• Title/Summary/Keyword: Urethane rubber

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Turning the Machining Characteristics of Feed-through Ceramics (피드스루용 세라믹의 선삭 가공 특성에 관한 연구)

  • Park, Se-Jin;Ha, Jun-Tae;Yang, Dong-Ho;Lee, Jong-Chan
    • Journal of the Korean Society of Manufacturing Process Engineers
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    • v.19 no.10
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    • pp.81-86
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    • 2020
  • A ceramic vacuum chamber feedthrough ceramic insulator is made of Al2O3; the manufacturing process involves filling alumina powder into a urethane mold and pressing it with a rubber press to produce a molded body. Thereafter, manufacturing is completed through primary shape processing, sintering, and secondary shape processing in the green body, which is a pressurized molding body, This work is intended to prevent defects in the first shape processing by improving the ceramic insulator in the green body, and to improve the productivity of the ceramic insulator by determining the optimal processing conditions.

Numerical Study on Effect of Using Elastic Pads in Flexible Forming Process (가변성형 공정에서 탄성 패드의 영향에 관한 수치적 연구)

  • Heo, Seong-Chan;Seo, Young-Ho;Noh, Hak-Gon;Ku, Tae-Wan;Kang, Beom-Soo
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.34 no.5
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    • pp.549-556
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    • 2010
  • In general, materials that can be used to form elastic pads, such as urethane and rubber, are often used in flexible forming processes by inserting the pads between a blank and flexible die for smoothing the forming surface that is formed by a reconfigurable die. In this study, the effects of the elastic pad on formability in the flexible forming process for sheet metals are investigated by performing numerical simulations. In the simulation, the hyperelastic material model is used, where the urethane elastic pads serve as elastic cushions. Case studies are carried out for elastic materials with different hardness values and thicknesses. The results are used to evaluate formability by comparing the configuration of the deformed blank and its major cross-sectional profiles. It is verified that the elastic pad used in the flexible forming process for sheet materials should be hard and that its thickness should be chosen appropriately.

Service Life Prediction for Steel Bridge Coatings with Type of Coating Systems (도장계 종류에 따른 강교 도장의 공용수명 예측)

  • Lee, Chan Young;Chang, Taesun
    • Journal of Korean Society of Steel Construction
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    • v.28 no.5
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    • pp.325-335
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    • 2016
  • To predict service life of coating systems registered in Korean specifications for steel bridge coatings, field deterioration evaluation and accelerated weatherproof test were carried out, and deterioration models were drawn through regression analysis for evaluation results. For the coating systems that have not been used in field, regression analyses were carried out for the virtual evaluation results drawn by applying coordination factor to the field evaluation results for chlorinated rubber and urethane topcoat system. Service life prediction results showed that application of thermal sprayed coating (TSC) could extend service life of coatings to more than twice of general coatings.

Study on Type of Different Polyols for Physical Properties of Polyurethane Foam Under Sea Water (해수에서 폴리올 종류가 폴리우레탄 폼의 물성에 미치는 영향)

  • Kim, Sang-Bum
    • Elastomers and Composites
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    • v.46 no.2
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    • pp.158-163
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    • 2011
  • Rigid polyurethane foam (PUF) was synthesized with different contents of aliphatic polyester polyol, aromatic polyester polyol and aliphatic polyether polyol to know change of properties under sea water. UTM(universal testing machine), DSC(differential scanning calorimetry), hardness meter and FT-IR(Fourier transform spectroscopy) were used to study the PUF`s physical properties under sea water. Compressive strength and hardness of PUF decreased with increasing the content of aromatic polyester polyol under sea water as aging. According to the results of IR spectral analysis, reduction of urethane and urea peak was found and allophanate and biuret peak increased. Although glass transition temperature of PUF increased, mechanical properties of PUF decreased under sea water, because PUF gets brittle when crosslink density increase.

