• Bulletin of the Korean Chemical Society
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• v.33 no.10
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• pp.3269-3273
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• 2012

In this study, we report a new method for the high contrast imaging of biomolecular interactions at roller printed protein surfaces using thermotropic liquid crystals (LCs). Avidin was roller printed and covalently immobilized onto the obliquely deposited gold surface that was decorated with carboxylic acid-terminated self-assembled monolayers (SAMs). The optical response of LCs on the roller printed film of avidin contrasted sharply with that on the obliquely deposited gold surface. The binding of biotin-peroxidase to the roller printed avidin was then investigated on the obliquely deposited gold substrate. LCs exhibited a non-uniform and random orientation on the roller printed area decorated with the complex of avidin and biotin-peroxidase, while LCs displayed a uniform and planar orientation on the area without roller printed proteins. The orientational transition of LCs from uniform to non-uniform state was triggered by the erasion of nanometer-scale topographies on the roller printed surface after the binding of biotin-peroxidase to the surface-immobilized avidin. The specific binding events of protein-receptor interactions were also confirmed by atomic force microscopy and ellipsometry. These results demonstrate that the roller printing of proteins on obliquely deposited gold substrates could provide a high contrast signal for imaging biomolecular interactions using LC-based sensors.

• Korean Journal of Materials Research
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• v.28 no.7
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• pp.411-416
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• 2018

Tungsten oxide($WO_3$) films with uniform surface morphology are fabricated using a spin-coating method for applications of electrochromic(EC) devices. To improve the EC performances of the $WO_3$ films, we control the heating rate of the annealing process to 10, 5, and $1^{\circ}C/min$. Compared to the other samples, the $WO_3$ films fabricated at a heating rate of $5^{\circ}C/min$ shows superior EC performances for transmittance modulation(49.5 %), response speeds(8.3 s in a colored state and 11.2 s in a bleached state), and coloration efficiency($37.3cm^2/C$). This performance improvement is mainly related to formation of a uniform surface morphology with increased particle size without any cracks by an optimized annealing heating rate, which improves the electrical conductivity and electrochemical activity of the $WO_3$ films. Thus, the $WO_3$ films with a uniform surface morphology prepared by the optimized annealing heating rate can be used as a potential candidate for performance improvement of the EC devices.

• Journal of Biosystems Engineering
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• v.15 no.1
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• pp.14-22
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• 1990

For efficient use of solar energy in plastic greenhouse, thermal storage system was developed. The system was constructed with the counter-flow type air-water heat exchanger using a thin polyethylene film as a medium of heat exchange parts. Experiments were carried out to investigate the heat exchange rate, optimum water flow rate, overall heat transfer coefficient, and the effectiveness of the counter-flow type air-water heat exchanger with polyethylene film bags. Mathematical model to predict air temperature leaving heat exchanger was developed. The results obtained in the present study are summarized as follows. 1. Heat exchange rate in the counter-flow type air-water heat exchanger with polyethylene film bags was compared to that of polyethylene film. Heat exchange rate was almost identical at air velocity of 0.5m/s on polyethylene film surface. But, heat exchange rate of heat exchanger with polyethylene film bag was $32{\sim}55KJ/m^2$ hr higher than that of polyethylene film at air velocity of 1.0m/s. 2. Considering the formation of uniform water film and the sufficient heat exchange rate of polyethylene film bags, optimum water flow rate in polyethylene film bags was $3.0{\sim}6.0{\ell}/m^2$ min. 3. The overall heat transfer coefficient of polyethylene film bags was found to be $35.0{\sim}130.0KJ/m^2\;hr\;^{\circ}C$ corresponding to the air velocity ranging 0.5 to 4.0 m/s on polyethylene film surface. And the overall heat transfer coefficient showed almost linearly increasing tendency to the variation of air velocity. 4. Mathematical model to predict air temperature leaving the heat exchanger was developed, resulting in a good agreement between the experimental and predicted values. But, the experimental results were a little lower than predicted. 5. Effectiveness of heat exchanger for the experiment was found to be 0.40~0.81 corresponding to the number of transfer units due to the variation of air velocity ranging 0.6 to 1.7 m/s.

• Progress in Superconductivity
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• v.3 no.2
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• pp.252-256
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• 2002

We studied YBCO films for current limiting of the resistive type which utilizes a transition from superconducting to normal state caused by exceeding critical current. The films were deposited on sapphire substrates and covered by gold top layer. The current limiting element consists of 2 mm wide YBCO stripes connected in series. A serious problem in using YBCO films for current limiting is inhomogeneities caused by imperfect manufacturing. Therefore simultaneous quench is a difficult problem when elements for current limiting are connected in series. So some researchers have recently proposed using magnetic field and heating for simultaneous quench. We have measured extended exec trim field-current density(E-J) characteristics for current limiting elements of YBCO films in applied magnetic field of 0 - 130 mT. And we have investigated quench characteristics in current limiting elements and between elements of YBCO films in applied magnetic field. The result of the experiments show that the presence of applied magnetic fields induces uniform quench distribution fur the stripes in element at $50V_{rms}$, otherwise non-uniform quenches were observed. And simultaneous quenches between elements were investigated at $150V_{rms}$. We suggest that suppressing the critical current by increased fields due to fault current effectively forced the stripes of higher $J_{c}$(0) to quench, resulting in equalizing quench times.s.s.s.

