• Title/Summary/Keyword: Uniform Temperature

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A Study on Reaction Rate of Solid SCR for NOx Reduction of Exhaust Emissions in Diesel Engine (디젤엔진 배출가스 질소산화물 저감을 위한 Solid SCR의 반응률에 관한 연구)

  • Lee, Hoyeol;Yoon, Cheon Seog;Kim, Hongsuk
    • Transactions of the Korean Society of Automotive Engineers
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    • v.21 no.6
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    • pp.183-194
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    • 2013
  • Liquid urea based SCR has been used in the market to reduce NOx in the exhaust emission of the diesel engine vehicle. This system has several problems at low temperature, which are freezing below $-12^{\circ}C$, solid deposit formation in the exhaust, and difficulties in dosing system at exhaust temperature below $200^{\circ}C$. Also, it is required complicated exhaust packaging equipment and mixer due to supply uniform ammonia concentration. In order to solve these issues, solid urea, ammonium carbonate, and ammonium carbamate are selected as ammonia sources for the application of solid SCR. In this paper, basic research on reaction rate of three ammonia-transporting materials was performed. TGA (Thermogravimetric Analysis) and DTA (Differential Thermal Analysis) tests for these materials are carried out for various heating conditions. From the results, chemical kinetic parameters such as activation energy and frequency factor are obtained from the Arrhenius plot. Additionally, from test results of DSC (Differential Scanning Calorimeter) for these materials, chemical kinetic parameters using the Kissinger method are calculated. Activation energies of solid SCR from this experiment are compared with proper data of literature study, then obtained data of this experiment are used for the design of reactor and dosing system for candidate vehicle.

Laminar Convective Heat Transfer in Vertical Square Duct with Variational Symmetric Heat Flux (비균일 대칭성 열Flux인 수직 사각 닥트내의 층류조합대류 열전달 효과)

  • 김시영
    • Journal of the Korean Society of Fisheries and Ocean Technology
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    • v.18 no.1
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    • pp.47-53
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    • 1982
  • An analysis of convection, in a fully developed laminar steady flow through the vertical square duct under the condition of variational symmetric heat flux, is considered. Finite element solution algorithm by Galerkin's method with triangular elements and linear interpolation polynominals for the temperature and velocity profiles are derived for the vertical square duct. The comparison of temperature distribution due to variational symmetric heat flux in the duct were made with available the other data when the condition of peripheral heat flux were uniform and zero. Numerical values for the dimensionless temperatures and Nusselt numbers at selected Rayleigh numbers and pressure gradient parameters were obtained at a few nodal points for the vertical square ducts and effects of corner in the duct were investigated.

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Effect of Dietary L-ascorbic Acid (L-AA) on Production Performance, Egg Quality Traits and Fertility in Japanese Quail (Coturnix japonica) at Low Ambient Temperature

  • Shit, N.;Singh, R.P.;Sastry, K.V.H.;Agarwal, R.;Singh, R.;Pandey, N.K.;Mohan, J.
    • Asian-Australasian Journal of Animal Sciences
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    • v.25 no.7
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    • pp.1009-1014
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    • 2012
  • Environmental stress boosts the levels of stress hormones and accelerates energy expenditure which subsequently imbalance the body's homeostasis. L-ascorbic acid (L-AA) has been recognized to mitigate the negative impact of environmental stress on production performances in birds. The present investigation was carried out to elucidate the effect of different dietary levels of L-AA on production performance, egg quality traits and fertility in Japanese quail at low ambient temperature. Sixty matured females (15 wks) were equally divided into three groups (20/group) based on the different dietary levels of L-AA (0, 250 and 500 ppm) and coupled with an equal number of males (1:1) obtained from the same hatch. They were managed in uniform husbandry conditions without restriction of feed and water at 14 h photo-schedule. Except for feed efficiency, body weight change, feed consumption and hen-day egg production were recorded highest in 500 ppm L-AA supplemented groups. Among the all egg quality traits studied, only specific gravity, shell weight and thickness differed significantly (p<0.05) in the present study. Fertility was improved significantly ($p{\leq}0.01$) to a dose dependent manner of L-AA. The findings of the present study concluded that dietary L-AA can be a caring management practice at least in part to alleviate the adverse effect of cold induced stress on production performance in Japanese quail.

