextran Conjugate in a Rat Model of Arterial Thrombosis (흰쥐의 대퇴동맥 혈전 모델에서의 스트렙토키나제-덱스트란 포합체의 혈전용해효과의 평가)

  • Kim, Yang-Woo;Kim, Dong-Chool
    • Journal of Pharmaceutical Investigation
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    • v.29 no.3
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    • pp.211-216
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    • 1999
  • To evaluate the thrombolytic activity of streptokinase-dextran conjugate, a rat model of arterial thrombosis was used. Briefly, the femoral artery was exposed and a filter paper saturated with 70% $FeCl_3$ solution was placed around the femoral artery in order to stop the blood flow. Six minutes after the stop of the blood flow in the femoral artery, streptokinase $(10000{\sim}30000\;units\;per\;rat)$ or streptokinase-dextran conjugate $(5000{\sim}17000\;units\;per\;rat)$ was administered by i.v. bolus injection through the femoral vein. Then the blood flow in the femoral artery was monitored using a Doppler laser flow meter. The i.v. bolus administration of streptokinase could not restore the blood flow in the femoral artery in the dose range of $10000{\sim}30000$ units per rat. The i.v. bolus administration of streptokinase-dextran conjugate could restore the blood flow in the femoral artery in the dose range of $5000{\sim}17000$ units per rat. A good correlation between the dose of streptokinase-dextran conjugate and the total thrombolytic effect was observed. In addition, the lag time between the injection of streptokinase-dextran conjugate and the restoring of the blood flow was decreased as the i.v. dose of streptokinase dextran conjugate increased. These results show the superior beneficial effect of streptokinase-dextran conjugate compared with the unconjugated streptokinase with respect to the elongation of thrombolytic activity, the administration method (single injection versus continuous infusion), and the reduced dose necessary for a equivalent thrombolytic effect.

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EMC filter development for ships mounted electromagnetic (선박 탑재 전자기기용 EMC 필터 개발)

  • Kim, Eun-Mi;Jeon, Mi-Hwa;Kim, Dong-Il
    • Proceedings of the Korean Institute of Navigation and Port Research Conference
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    • 2009.06a
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    • pp.183-184
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    • 2009
  • In this paper the internal or external of the ships mounted electronic devices due to the propagation of electromagnetic interference and to prevent malfunction EMC filter was designed and fabricated. It was designed and fabricated with Ni-Zn ferrite beads of high permeability to make large inductance as the inductor and Feed-through capacitors, which did not have any resonance point, to restraint resonance effectively, and the characteristics was evaluated. The results from the 0 kHz$\sim$1.5 GHz bandwidth of $25{\sim}70$ dB were able to obtain excellent attenuation characteristics. And, when the Electric Fast Transient (EFT) of 4 kV in the level 4 of IEC 61000-4-4 was induced, it was soon attenuated more than 1/6 to 600 V. Therefore, it was confirmed that the developed EMC filter can be used for suppressing ships mounted electromagnetic interference between electronic devices.

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The Biosensor for L-Glutamine Using Tissue Slices of Wistar Rat (Wistar 쥐 조직을 이용한 L-Glutamine 바이오센서)

  • Bae, Jin Hyeon;Choe, Seong Mun;Im, Dong Jun;Kim, Wi Rak
    • Journal of the Korean Chemical Society
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    • v.38 no.3
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    • pp.200-207
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    • 1994
  • A biosensor for the measurement of L-glutamine has been constructed by immobilizing the slice of Wistar rat kidney and it's organelle on $NH_3$ gas-sensing electrode. The effects of pH, buffer solution, temperature and thickness of slice were investigated in order to optimize electrode response. The tissue sensor had the linearity in the range of L-glutamine concentration $8.0{\times}10^{-5}{\sim}1.0{\times}10^{-2} M$ with a slope of 53.8 mV/decade in 0.05 M phosphate buffer solution, pH 7.8 at $30^{\circ}C$, and optimum thickness of slice and response time were 30 ${\mu}m$ and 3∼5 min, respectively. The organelle sensor showed the linearity within L-glutamine concentration range of $1.2{\times}10^{-4}{\sim}5.0{\times}10^{-3} M$ with a slope of 54.0 mV/decade in 0.05 M phosphate buffer solution, pH 7.8 at $30^{\circ}C$, and response time was 6∼7 min, respectively. Thus, it is clear that the tissue and organelle sensor will be useful for L-glutamine measurements.