• Korean Journal of Materials Research
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• v.27 no.6
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• pp.307-311
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• 2017

Organometal halide perovskite materials, due to the tunability of their electronic and optical properties by control of composition and structure, have taken a position of significant importance in optoelectronic applications such as photovoltaic and lighting devices. Despite numerous studies on the structure - property relationship, however, practical application of these materials in electronic and optical devices is still limited by their processability during fabrication. Achieving nano-sized perovskite particles embedded in a polymer matrix with high loading density and outstanding photoluminescence performance is challenging. Here, we demonstrate that the careful control of nanoparticle formation and growth in the presence of poly(methyl methacrylate) results in perovskite nanoparticle - polymer nanocomposites with very good dispersion and photoluminescence. Furthermore, this approach is found to prevent further growth of perovskite nanoparticles, and thus results in a more uniform film, which enables fabrication using the perovskite nanoparticles.

• Journal of the Korean Magnetics Society
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• v.22 no.1
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• pp.6-10
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• 2012

We have observed the change in the film resistance of thin nickel film up to 13 nm, which is deposited on a porous anodic alumina substrate, prepared by two-step anodization technique under phosphoric acid. The resulting film grows as a porous film, following the pore structure on the surface of the alumina substrate, and the value of the resistance lies above $150k{\Omega}$ within the range of thickness studied here, decreasing very slowly with the film thickness. The observed resistance value is much higher than the reported value of a uniform film at the same thickness. Since the observed value of the surface coverage with the pores is smaller than the critical value, expected from the percolation theory, the pore structure limits the formation of conduction channel across the film. In addition, by comparing to the typical model of thickness-dependent resistivity, we expect that the scattering at the pore edge further increases the film resistance.

• Tribology and Lubricants
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• v.28 no.4
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• pp.153-159
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• 2012

Tapered roller bearings are widely used in high axial-load and radial-load applications. In this study, a numerical analysis is performed to study a finite line contacts EHL problem between a tapered roller and raceway in tapered roller bearings. Converged solutions are obtained for moderate load and material parameters using a finite difference method with non-uniform grids and the Newton-Raphson method. The contours and sectional plots of pressure distribution and film shape are compared. The pressure distribution and film shapes near both ends of the roller are very different from those in the central part and are transversely asymmetric. The maximum pressure and absolute minimum film thickness always occur at the small end of the roller.

• Proceedings of the Korean Vacuum Society Conference
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• 2016.02a
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• pp.312.1-312.1
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• 2016

We have deposited ZnO thin films by ultraviolet (UV) enhanced atomic layer deposition using diethylznic (DEZ) and water (H2O) as precursors with UV light. The atomic layer deposition relies on alternating dose of the precursor on the surface and subsequent chemisorption of the precursors with self-limiting growth mechanism. Though ALD is useful to deposition conformal and precise thin film, the surface reactions of the atomic layer deposition are not completed at low temperature in many cases. In this experiment, we focused on the effects of UV radiation during the ALD process on the properties of the inorganic thin films. The surface reactions were found to be complementary enough to yield uniform inorganic thin films and fully react between DEZ and H2O at the low temperature by using UV irradiation. The UV light was effective to obtain conductive ZnO film. And the stability of TFT with UV-enhanced ZnO was improved than ZnO by thermal ALD method. High conductive UV-enhanced ZnO film have the potential to applicability of the transparent electrode.

• Tribology and Lubricants
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• v.26 no.5
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• pp.263-271
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• 2010

The rollers of cylindrical roller bearing are axially profiled to relieve high edge stress concentration caused by mainly their finite length and by misalignment. In this paper, a numerical analysis is carried to study the EHL of misaligned (tilted) rollers with axially profiled ends. Using a finite difference method with non-uniform grids and the Newton-Raphson method, the highly nonlinear EHL problems are systematically solved. Physically consistent solutions are obtained for moderate load, material parameters and very small misalignment. For different misalignment angles, contours and sectional plots of pressure and film shape near both edge regions are compared. The asymmetric pressure distributions and film shapes show that the EHL results of finite line contacts are highly dependent upon very small amounts of roller misalignment. Especially, the effect of misalignment on the EHL pressure distribution is much higher than the film shapes.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2006.11a
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• pp.311-312
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• 2006

We studied homeotropic alignment effect for a nematic liquid crystal (NLC) on the $SiO_x$, thin film irradiated by the new ion beam method $SiO_x$ thin films were deposited by plasma enhanced chemical vapor deposition (PECVD) and were treated by the DuoPIGatron ion source. A uniform liquid crystal alignment effect was achieved over 2100 eV ion beam energy. Tilt angle were about $90^{\circ}$ and were not affected by various ion beam energy.