Effect of Seed-layer on the Crystallization and Electric Properties of SBN60 Thin Films (SBN60 박막의 결정화 및 전기적 특성에 관한 씨앗층의 영향)

  • Jang, Jae-Hoon;Lee, Dong-Gun;Lee, Hee-Young;Jo, Sang-Hee
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2003.07b
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    • pp.723-727
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    • 2003
  • [ $Sr_xBa_{1-x}Nb_2O_6$ ] (SBN, $0.25{\leq}x{\leq}0.75$) ceramic is a ferroelectric material with tetragonal tungsten bronze (TTB) type structure, which has a high pyroelectric coefficient and a nonlinear electro-optic coefficient value. In spite of its advantages, SBN has not been investigated well compared to other ferroelectric materials with perovskite structure. In this study, SBN thin film was manufactured by ion beam sputtering technique using the prepared SBN target in $Ar/O_2$ atmosphere. SBN30 thin film of $1000{\AA}$ was pre-deposited as a seed layer on $Pt(100)/TiO_2/SiO_2/Si$ substrate followed by SBN60 deposition up to $3000{\AA}$ in thickness. As-deposited SBN60/SBN30 layer was heat-treated at different temperatures of 650, 700, 750, and $800^{\circ}C$ in air, respectively The crystallinity and orientation behavior as well as electric properties of SBN60/SBN30 multi-layer were examined. The deposited layer was uniform and the orientation was shown primarily along (001) plane from XRD pattern. There was no difference in the crystal structure with heat-treatment temperature, but the electric properties depended on the heating temperature and was the best at $750^{\circ}C$. In electric properties of Pt/SBN60/SBN30/Pt thin film capacitor prepared, the remnant polarization (2Pr) value was $15{\mu}C/cm^2$, the coercive field (Ec) 75 kV/cm, and the dielectric constant 1075, respectively.

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Advanced Transmittance and Surface-Morphology of CdS thin films prepared by chemical bath deposition using various complexing agents for solar cells (용액 증착법으로 증착된 CdS 박막의 제조와 고상과 액상 화합제에 따른 표면 특성 비교)

  • Yoo, Beom-Keun;Kim, Jin-Sang;Park, Yong-Wook;Choi, Doo-Jin;Yoon, Seok-Jin
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2008.11a
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    • pp.456-456
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    • 2008
  • In the past few years, the deposition and characterization of cadmium sulfide semiconducting thin films has received a considerable amount of interest due to their potential application in the area of electronic and opto-electronic devices fabrications. Polycrystalline CdS thin films posses good optical transmittance, wide band-gap and electrical properties makes it as one of the ideal material for their application to solar cell fabrication. Cadmium sulfate thin films were deposited by the chemical bath deposition method using tartaric acid and triethanolamine as a complexing agent. Deposition parameters such as pH, temperature, deposition time and concentration of the reactant species were optimized so as to obtain reflecting, good adherent uniform thin films on the glass substrate. Reaction mechanism of the thin film formation is also reported. The crystallographic structure and the crystallite size were studied by the X-ray diffraction pattern. The optical band-gap of deposited film is identified by measuring the transmittance in the visible region. Temperature dependence of resistivity confirmed the semiconducting behavior of the film. Scanning electron micrographs (SEM) showed the presence of grain particles of size 50 nm.

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Thermal Deformation Measurement Spherical Glasses Lens Using ESPI (ESPI를 이용한 안경용 렌즈의 열변형 측정)

  • Kim, Koung-Suk;Jang, Ho-Sub;Kim, Hyun-Min;Yang, Seung-Pill
    • Journal of the Korean Society for Nondestructive Testing
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    • v.28 no.2
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    • pp.137-143
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    • 2008
  • The spherical glasses lenses are typically classified into two groups such as (+) diopter lens and (-) diopter lens by the refractive power index. The thermal deformation of a lens is occurred by external heat source and is changed respected to the diopter of a lens. In this paper, the thermal deformation of spherical glasses lenses were quantitatively measured by using ESPI (electronic speckle pattern interferometry) which has an advantage that the non-contact, non-destructive and precise deformation measurement is available due to the coherency characteristic. The temperature changes were measured by IR camera. It makes experiments over 14 types of the plastic glasses lenses. From the results, it was confirmed that the larger diopter lens showed the less thermal deformation in case of the (+) diopter lens. On the other hand, the thermal deformation of the (-) diopter lens was measured with uniform pattern when the same temperature changes were applied. Also, it was found that the thermnal deformation of the (+) diopter lens is less than that of the (-) diopter lens. Therefore, it is expected that when the thermal deformation is occurred to the various types of the lens, the variation of the focal length caused by the thermal distortion of a lens would be measured quantitatively.

Diffusion rate of C. I. Disperse Yellow 54 Dye in PTT and PET Textiles in the Presence of Supercritical Carbon Dioxide (초임계이산화탄소에 의한 PTT와 PET섬유 내에서의 C. I. Disperse Yellow 54염료의 확산속도)

  • Ihm, Bang-Hyun;Choi, Jun-Hyuck;Shim, Jae-Jin
    • Clean Technology
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    • v.13 no.4
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    • pp.244-250
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    • 2007
  • Sorption of C. I. Disperse Yellow 54 dye in poly(trimethylene terephthalate) (PTT) and poly (ethylene terephthalate) (PET) textile fibers were measured at various pressures, temperatures, and times in the presence of supercritical carbon dioxide and thereby the diffusivities of the dye in the fibers were calculated. The diffusivity of dye in the polymeric fibers was very low, only in the order of $10^{-12}\;cm^2/sec$, but increased with increasing temperature at constant pressure and with increasing pressure at constant temperature. The diffusivity in PTT fibers were about 1.5 to 3 times as large as that in PET fibers. As the fiber was very thin, the dye distribution in the fiber was almost uniform everywhere inside the fiber.