Evaluation of the Dynamic Stiffness and Heavy-weight Floor Impact Sound Reduction by Composition of Resilient Materials (완충재 구성방법에 따른 동탄성계수 및 중량바닥충격음 저감특성 평가)

  • Kim, Kyoung-Woo;Jeong, Gab-Cheol;Sohn, Jang-Yeul
    • Transactions of the Korean Society for Noise and Vibration Engineering
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    • v.18 no.2
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    • pp.247-254
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    • 2008
  • Resilient materials are generally used for the floating floors to reduce the floor impact sound. Dynamic stiffness of resilient material, which has the most to do with the floor impact sound reduction. The resilient materials available in Korea include EPS(styrofoam), recycled urethane types, EVA(ethylene vinylacetate) foam rubber, foam PE(polyethylene). glass fiber & rock wool, recycled tire, foam polypropylene. compressed polyester, and other synthetic materials. In this study, we tested dynamic stiffness of resilient material and floor impact sound reduction characteristic to a lot of kinds of resilient materials. It was found that dynamic stiffness of multi-layered damping material could be estimated if know value of each layer that compose whole structure. And the test showed that the amount of the heavy-weight impact sound reduction appeared by being influenced from this dynamic stiffness of resilient material. The dynamic stiffness looked like between other resilient materials, a similar to the amount of the heavy-weight impact sound reduction was shown.

Characterization of Flame-Retardant Foam Asphalt (난연성 폼아스팔트 특성에 관한 연구)

  • Hong, Young-Keun
    • Elastomers and Composites
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    • v.47 no.3
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    • pp.246-253
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    • 2012
  • This study was carried out to prepare a type of warm mix asphalt. Through urethane foam and emulsion asphalt preparation techniques a protocol of asphalt foam was made. Then three kinds of flame retardant agents were added in there to alleviate the inherent susceptability of asphalt and foam material to flame and thus flame retardant asphalt foam was made. The internal structure of form asphalt was composed of open cell. The higher the NCO% brought the larger the cell and the stronger also. Asphalt increased the strength of the foam. Among the flame retardant agents employed tritorylphosphate was the most effective.

Effect of NCO/OH Ratio and Chain Extender Content on Properties of Polycarbonate Diol-based Waterborne Polyurethane

  • Kim, Eun-jin;Kwon, Yong Rok;Chang, Young-Wook;Kim, Dong Hyun
    • Elastomers and Composites
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    • v.57 no.1
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    • pp.13-19
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    • 2022
  • Polycarbonate diol-based waterborne polyurethane (WPU) was prepared by prepolymer mixing process. The prepolymer mixture contained the polycarbonate diol, isophorone diisocyanate (IPDI), dimethylol propionic acid, triethylamine, and ethylenediamine (EDA). The NCO/OH ratio in the prepolymer was adjusted by controlling the molar ratio of IPDI, and its effects on the properties of WPU were studied. The structure of WPU was characterized by fourier transform infrared spectroscopy. The average particle size increased and viscosity decreased with increasing NCO/OH ratio and EDA content in WPU. The reduced phase separation between soft and hard segments increased glass transition temperature. The reduction in the thermal decomposition temperature could be attributed to the low bond energy of urethane and urea groups, which constituted the hard segment. Additionally, the polyurethane chain mobility was restricted, elongation decreased, and tensile strength increased. The hydrogen bond between the hard segments formed a dense structure that hindered water absorption.

Effect of the Diisocyanate Type on the Hydrolysis Behavior of Polyurethane

  • Dong-Eun Kim;Seung-Ho Kang;Sang-Ho Lee
    • Elastomers and Composites
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    • v.58 no.3
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    • pp.121-127
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    • 2023
  • The effect of diisocyanate type on the decomposition temperature of polyurethane (PU) hydrolysis was investigated in a subcritical water medium up to 250℃. PU samples were prepared using different types of diisocyanate: two aromatic diisocyanates (4,4'-methylene diphenyl diisocyanate (MDI) and methyl phenylene diisocyanate (TDI)), one unbranched aliphatic diisocyanate (hexamethylene diisocyanate (HDI)), and two cyclic aliphatic diisocyanates (4,4'-methylene dicyclohexyl diisocyanate (H12MDI) and isophorone diisocyanate (IPDI)). The pressure had no effect on hydrolysis in the range of 70-250 bar. The decomposition temperature of the PU samples increased in the following order: TDI-PU (199℃) < H12MDI ≈ IPDI ≈ HDI (218-220℃) < MDI-PU (237℃). This order of increase in temperature is related to the electron-donating ability of the group to connected to the nitrogen of the urethane unit. When the temperature of the (PU + water) mixture reached the specific decomposition temperature, the PU samples hydrolyzed completely within 5 min into primary amine and 1,4-butanediol. The hydrolysis products from MDI-PU and H12MDI-PU were separated into a liquid phase rich in (BD + water) and a solid low phase rich in amine, whereas the products from TDI-, IPDI-, and HDI-PU existed in a single aqueous phase.

