• Title/Summary/Keyword: Urea-water Solution

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Quantification of Karanjin Using High Performance Liquid Chromatography in Raw and Detoxified Karanj (Pongamia glabra vent) Seed Cake

  • Prabhu, T.M.;Devakumar, C.;Sastry, V.R.B.;Agrawa, D.K.
    • Asian-Australasian Journal of Animal Sciences
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    • v.15 no.3
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    • pp.416-420
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    • 2002
  • Various products of karanj (Pongamia glabra) are utilized for industrial, health and animal agriculture applications in the Indian subcontinent. Despite a rich source of protein (CP, 28-34%), karanj cake was found to be slightly bitter in taste and toxic owing to the presence of flavonoid (Karanjin), restricting its safe inclusion in the livestock diets. Feeding trials with raw cake revealed its poor palatability and adverse performance among different categories of livestock including poultry. The present study was, therefore, aimed to detoxify karanj cake by various physico-chemical methods like solvent extraction, water washing, pressure cooking and alkali and acid treatments. The level of residual karanjin in raw and variously processed cake was quantified using high performance liquid chromatography (HPLC). The raw expeller karanj cake was found to contain about 0.19% of karanjin. Though a non-polar solvent, soxhlet extraction of expeller pressed cake with petroleum ether drastically reduced karanjin content (0.01%). Soaking of cake for 24 h in 1% NaOH (w/w) solution was found to reduce karanjin to a major extent with little further benefit by increasing alkali level. Milder alkalies like lime and fertilizer grade urea reduced the karanjin levels marginally. Similar was the case with mineral acids such as HCl and glacial acetic acid. It was, therefore, concluded that solvent extraction of karanj seeds would be the best method of detoxification as well as for more recovery of oil and karanjin.

Granulation Characteristics of Mono-granular NPK(10-0-30) Fertilizer Incorporated with Rock-Phosphate Powder and its Effects on Tobacco Plant (인광석분말을 증량제로 사용한 연초(煙草)재배용 복합비료(10-0-30)의 조립(造粒)특성 및 비효)

  • Lee, Yun-Hwan;Jeong, Hun-Chae;Kim, Yong-Yeon
    • Korean Journal of Soil Science and Fertilizer
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    • v.35 no.5
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    • pp.290-295
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    • 2002
  • Fertilizer granulation test was carried out by a small pan granulator. A premixture composed of SOP 60%, urea 22% and RP powder 18% was rolled in the pan granulator while 10% phosphoric acid solution(binder) was sprayed on the rolling powder bed. Granules were developed very fast along with a little amount of binder. Hardness, brittle ratio in water and hygroscopicity of granules were improved enough to evaluate physical properties of the fertilizer. Growth responses of tobacco plant to the fertilizer were investigated at seedling and flowering stage by pot experiment under plastic film roof. Seedlings showed poor growth at nursery pot cell. In virgin soil with deficient available phosphate tobacco plant showed poor growth until budding and flowering stage but good growth in tillage soil with high cumulative phosphate.

Effect of Mixer Structure on Turbulence and Mixing with Urea-water Solution in Marine SCR System (선박용 SCR 시스템에서 혼합기 구조에 따른 난류유동과 우레아 수용액의 혼합특성)

  • Kim, Tae-Kyoung;Sung, Yon-Mo;Han, Seung-Han;Ha, Sang-Jun;Choi, Gyung-Min;Kim, Duck-Jool
    • Journal of Advanced Marine Engineering and Technology
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    • v.36 no.6
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    • pp.814-822
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    • 2012
  • To improve the flow and mixing characteristics of marine SCR system, two different mixer including up-down and swirl type mixer were considered. The purpose of this study is to analyse turbulence intensity and uniformity index in detail and to improve the performance of SCR with respect to the mixer structure. The results showed that, the concentration uniformity index is improved by about 5% with the utilization of both mixers in the front of catalyst part. Although the RMS value and relative turbulence intensity increased after the up-down type mixer, it could observed that the value of two parameters decreased with the flow proceeding forward to the downstream. For the case of swirl type mixer, the decrease of RMS value and relative turbulence intensity were relatively smaller than that of up-down type mixer, and uniform distribution of relative turbulence intensity was observed. As a results, it could be concluded that the mixing effects and the distance of the two kinds of mixer were different.