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Thermophysical Properties of the Soybean Curd and Prediction of its Thermal Conductivity 1 Measurement of Thermophysical Properties of the Soybean Curd (두부의 전열물성 및 유효열전도도의 추정 1. 두부의 전열물성의 추정)

  • KONG Jai-Yul
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.15 no.3
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    • pp.211-218
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    • 1982
  • The specific heat capacity and density of soybean oil and soy protein composing of the soybean curd were measured between $30^{\circ}C\;and\;-40^{\circ}C$. The thermal conductivity of soybean oil was measured to be 0.160 and 0.140, $W/m{\cdot}K$ at unfrozen and frozen states, respectively. The effective thermal conductivity of the soybean curd depended not only on its water content but also on its fat and protein contents.

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InSb 적외선 감지 소자용 $Si_3N_4$, $SiO_2$ 절연막 계면 특성 연구

  • Park, Se-Hun;Lee, Jae-Yeol;Kim, Jeong-Seop;Kim, Su-Jin;Seok, Cheol-Gyun;Yang, Chang-Jae;Park, Jin-Seop;Yun, Ui-Jun
    • Proceedings of the Korean Vacuum Society Conference
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    • 2010.08a
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    • pp.163-163
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    • 2010
  • 중적외선 영역 ($3{\sim}5\;{\mu}m$)은 공기 중에 존재하는 이산화탄소나 수증기에 의해 흡수가 일어나지 않기 때문에 군사적으로 중요한 파장 영역이며, 야간에 적을 탐지하는데 응용되고 있다. InSb는 77 K에서 중적외선 파장 흡수에 적합한 밴드갭 에너지 (0.228 eV)를 갖고 있으며, 다른 화합물 반도체와 달리 전하 수송자 이동도 (전자: $10^6\;cm^2/Vs$, 정공: $10^4\;cm^2/Vs$)가 매우 빠르기 때문에 적외선 화상 감지기 재료로 매우 적합하다. 또한 현재 중적외선 영역대에서 널리 사용되는 HgCdTe (MCT)와 대등한 소자 성능을 나타냄과 동시에 낮은 기판 가격, 소자의 제작 용이성 때문에 MCT를 대체할 물질로 주목 받고 있다. 하지만, 기판과 절연막의 계면에 존재하는 결함 때문에 에너지 밴드갭 내에 에너지 준위를 형성하여 높은 누설 전류 특성을 보인다. 따라서 InSb 적외선 소자의 구현을 위하여 고품질의 절연막의 연구가 필수적이라고 할 수 있겠다. 절연막의 특성을 알아보기 위해, n형 InSb 기판에 플라즈마 화학 기상 증착법 (PECVD)을 이용하여 $SiO_2$, $Si_3N_4$를 증착하였으며, 증착 온도를 $120^{\circ}C$에서 $240^{\circ}C$까지 $40^{\circ}C$ 간격으로 변화하여 증착온도가 미치는 영향에 대하여 알아보았다. 절연막과 기판의 계면 특성을 분석하기 위하여 77 K에서 커패시턴스-전압 (C-V) 분석을 하였으며, 계면 트랩 밀도는 Terman method를 이용하여 계산하였다 [1]. $Si_3N_4$를 증착하였을 경우, $120{\sim}240^{\circ}C$의 증착 온도에서 $2.4{\sim}4.9{\times}10^{12}\;cm^{-2}eV^{-1}$의 계면 트랩 밀도를 가졌으며, 증착 온도가 증가할수록 계면 트랩 밀도가 증가하는 경향을 보였다. 또한 모든 증착 온도에서 flat band voltage가 음의 전압으로 이동하였다. $SiO_2$의 경우 $120{\sim}200^{\circ}C$의 증착온도에서 $7.1{\sim}7.3{\times}10^{11}\;cm^{-2}eV^{-1}$의 계면 트랩 밀도 값을 보였으나, $240^{\circ}C$ 이상에서 계면 트랩밀도가 $12{\times}10^{11}\;cm^{-2}eV^{-1}$로 크게 증가하였다. $SiO_2$ 절연막을 사용함으로써, $Si_3N_4$ 대비 약 25% 정도 낮은 계면 트랩 밀도를 얻을 수 있었으며, 모든 증착 온도에서 양의 전압으로 flat band voltage가 이동하였다. 두 절연막에 대한 계면 트랩의 원인을 분석하기 위하여 XPS 측정을 진행하였으며, 깊이에 따른 조성 분석을 하였다. 본 실험에서 최적화된 $SiO_2$ 절연막을 이용하여 InSb 소자의 pn 접합 연구를 진행하였다. Be+ 이온 주입을 진행하고, 급속열처리(RTA) 공정을 통하여 p층을 형성하였다. -0.1 V에서 16 nA의 누설 전류 값을 보였으며, $2.6{\times}10^3\;{\Omega}\;cm^2$의 RoA (zero bias resistance area)를 얻을 수 있었다.