An Experimental Study on the Basic Properties of Elastic Paving Materials (탄성포장재의 기초물성에 관한 실험적 연구)

  • Ko, Hune-Bum;Ko, Man-Young
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.16 no.7
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    • pp.5021-5028
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    • 2015
  • Previous studies have considered the permeability and construction method of paving materials, thus focusing on more practical issues rather than basic research of their properties. The present study investigated the possibility of using an elastic paving material having lesser thickness in the resurfacing of existing concrete or asphalt paved areas while satisfying the necessary conditions of resilience and water permeability. An alternative to complete reconstruction would reduce the amount of resource wastage and environmental pollution, as well as the cost of projects. This study investigated five variants of thickness (10, 13, 15, 20, 25mm) and three mixing ratios of binder to rubber chips (20, 22.5, 25%) to ascertain the ideal basic properties of each. The obtained test data revealed that a minimum thickness(10~25mm) of the elastic paving materials can be determined from a qualitative point of view, and alternatives should be provided to improve the durability of the paving material on account of the temperature sensitivity.

Printing Technology of Nano fiber under 900nm (900nm 이하급 나노섬유의 현장적용 날염기술)

  • Yong, Kwang-Joong;Lee, Beom-Soo;Lee, Hee-Jun;Hwang, Tea-Yeon
    • Proceedings of the Korean Society of Dyers and Finishers Conference
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    • 2011.03a
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    • pp.83-83
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    • 2011
  • 나노섬유는 마이크로 섬유에 비해 $10^3$배 정도의 넓은 표면적을 가지며, 다른 섬유와 비교하여 유연성, 투습성과 같은 특성이 우수하다. 나노섬유의 제조방법은 여러 가지가 있으나, 상용화의 가능성, 적용 고분자의 다양성, 제조공정의 단순성, 다양한 제품기술에의 응용성 등을 고려하여 선택하여야 한다. 나노섬유의 제조기술은 방법에 따라 전기방사, 복합방사, 멜트블로운 공정, 에어레이드 공정, 습식 공정 등으로 나눌 수 있다. 전기방사 등 나노섬유를 대량생산하여 상용화하려는 노력을 지속적으로 하고 있으나 나노섬유의 염색가공에 관련되어 기술적 한계로 제품전개에 많은 어려움을 겪고 있다. 그리하여 본 연구에서는 나노섬유 단독으로 제품화하기에는 강도 등의 문제로 PET에 워터펀칭한 복합소재로 개발하여 900nm 이하의 나노섬유에 대한 최적의 날염조건과 현장적용 생산기술을 개발하고자 하였다. 나노섬유 복합소재에 대하여 Brown, Red, Blue, Black 색상의 안료와 Urethane, Rubber, Acrylic, Eco Binder를 사용하여 날염 실험하였으며, 최적의 조건으로 현장생산에 적용하여 생산하였다. 안료의 고착성을 높여 날염성과 염색견뢰도를 증진시키기 위하여 원적외선 열처리기를 개발하여 현장생산에 접목시켰다. 원적외선 열처리기는 벙커C유 또는 가스 등을 사용하는 텐터나 증열기와는 다르게 전기를 에너지원으로 하여 원적외선 램프를 이용한 건열시스템의 형태로 저공해 및 그린 형태의 열처리기 시스템으로, 섬유에 대한 원적외선의 조사거리, 원적외선 램프의 간격, 적용 온도, 원단이송 속도 등에 따른 최적의 원적외선 열처리기 날염조건을 설정하였다. 바인더에 따른 날염성은 우레탄계 바인더를 사용하였을 경우에 가장 선명하고 깊은 색상을 보였으며, 아크릴계 바인더의 경우가 가장 낮은 색상을 보였으며 염색견뢰도는 대체적으로 양호한 결과를 얻었다. 그리고, 최근 환경적인 추세에 맞추어 에코 바인더를 사용하여 날염한 결과 염색성과 내구성 등은 우레탄계와 아크릴계 바인더의 중간 정도의 결과를 보였다.

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