A Study on the Dyeing Technology for Thin Cloth of Microfiber (섬유의 극세섬유 부지물 염색가공기술에 관한 연구)

  • Cho Seung Shick;Lee Sun Jae;Hong Youn Sook
    • Journal of the Korean Society of Clothing and Textiles
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    • v.9 no.2
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    • pp.75-84
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    • 1985
  • In order to improve dyeing and finishing technology of thin cloth of microfiber(super-fine fiber), the degrees of deep dyeing method, the light fastness, and the washing fastness were investiagted. 1. The thin cloth made of microfiber, $0.15^d\~0.2^d$, was conjugated type and the dyeing degree was lower at 5 to $10\%$ than that of cloth made of common fiber. The cloth of excellent dyeing fastness, light fastness, was developed by increasing the concentration of dye of high quality up to $5\~10\%$. 2. Because refractory rate of microfiber of $0.2^d$ was lower than that of $0.01^d$, the surface refractory rate of $0.2^d$ was lower than that of $0.01^d$ fiber. Therefore the surface of micro-fiber, $0.2^d$, was more rougher than that of $0.01^d$ and it belongs to separate type. 3. The higher degree of dyeing was increased by using dye of microparticle. Also the degree of textile printing was increased by adding urea solution ($20\%$) and glycerine diethylene glycol. 4. Light fastness was very excellent, marked 5 grade. However, washing fastness was 2$\~$3 grade. After dyeing, we could improve to 4 grade, through hot water washing including some organic chlorine solvent. 5. Super microfiber of $0.01^d$ will not be dyed by present dye and dyeing equipment, because right reflection light rate(white light) of fiber surface was too high and the more refraction rate higher the more surface refraction rate will be increased.

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An Experimental Study on Optimization of $NH_3$ Injection for the Selective Catalytic Reduction(SCR) System (선택적 환원 촉매(SCR)에서 암모니아($NH_3$) 분사량 최적화에 대한 실험적 연구)

  • Jang, Ik-Kyoo;Yoon, Yu-Bin;Park, Young-Joon;Lee, Seang-Wock;Cho, Yong-Seok
    • Proceedings of the KSME Conference
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    • 2008.11b
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    • pp.2874-2879
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    • 2008
  • The Selective catalytic reduction(SCR) system is a highly-effective device of $NO_x$ reduction for diesel engines. Generally, the ammonia($NH_3$) generated from a liquid urea-water solution is used for the reductant. The ideal ratio of $NH_3$ molecules to $NO_x$ molecules is 1:1 based on $NH_3$ consumption and having $NH_3$ available for reaction of all of the exhaust $NO_x$. However, under the too low and too high temperature condition, the $NO_x$ reduction efficiency becomes lower, due to temperature window. And space velocity also affects to $NO_x$ conversion efficiency. This paper reviews a laboratory study to evaluate the effects of $NO_x$ and $NH_3$ concentrations, gas temperature and space velocity on the $NO_x$ conversion efficiency of the SCR system. The maximum conversion efficiency of $NO_x$ was indicated when the $NH_3$ to $NO_x$ ratio was 1.2 and the space velocity was $60,000\;h^{-1}$. The results of this paper contribute to improve overall $NO_x$ reduction efficiency and $NH_3$ slip.

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Improvement of floating ability and storage stability for jumbo granules (수면부상성 점보입제의 수면부상성 및 경시분해 안정성 개선)

  • Kim, Seung-Ho;An, Byoung-Woo;Chung, Bong-Jin
    • The Korean Journal of Pesticide Science
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    • v.2 no.1
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    • pp.32-39
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    • 1998
  • This study was performed to develop jumbo granules floated and spreaded on the water surface after application, having low production and formulation cost, and safe to environment for paddy herbicides and to establish the formulation recipe. The jumbo granules of azimsulfuron with molinate(0.075+7.5%) was formulated by KCl as water soluble carrier and paraffin oil as solvent to impose the floating and spreading force to granules. That showed 100% of total granules to be floated on and spreaded upto the water surface within 25 minutes after application. Change in carriers, surfactants and pH did not affected to improve the time-course degradation of azimsulfuron in jumbo granules, but salt formation of azimsulfuron added by 1.15M solution of NaOH a little. Addition of N-methyl acrylate and modification of formulation process affected decrease in degradation of azimsulfuron upto 1.2, 2.1, and 7.2% after 2, 6 and 12 weeks under storage at $40{\pm}2^{\circ}C$, respectively, which showed the establishment of formulation recipe of the jumbo granules.

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Study on Enhancement of Ammonia Generation for Effective Collision Frequency (유효충돌빈도를 고려한 암모니아 생성 증대기법 연구)

  • Sejin Kim;Yongseok CHoi;Hyunchul Park
    • Journal of Aerospace System Engineering
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    • v.17 no.6
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    • pp.1-8
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    • 2023
  • Research, such as developing alternative energy in the transportation field, including aviation, is being actively conducted to solve the issue of current climate change. Interest in ammonia fuel as a carbon free energy (CFE) source is increasing due to the ease of liquefaction and transportation and similarity in energy density to that of methanol. However, explosiveness and toxicity of ammonia make it difficult to handle. Therefore, in this study, stable ammonia production was attempted using relatively easy-to-handle urea water solution (UWS). High temperature steam was used to promote the hydrolysis of ammonia. In order to determine the causes for ammonia production below the theoretical equivalent ratio, it was suggested that there were not enough collisions to promote the hydrolysis based on the kinetic theory of gases. The hydrolysis of unreacted isocyanic acid (HNCO) was tested according to the change in water supply. As a result, an increased amount of ammonia produced was confirmed. The increased amount of ammonia produced in a certain section was dependent on the steam temperature and the flow rate of water supplied.