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Rheological Properties of Flour Dough Added Power of Poria Cocos Wolf (백복령분말을 첨가한 밀가루 반죽의 물성특성)

  • Shin, Gil-Man
    • Food Science and Preservation
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    • v.15 no.2
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    • pp.197-202
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    • 2008
  • The effects of flour dough by addition of Poria Cocos Wolf powder were investigated in dough added with $0{\sim}5%$ powder by evaluation of dough. Rheological properties of dough by mixograph, farinograph, alveograph and extensograph, and scanning electron microscope. The water absorption rate and resistance were increased by Increase of Poria Cocos Wolf powder. Mixograph for dough stability and v/v point dough were increased in dough added $1{\sim}2$ percent of Poria Cocos Wolf powder. In water absorption, stability and valorimeter value of the dough increased in weakness of the dough, as revealed through farinogram, extensiblity, resistance to extension, and energy increased in R/E ratio, as revealed through extensogram. Scanning electron microscope of bread wasn't changed by Poria Cocos Wolf powder.

DNA Selective Immobilization on a Microcantilever with Nano-Interdigitated Electrodes (Nano-IDEs) Using Cyclic Voltammetry (맞물린 나노전극을 가지는 마이크로 캔틸레버의 제작 및 순환전압전류방법을 이용한 DNA의 선택적인 고정화)

  • Lee, Jung-A;Lee, Kwang-Cheol
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.32 no.6
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    • pp.459-464
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    • 2008
  • We present a novel microcantilever device with nano-interdigitated electrodes (nano-IDEs) and DNA selective immobilization on the nano-IDEs for biosensing applications. Using the nano-IDEs and cyclic voltammetric methods, we have achieved selective immobilization of DNA with submicrometer spatial resolution on a freestanding microcantilever. $70{\sim}500\;nm$-wide gold (Au) nano-IDEs are fabricated on a low-stress SiNx microcantilever with dimensions of $100{\sim}600\;{\mu}m$ in length, and $15{\sim}60\;{\mu}m$ in width, with a $0.5\;{\mu}m$ thickness using electron beam lithography and bulk micromachining. Streptavidin is selectively deposited on one side of the nano-IDEs using cyclic voltammetry at a scan rate of 0.1 V/s with a range of $-0.2{\sim}0.7\;V$ during $1{\sim}5$ cycles. The selective deposition of dsDNA is confirmed by fluorescence microscopy after labeling with YOYO-1 dye.

A Study on the Characteristics of TSC for BOPP Irradiatied by $Co^{60}-{\gamma}$ ray ($Co^{60}-{\gamma}$ 선으로 조사된 이축 연신된 폴리프로필렌 필름의 열자격 특성에 관한 연구)

  • Song, K.Y.;Park, S.H.;Ryu, B.H.;Hong, J.W.;Lee, J.U.;Kim, B.H.
    • Proceedings of the KIEE Conference
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    • 1990.07a
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    • pp.195-198
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    • 1990
  • In order to investigate the radiation effects induced to electrical properties of Biaxially-Oriented Polypropylen film, several observations were carried out to the sample irradiated to various dose by $Co^{60}-{\gamma}$ ray, on the characteristics of TSC spectra measuered as a function of electric field applied to a sample of 15[ ${\mu}m$] thick. The TSC spectra observed in the temperature range of $153{\sim}403[K]$ with the electric field of intensity $10{\sim}60$ [MV/m], have shown two of the distinguished peak such as ${\beta}$, ${\alpha}$, each of which appeared at $-5{\sim}20$ [ $^{\circ}C$] and 90 [ $^{\circ}C$] respectively. As the conclusions, obtained from the studies, the origin of ${\alpha}$ peak in TSC seems to be attributed by thermal excitation of ions trapped with $0.4{\sim}0.8[eV]$ deep, at the defects formed by $Co^{60}-{\gamma}$ irradiation in a crystaline region. The origin of ${\beta}$ peak was regarded as the depolarization process of "OH" or "CO" dipole with the activation energy of $0.4{\sim}0.6[eV]$ in an amorphous region.

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