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Study on the Epoxy/BaTiO$_3$Embedded Capacitor Films for PWB Applications (인쇄회로기판 용 Epoxy/BaTiO$_3$내장형 커패시터 필름에 관한 연구)

  • 조성동;이주연;백경욱
    • Journal of the Microelectronics and Packaging Society
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    • v.8 no.4
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    • pp.59-65
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    • 2001
  • Epoxy/$BaTiO_3$composite capacitor films with excellent stability at room temperature, uniform thickness, and electrical properties over a large area ware successfully fabricated. The composite capacitor films with good film formation capability and easy process ability were made from epoxy resin developed for ACF as a matrix and two kinds of $BaTiO_3$powders as fillers to increase the dielectric constant of the composite film. The crystal structure of the powders and its effects on dielectric constant of the films were investigated by X-ray diffraction (XRD). And the optimum amount of dispersant, phosphate ester, was determined by viscosity measurement of suspension. DSC and dielectric property tests were conducted to decide the right curing temperature and the optimum amount of the curing agent. As a result, the capacitors of 7 $\mu \textrm{m}$ thick film with 10 nF/$\textrm{cm}^2$ and low leakage current were successfully demonstrated.

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Bloating mechanism of artificial lightweight aggregate with reject ash (잔사회를 이용한 인공경량골재의 발포기구)

  • Lee, Ki-Gang
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.22 no.3
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    • pp.158-163
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    • 2012
  • The purpose of this study is to improve recycling rate of the coal reject ash by investigating bloating mechanism for artificial lightweight aggregate of reject ash. In this study, we use reject ash (R/A) and dredged soil (D/S) as raw materials. The artificial lightweight aggregates were formed by plastic forming (${\phi}$ = 10 mm) and sintered by temperature raising method at different temperatures (between 1200 and $1275^{\circ}C$). The physical properties of the aggregates such as bulk specific gravity, adsorption and microstructure of surface and cross-section are investigated with the sintering temperature and rate of R/A-D/S contents. As the result of the bulk specific gravity graphs, we can found out the inflection point at content of R/A 80 wt.%. From the microstructure images, we considered the artificial lightweight aggregates content of R/A over 80 wt.% are distributed numerous uniform micro-pores by vitrification without Black Core and the artificial lightweight aggregates of R/A below 80wt.% are distributed macro-pores with Black Core.

Kinetics of In-situ Degradation of Nerve Agent Simulants and Sarin on Carbon with and without Impregnants

  • Saxena, Amit;Sharma, Abha;Singh, Beer;Suryanarayana, Malladi Venkata Satya;Mahato, Timir Haran;Sharma, Mamta;Semwal, Rajendra Prasad;Gupta, Arvind Kumar;Sekhar, Krishnamurthy
    • Carbon letters
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    • v.6 no.3
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    • pp.158-165
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    • 2005
  • Room temperature kinetics of degradation of nerve agent simulants and sarin, an actual nerve agent at the surface of different carbon based adsorbent materials such as active carbon grade 80 CTC, modified whetlerite containing 2.0 and 4.0 % NaOH, active carbon with 4.0 % NaOH, active carbon with 10.0 % Cu (II) ethylenediamine and active carbon with 10.0 % Cu (II) 1,1,1,5,5,5-hexafluoroacetylacetonate were studied. The used adsorbent materials were characterized for surface area and micropore volume by $N_2$ BET. For degradation studies solution of simulants of nerve agent such as dimethyl methylphosphonate (DMMP), diethyl chlorophosphate (DEClP), diethyl cyanophosphate (DECnP) and nerve agent, i.e., sarin in chloroform were prepared and used for the uniform adsorption on the adsorbent systems using their incipient volume at room temperature. Degradation kinetics was monitored by GC/FID and was found to be following pseudo first order reaction. Kinetics parameters such as rate constant and half life were calculated. Half life of degradation with modified whetlerite (MWh/NaOH) system having 4.0 % NaOH was found to be 1.5, 7.9, 1206 and 20 minutes for DECnP, DEClP, DMMP and sarin respectively. MWh/NaOH system showed maximum degradation of simulants of nerve agents and sarin to their hydrolysis products. The reaction products were characterized using NMR technique. MWh/NaOH adsorbent was also found to be active against sulphur mustard.

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