Histological and Biochemical Study on the Effects of the Green-Tea in Rat Kidney Toxicated by Lead (녹차가 납중독된 흰쥐의 신장에 미치는 조직학적 및 생화학적 연구)

  • Chung, Kyoung-A;Roh, Young-Bok
    • Applied Microscopy
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    • v.30 no.3
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    • pp.273-283
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    • 2000
  • To investigate the defensive effect of green tea against the lead toxicity, Sprague-Dewley rats (150 gm) were divided into 5 groups; the control group (A), the group treated with lead for 4 weeks (Group B-1), the group treated with lead and green tea for 4 weeks (Group B-2), the group treated with lead for 8 weeks (Group C-1), and the group treated with lead and green tea for 8 weeks (Group C-2). The lead acetate (500 ppm) was injected two times for one week into the abdomen and green tea solution (3 g/100 ml distilled water) offered freely. The results of histological and biocheical study are as follows; 1. Blood Urea Nitrogen (BUN) were increased in all the tested groups. The Group B-1 was more increased than the Group B-2, and the Group C-1 more than the Group C-2. The values of Alkaline phosphatase (ALP) were also decreased in all the tested groups, as such the former phenomenon. 2 In the Group B-1, some microvilli, mitochondria and rER were modificated on epithelial cell of proximal renal tubules. The cristae of mitochondria were enlarged, microvilli and nucleus were observed normally on the Group B-2. The number of Microvilli, mitochodria and rER were decreased, many lysosomes and irregular nucleus observed in the Group C-1. In the Group C-2, microvilli were modificated slightly and other organelles were observed similary with the Group B-2.

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Effects of Treatment Methods of Fire-retardant and Layup of Treated Veneers on the Performances of Plywoods (내화약제(耐火藥劑)의 처리방법(處理方法) 및 처리단판(處理單板)의 조판형태(調板形態)가 합판(슴板)의 성능(性能)에 미치는 영향(影響))

  • Son, Jung-Il;Cho, Jae-Sung;Suh, Jin-Suk
    • Journal of the Korean Wood Science and Technology
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    • v.27 no.3
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    • pp.39-50
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    • 1999
  • This research was carried out to investigate the development of fire-retardancy treatment technology and performance evaluation of fire-retardant treated plywoods. Radiata pine, keruing, dillenia, calophyllum and terminalia veneers were treated by normal(conventional) pressure soak(NPS) and vacuum-pressure-soak(VPS) using 20% water solution of diammonium phosphate. Then, 4.8mm thick, 3ply plywoods were fabricated with combination of fire-retardant treated, untreated or water-immersion types and several composition types of radiata pine and keruing veneers, i,e. the uniform and the mixed types in species composition, and the homogenious and the alternate layer types in veneer treatment. In composed species, the retention and the treatment effects of fire-retardant chemicals III radiata pine was still greater than those of keruing. The effect of VPS treatment was larger than that of NPS treatment, however, adhesive bonding strength and bending strength of plywoods treated by these two methods were not necessarily lowered, compared to those of untreated plywood. And also, fire endurance performance of the urea melamine resin-bonded plywood was greater than that of the phenol resin-bonded plywood. In result, the appropriate combination in veneer species and layer as well as alternate fire-retardant treatments would be more efficiently available in service.

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Studies on the Manufacture of Fiber Pot and its Effect for the Good Transplanting (이식용(移植用)Pot의 제조(製造) 및 그 효과(効果)에 관(關)한 연구(硏究))

  • Kim, Ji Moon;Lee, Hwa Hyung;Kwon, Ki Won;Song, Ho Kyong
    • Journal of Korean Society of Forest Science
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    • v.46 no.1
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    • pp.1-9
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    • 1980
  • This study was carried out to examine the substitution possibility into fiber pot instead of Jiffy pot for the good transplanting. Fiber pot was made of fiber, wood waste particle, and bark powder (10% of the particle weight) and also latex was added into the furnish as a binder. The pots were sprayed with just enough urea solution to prevent nitrogen deficiency of pot media coming from the breakdown of wood fiber in the pot wan during the plant growing. The utility of fiber pot was compared with that of Jiffy pot in the service test of two tree species under a green-house condition. The results obtained can be summarized as follows ; 1. Fiber pot made of 30% wood fiber+70% particle including 10% of bark powder, and 3%-latex has shown a good results like that of Jiffy pot in the sp. gr., tear factor and burst factor. For water absorption, fiber pot made of 50% fiber+50% particle, and 3%-latex got the best result. In the consideration of the above physical and mechanical properties of the fiber pot for good root penetration through the pot wall and facile handling, fiber pot made of 30% fiber+70% particle, and 3%-latex may be seemed to be good. 2. There were no harms in sapling growth in fiber pot as well as in Jiffy pot. The root penetration ability through the fiber pot was slightly inferior to that of Jiffy pot, and yet the pot damage through transportation seemed to be slighter in fiber pot than in Jiffy pot.

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